授权专利
【1】一种磺酸基功能纳米碳插层粘土催化材料及其制备方法 ZL201810182541.9
一种磺酸基功能纳米碳插层粘土催化材料及其制备方法，涉及一种非均相纳米碳/粘土复合催化材料的制备方法。本发明的目的是提供一 种非均相纳米复合酸催化材料的制备方法，具体制备过程是将插层前驱体有机物和蒙脱石颗粒 分散介质中，分散均匀,调节pH值进行插层,再经 水热处理后得到磺酸基功能纳米碳插层粘土催化材料-该制备方法过程简单，反应条件简单易行,制备材料具有比表面积高、孔容量大、酸催化 活性位多、可循环利用的特点。
研究论文
[1]Xiazhang Li, Haiyang Shi , Xiangyu Yan , Shixiang Zuo , Yuying Zhang , Qun Chen , Chao Yao, Chaoying Ni. Rational construction of direct Z-scheme doped perovskite/palygorskite nanocatalyst for photoSCR removal of NO: Insight into the effect of Ce incorporation. Journal of Catalysis 369 (2019) 190–200.
[2] Lizhen Qin, Huihui Mao, Chong Lei, Qianqian Wang, Zhaoping Gao. The SO3H-functionalized carbonaceous@montmorillonite efficient heterogeneous catalyst for synthesis of trimethylolpropane from long-chain fatty acid. Microporous and Mesoporous Materials, 289, 2019, 109623
[3] Huihui Mao, Fei Cheng, Chong Lei, Zhengyu Feng, Qianqian Wang, Baolin Chu, Yong Kong, Yongxin Tao, Chao Yao, Shixiang Zuo. Hydrothermal fabrication of Fe3O4@Carbonaceous Mmicrospheres for efficient removal of oil and metal ions from the aqueous phase. Industrial & Engineering Chemistry Research 2019, 58, 40, 18613-18622
[4] Shixiang Zuo, Zhan Liu, Wenjie Liu, Xiazhang Li, Zhongyu Li, Chao Yao, Qun Chen, Yongsheng Fu. TiO2 nanorod arrays on the conductive mica combine photoelectrochemical cathodic protection with barrier properties. Journal of Alloys and Compounds.776, 2019, 529-535.
[5] Xiazhang Li , Xiangyu Yan , Xiaowang Lu , Shixiang Zuo , Zhongyu Li , Chao Yao, Chaoying Ni. Photo-assisted selective catalytic reduction of NO by Z-scheme natural clay based photocatalyst: Insight into the effect of graphene coupling. Journal of Catalysis 357 (2018) 59–68.
[6] Xiazhang Li, Haiyang Shi, Wei Zhu, Shixiang Zuo, Xiaowang Lu, Shiping Luo, Zhongyu Li, Chao Yao⁎, Yongsheng Chen⁎, Nanocomposite LaFe1-xNixO3 /Palygorskite catalyst for photo-assisted reduction of NOx: Effect of Ni doping. Applied Catalysis B: Environmental 231 (2018) 92–100
[7] Shixiang Zuo, Jian Chen, Wenjie Liu, Xiazhang Li, Yong Kong, Chao Yao, Yongsheng Fu. Preparation of 3D interconnected hierarchical porous N-doped carbon nanotubes. Carbon 129, 2018, 199-206.
[8] Xiazhang Li, Xiangyu Yan, Shixiang Zuo, Xiaowang Lu, Shiping Luo, Zhongyu Li, Chao Yao*, Chaoying Ni，Construction of LaFe1-xMnxO3/attapulgite nanocomposite for photo-SCR of NOx at low temperature. Chemical Engineering Journal, 2017, 320, 211-221
[9] Xiazhang Li, Wei Zhu, Xiaowang Lu, Shixiang Zuo, Chao Yao, Chaoying Ni.Integrated nanostructures of CeO2/attapulgite/g-C3N4 as efficient catalyst for photocatalytic desulfurization: Mechanism, kinetics and influencing factors. Chemical Engineering Journal, 2017，326,87-98.
[9] Xinyu Lyu, Huihui Mao, Kongnan Zhu, Yong Kong, Motoyoshi Kobayash. Selective cyclohexane oxidation over vanadium incorporated silica pillared clay catalysts: The effect of VOx content and dispersion. Microporous and Mesoporous Materials, 252, 2017, 1-9