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成果及论文


45. Zhang, Y.-Y.; Yang, G.-W.*; R. Xie, Zhu, X.-F.; Wu, G.-P.* Sequence-Reversible Construction of Oxygen-Rich Block Copolymers from Epoxide Mixtures by Organoboron Catalyst, J. Am. Chem. Soc.2022,144, 19896-19909.


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10.1021/jacs.2c07857



44. Qi, H.#(共一); R. Xie.#(共一)Yang, G.-W.*; Zhang, Y.-Y.; Xu, C.-K.; Wang, Y.; Wu, G.-P.*, Rational Optimization of Bifunctional Organoboron Catalysts for Versatile Polyethers via Ring-Opening Polymerization of Epoxides. Macromolecules 2022DOI: 10.1021/acs.macromol.2c01596, on line.


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10.1021/acs.macromol.2c01596



43. Yang, G.-W..#(共一);  Wang, Y..#(共一);  Qi, H.;  Zhang, Y.-Y.;  Zhu, X.-F.;  Lu, C.;  Yang, L.; Wu, G.-P.*, Highly Selective Preparation and Depolymerization of Chemically Recyclable Poly(cyclopentene carbonate) Enabled by Organoboron Catalysts. Angew. Chem. Int. Ed.2022, e202210243, online.


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10.1002/anie.202210243



42. Yang, G.-W.; Xu, C.-K.; Xie, R.; Zhang, Y.-Y.; Yang, L.; Lu, C.; Qi, H.; Wang, Y.; Wu, G.-P.*, Precision Copolymerization of CO2 and Epoxides Enabled by Organoboron Catalysts,  Nature Synthesis2022, doi: 10.1038/s44160-022-00137-x.


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10.1038/s44160-022-00137-x




41. Zhang, Y.-Y.; Lu, C.; Yang, G.-W.; Xie, R.; Fang, Y.-B.; Wang, Y.; Wu, G.-P.*, Mechanism-Inspired Upgradation of Phosphonium-Containing Organoboron Catalysts for Epoxide-Involved Copolymerization and Homopolymerization. Macromolecules 2022, DOI: 10.1021/acs.macromol.2c01180. 


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10.1021/acs.macromol.2c01180



40. Li, Z.-Q.;  Zhang, Y.-Y.;  Zheng, Y.-J.;  Li, B.*; Wu, G.-P.*, Insights into Thiourea-Based Bifunctional Catalysts for Efficient Conversion of CO2 to Cyclic Carbonates. J. Org. Chem. 2022, doi: 10.1021/acs.joc.1c02888, online (Cover Paper).


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10.1021/acs.joc.1c02888



39. Li, B.*;  Zhang, Y.-L.;  Zhu, X.-F.;  Li, Z.-Q.;  Li, Z.-H.;  Qiu, H.-Y.; Wu, G.-P.*, Poly(ether ester) and related block copolymers via organocatalytic ring-opening polymerization. J Polym Sci. 2022, 1–13. 10.1002/pol.20210820, online.

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10.1002/pol.20210820


38. Zhu, X.-F.; Yang, G.-W.; Xie, R.; Wu, G.-P.*,  One-pot Construction of Sulfur-Rich Thermoplastic Elastomers Enabled by Metal-free Self-Switchable Catalysis and Air-Assisted Coupling. Angew. Chem. Int. Ed.,  2022, 61(7), 280-285.  


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10.1002/anie.202115189


37.   Zhang, Y.-Y.; Yang, G.-W.; Wu, G.-P.*, Recent Progress in Synthesizing Polyethers via Organocatalysts. Synlett2022, 33(01), 8-15.

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10.1055/a-1679-7959

36.  Yang, G.-W.; Zhang, Y.-Y.; Wu, G.-P.*, Modular Organoboron Catalysts Enable Transformations with Unprecedented Reactivity. Acc. Chem. Res. 2021, 54 (23), 4434-4448 (Cover Paper). 

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 10.1021/acs.accounts.1c00620


35. Ren, J.;  Shu, X.;  Wang, Y.;  Wang, D.;  Wu, G-P.*;  Zhang, X.*;  Jin, Q.*;  Liu, J.*;  Wu, Z.*;  Xu, Z.*;  Li, C.-Z.*; Li, H.*, Key progresses of MOE key laboratory of macromolecular synthesis and functionalization in 2020. Chin Chem Lett. 2021, on line.

 

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10.1016/j.cclet.2021.10.052


34.   Zhang, Y.-Y.; Yang, G.-W.; Wu, G.-P.*, Recent Progress in Synthesizing Polyethers via Organocatalysts. Synlett2021, online.

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10.1055/a-1679-7959


33.  Zhang, Y.-Y.; Yang, L.; Xie, R.; Yang, G.-W.; Wu, G.-P.*, Perfectly Alternating Copolymerization of CO and Epoxides to Aliphatic Polyester Oligomers via Cooperative Organoboron–Cobalt Complexes. Macromolecules 2021, 54, 9427-9436. 


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10.1021/acs.macromol.1c01324


32. 陆新宇, 马彬泽, 罗皓, 齐欢, 李强, 伍广朋*.Optimization of Development Process for Carbon Dioxide-Based Poly(cyclohexene carbonate) Electron Beam Resist, Chinese Journal of Applied Chemistry,

二氧化碳基聚碳酸环己撑酯电子束光刻胶显影工艺优化.《应用化学》, 202138(9): 1189-1198.光刻胶专刊邀稿


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http://yyhx.ciac.jl.cn/CN/Y2021/V38/I9/0


31. Xie, R.#(共一);  Zhang, Y.-Y.#(共一); Yang, G.-W.;  Zhu, X.-F.;  Li, B.; Wu, G.-P.*, Record Productivity and Unprecedented Molecular-Weight for Ring-Opening Copolymerization of Epoxides and Cyclic Anhydrides Enabled by Organoboron Catalysts. Angew. Chem. Int. Ed., 202160, 19253-19261.



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10.1002/anie.202104981


30. Yang, L.#(共一);  Zhang, Y.-Y.#(共一);  Yang, G.-W.;  Xie, R.; Wu, G.-P.*, Controlled Ring-Opening Polymerization of β-Butyrolactone Via Bifunctional Organoboron Catalysts. Macromolecules 2021, 54, 5509-5517

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10.1021/acs.macromol.1c00250



29. Yang, G.-W.; Xu, C.-K.; Xie, R.; Zhang, Y.-Y.; Zhu, X.-F. Wu, G.-P.*, Pinwheel-Shaped Tetranuclear Organoboron Catalysts for Perfectly Alternating Copolymerization of CO2 and Epichlorohydrin,  J. Am. Chem. Soc.2021, 143, 3455-3465. 


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10.1021/jacs.0c12425



28. 张瑶瑶、杨贯文、伍广朋*,利用双功能β-二亚胺锌催化剂正交构建丙交酯-苯乙烯嵌段共聚物《高分子学报》,2021,52(5), doi: 10.11777/j.issn1000-3304.2020.20255 (沈之荃院士纪念专刊


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10.11777/j.issn1000-3304.2020.20255


27. Zhu, X.-F.#(共一);  Xie, R.#(共一);  Yang, G.-W.;  Lu, X.-Y.; Wu, G.-P.*, Precisely Alternating Copolymerization of Episulfides and Isothiocyanates: A Practical Route to Construct Sulfur-Rich Polymers. ACS Macro Letters 202110, 135-140.


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10.1021/acsmacrolett.0c00831


26. Lu, X.-Y.#(共一) ; Luo, H.#(共一) Wang, K.#(共一); Zhang, Y.-Y.#(共一); Zhu, X.-F.#(共一);  Li, D.; Ma, B.; Xiong, S.;  Nealey,  P. F.*;  Li, Q.*;  Wu, G.-P.*CO2-based Dual-Tone Resists for Electron Beam LithographyAdv. Funct. Mater. 2021, 31, 2007417.

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10.1002/adfm.202007417


25. Zhang, Y.-Y.; Yang, G.-W.Xie, R.; Yang, L.; Li, B.; Wu, G.-P.*Scalable, Durable, and Recyclable Metal‐Free Catalysts for Highly‐Efficient Conversion of CO2 to Cyclic CarbonatesAngew. Chem. Int. Ed.202059, 23291-23298.


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10.1002/anie.202010651


24. Jacobberger, R.-M.Thapar, V.; Wu, G.-P.*Chang, T.-H.; Saraswat, V.; Way, A. J.; Jinkins, K. R.; Ma, Z.-Q.; Nealey, P. F.; Hur, S.-M.*; Xiong, S.-S.*; ArnoldM. S.*, Boundary-directed epitaxy of block copolymersNat. Commun.202011, 4151.


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10.1038/s41467-020-17938-3



23. Dong, T.-F.; Zheng, Y.-J.; Yang, G.-W.; Zhang, Y.-Y.; Li, B.*; Wu, G.-P.*Cross‐linked resin supported bifunctional organocatalyst for conversion of CO2 to cyclic carbonatesChemSusChem202013, 4121-4127.


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10.1002/cssc.202001117



22. Yang, G.-W.#(共一); Zhang, Y.-Y.#(共一); Xie, R.; Wu, G.-P.*High-Activity Organocatalysts for Synthesis of Polyether via Intramolecular Ammonium Cation-Assisted SN2 Ring-Opening Polymerization. Angew. Chem. Int. Ed.202059, 16910-16917. (Hot Paper)


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10.1002/anie.202002815



21. Yang, G.-W.; Zhang, Y.-Y.; Xie, R.; Wu, G.-P.*Scalable bifunctional organoboron catalysts for copolymerization of CO2 and epoxides with unprecedented efficiency. J. Am. Chem. Soc.2020142, 12245-12255.


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10.1021/jacs.0c03651



20. Zhang, Y.-Y.; Wu, G.-P.*Darensbourg, D. J.*, CO2-Based Block Copolymers: Present and Future Designs. Trends in Chemistry20202, 750-763.


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10.1016/j.trechm.2020.05.002



19. Zheng, Y.-J.#(共一); Yang, G.-W.#(共一); Li, B.*; Wu, G.-P.*, Construction of polyphosphoesters with the main chain of rigid backbones and stereostructures via organocatalyzed ring-opening polymerizationPolym. Chem.202011, 3475-3480.

image.pngGraphical abstract: Construction of polyphosphoesters with the main chain of rigid backbones and stereostructures via organocatalyzed ring-opening polymerization

10.1039/d0py00262c



18. Zhao, J.-K.; Yang, G.-W.; Zhu, X.-F.; Wu, G.-P.*, Highly elastic and degradable thermoset elastomers from CO2-based polycarbonates and bioderived polyesters, Polym. Chem., 201910, 5265-5270.

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10.1039/C9PY01085H



17. Yang, G.-W.;  Wu, G.-P.*, High-Efficiency Construction of CO2-Based Healable Thermoplastic Elastomers via a Tandem Synthetic Strategy. ACS Sustainable Chem. Eng20197, 1372-1380.

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10.1021/acssuschemeng.8b05084



16. Zhou, H.-J.#(共一);  Yang, G.-W.#(共一);  Zhang, Y.-Y.;  Xu, Z.-K.; Wu, G.-P.*, Bio-Inspired Block Copolymer for Mineralized Nanoporous Membrane. ACS Nano201812, 11471-11480.


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10.1021/acsnano.8b06521



15. Zhang, Y.-Y.;  Yang, G.-W.; Wu, G.-P.*, A Bifunctional β-Diiminate Zinc Catalyst with CO2/Epoxides Copolymerization and RAFT Polymerization Capacities for Versatile Block Copolymers Construction. Macromolecules201851, 3640-3646.



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10.1021/acs.macromol.8b00576



14. Zhang, Y.-Y.;  Yang, G.-W.;  Wang, Y.;  Lu, X.-Y.;  Wu, G.-P.*;  Zhang, Z.-S.;  Wang, K.;  Zhang, R.-Y.;  Nealey, P. F.;  Darensbourg, D. J.*; Xu, Z.-K., Synthesis of CO2-Based Block Copolymers via Chain Transfer Polymerization Using Macroinitiators: Activity, Blocking Efficiency, and Nanostructure. Macromolecules201851, 791-800.



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10.1021/acs.macromol.7b02231



13. Yang, G.-W.;  Zhang, Y.-Y.;  Wang, Y.;  Wu, G.-P.*;  Xu, Z.-K.; Darensbourg, D. J.*, Construction of Autonomic Self-Healing CO2-Based Polycarbonates via One-Pot Tandem Synthetic Strategy. Macromolecules2018, 51, 1308-1313.



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10.1021/acs.macromol.7b02715



12. Yang, G.-W.;  Wu, G.-P.*;  Chen, X.;  Xiong, S.;  Arges, C. G.;  Ji, S.;  Nealey, P. F.*;  Lu, X.-B.;  Darensbourg, D. J.; Xu, Z.-K.*, Directed Self-Assembly of Polystyrene-b-poly(propylene carbonate) on Chemical Patterns via Thermal Annealing for Next Generation Lithography. Nano Letters201717, 1233-1239 (Highlight by Science China Chemistry, 2017, 60, 679-680).


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10.1021/acs.nanolett.6b05059



11. Pang, Y.;  Wan, L.;  Huang, G.;  Zhang, X.;  Jin, X.;  Xu, P.;  Liu, Y.;  Han, M.;  Wu, G.-P.; Ji, S.*, Controlling Block Copolymer–Substrate Interactions by Homopolymer Brushes/Mats. Macromolecules 201750, 6733−6741.



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10.1021/acs.macromol.7b00743



10. Wu, G.-P.*; Darensbourg, D. J.,* Mechanistic Insights into Water-Mediated Tandem Catalysis of Metal-Coordination CO2/Epoxide Copolymerization and Organocatalytic Ring-Opening Polymerization: One-Pot, Two Steps, and Three Catalysis Cycles for Triblock Copolymers Synthesis. Macromolecules201649, 807-814.



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10.1021/acs.macromol.5b02752



09. Wu, G.-P.;  Xu, P.-X.;  Lu, X.-B.*;  Zu, Y.-P.;  Wei, S.-H.;  Ren, W.-M.; Darensbourg, D. J.*, Crystalline CO2 Copolymer from Epichlorohydrin via Co(III)-Complex-Mediated Stereospecific Polymerization. Macromolecules201346, 2128-2133.



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10.1021/ma400252h



08. Darensbourg, D. J.*; Wu, G.-P., A One-Pot Synthesis of a Triblock Copolymer from Propylene Oxide/Carbon Dioxide and Lactide: Intermediacy of Polyol Initiators. Angew. Chem. Int. Ed., 201352, 10602-10606.


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10.1002/anie.201304778



07. Wu, G.-P.;  Ren, W.-M.;  Luo, Y.;  Li, B.;  Zhang, W.-Z.; Lu, X.-B.*, Enhanced Asymmetric Induction for the Copolymerization of CO2 and Cyclohexene Oxide with Unsymmetric Enantiopure SalenCo(III) Complexes: Synthesis of Crystalline CO2-Based Polycarbonate. J. Am. Chem. Soc., 2012134 , 5682-5688.



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10.1021/ja300667y



06. Wu, G.-P.;  Jiang, S.-d.;  Lu, X.-b.*;  Ren, W.-m.; Yan, S.-k.*, Stereoregular poly(cyclohexene carbonate)s: Unique crystallization behavior. Chinese Journal of Polymer Science2012, 30, 487-492.



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10.1007/s10118-012-1171-x



05. Wu, G.-P.;  Darensbourg, D. J.*; Lu, X.-B.*, Tandem Metal-Coordination Copolymerization and Organocatalytic Ring-Opening Polymerization via Water To Synthesize Diblock Copolymers of Styrene Oxide/CO2 and Lactide. J. Am. Chem. Soc., 2012, 134, 17739-17745.



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10.1021/ja307976c



04. Lu, X.-B.*;  Ren, W.-M.; Wu, G.-P., CO2 Copolymers from Epoxides: Catalyst Activity, Product Selectivity, and Stereochemistry Control. Accounts of Chemical Research201245, 1721-1735.


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10.1021/ar300035z



03. Wu, G.-P.;  Wei, S.-H.;  Ren, W.-M.;  Lu, X.-B.*;  Xu, T.-Q.; Darensbourg, D. J.*, Perfectly Alternating Copolymerization of CO2 and Epichlorohydrin Using Cobalt(III)-Based Catalyst Systems. J. Am. Chem. Soc., 2011133, 15191-15199.



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10.1021/ja206425j



02. Wu, G.-P.;  Wei, S.-H.;  Ren, W.-M.;  Lu, X.-B.*;  Li, B.;  Zu, Y.-P.; Darensbourg, D. J.*, Alternating copolymerization of CO2 and styrene oxide with Co(iii)-based catalyst systems: differences between styrene oxide and propylene oxide. Energy & Enviromental Science20114, 5084-5092.



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10.1039/C1EE02566J



01. Wu, G.-P.;  Wei, S.-H.;  Lu, X.-B.*;  Ren, W.-M.; Darensbourg, D. J.*, Highly Selective Synthesis of CO2 Copolymer from Styrene Oxide. Macromolecules201043, 9202-9204.



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10.1021/ma1021456