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成果及论文

19. Qian-Cheng Zhang, Qin Zhong,* and Jian Zhao* Catalyst-free Propargylboration of Ketones with Allenyl-Bpins: Highly Stereoselective Synthesis of tert-Homopropargyl Alcohols Bearing Vicinal Stereocenters. Chem. Eur. J. 2023, accepted.

18. Xin-Ru Ma, Qin Zhong,* Qian-Cheng Zhang, Hua-Xing Hu, Ma-Hong Yu and Jian Zhao* Pd-Catalysed Cross-Coupling of Allenylic Carbonates with gem-Diborylalkanes: Efficient Synthesis of Isoprenylboronates. Org. Biomol. Chem., 2023, 21, 3355-3359. DOI: 10.1039/D3OB00109A

17. Hua-Xing Hu, Xin-Ru Ma, Qin Zhong,* Qiang Chen  and Jian Zhao* Homoallenylboration of Carbonyl Compounds Using Stable 2-Pinacolateboryl 1,3-Butadienes via in-situ Generated Borinic-TFA Mixed Anhydrides: Efficient Synthesis of Homoallenyl Alcohols. Org. Chem. Front., 2023, 10, 514 - 523. DOI: 10.1039/d2qo01705a

16. Shi-Sen Li, Qin Zhong* and Jian Zhao* Copper Catalysed Protoboration of Allenyl-Bdans: Efficient Synthesis of β-Boryl Allyl-Bdans. Org. Biomol. Chem., 2022, 20, 8605. DOI: 10.1039/D2OB01694J


15. Wei-Dong Zhang, Jia-Yu Zou, Qin Zhong*, Shi-Sen Li and Jian Zhao* Synergistic Pd/Cu-catalysed regio- and stereoselective borylation of allenylic carbonates. Chem. Commun. 2022, 58, 1037-1040. DOI: 10.1039/d1cc05854a

Prior to NJUST


14. Zhao, J.; Jonker, S; Meyer, D; Göran, S.; Tran, C.-D.; Eriksson, L; Szabo, K.* Copper-Catalyzed Synthesis of Allenylboronic Acids. Access to Sterically Encumbered Homopropargylic Alcohols and Amines by Propargylboration. Chem. Sci. 2018, 9, 3305-3312.


13. Zhao, J.; Szabo, K.* Catalytic Borylative Opening of Propargyl Cyclopropane, Epoxide, Aziridine and Oxetane Substrates. Ligand Controlled Synthesis of Allenyl Boronates and Alkenyl Diboronates. Angew. Chem. Int. Ed. 2016, 55, 1502-1506. 


12. Zhao, J.; Xu, Z.; Oniwa, K.; Asao, N.; Yamamoto, Y.; Jin, T.* FeCl3-Mediated Oxidative Spirocyclization of Difluorenylidene Diarylethanes Leading to Dispirofluorene-indeno[2,1-a]indene-fluorenes. Angew. Chem. Int. Ed. 2016, 55, 259-263. 


11. Zhao, J.; Asao, N.; Yamamoto, Y.; Jin, T.* Pd-Catalyzed Synthesis of 9,9’-Bifluorenylidene Derivatives via Dual C–H Activation of Bis-biaryl Alkynes. J. Am. Chem. Soc. 2014, 136, 9540-9543. 


10. Zhao, J.; Oniwa, K.; Asao, N.; Yamamoto, Y.; Jin, T.* Pd-Catalyzed Cascade Crossover-Annulation of o-Alkynylarylhalides and Diarylacetylenes Leading to Dibenzo[a,e]pentalenes. J. Am. Chem. Soc. 2013, 135, 10222-10225. 


9. Zhao, J.; Asao, N.; Yamamoto, Y.; Jin, T.* Pd-catalyzed cascade cyclization of o-alkynylarylbromides with dialkylalkynes via consecutive carbopalladation. Tetrahedron Lett. 2015, 56, 3133-3136. 


8. Zhao, J.; Oniwa, K.; Islam, A.; Qin, C.; Asao, N.; Han, L.; Yamamoto, Y.; Jin, T.* Thieno[2, 3, a] carbazole donor-based organic dyes for high efficiency dye-sensitized solar cells. Org. Chem. Front. 2015, 2, 253-258. 


7. Jin, T.*; Zhao, J.; Asao, N.; Yamamoto, Y. Metal-Catalyzed Annulation Reactions for π-Conjugated Polycycles. Chem. Eur. J. 2014, 20, 3554-3576. 


6. Zhao, J.; Jin, T.*; Islam, A.*; Kwon, E.; Akhtaruzzaman, Md.; Asao, N.; Han, L.; Alamry, K.; Kosa, S.; Asiri, A.; Yamamoto, Y. Thieno[2,3-a]carbazole-based donor-π-acceptor organic dyes for efficient dye-sensitized solar cells. Tetrahedron. 2014, 70, 6211-6216. 


5. Zhao, T.; Zhao, J.; Szabo, K.* Stereoselective Synthesis of 1,4-Diols by a Tandem Allylboration-Allenylboration Sequence. Org. Lett. 2015, 17, 2290-2293. 


4. Jiang, H.; Oniwa, K.; Islam, A.; Zhao, J.; Han, L.; Sun, Y.; Bao, M.; Asao, N.; Yamamoto, Y.; Jin, T.* Efficient thieno[3, 2-a]carbazole-based organic dyes for dye-sensitized solar cells. Tetrahedron. 2015, 71, 6534-6540. 


3. Chen, Q.; Zhao, J.; Ishikawa, Y.; Asao, N.; Yamamoto, Y.; Jin, T.* Remarkable Catalytic Property of Nanoporous Gold on Activation of Diborons for Direct Diboration of Alkynes. Org. Lett. 2013, 15, 5766-5769. 


2. Ferrara, G.; Jin, T.; Oniwa, K.; Zhao, J.; Ashiri, A. M.; Yamamoto, Y. Synthesis of new donor-acceptor-donor materials via Au-catalyzed double cascade cyclization” Tetrahedron Lett. 2012, 53, 914-918.


1. Zhao, J.; Wu, J.-L.* (3aR*,6S*,7S*,7aR*)-2-(4-Methoxybenzyl)-7-(4-nitrophenyl)-6-phenyl-3a,6,7,7a-tetrahydroisoindolin-1-one. Acta. Cryst. 2010, 66 (6), o1387.