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成果及论文

代表性论著

2024:

53. Cui, H.; Chen, X.; An, B.; Lan, F.; Zhang, X.* Photocatalysis as a tool for upcycling of polymers. Trends Chem. 2024, 6, 392-405. (Special issue: Emerging leaders in chemistry, see: https://authors.elsevier.com/a/1jFHA9CpcYaP%7Ep)

https://authors.elsevier.com/a/1jGT09CpcYaP%7Ed


52. An, B.; Cui, H.; Zheng, C.*; Chen, J.-L.; Lan, F.; You, S.-L.*; Zhang, X.* Tunable C-H Functionalization and Dearomatization Enabled by an Organic Photocatalyst. Chem. Sci. 202415, 4114-4120.

https://pubs.rsc.org/en/content/articlelanding/2024/sc/d4sc00120f


2023:

51. Zhou, C.; An, B.; Lan, F.; Zhang, X.* Optoelectronic materials as emerging photocatalysts: opportunities in sustainable organic synthesis. Chem. Commun. 2023, 59, 13245-13257. (This feature article is part of the themed collection: 2023 Emerging Investigators)

https://pubs.rsc.org/en/Content/ArticleLanding/2023/CC/D3CC04612E


50. Gao, L.; Zhou, C.; Wang, R.; Lan, F.; An, B.; Huang, X.; Zhang, X.* Unveiling inverse vulcanized polymers as metal-free, visible-light-driven photocatalysts for cross-coupling reactions. Chin. Chem. Lett. 2024, 35, 108832.

https://www.sciencedirect.com/science/article/pii/S1001841723006617?via%3Dihub


49. Hu, Y.-Q.; Zhou, C.; Huang, X.; An, B.; Wang, R.; Lan, F.; Zhang, X.* Mechanochemical Construction of Benzimidazole-Bridged Conjugated Porous Polymer Toward Versatile Photocatalysis. ACS Sustainable Chem. Eng. 2023, 11, 10225-10232.

https://pubs.acs.org/doi/full/10.1021/acssuschemeng.3c02223 


48. Wang, R.#; Gao, L.#; Zhou, C.; Zhang, X.* Heterogeneous Transition-Metal-Free Haloperfluoroalkylation of Unactivated Terminal Alkenes over Phenylphenothiazine-Based Porous Organic Polymers. Chin. J. Org. Chem. 2023, 43, 1136-1145. (Special Issue“中国女科学家”专辑)

http://sioc-journal.cn/Jwk_yjhx/CN/10.6023/cjoc202211013

Highlighted by 有机化学https://mp.weixin.qq.com/s/wBIFnPhjynAhwJeCyuZZFg

Selected as中国女科学家专辑"封面文章"

https://mp.weixin.qq.com/s/HWkcfgli7K8bMtYYpoY_Vw


2022:

47. Gao, R.; An, B.; Zhou, C.*; Zhang, X.* Synthesis of a Triazaisotruxene-Based Porous Organic Polymer and Its Application in Iodine Capture. Molecules 2022, 27, 8722. (Special Issue "Porous Organic Materials: Design and Applications")

https://www.mdpi.com/1420-3049/27/24/8722


46. Zhu, M.; Zhang, X.*; Zheng, C.*; You, S.-L.Energy-Transfer-Enabled Dearomative Cycloaddition Reactions of Indoles/Pyrroles via Excited-State Aromatics. Acc. Chem. Res. 2022, 55, 2510-2525.

https://doi.org/10.1021/acs.accounts.2c00412   

 

45. Lan, F.#; Liu, C.-S.#; Zhou, C.*; Huang, X.; Wu, J.-Y.; Zhang, X.* Developing Highly Reducing Conjugated Porous Polymer: A Metal-Free and Recyclable Approach with Superior Performance for Pinacol C-C Coupling Under Visible Light. J. Mater. Chem. A 2022, 10, 16578-16584 (#equal contribution).

https://pubs.rsc.org/en/content/articlelanding/2022/ta/d2ta03341k

Highlighted by 科匠文化https://mp.weixin.qq.com/s/TEvwyTq7pSj67lLPas_buw


44. Huang, X.; Hu, Y.-Q.; Zhou, C.*; Zheng, Y.; Zhang, X.* Urushiol Derivatives as Biomass-Based Photocatalysts for Transition-Metal-Free Synthesis of 1,2-Amino Alcohols. Green Chem. 2022, 24, 5764-5769.

https://pubs.rsc.org/en/content/articlelanding/2022/gc/d2gc01410f

Highlighted by Industrial Crops and Productshttps://www.sciencedirect.com/science/article/pii/S092666902300362X?via%3Dihub


43. Zhou, C.#; Wang, R.#; Gao, L.; Huang, X.; Zhang, X.* Unveiling the Synthetic Potential of 1,3,5-Tri(10H-phenothiazin-10-yl)benzene-Based Optoelectronic Material: A Metal-Free and Recyclable Photocatalyst for Sequential Functionalization of C(sp2)–H Bonds. ACS Appl. Mater. Interfaces 202214, 30962-30968 (#equal contribution).

https://pubs.acs.org/doi/10.1021/acsami.2c08766

Highlighted by 化学与材料科学https://mp.weixin.qq.com/s/B6vCBycJR8PDglQ8yYWm6Q

邃瞳科学云https://mp.weixin.qq.com/s/aFe6cdmo19F8nUJDAIh_iQ

今日论文https://mp.weixin.qq.com/s/lVq0INpI-99FkZnbVNcGhQ

科学留声机https://mp.weixin.qq.com/s/WdFe1c7FL5weI0bkvbe1Xg


42. Wang, R.; Zhou, C.; Huang, X.; Wu, J.-Y.; Zhang, X.* Phenylphenothiazine-Based Porous Organic Polymers as Visible-Light Heterogeneous Photocatalysts for Switchable Bromoalkylation and Cyclopropanation of Unactivated Terminal Alkenes. ACS Sustainable Chem. Eng. 202210, 4650-4659.

https://pubs.acs.org/doi/full/10.1021/acssuschemeng.2c00054

Highlighted by 孔道 https://mp.weixin.qq.com/s/MWd80HeXF-Bi6Z_v8RlAcg


41. Lan, F.; Zhou, C.*; Huang, X.; An, B.; Zhang, X.* Metal-free, atom and redox-economical construction of C–C bonds enabled by oligofluorene-containing hypercrosslinked polymers. Green Chem. 2022, 24, 2391-2396.

https://pubs.rsc.org/en/content/articlelanding/2022/gc/d2gc00107a

Highlighted by Synfacts (Synfacts 2022; 18(06): 0658)https://www.thieme-connect.de/products/ejournals/abstract/10.1055/s-0041-1737465


40. Cheng, Y.-Z.; Feng, Z.; Zhang, X.*; You, S.-L.* Visible-light induced dearomatization reactions. Chem. Soc. Rev. 2022, 51, 2145-2170.

https://pubs.rsc.org/en/content/articlelanding/2022/cs/c9cs00311h


39. Zhou, C.#; Huang, X.#; Hu, Y.; Wu, J.; Zheng, Y.; Zhang, X.* Catalyst-free visible light-induced decarboxylative amination of glycine derivatives with azo compounds. New J. Chem. 2022, 46, 465-469 (#equal contribution).

https://pubs.rsc.org/en/content/articlelanding/2022/NJ/D1NJ05079F


2021:

38. Zhang, H.; Zhou, C.*; Zheng, Y.; Zhang, X.* Isotruxene-based porous polymers as efficient and recyclable photocatalysts for visible-light induced metal-free oxidative organic transformations. Green Chem. 2021, 23, 8878-8885. 

https://pubs.rsc.org/en/Content/ArticleLanding/2021/GC/D1GC03165A

Highlighted by Synfacts (Synfacts 2022; 18(02): 0182)https://www.thieme-connect.de/products/ejournals/abstract/10.1055/s-0041-1737750


37. Huang, X.#; Wang, R.#; Zhou, C.*; Gao, R.; Zhang, H.; Zheng, Y.*; Zhang, X.* Visible-light-induced, catalyst and additive-free cycloaddition of vinylcyclopropanes: access to sulfur-containing seven-membered heterocycles. Org. Chem. Front. 2021, 8, 5454-5459 (#equal contribution).

https://pubs.rsc.org/en/content/articlelanding/2021/QO/D1QO01007G


36. Zhu, M.; Xu, H.; Zhang, X.*; Zheng, C.*; You, S.-L.* Visible‐Light‐Induced Intramolecular Double Dearomative Cycloaddition of Arenes. Angew. Chem. Int. Ed. 2021, 60, 7036-7040 (selected as "Hot Paper").

https://onlinelibrary.wiley.com/doi/10.1002/anie.202016899


35. Zhuang, W.; Cheng, Y.-Z.; Huang, X.-L.; Huang, Q.*; Zhang, X.* Visible-light induced divergent dearomatization of indole derivatives: controlled access to cyclobutane-fused polycycles and 2-substituted indolines. Org. Chem. Front. 2021, 8, 319-325. 

https://pubs.rsc.org/en/content/articlelanding/2021/QO/D0QO01322F


2020:

34. Huang, X.-L.#; Cheng, Y.-Z.#; Zhang, X.*; You, S.-L.* Photoredox-Catalyzed Intermolecular Hydroalkylative Dearomatization of Electron-Deficient Indole Derivatives. Org. Lett. 2020, 22, 9699-9705 (#equal contribution).

https://pubs.acs.org/doi/10.1021/acs.orglett.0c03759


33. Zhu, M.; Zhang, X.*; Zheng, C.*; You, S.-L.* Visible-light-induced Dearomatization via [2+2] Cycloaddition or 1,5-Hydrogen Atom Transfer: Divergent Reaction Pathways of Transient Diradicals. ACS Catal. 2020, 10, 12618-12626.

https://pubs.acs.org/doi/10.1021/acscatal.0c03808


32. Cheng, Y.-Z.; Huang, X.-L.; Zhuang, W.-H.; Zhao, Q.-R.; Zhang, X.*; Mei, T.-S.*; You, S.-L.* Intermolecular Dearomatization of Naphthalene Derivatives by Photoredox‐Catalyzed 1,2‐Hydroalkylation. Angew. Chem. Int. Ed. 2020, 59, 18062-18067.

https://onlinelibrary.wiley.com/doi/10.1002/anie.202008358


31. Zhu, M.; Huang, X.-L.; Xu, H.; Zhang, X.*; Zheng, C.*; You, S.-L.* Visible-Light-Mediated Synthesis of Cyclobutene-Fused Indolizidines and Related Structural Analogs. CCS Chem. 2020, 3, 652-664.

https://www.chinesechemsoc.org/doi/10.31635/ccschem.020.202000254


30. Zhang, X.; You, S.-L.* Asymmetric Allylic Substitutions Catalyzed by Iridium Complexes Derived from C(sp2)–H Activation of Chiral Ligands. Aldrichimica Acta. 2020, 53, 11-18.

https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/108/925/acta-53-mk.pdf



29. Xu-Xu, Q.-F.; Zhang, X.; You, S.-L.* Enantioselective Synthesis of 4-Allyl Tetrahydroquinolines via Copper(I) Hydride-Catalyzed Hydroallylation of 1,2-Dihydroquinolines. Org. Lett. 2020, 22, 1530-1534.

https://pubs.acs.org/doi/10.1021/acs.orglett.0c00113


2019:

28. Cheng, Y.-Z.; Zhao, Q.-R.; Zhang, X.*; You, S.-L.* Asymmetric Dearomatization of Indole Derivatives with N-Hydroxycarbamates Enabled by Photoredox Catalysis. Angew. Chem. Int. Ed. 2019, 58, 18069-18074.

https://onlinelibrary.wiley.com/doi/10.1002/anie.201911144


27. Tang, S.-B.; Tu, H.-F.; Zhang, X.; You, S.-L.* Rhodium-Catalyzed Asymmetric Allylic Dearomatization of β-Naphthols: Enantioselective Control of Prochiral Nucleophiles. Org. Lett. 2019, 21, 6130-6134.

https://pubs.acs.org/doi/10.1021/acs.orglett.9b02285


26. Xu-Xu, Q.-F.; Zhang, X.*; You, S.-L.* Enantioselective Synthesis of 4‑Aminotetrahydroquinolines via 1,2-Reductive Dearomatization of Quinolines and Copper(I) HydrideCatalyzed Asymmetric Hydroamination. Org. Lett. 2019, 21, 5357-5362.

https://pubs.acs.org/doi/10.1021/acs.orglett.9b02034


25. Zhu, M.; Zheng, C.*; Zhang, X.*; You, S.-L.* Synthesis of Cyclobutane-Fused Angular Tetracyclic Spiroindolines via Visible-Light-Promoted Intramolecular Dearomatization of Indole Derivatives. J. Am. Chem. Soc. 2019, 141, 2636-2644. Highlighted by Synfacts, Victor Snieckus, Lívia C. R. M. da Frota, Synfacts, 2019, 0355.

https://pubs.acs.org/doi/10.1021/jacs.8b12965


2018:

24. Bao, C.-C.#; Zheng, D.-S.#; Zhang, X.*; You, S.-L.* Iridium/N-Heterocyclic Carbene Complex-Catalyzed Intermolecular Allylic Alkylation Reaction. Organometallics 2018, 37, 4763-4772 (#equal contribution).

https://pubs.acs.org/doi/10.1021/acs.organomet.8b00762


23. Xu-Xu, Q.-F.; Liu, Q.-Q.; Zhang, X.*; You, S.-L.* Copper-Catalyzed Ring Opening of Benzofurans and an Enantioselective Hydroamination Cascade. Angew. Chem. Int. Ed. 2018, 57, 15204-15208.

https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201809003


22. Zhu, M.; Zhou, K.; Zhang, X. *; You, S.-L.* Visible-Light-Promoted Cascade Alkene Trifluoromethylation and

Dearomatization of Indole Derivatives via Intermolecular Charge Transfer. Org. Lett. 2018, 20, 4379-4383.

https://pubs.acs.org/doi/10.1021/acs.orglett.8b01899


21. Cheng, Y.-Z.; Zhou, K.; Zhu, M.; Li, L.-A.-C.; Zhang, X.*; You, S.-L.* Visible-Light Promoted Intermolecular Oxidative Dearomatization of β-Naphthols with N-Hydroxycarbamates. Chem. Eur. J. 2018, 24, 12519-12523.

https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/chem.201803149


20. Cheng, Y.-Z.; Zhang, X.*; You, S.-L.* Visible light mediated photocatalysis as a new tool for catalytic asymmetric dearomatization (CADA) reactions. Sci. Bull. 2018, 63, 809-811.

https://www.sciencedirect.com/science/article/abs/pii/S2095927318302780?via%3Dihub


19. Zhang, X.; You, S.-L.* THQphos in Ir-Catalyzed Asymmetric Allylic Substitution Reactions. Chimia 2018, 72, 589-594. (Invited paper for Homogeneous Catalysis – New Transformations and Mechanistic Insights Special Issue)


18. Tu, H.-F.#; Zhang, X.#; Zheng, C.; Zhu, M.; You, S.-L.* Enantioselective dearomative prenylation of indole derivatives. Nat. Catal. 2018, 1, 601-608 (#equal contribution). Highlighted by Chem, Yin Zheng, Weiwei Zi, Chem, 2018, 4, 2730-2747.


17. Tang, S.-B.; Zhang, X.; Tu, H.-F.; You, S.-L.* Regio- and Enantioselective Rhodium-Catalyzed Allylic Alkylation of Racemic Allylic Alcohols with 1,3-Diketones. J. Am. Chem. Soc. 2018, 140, 7737-7742.


16. Ma, J.#; Zhang, X. #; Huang, X.; Luo, S.; Meggers, E.* Preparation of Chiral-at-Metal Catalysts and their Use in Asymmetric Photoredox Chemistry. Nat. Protoc. 2018, 13, 605-632 (#equal contribution).


15. Zhang, X. ; Qin, J.; Huang, X.; Meggers, E.* One-Pot Sequential Photoredox Chemistry and Asymmetric Transfer Hydrogenation with a Single Catalyst. Eur. J. Org. Chem. 2018, 2018, 571-577.


14. Zhang, X. ; Qin, J.; Huang, X.; Meggers, E.* Sequential Asymmetric Hydrogenation and Photoredox Chemistry with a Single Catalyst. Org. Chem. Front. 2018, 5, 166-170.


13. Shao, W.; Wang, Y.; Yang, Z.-P.; Zhang, X.; You, S.-L.* Efficient Synthesis of N-Alkylated 4-Pyridones by Copper-Catalyzed Intermolecular Asymmetric Propargylic Amination. Chem. Asian. J. 2018, 13, 1103-1107.


Before 2018:

12. Luo, S.; Zhang, X.; Zheng, Y.; Harms, K.; Zhang, L.; Meggers, E.* Enantioselective Alkynylation of Aromatic Aldehydes Catalyzed by a Sterically Highly Demanding Chiral-at-Rhodium Lewis Acid. J. Org. Chem. 2017, 82, 8995-9005.


11. Zhang, X.; You, S.-L.* Removing the Mask in Catalytic Asymmetric Diamination of Alkenes. Chem 2017, 2, 917-919.


10. Zhang, X.; Liu, W.-B.; Cheng, Q.; You, S.-L.* Iridium-Catalyzed Asymmetric Allylic Amination Reaction with N-Aryl Phosphoramidite Ligands. Organometallics 2016, 35, 2467-2472.


9. Zhuo, C.-X.; Zhang, X.; You, S.-L.* Enantioselective Synthesis of Pyrrole-Fused Piperazine and Piperazinone Derivatives via Ir-Catalyzed Asymmetric Allylic Amination. ACS Catal. 2016, 6, 5307-5310. Highlighted by Synfacts, Hisashi Yamamoto, Ramesh C. Samanta, Synfacts, 2016, 1043.


8. Zhang, X.; Liu, W.-B.; Tu, H.-F.; You, S.-L.* Ligand-Enabled Ir-Catalyzed Intermolecular Diastereoselective and Enantioselective Allylic Alkylation of 3-Substituted Indoles. Chem. Sci. 2015, 6, 4525-4529.


7. Zhang, X.; Yang, Z.-P.; Huang, L.; You, S.-L.* Highly Regio- and Enantioselective Synthesis of N-Substituted 2-Pyridones: Iridium-Catalyzed Intermolecular Asymmetric Allylic Amination. Angew. Chem. Int. Ed. 2015, 54, 1873-1876.


6. Ye, K.-Y.; Zhang, X.; Dai, L.-X.; You, S.-L.* Ruthenium-Catalyzed Regioselective Allylic Trifluoromethylthiolation Reaction. J. Org. Chem. 2014, 79, 12106-12110 (Invited for a thematic issue).


5. Zhang, X.; Han, L.; You, S.-L.* Ir-Catalyzed Intermolecular Asymmetric Allylic Dearomatization Reaction of Indoles. Chem. Sci. 2014, 5, 1059-1063. Highlighted by Synfacts, Hisashi Yamamoto, Sukalyan Bhadra, Synfacts, 2014, 0596.


4. Zhang, X.; Wu, Q.-F.; Liu, W.-B.; You, S.-L.* Ruthenium-Catalyzed Intramolecular Allylic Dearomatization Reaction of Indole Derivatives. Org. Lett. 2013, 15, 3746-3749. Highlighted by Synfacts, Mark Lautens, Marcel Sickert, Synfacts, 2013, 1307.


3. Zhang, X.; Yang, Z.-P.; Liu, C.; You, S.-L.* Ru-Catalyzed Intermolecular Dearomatization Reaction of Indoles with Allylic Alcohols. Chem. Sci. 2013, 4, 3239-3243. Highlighted by Synfacts, Mark Lautens, Lei Zhang, Synfacts, 2013, 0960.


2. Cai, Q.; Liang, X.-W.; Wang, S.-G.; Zhang, J.-W.; Zhang, X.; You, S.-L.* Ring-Closing Metathesis/Isomerization/Pictet-Spengler Cascade via Ruthenium/ Chiral Phosphoric Acid Sequential Catalysis. Org. Lett. 2012, 14, 5022-5025.


1. Liu, W.-B.; Zhang, X.; Dai, L.-X.; You, S.-L.* Asymmetric N-Allylation of Indoles via Ir-Catalyzed Allylic Alkylation of Indolines and Oxidation Strategy. Angew. Chem. Int. Ed. 2012, 51, 5183-5187.


Book Chapter:

Zhang, X., You, S.-L.; Science of Synthesis: Metal-Catalyzed Cyclization Reactions 1. (Volume Editors: Ma, S.; Gao, S.) Chapter 3. Metal-Catalyzed Intramolecular Allylic Substitution Reactions. 2016, 95-150.