成果及论文 - 王文光课题组

Xin Zhang, Xuebin Jiang, Qiuting Zhao, Yongxian Li, Lei Feng, Shengfa Ye,* Chen-Ho Tung, and Wenguang Wang*, Synthesis and characterization of Bridging-Diazene Diiron HalfSandwich Complexes: The Role of Sulfur Hydrogen Bonding, Inorg. Chem. 2024. https://pubs.acs.org/doi/10.1021/acs.inorgchem.4c01783

Yufang Xie, Xin Yu, and Wenguang Wang*, Synergistic metal-ligand reactivity in half-sandwich complexes of iron, cobalt, and nickel for bond activation and catalysis, Adv. Organomet. Chem. Academic Press, 2024, ISSN 0065-3055. https://doi.org/10.1016/bs.adomc.2024.06.004.
Rui Sun, Yang Jiang, Hao-Ran Chen, Xuebin Jiang, Yu-Chen Cao, Shengfa Ye*, Rong-Zhen Liao*, Chen-Ho Tung, and Wenguang Wang*, Bimetallic H₂ Addition and Intramolecular Caryl–H Activation Mediated by an Iron–Zinc Hydride, Inorg. Chem. 2024, 63, 13, 6082. https://pubs.acs.org/doi/10.1021/acs.inorgchem.4c00454

Minghui Xue, Zhiqiang Peng, Keyan Tao, Jiong Jia, Datong Song*, Chen-Ho Tung and Wenguang Wang*, Catalytic hydrogenation of olefins by a multifunctional molybdenum-sulfur complex, Nat. Commun. 2024, 15, 797. https://www.nature.com/articles/s41467-024-45018-3
Yongxian Li, Jia-Yi Chen, Xinchao Zhang, Zhiqiang Peng, Qiyi Miao, Wang Chen, Fei Xie, Rong-Zhen Liao*, Shengfa Ye*, Chen-Ho Tung, and Wenguang Wang*, Electrocatalytic Interconversions of CO2 and Formate on a Versatile Iron-Thiolate Platform, J. Am. Chem. Soc. 2023, 145, 49, 26915. https://pubs.acs.org/doi/10.1021/jacs.3c09824
- Xin Zhang, Lei Feng, Chen-Ho Tung, and Wenguang Wang*, Transformation of Acetylene to Ethenylidene, Carbene, Acetylide, Vinyl, and Olefin Groups with Cp*Fe(1,2-Cy2PC6H4S), Inorg. Chem. 2023, 62, 45, 18599. https://pubs.acs.org/doi/full/10.1021/acs.inorgchem.3c02911
- Hongjie Gao, Jiong Jia, Chen-Ho Tung, and Wenguang Wang*, Iron-Catalyzed Selective Hydroboration of CO2 by Cooperative B–H Bond Activation, Organometallics 2023, 42, 10, 944. https://doi.org/10.1021/acs.organomet.3c00119
Boying Yu, Xiaocheng Xu, Zhen-Na Huang, Keyan Tao, Hao-Ling Sun*, Qing-Zheng Yang, and Wenguang Wang*, Iron–Aryloxide Complex Bearing Bis(dipyrromethene) Ligands for the Ring-Opening Polymerization of ε-Caprolactone, Organometallics 2023, 42, 7, 565. https://doi.org/10.1021/acs.organomet.2c00618
- Zhuohao Zhao, Jianguo Liu, Chen-Ho Tung, Wenguang Wang*, Nickel catalyzed cooperative B-H bond activation for hydroboration of N–heteroarenes, ketones and imines, Chin. Chem. Lett. 2023, 34, 108293. https://doi.org/10.1016/j.cclet.2023.108293
- Wenguang Wang, Xiaofang Zhai and Shu-Fen Hou, (2022) Cyclic and Non-Cyclic Pi Complexes of Molybdenum. In: Parkin, G., Meyer, K., O'Hare, D. (eds.), Comprehensive Organometallic Chemistry IV. Vol. 5, pp. 174-256. Kidlington, UK: Elsevier. https://doi.org/10.1016/B978-0-12-820206-7.00031-7
Rui Sun, Wen-Hao Deng, Boying Yu, Yilei Lu, Xiaofang Zhai, Rong-Zhen Liao*, Chen-Ho Tung, and Wenguang Wang*, Hydroboration of the (C5Me5)Fe(1,2-Ph2PC6H4) System To Derive Hydridoborate and Hydridosilicate Complexes, Organometallics 2022, 41, 17, 2504. https://pubs.acs.org/doi/full/10.1021/acs.organomet.2c00331

- - - Hongjie Gao, Jia-Yi Chen, Zhiqiang Peng, Lei Feng, Chen-Ho Tung, and Wenguang Wang*, Bioinspired Iron-Catalyzed Dehydration of Aldoximes to Nitriles: A General N-O Redox-Cleavage Method, J. Org. Chem. 2022, 87, 16, 10848. https://pubs.acs.org/doi/10.1021/acs.joc.2c01122

- - Maofu Pang, Le-Le Shi, Yufang Xie, Tianyi Geng, Lan Liu, Rong-Zhen Liao*, Chen-Ho Tung, and Wenguang Wang*, Cobalt-Catalyzed Selective Dearomatization of Pyridines to N-H 1,4-Dihydropyridines, ACS Catal. 2022, 12, 5013. https://pubs.acs.org/doi/10.1021/acscatal.2c00271
- Yongxian Li, Jia-Yi Chen, Qiyi Miao, Xin Yu, Lei Feng, Rong-Zhen Liao*, Shengfa Ye*, Chen-Ho Tung, and Wenguang Wang*, A Parent Iron Amido Complex in Catalysis of Ammonia Oxidation, J. Am. Chem. Soc. 2022, 144, 10, 4365. https://pubs.acs.org/doi/abs/10.1021/jacs.1c08609
- Yufang Xie, Qiyi Miao, Wenhao Deng, Yilei Lu, Yinuo Yang, Xiaohui Chen, Rong-Zhen Liao, Shengfa Ye, Chen-Ho Tung, Wenguang Wang*, Facile Transformations of a Binuclear Cp*Co(II) Diamidonaphthalene Complex to Mixed-Valent Co(II)Co(III), Co(III)(µ-H)Co(III) and Co(III)(µ-OH)Co(III) Derivatives, Inorg. Chem. 2022, 61, 4, 2204. https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.1c03451

- Jianguo Liu, Heng Song, Tianlin Wang, Jiong Jia, Qing-Xiao Tong*, Chen-Ho Tung, Wenguang Wang*, Iron-Catalyzed Regiodivergent Hydrostannation of Alkynes: Intermediacy of Fe(IV)-H versus Fe(II)-Vinylidene, J. Am. Chem. Soc. 2021, 143, 409. https://pubs.acs.org/doi/abs/10.1021/jacs.0c11448
- Xiaofang Zhai, Maofu Pang, Lei Feng, Jiong Jia, Chen-Ho Tung, Wenguang Wang*, Dehydrogenation of Iron Amido-Borane and Resaturation of the Imino-Borane Complex, Chem. Sci. 2021, 12, 2885. https://pubs.rsc.org/en/content/articlelanding/2021/SC/D0SC06787C#!divAbstract

- Shengnan Zhang, Xiaofang Zhai, Yike Song, Lei Feng, Chen-Ho Tung, and Wenguang Wang*, Insertion of BH3 into a Cobalt–Aryl Bond: Synthetic Routes to Arylborohydride and Borane-Amino Hydride Complexes, Organometallics 2021, 40(11), 1692. https://pubs.acs.org/doi/10.1021/acs.organomet.1c00174

Maofu Pang, Jia-Yi Chen, Shengjie Zhang, Rong-Zhen Liao*, Chen-Ho Tung and Wenguang Wang*, Controlled partial transfer hydrogenation of quinolines by cobalt-amido cooperative catalysis, Nat. Commun. 2020, 11, 1249. https://www.nature.com/articles/s41467-020-15118-x

- Shu-Fen Hou, Jia-Yi Chen, M. H. Xue, Mengjing Jia, Xiaofang Zhai, Rong-Zhen Liao*, Chen-Ho Tung and Wenguang Wang*, Cooperative Molybdenum-Thiolate Reactivity for Transfer Hydrogenation of Nitriles, ACS Catal. 2020, 10, 1, 380. https://pubs.acs.org/doi/10.1021/acscatal.9b04455
- Heng Song, Zhuoyi Yang, Chen-Ho Tung and Wenguang Wang*, Iron-Catalyzed Reductive Coupling of Nitroarenes with Olefins: Intermediate of Iron-Nitroso Complex, ACS Catal. 2020, 10, 1, 276. https://pubs.acs.org/doi/10.1021/acscatal.9b03604
Yufang Xie, Chengjuan Wu, Changhao Jia, Chen-Ho Tung, Wenguang Wang*, Iron-cobalt-catalyzed heterotrimerization of alkynes and nitriles to polyfunctionalized pyridines, Org. Chem. Front. 2020, 7, 2196. https://pubs.rsc.org/en/content/articlehtml/2020/qo/d0qo00693a

- Xiangyu Liu, Heng Song, Xiaofang Zhai, Chen-Ho Tung and Wenguang Wang*, Cobalt-catalyzed regioselective hydrohydrazination of epoxides, Org. Biomol. Chem. 2020, 18, 1572. https://pubs.rsc.org/no/content/articlehtml/2020/ob/d0ob00037j
- Jianguo Liu, Jiayi Chen, Mengjing Jia, Bangrong Ming, Jiong Jia, Rong-Zhen Liao*, Chen-Ho Tung and Wenguang Wang*, Ni-O Cooperation versus Nickel(II) Hydride in Catalytic Hydroboration of N-Heteroarenes, ACS Catal. 2019, 9, 3849. https://pubs.acs.org/doi/abs/10.1021/acscatal.8b05136

Xiaoxiao Chu, Jihao Jin, Bangrong Ming, Maofu Pang, Xin Yu and Chen-Ho Tung, Wenguang Wang*, Bimetallic Nickel-Cobalt Hydride in H2 Activation and Catalytic Proton Reduction, Chem. Sci. 2019, 10, 761. https://pubs.rsc.org/en/content/articlelanding/2019/sc/c8sc04346a#!divAbstract

Shengnan Zhang, Yike Song, Xueshan He, Raja Angamuthu*, Chen-Ho Tung and Wenguang Wang*, Reductive Coupling of Bridging Diaryl Ligands in Half-Sandwich Cobalt(II) Dimers: Revisiting Triple-Decker Cobalt(I) Complexes, Organometallics 2019, 38, 3610. https://pubs.acs.org/doi/abs/10.1021/acs.organomet.9b00439

Xuewen Zhuang, Jia-Yi Chen, Zhuoyi Yang, Mengjing Jia, Chengjuan Wu, Rong-Zhen Liao*, Chen-Ho Tung and Wang, Wenguang*, Sequential Transformation of Terminal Alkynes to 1,3-Dienes by a Cooperative Cobalt Pyridonate Catalyst, Organometallics 2019, 38, 3752. https://pubs.acs.org/doi/abs/10.1021/acs.organomet.9b00486

- Zhennan Yang, Maofu Pang, Shu-Guang Xia, Xiao-Ya Gao, Qing Guo, Dr. Xu-Bing Li, Prof. Dr. Chen-Ho Tung, Prof. Dr. Li-Zhu Wu*, Prof. Dr. Wenguang Wang*, Catalytic Hydrogen Production Using A Cobalt Catalyst Bearing a Phosphinoamine Ligand, ChemPhotoChem. 2019, 3, 220. https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/cptc.201800246

- Xin Yu, Maofu Pang, Shengnan Zhang, Xinling Hu, Chen-Ho Tung, and Wenguang Wang*, Terminal Thiolate-Dominated H/D Exchanges and H2 Release: Diiron Thiol-Hydride, J. Am. Chem. Soc. 2018, 140, 11454. https://pubs.acs.org/doi/abs/10.1021/jacs.8b06996
Maofu Pang, Chengjuan Wu, Xuewen Zhuang, Fanjun Zhang, Mincong Sun, Qingxiao Tong, Chen-Ho Tung*, and Wenguang Wang*, Addition of a B-H Bond across an Amido-Cobalt Bond: CoII-H-Catalyzed Hydroboration of Olefins, Organometallics 2018, 37, 1462. https://pubs.acs.org/doi/abs/10.1021/acs.organomet.8b00114

Xiangyu Liu, Chengjuan Wu*, Jing Zhang, Yihan Shi, Shengnan Zhang, Yan Geng and Chen-Ho Tung, Wenguang Wang*, Cobalt-Catalyzed Radical Cyclization of Isocyanides Forming Phenanthridine Derivatives, Org. Chem. Front. 2018, 5, 2997. https://pubs.rsc.org/en/content/articlelanding/2018/qo/c8qo00887f#!divAbstract

Ailing Zhang, Congxiao Wang, Xiaoyu Lai, Xiaofang Zhai, Maofu Pang and Chen-Ho Tung, Wenguang Wang*, Reactivity of Diphosphinodithio Ligated Nickel(0) Complex toward Alkyl Halides and Resultant Nickel(I) and Nickel(II)-alkyl Complexes, Dalton Trans. 2018, 47, 15757. https://pubs.rsc.org/en/content/articlelanding/2018/dt/c8dt03188f#!divAbstract

- Yingjie Zhao, Xin Yu, Huilan Hu, Xinlong Hu, Sakthi Raje, Raja Angamuthu, Chen-Ho Tong, and Wenguang Wang*, Synthetic [FeFe]-H2ase Models Bearing Phosphino Thioether Chelating Ligands, Chin. Chem. Lett. 2018, 29, 1651. https://www.sciencedirect.com/science/article/pii/S1001841718301165
- Jianguo Liu, Ailing Zhang, Heng Song, Qingxiao Tong*, Chen-Ho Tung, and Wenguang Wang*, Iron(II) hydrides Bearing a Tetradentate PSNP Ligand, Chin. Chem. Lett. 2018, 29, 949. https://www.sciencedirect.com/science/article/pii/S1001841717304096
- - Fanjun Zhang, Heng Song, Xuewen Zhuang, Chen-Ho Tung, and Wenguang Wang*, Iron-Catalyzed 1,2-Selective Hydroboration of N-Heteroarenes, J. Am. Chem. Soc. 2017, 139, 17775. https://pubs.acs.org/doi/abs/10.1021/jacs.7b11416
- Heng Song, Ke Ye, Peiyu Geng, Xiao Han, Rong-Zhen Liao,* Chen-Ho Tung, and Wenguang Wang*, Activation of Epoxides by a Cooperative Iron-Thiolate Catalyst: Intermediacy of Ferrous Alkoxides in Catalytic Hydroboration, ACS Catal. 2017, 7, 7709. https://pubs.acs.org/doi/abs/10.1021/acscatal.7b02527
- Xin Yu, Chen-Ho Tung, Wenguang Wang*, Mioy T. Huynh, Danielle L. Gray, Sharon Hammes-Schiffer,* and Thomas B. Rauchfuss*, Interplay between Terminal and Bridging Diiron Hydrides in Neutral and Oxidized States, Organometallics 2017, 36, 2245. https://pubs.acs.org/doi/abs/10.1021/acs.organomet.7b00297
- Ailing Zhang, Sakthi Raje, Jianguo Liu, Xiaoyan Li, Raja Angamuthu, Chen-Ho Tung, and Wenguang Wang*, Nickel-Mediated Stepwise Transformation of CO to Acetaldehyde and Ethanol, Organometallics 2017, 36, 3135. https://pubs.acs.org/doi/abs/10.1021/acs.organomet.7b00472
- Fanjun Zhang, Xin Xu, Yingjie Zhao, Jiong Jia, Chen-Ho Tung, and Wenguang Wang*, Solvent Effects on Hydride Transfer from Cp*(P-P)FeH to BNA+ Cation, Organometallics 2017, 36, 1238. https://pubs.acs.org/doi/abs/10.1021/acs.organomet.6b00907
- Xiaoxiao Chu, Xin Xu, Hao Su, Sakthi Raje, Raja Angamuthu, Chen-Ho Tung and Wenguang Wang*, Heteronuclear assembly of Ni-Cu Dithiolato Complexes: Synthesis, Structures, and Reactivity Studies, Inorg. Chem. Front. 2017, 4, 706. https://pubs.rsc.org/en/content/articlelanding/2017/qi/c6qi00536e#!divAbstract
- - Xiaoxiao Chu, Xin Yu, Sakthi Raje, Raja Angamuthu, Jianping Ma, Chen-Ho Tung, and Wenguang Wang*, Synthetic [NiFe] Models with a Fluxional CO ligand, Dalton Trans. 2017, 46, 13681. https://pubs.rsc.org/en/content/articlelanding/2017/dt/c7dt02892j#!divAbstract
- Jia-Heng Xu, Ling-Yu Guo, Hai-Feng Su, Xiang Gao, Xiao-Fan Wu,Wen-Guang Wang*, Chen-Ho Tung,and Di Sun*, Heptanuclear CoII5CoIII2 Cluster as Efficient Water Oxidation Catalyst, Inorg. Chem. 2017, 56, 1591. https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.6b02698

Li, Ran Xu, Wenyuan Zhao, Jinqin Yu, Xin Wang, Wenguang*, Tung, Chen-Ho , Azo-bridged New Diiron Carbonyl Complex: Synthesis of Fe2(NR)2(CO)6-x(PR3)x and the Derivatives, Acta Chimica Sinica 2017, 75, 92. http://sioc-journal.cn/Jwk_hxxb/CN/10.6023/A16070364

Fanjun Zhang, Jiong Jia, Shuli Dong, Wenguang Wang* and Chen-Ho Tung , Hydride Transfer from Iron(II) Hydride Compounds to NAD(P)+ Analogues, Organometallics 2016, 35, 1151. https://pubs.acs.org/doi/10.1021/acs.organomet.6b00179

- Jiaheng Xu, Zhi Wang, Wenguang Yu, Di Sun*, Qing Zhang, Chen-Ho Tung, and Wenguang Wang*, Kagóme Cobalt(II)-Organic Layers as Robust Scaffolds for Highly Efficient Photocatalytic Oxygen Evolution, ChemSusChem 2016, 9, 1146. https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/cssc.201600101
Jianguo Liu, Fanjun Zhang, Ailing Zhang, Qingxiao Tong*, Chen-Ho Tung, Wenguang Wang*, New Class of Hydrido Iron (II) Compounds with cis‐Reactive Sites: Combination of Iron and Diphosphinodithio Ligand, Chem. Asian J. 2016, 11, 2271. https://onlinelibrary.wiley.com/doi/full/10.1002/asia.201600695

- Wang, W.; Rauchfuss, T. B.*; Zhu, L.; Zampella, G*., New Reactions of Terminal Hydrides on a Diiron Dithiolate, J. Am. Chem. Soc. 2014, 136(15), 5773. https://pubs.acs.org/doi/10.1021/ja501366j
- Wenguang Wang, Mark J. Nilges, Thomas B. Rauchfuss*, and Matthias Stein*Isolation of a Mixed Valence Diiron Hydride: Evidence for a Spectator Hydride in Hydrogen Evolution Catalysis, J. Am. Chem. Soc. 2013, 135, 9, 3633. https://pubs.acs.org/doi/10.1021/ja312458f
- Wang, W., Rauchfuss, T. B.*, Moore, C.E., Rheingold, A. L*., De Gioia, L. and Zampella, G*., Crystallographic Characterization of a Fully Rotated, Basic Diiron Dithiolate: Model for the Hred State?, Chem. Eur. J. 2013, 19, 15476. https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.201303351
- Wenguang Wang, Luca Bertini, Giuseppe Zampella, Thomas B. Rauchfuss*, Unsensitized Photochemical Hydrogen Production Catalyzed by Diiron Hydrides, J. Am. Chem. Soc. 2012, 134(10), 4525. https://pubs.acs.org/doi/10.1021/ja211778j
- Wang, W.-G.; Wang, F.; Wang, H.-Y.; Tung, C.-H.; Wu, L.-Z*., Electron transfer and hydrogen generation from a molecular dyad: platinum(ii) alkynyl complex anchored to [FeFe] hydrogenase subsite mimic, Dalton Trans. 2012, 41(8), 2420. https://pubs.rsc.org/lv/content/articlehtml/2012/dt/c1dt11923k
- Wang, W.-G., Wang, F., Wang, H.-Y., Si, G., Tung, C.-H. and Wu, L.-Z*., Photocatalytic Hydrogen Evolution by [FeFe] Hydrogenase Mimics in Homogeneous Solution, Chem. Asian J. 2010, 5, 1796. https://onlinelibrary.wiley.com/doi/full/10.1002/asia.201000087

Wang, W.-G.; Wang, H.-Y.; Si, G.; Tung, C.-H.;Wu, L.-Z*., Fluorophenyl-substituted Fe-only hydrogenases active site ADT models: different electrocatalytic process for proton reduction in HOAc and HBF4/Et2O, Dalton Trans. 2009, 2712. https://pubs.rsc.org/en/content/articlelanding/2009/DT/b818012a#!divAbstract