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成果及论文

    2021

    Rare Earth Metal Complexes Supported by a Tripodal Tris(amido) Ligand System Featuring an Arene Anchor

    Xin, T.*; Wang, X.*; Yang, K.; Liang, J.; Huang, W. Inorg. Chem., 2021, 60, 15321-15329

    DOI: 10.1021/acs.inorgchem.1c01922

    * These authors contributed equally.


    Homoleptic Tris(6,6′-dimethyl-2,2′-bipyridine) Rare Earth Metal Complexes

    Xiao, Y.; Sun, R.; Liang, J.; Fang, Y.; Liu, Z.; Jiang, S.; Wang, B.; Gao, S.; Huang, W. Inorg. Chem. Front., 2021, 8, 2591–2602

    DOI: 10.1039/D1QI00240F


    Chemistry of Unusual Oxidation States of Actinides Ⅱ. Molecular Complexes

    Deng, C.; Su, Y.; Huang, W. J. Nucl. Radiochem., 2021, 43, 1-20

    DOI: 10.7538/hhx.2021.YX.2020090


    Distinct Electronic Structures and Bonding Interactions in Inverse-Sandwich Samarium and Ytterbium Biphenyl Complexes

    Xiao, Y.; Zhao, X.; Wu, T.; Miller, J. T.; Hu, H.; Li, J.; Huang, W.; Diaconescu, P. L. Chem. Sci., 2021, 12, 227-238

    DOI: 10.1039/D0SC03555F


    2020

    Chemistry of Unusual Oxidation States of Actinides Ⅰ. Gas Phase, Solid State and Aqueous Solution

    Deng, C.; Su, Y.; Huang, W. J. Nucl. Radiochem., 2020, 42, 443-464

    DOI: 10.7538/hhx.2020.YX.2020090


    Arene-Bridged Dithorium Complexes: Inverse Sandwiches Supported by a δ Bonding Interaction

    Yu, C.; Liang, J.; Deng, C.; Lefèvre, G.; Cantat, T.; Diaconescu, P. L.; Huang, W. J. Am. Chem. Soc., 2020, 142, 21292-21297

    DOI: 10.1021/jacs.0c11215


    Chemistry of non-traditional oxidation states of rare earth metals 

    Wang, Y.; Huang, W. SCIENTIA SINICA Chimica, 2020, 50, 1504-1559

    DOI: 10.1360/SSC-2020-0154


    2018

    Molecular Design of Deep Blue Thermally Activated Delayed Fluorescence Materials Employing a Homoconjugative Triptycene Scaffold and Dihedral Angle Engineering

    Huang, W.; Einzinger, M.; Zhu, T.; Chae, H.-S.; Jeon, S.; Lee, S.-Y.; Ihn, S.-G.; Sim, M.; Kim, S.; Su, M.; Teverovskiy, G.; Wu, T.; Voorhis, T. Van;  Swager, T. M.; Baldo, M. A.; Buchwald, S. L. Chem. Mater., 2018, 30, 1462-1466

    DOI: 10.1021/acs.chemmater.7b03490


    2017

    Reduction of Diphenylacetylene Mediated by Rare-Earth Ferrocene Diamide Complexes

    Brosmer J. L.; Huang, W.; Diaconescu, P. L. Organometallics, 2017, 36, 4643–4648

    DOI:10.1021/acs.organomet.7b00541


    Aromatic C–F Bond Activation by Rare-Earth Metal Complexes

    Huang, W.; Diaconescu, P. L. Organometallics, 2017, 36, 89–96

    DOI:10.1021/acs.organomet.6b00661


    2016

    Reactivity and Properties of Metal Complexes Enabled by Flexible and Redox-Active Ligands with a Ferrocene Backbone

    Huang, W.; Diaconescu, P. L. Inorg. Chem., 2016, 55, 10013–10023

    DOI:10.1021/acs.inorgchem.6b01118


    Palladium catalyzed N-Arylation of Iminodibenzyls and Iminostilbenes with Aryl and Hetero‐Aryl Halides

    Huang, W.; Buchwald, S. L. Chem. Eur. J., 2016, 22, 14186–14189

    DOI:10.1002/chem.201603449


    Design of Efficient Molecular Organic Light-Emitting Diodes by a High-Throughput Virtual Screening and Experimental Approach

    Gómez-Bombarelli, R.; Aguilera-Iparraguirre, J.; Hirzel, T.; Duvenaud, D.; Maclaurin, D.; Blood-Forsythe, M.; Chae, H.-S.; Einzinger, M.; Ha, D.-G.; Wu, T.; Markopoulos, G.; Jeon, S.; Kang, H.; Miyazaki, H.; Numata, M.; Kim, S.; Huang, W.; Hong, S.-I.; Baldo, M. A.; Adams, R.; Aspuru-Guzik, A. Nat. Mater., 2016, 15, 1120-1127

    DOI:10.1038/nmat4717


    Organometallic Chemistry of Lanthanides (Chapter 5)

    Huang, W.; Diaconescu, P. L. In: Liddle, Stephen; Natrajan, Louise, Editor(s), The Lanthanides and Actinides: Synthesis, Reactivity, Properties and Applications Imperial College Press


    2015

    Chapter Two: C–H Bond Activation of Hydrocarbons Mediated by Rare-Earth Metals and Actinides: Beyond σ-Bond Metathesis and 1,2-Addition

    Huang, W.; Diaconescu, P. L., In: Pérez, Pedro J., Editor(s), Advances in Organometallic Chemistry, Academic Press 2015, 64, 41-75

    Link:Chapter Two


    In situ Synthesis of Rare-Earth Metal Complexes Supported by Ferrocene Diamide Ligand: Extension to Redox Active Lanthanide Ions

    Huang, W.; Brosmer, J. L.; Diaconescu, P. L. New J. Chem., 2015, 39, 7696-7702

    DOI:10.1039/C5NJ01402F


    Rare-Earth Metal π-Complexes of Reduced Arenes, Alkenes, and Alkynes: Bonding, Electronic Structure and Comparison with Actinides and Other Highly Electropositive Metals

    Huang, W.; Diaconescu, P. L. Dalton Trans., 2015, 44, 15360-15371

    DOI:10.1039/C5DT02198G


    Tetraanionic Biphenyl Lanthanide Complexes as Single-Molecule Magnets

    Huang, W.; Le Roy, J. J.; Khan, S. I.; Ungur, L.; Murugesu, M.; Diaconescu, P. L., Inorg. Chem., 2015, 54, 2374–2382

    DOI:10.1021/ic5029788


    2010-2014

    Bimetallic Cleavage of Aromatic C–H Bonds by Rare-Earth-Metal Complexes

    Huang, W.; Dulong, F.; Khan, S. I.; Cantat, T.; Diaconescu, P. L. J. Am. Chem. Soc., 2014, 136, 17410–17413

    DOI:10.1021/ja510761j


    Rare Earth Arene-bridged Complexes Obtained by Reduction of Organometallic Precursors

    Huang, W.; Diaconescu, P. L. Handbook on the Physics and Chemistry of Rare Earths


    Group 3 Metal Stilbene Complexes: Synthesis, Reactivity, and Electronic Structure Studies

    Huang, W.; Abukhalil, P. M.; Khan, S, I.; Diaconescu, P. L. Chem. Commun., 2014, 50, 5221-5223

    DOI:10.1039/C3CC47505K


    P4 Activation by Lanthanum and Lutetium Naphthalene Complexes Supported by a Ferrocene Diamide Ligand

    Huang, W.; Diaconescu, P. L. Eur. J. Inorg. Chem., 2013, 4090-4096

    DOI:10.1002/ejic.201300225


    Synthesis and Characterization of Paramagnetic Lanthanide Benzyl Complexes

    Huang, W.; Upton, B. M.; Khan, S. I.; Diaconescu, P. L. Organometallics, 2013, 32, 1379–1386

    DOI:10.1021/om3010433


    A Six-carbon, 10π-electron Aromatic System Supported by Group 3 Metals

    Huang, W.; Dulong, F.; Wu, T.; Khan, S. I.; Miller, J. T.; Cantat, T.; Diaconescu, P. L. Nat. Commun., 2013, 4, 1448

    DOI:10.1038/ncomms2473


    P4 activation by Group 3 Metal Arene Complexes

    Huang, W.; Diaconescu, P. L. Chem. Commun., 2012, 48, 2216-2218

    DOI:10.1039/C2CC17638F


    Visible-Light-Induced Reversible C–C Bond Formation of an Imidazole-derived Scandium Complex

    Huang, W.; Diaconescu, P. L. Inorg. Chim. Acta, 2012, 380, 274-277

    DOI:10.1016/j.ica.2011.08.066


    Inverted Sandwiches of Scandium Arene Complexes Supported by a Ferrocene Diamide Ligand

    Huang, W.; Khan, S. I.; Diaconescu, P. L. J. Am. Chem. Soc., 2011, 133, 10410–10413

    DOI:10.1021/ja204304f


    Transmetalation Reactions of a Scandium Complex Supported by a Ferrocene-Diamide Ligand

    Huang, W.; Carver, C. T.; Diaconescu, P. L. Inorg. Chem., 2011, 50, 978–984

    DOI:10.1021/ic1016005


    Group 3 Metal Complexes of Radical-Anionic 2,2'-Bipyridyl Ligands

    Williams, B. N.; Huang, W.; Miller, K. L.; Diaconescu, P. L. Inorg. Chem., 2010, 49, 11493–11498

    DOI:10.1021/ic101493k