37. Zhao, Y.; Jian. Z. ; Guang, Pu.; Wang, C.; Qiu, H.; Zhang, M. An asymmetric propargylation of cyclopropanols. https://doi.org/10.1016/j.trechm.2024.07.001

36. Zhao, Y.; Yan, H.; Zhang, Y.; Zhou, T.; Tian, M.; Zhang, C.; Yuan, H.; Qiu, H.; He, L.; Zhang, M. Catalytic asymmetric intramolecular propargylation of cyclopropanols to access the cuparane core. Chem. Sci., 2024. 10.1039/D4SC02504K.

35. Wu, Y.*; Zhang, H.; Wang, Q.; Jiang, D.; Mo, J..; Qiu, H.; He, L.*; Zhang, M.* Ring-opening Coupling of Cyclopropanol with 1,2,3-Triazole for the Synthesis of Fused Triazoles. Org. Lett. 2024, 26, 4043-4048.

34. Zhou, W.; Xi, S.; Chen, H.; Jiang, D.; Yang, J.; Liu, S.; He, L.; Qiu, H.; Lan, Y.*; Zhang, M.* A bridged backbone strategy enables collective synthesis of strychnan alkaloids. Nat. Chem. 2023, 15, 1074-1082.

33. Qiu, H.; Fei, X.; Yang, J.; Qiao, Z.; Yuan, S.; Zhang, H.; He, L.; Zhang, M.* A Bischler-Napieralski and homo-Mannich sequence enables diversified syntheses of sarpagine alkaloids and analogues. Nat. Commun. 2023, 14, 5560.

32. Jiang, D.; Tang, P.; Xiong, H.; Lei, S.; Zhang, Y.; Zhang, C.; He, L.; Qiu, H.; Zhang, M.* A Homo-Mannich Reaction Strategy Enables Collective Access to Ibophyllidine, Aspidosperma, Kopsia, and Melodinus Alkaloids. Angew. Chem. Int. Ed. 2023, 62, e202307286.

31. Qiu, H.; Du, Z.; Zhao, Y.; Yuan, S.; Xi, S.; Zhou, T.; Yang, J.; Zhang, C.; Xiong, Y.; Xia, Y.; Zhang, S.; Fu, L.; He, L.; Zhang, M.* Enantioselective Synthesis and Biological Evaluation of Pyrrolidines Bearing Quaternary Stereogenic Centers. J. Med. Chem. 2023, 66, 9866−9880.

30. Liu, S.; Su, X.; Jiang, D.; Xiong, H.; Miao, D.; Fu, L.; Qiu, H.*; He, L.*; Zhang, M.* Org. Lett. 2023, 25, 2058−2062.

29. Xi, S.; Jiang, Y.; Yang, J.; Yang, J.; Miao, D.; Chen, B.; Huang, W.; He, L.*; Qiu, H.*; Zhang, M.* Generation and [2,3]-Sigmatropic Rearrangement of Ammonium Ylides from Cyclopropyl Ketones for Chiral Indolizidines with Bridgehead Quaternary Stereocenters. Org. Lett. 2022, 24, 6957−6961.

28. Jiang, Y.; Xi, S.; Wang, Q.; Fu, L.; He, L.*; Wang, Z.; Zhang, M.* Facile synthesis of δ-ketoesters via formal two-carbon insertion into β-ketoesters. Tetrahedron Lett. 2022, 92, 153656.

27. Yang, Z.; Tan, Q.; Jiang, Y.; Yang, J.; Su, X.; Qiao, Z.; Zhou, W.; He, L.; Qiu, H.; Zhang, M. Asymmetric Total Synthesis of Sarpagine and Koumine Alkaloids. Angew. Chem. Int. Ed. 2021, 60, 13105–13111.

26. Zhang, Q.; Yang, Z.; Wang, Q.; Liu, S.; Zhou, T.; Zhao, Y.; Zhang, M.* Asymmetric Total Synthesis of Hetidine-Type C₂₀-Diterpenoid Alkaloids: (+)-Talassimidine and (+)-Talassamine. J. Am. Chem. Soc. 2021, 143, 7088−7095.

25. Zhou, W.; Zhou, T.; Tian, M.; Jiang, Y.; Yang, J.; Lei, S.; Wang, Q.; Zhang, C.; Qiu, H.; He, L.; Wang, Z.; Deng, J.; Zhang, M.* Asymmetric Total Syntheses of Schizozygane Alkaloids. J. Am. Chem. Soc. 2021, 143, 19975−19982.

24. Xi, S.; Dong, J.; Chen, H.; Dong, Q.; Yang, J.; Tan, Q.; Zhang, C.; Lan, Y.; Zhang, M. Lewis acid–catalyzed domino generation/[2,3]-sigmatropic rearrangement of ammonium ylides to access chiral azabicycles. Sci. Adv. 2021, 7, eabd5290.

23. Tan, Q.; Wang, X.; Fu, L.; He, L.; Zhang, M. Stereoselective allylation of isatinimines with γ-substituted allylboronic acids. Tetrahedron Lett. 2021, 70, 153005.

22. Jiang, D.; Tang, P.; Tan, Q.; Yang, Z.; He, L.*; Zhang, M.* Enantioselective Alkynylation of Isatins: A Combination of Metal Catalysis and Organocatalysis. Chem. Eur. J. 2020, 26, 15830–15834.

21. Tan, Q.; Yang, Z.; Jiang, D.; Cheng, Y.; Yang, J.; Xi, S.; Zhang, M. Copper-Catalyzed Aerobic Oxidative Cyclization Cascade to Construct Bridged Skeletons: Total Synthesis of (-)-Suaveoline. Angew. Chem. Int. Ed. 2019, 58, 6420 –6424.

20. Xiong, Y.; Du, Z.; Chen, H.; Yang, Z.; Tan, Q.; Chang, C.; Zhu, L.; Lan, Y.*; Zhang, M.* Well-Designed Phosphine−Urea Ligand for Highly Diastereo- and Enantioselective 1,3-Dipolar Cycloaddition of Methacrylonitrile: A Combined Experimental and Theoretical Study. J. Am. Chem. Soc. 2019, 141, 961−971.

19. Li, L.; Yang, Z.; Yang, Z.; Zhang, Q.; Tan, Q.; Zhang, C.; Zhang, M.* Neighboring Hydroxyl Group-Assisted Allylboration and Lewis Acid-Mediated Carbonyl-Ene Reaction for Access to a Hapalindole Cyclohexane Core with Multiple Contiguous Stereogenic Centers. J. Org. Chem. 2019, 84, 1605−1613.

18. Zhang, C.; Yang. J.; Zhou, W.; Tan, Q.; Yang, Z.; He, L.; Zhang, M. Enantioselective Mannich Reaction of Glycine Iminoesters with N‑Phosphinoyl Imines: A Bifunctional Approach. Org. Lett. 2019, 21, 8620−8624.

17. Zhang, Q.; Xu, D.; Yang, J.; He, L.; Zhang, M. Construction of the A/B/C core of mexicanolides via a tandem double-aldol reaction. Tetrahedron Lett. 2019, 60, 150992.

16. Li, Y.; Dong, Q.; Xie, Q.; Tang, P.*, Zhang, M.; Qin, Y.* Enantioselective Synthesis of ABCF Tetracyclic Framework of Daphniphyllum Alkaloid Calyciphylline N. Org. Lett. 2018, 20, 5053−5057.

15. Zhang, Q.; Zhang, Z.; Huang, Z.; Zhang, C.; Xi, S.; Zhang, M.* Stereoselective Total Synthesis of Hetisine-type C₂₀-Diterpenoid Alkaloids: Spirasine IV and XI. Angew. Chem. Int. Ed. 2018, 57, 937–941.

14. Tan, Q.; Wang, X.; Xiong, Y.; Zhao, Z.; Li, L.; Tang, P.; Zhang, M.* Chiral Amino Alcohol Accelerated and Stereocontrolled Allylboration of Iminoisatins: Highly Efficient Construction of Adjacent Quaternary Stereogenic Centers. Angew. Chem. Int. Ed. 2017, 56, 4829–4833.

13. Dai, X.; Liu, W.; Zhou, Q.; Cheng, C.; Yang, C.; Wang, S.; Zhang, M.; Tang, P.* Song, H.; Zhang, D. Qin, Y.* Formal Synthesis of Anticoagulant Drug Fondaparinux Sodium. J. Org. Chem. 2016, 81, 162–184.

12. Liu, N.; Song, W.; Schienebeck, C. M.; Zhang, M.*; Tang, W.* Synthesis of naturally occurring tropones and tropolones. Tetrahedron 2014, 70, 9281–9305.

11. Zhang, M.; Liu, N.; Tang, W.* Stereoselective Total Synthesis of Hainanolidol and Harringtonolide via Oxidopyrylium-Based [5+2] Cycloaddition. J. Am. Chem. Soc. 2013, 135, 12434.

10. Liu, R.; Zhang, M.; Winston-McPherson, G. and Tang, W.* Ring Expansion of Alkynyl Cyclopropanes to Highly Substituted Cyclobutenes via a N-Sulfonyl-1,2,3- Triazole Intermediate. Chem. Commun. 2013, 49, 4376.

9. Zhang, M.; Tang, W.* Synthesis of Functionalized Cyclohexenone Core of Welwitindolinones via Rhodium-Catalyzed [5 + 1] Cycloaddition. Org. Lett. 2012, 14, 3756.

8. Shu, D.; Li, X.; Zhang, M.; Robichaux, P. J.; Guzei, I. A. and Tang, W.* Rhodium-Catalyzed Carbonylation of Cyclopropyl Substituted Propargyl Esters: A Tandem 1,3-Acyloxy Migration [5 + 1] Cycloaddition. J. Org. Chem., 2012, 77, 6463-6572.

7. Liu, R.; Zhang, M.; Wyche, T. P.; Winston-McPherson, G. N.; Bugni, T. S. and Tang, W.* Stereoselective Preparation of Cyclobutanes with Four Different Substituents: Total Synthesis and Structural Revision of Pipercyclobutanamide A and Piperchabamide G. Angew. Chem. Int. Ed., 2012, 51, 7503-7506.

6. Zhang, D.; Zhang, M.; Ding, B.; Wang, X. –L.; Qiu, Z. –Y.and Qin, Y.* Synthesis of a novel phosphate analog of 20-hydroxyecdysone with potent hypoglycemic activity, J. Asian. Nat. Prod. Res. 2011, 13(4), 297-303.

5. Li, X.; Zhang, M.; Shu, D.; Robichaux, P. J.; Huang, S. and Tang, W.* Rhodium-catalyzed Ring Expansion of Cyclopropanes to Seven-membered Rings via 1,5-C-C Bond Migration. Angew. Chem. Int. Ed., 2011, 50 , 10421-10424.

4. Shu, D.; Li, X.; Zhang, M.; Robichaux, P. J. and Tang, W.* Synthesis of Highly Functionalized Cyclohexenone Rings: Rhodium-Catalyzed 1,3-Acyloxy Migration and Subsequent [5+1] Cycloaddition. Angew. Chem. Int. Ed. 2011, 50, 1346-1349.

3. Zhang, M.; Huang, X.; Shen, L. and Qin, Y.* Total Synthesis of the Akuammiline Alkaloid (±)-Vincorine. J. Am. Chem. Soc. 2009, 131, 6013. 

2. Shen, L.; Zhang, M.(co-first author); Wu, Y. and Qin, Y.* Efficient Assembly of an Indole Alkaloid Skeleton by Cyclopropanation: Concise Total Synthesis of (±)-Minfiensine. Angew. Chem. Int. Ed. 2008, 47, 3618.

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