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成果及论文

代表性第一作者和通讯作者论文:

  1. Yingjian Zhang, Taishan Wang*. Spin Probe for Dynamics of the Internal Cluster in Endohedral Metallofullerenes, Chem. Commun., 2025, 61, 61-68. https://doi.org/10.1039/D4CC04731A

  2. Chaofeng Zheng, Guixian Li, Jiayi Liang, Lu Yu, Wang Li, Yibo Han*, Chunru Wang, and Taishan Wang*. Magnetophotoluminescence Response Triggered by the Triplet State in Metallofullerene, Adv. Optical Mater. 2024, 2303334. https://doi.org/10.1002/adom.202303334

  3. Jie Zhang, Linshan Liu, Chaofeng Zheng, Wang Li, Chunru Wang, Taishan Wang*. Embedded nano spin sensor for in situ probing of gas adsorption inside porous organic frameworks, Nat. Commun., 2023, 14, 4922. https://doi.org/10.1038/s41467-023-40683-2

  4. Wang Li, Fayu Qu, Linshan Liu, Zhuxia Zhang, Chaofeng Zheng, Lin Wang*, Chunru Wang, and Taishan Wang*. Structure and single-molecule conductance of two endohedral metallofullerenes with large C88 cage. Nanoscale, 2023, 15, 13645-13652. https://doi.org/10.1039/D3NR02389C

  5. Linshan Liu, Yang Liu, Zhuxia Zhang*, and Taishan Wang*. Theoretical Study on a Supramolecular Dimeric Structure Constructed by Metallofullerene Y3N@C80 and Figure-of-Eight Nanoring. ACS Omega, 2023, 8, 23754-23762. https://doi.org/10.1021/acsomega.3c02049

  6. Yuxi Lu, Chong Zhao, Jie Zhang, Wang Li, Linshan Liu, Chaofeng Zheng, Chunru Wang, and Taishan Wang*. Enhanced Spin-Nuclei Couplings of Paramagnetic Azametallofullerene Hooped in Cycloparaphenylene. J. Phys. Chem. C, 2023, 127, 4660−4664. https://doi.org/10.1021/acs.jpcc.3c00158

  7. Jie Zhang, Zhenlin Qiu, Chong Zhao, Yuxi Lu, Wang Li, Linshan Liu, Chunru Wang, Yuanzhi Tan, and Taishan Wang*. Synergistic modulation of spin and fluorescence signals in a nano-Saturn assembled by a metallofullerene and cycloparaphenylene nanohoop. Nano Res., 2023, 16, 3372–3378. https://doi.org/10.1007/s12274-022-5158-9

  8. Wang Li, Chunru Wang, Taishan Wang*, Metallofullertube: From Tubular Endohedral Structures to Properties, ChemPhysChem2022, 23, e202200507, https://doi.org/10.1002/cphc.202200507

  9. Ling Qiu, Jiayi Liang, Zhuxia Zhang*, Taishan Wang*. Synthesis and Characterizations of 15N Isotope Labeling Metal Nitride Clusterfullerene. Acta Chimica Sinica202280, 874-878. http://sioc-journal.cn/Jwk_hxxb/EN/10.6023/A22020087

  10. Jiayi Liang, Chunru Wang, Taishan Wang*. Studies on the Luminescence Property of Yttrium-Based Metallofullerenes. Chin. J. Struct. Chem. 2022, 41, 2209001-2209007. DOI: 10.14102/j.cnki.0254-5861.2022-0105

  11. Jiayi Liang, Yuxi Lu, Jie Zhang, Ling Qiu, Wang Li, Zhuxia Zhang*, Chunru Wang and  Taishan Wang*, Visible and near-infrared photoluminescence of a supramolecular complex constructed from a cycloparaphenylene nanoring and an erbium metallofullerene,  Dalton Trans., 2022, 51, 10227-10233. https://doi.org/10.1039/D2DT00983H

  12. Yuxi Lu, Chong Zhao, Jie Zhang, Wang Li, Jiayi Liang, Linshan Liu, Yongguang Li, Chunru Wang, Taishan Wang*. A Molecular Brake Hoop for the Motion of Metal Atoms inside Fullerene Cage, Sci. China Chem. 2022, 65(8), 1607–1614. https://doi.org/10.1007/s11426-022-1302-9

  13. Wang Li#, Fayu Qu#, Linshan Liu#, Zhuxia Zhang, Jiayi Liang, Yuxi Lu, Jie Zhang, Lin Wang*, Chunru Wang, Taishan Wang*, A Metallofullertube of Ce2@C100 with Carbon Nanotube Segment: Synthesis, Single-Molecule Conductance and Supramolecular Assembly. Angew. Chem. Int. Ed., 2022, 61, e202116854. https://doi.org/10.1002/anie.202116854.

  14. Mingzhe Nie#, Jiayi Liang#, Chong Zhao, Yuxi Lu, Jie Zhang, Wang Li, Chunru Wang, and Taishan Wang*, Single-Molecule Magnet with Thermally Activated Delayed Fluorescence Based on a Metallofullerene Integrated by Dysprosium and Yttrium Ions, ACS Nano, 2021, 15, 19080–19088. https://doi.org/10.1021/acsnano.1c05105

  15. Wang Li, Chunru Wang and Taishan Wang*, Molecular Structures and Magnetic Properties of Endohedral Metallofullerenes, Chem. Commun.2021, 57, 10317-10326. https://doi.org/10.1039/D1CC04218A

  16. Haibing Meng#, Yongqiang Chai#, Chong Zhao, Mingzhe Nie, Chunru Wang and Taishan Wang*, Covalently bonded two spin centers of paramagnetic metallofullerene dimer, Nano Res., 2021, 14, 4658–4663. https://doi.org/10.1007/s12274-021-3398-8

  17. Chong Zhao, Fupin Liu, Lai Feng, Mingzhe Nie, Yuxi Lu, Jie Zhang, Chunru Wang, and Taishan Wang*, Construction of A Double-Walled Carbon Nanoring, Nanoscale, 2021, 13, 4880-4886. https://doi.org/10.1039/D0NR08931A

  18. Yuxi Lu, Jie Zhang, Chong Zhao, Mingzhe Nie, Chunru Wang*, Taishan Wang*, Zirconium Nitride as a Highly Efficient Nitrogen Source to Synthesize the Metal Nitride Clusterfullerenes. Sci. China Chem.2021, 64, 29-33. https://doi.org/10.1007/s11426-020-9843-2

  19. Mingzhe Nie, Haibing Meng,  Chong Zhao, Yuxi Lu, Jie Zhang, Lai Feng,* Chunru Wang, Taishan Wang*, Crystallographic Evidence and Spin Activation for the Russian-Doll-Type Metallofullerene Sc4C2@C80. Chem. Commun.2020, 56, 10879-10882. https://doi.org/10.1039/D0CC04496B

  20. Chong Zhao, Kai Tan, Mingzhe Nie, Yuxi Lu, Jie Zhang, Chunru Wang, Xin Lu*, and Taishan Wang*. Scandium Tetrahedron Supported by H Anion and CN Pentaanion inside Fullerene C80. Inorg. Chem. 2020, 59, 8284–8290. https://doi.org/10.1021/acs.inorgchem.0c00681

  21. Jie Zhang, Chong Zhao, Haibing Meng, Mingzhe Nie, Qian Li, Junfeng Xiang, Zhuxia Zhang*, Chunru Wang, Taishan Wang*, Size-selective encapsulation of metallofullerenes by [12]Cycloparaphenylene and dissociation using metal-organic framework, Carbon2020161, 694-701. https://doi.org/10.1016/j.carbon.2020.01.096

  22. Mingzhe Nie, Le Yang, Chong Zhao, Haibing Meng, Lai Feng,* Peng Jin,* Chunru Wang* and  Taishan Wang*, A luminescent single-molecule magnet of dimetallofullerene with cage-dependent properties, Nanoscale, 2019, 11, 18612-18618. https://doi.org/10.1039/C9NR05255K

  23. Chong Zhao, Haibing Meng, Mingzhe Nie, Qiang Huang, Pingwu Du,* Chunru Wang*  and  Taishan Wang*, Construction of a short metallofullerene-peapod with a spin probe, Chem. Commun., 2019, 55, 11511-11514. https://doi.org/10.1039/C9CC05220H

  24. Chong Zhao, Mingzhe Nie, Haibing Meng, Chunru Wang,* Taishan Wang,* Synthesis and Structural Studies of Two Paramagnetic Metallofullerenes with Isomeric C72 Cage, Inorg. Chem., 201958, 8162-8168. https://doi.org/10.1021/acs.inorgchem.9b00954

  25. Chong Zhao, Haibing Meng, Mingzhe Nie, Xiang Wang, Zhen-Feng Cai, Ting Chen, Dong Wang, Chunru Wang,* and Taishan Wang,* Supramolecular Complexes of C80-Based Metallofullerenes with [12]Cycloparaphenylene Nanoring and Altered Property in a Confined Space, J. Phys. Chem. C, 2019, 123, 12514-12520. https://doi.org/10.1021/acs.jpcc.9b02451

  26. Mingzhe Nie, Jin Xiong, Chong Zhao, Haibing Meng, Kun Zhang, Yibo Han, Jie Li, Bingwu Wang*, Lai Feng* , Chunru Wang*, Taishan Wang*. Luminescent Single-Molecule Magnet of Metallofullerene DyErScN@Ih-C80, Nano Res., 2019, 12, 1727-1731. https://doi.org/10.1007/s12274-019-2429-1

  27. Along Liu, Mingzhe Nie, Yajuan Hao, Ying Yang, Taishan Wang,* Zdenek Slanina,* Hailin Cong,* Lai Feng,* Chunru Wang, and Filip Uhlik, Ho2O@C74: Ho2O Cluster Expands within a Small Non-IPR Fullerene Cage of C2(13333)-C74, Inorg. Chem., 2019, 58, 4774-4781. https://doi.org/10.1021/acs.inorgchem.8b03145

  28. Haibing Meng, Chong Zhao, Mingzhe Nie, Chunru Wang,* and Taishan Wang,* Changing the Hydrophobic MOF Pores through Encapsulating Fullerene C60 and Metallofullerene Sc3C2@C80, J. Phys. Chem. C, 2019, 123, 6265-6269. https://doi.org/10.1021/acs.jpcc.8b11659

  29. Taishan Wang, Chunru Wang*, Functional Metallofullerene Materials and Their Applications in Nanomedicine, Magnetics and Electronics, Small, 2019, 15, 1901522. https://doi.org/10.1002/smll.201901522

  30. Haibing Meng, Chong Zhao, Mingzhe Nie, Chunru Wang,* and Taishan Wang,* Optically Controlled Molecular Metallofullerene Magnetism via an Azobenzene-Functionalized Metal−Organic Framework, ACS Appl. Mater. Interfaces2018, 10, 32607–32612. https://pubs.acs.org/doi/10.1021/acsami.8b11098

  31. Haibing Meng, Chong Zhaoa, Mingzhe Niea, Chunru Wang* and Taishan Wang*, Triptycene Molecular Rotor Mounted on Metallofullerene Sc3C2@C80 and Their Spin-Rotation Couplings, Nanoscale, 2018, 10, 18119-18123. https://doi.org/10.1039/C8NR06045B

  32. Chong Zhao, Haibing Meng, Mingzhe Nie, Li Jiang, Chunru Wang*, and Taishan Wang*, Anisotropic Paramagnetic Properties of Metallofullerene Confined in a Metal–Organic Framework, J. Phys. Chem. C, 2018, 122, 4635-4640. https://doi.org/10.1021/acs.jpcc.7b11353

  33. Haibing Meng, Chong Zhao, Yongjian Li, Mingzhe Nie, Chunru Wang* and Taishan Wang*, An implanted paramagnetic metallofullerene probe within a metal–organic framework, Nanoscale201810, 3291-3298. https://doi.org/10.1039/C7NR09420E

  34. Chong Zhao, Taishan Wang,* Yongjian Li, Haibing Meng, Mingzhe Nie, Jianlei Tian, Chunru Wang*, Awaking N-hyperfine Couplings in Charged Yttrium Nitride Endohedral Fullerenes, Phys. Chem. Chem. Phys., 2017, 19, 26846-26850. https://doi.org/10.1039/C7CP05444K

  35. Yongjian Li, Taishan Wang,* Chong Zhao, Yu Qin, Haibing Meng, Mingzhe Nie, Li Jiang, Chunru Wang*, Magnetoreception System Constructed by Dysprosium Metallofullerene and Nitroxide Radical, Dalton Trans., 2017, 46, 8938-8941. https://doi.org/10.1039/C7DT01761H

  36. Yongjian Li, Taishan Wang,* Haibing Meng, Chong Zhao, Mingzhe Nie, Li Jiang, Chunru Wang*, Controlling the magnetic properties of dysprosium metallofullerene within metal-organic framework, Dalton Trans., 2016, 45, 19226-19229. https://doi.org/10.1039/C6DT04180A

  37. Jie Li, Taishan Wang,* Yongqiang Feng, Ying Zhang, Mingming Zhen, Chunying Shu, Li Jiang, Yuqing Wang and Chunru Wang*, A water-soluble gadolinium metallofullerenol: facile preparation, magnetic properties and magnetic resonance imaging application, Dalton Trans., 201645, 8696-8699. https://doi.org/10.1039/C6DT00223D

  38. Bo Wu, Yongjian Li, Li Jiang, Chunru Wang, and Taishan Wang*, Spin-Paramagnet Communication between Nitroxide Radical and Metallofullerene, J. Phys. Chem. C2016, 120 , 6252–6255. https://doi.org/10.1039/C7DT01761H

  39. Yongqiang Feng, Taishan Wang*, Yongjian Li, Jie Li, Jingyi Wu, Bo Wu, Li Jiang, Chunru Wang*, Steering Metallofullerene Electron Spin in Porous Metal-Organic Framework, J. Am. Chem. Soc., 2015, 137, 15055-15060. https://doi.org/10.1021/jacs.5b10796

  40. Bo Wu, Taishan Wang*, Yongqiang Feng, Zhuxia Zhang, Li Jiang and Chunru Wang*, Molecular magnetic switch for a metallofullerene. Nat. Commun., 2015, 6:6468. https://doi.org/10.1038/ncomms7468

  41. Yongqiang Feng, Jie Li, Zhuxia Zhang, Bo Wu, Yongjian Li, Li Jiang, Chunru Wang and Taishan Wang*. A highly soluble gadofullerene salt and its magnetic properties. Dalton Trans., 2015, 44, 7781-7784. https://doi.org/10.1039/C5DT00432B

  42. Zhuxia Zhang*, Yang Liu, Peide Han, Shengyi Zhuang, Taishan Wang*, Shuchang Luo and Bingshe Xu. Metallofullerenes Encaging Mixed-Metal Clusters: Synthesis and Structural Studies of GdxHo3−xN@C80 and GdxLu3−xN@C80.  ChemPhysChem2015, 16, 295-298. https://doi.org/10.1002/cphc.201402679

  43. Yongqiang Feng, Taishan Wang*, Junfeng Xiang, Lihua Gan, Bo Wu, Li Jiang and Chunru Wang*. Tuneable dynamics of a scandium nitride cluster inside an Ih-C80 cage. Dalton Trans.201544, 2057-2061. https://doi.org/10.1039/C4DT02892A

  44. Zhuxia Zhang*, Taishan Wang*, Bingshe Xu and Chunru Wang*. Paramagnetic and theoretical study of Y2@C81N: an endohedral azafullerene radical. Dalton Trans.201443, 12871-12875. https://doi.org/10.1039/C4DT01074D

  45. Yongqiang Feng, Taishan Wang*, Jingyi Wu, Zhuxia Zhang, Li Jiang, Hongbin Han* and Chunru Wang*. Electron-spin excitation by implanting hydrogen into metallofullerene: the synthesis and spectroscopic characterization of Sc4C2H@Ih-C80. Chem. Commun.201450, 12166-12168. https://doi.org/10.1039/C4CC05783J

  46. Taishan Wang*, Jingyi Wu* and Yongqiang Feng. Scandium carbide/cyanide alloyed cluster inside fullerene cage: synthesis and structural studies of Sc3(μ3-C2)(μ3-CN)@Ih-C80. Dalton Trans.2014, 43, 16270-16274. https://doi.org/10.1039/C4DT01781A

  47. Taishan Wang, and Chunru Wang*. Endohedral Metallofullerenes Based on Spherical Ih-C80 Cage: Molecular Structures and Paramagnetic Properties. Acc. Chem. Res.2014, 47, 450-458. https://doi.org/10.1021/ar400156z

  48. Xia-Xia Liao, Taishan Wang*, Jizheng Wang, Jin-Cheng Zheng*, Chunru Wang, and Vivian Wing-Wah Yam*. Optoelectronic properties of a fullerene derivative containing adamantane group. ACS Appl. Mater. Interfaces2013, 5, 9579-9584. https://doi.org/10.1021/am402523n

  49. Yongqiang Feng, Taishan Wang*, Jingyi Wu, Lai Feng,* Junfeng Xiang, Yihan Ma, Zhuxia Zhang, Li Jiang, Chunying Shu and Chunru Wang*. Structural and electronic studies of metal carbide clusterfullerene Sc2C2@Cs-C72, Nanoscale20135, 6704-6707. https://doi.org/10.1039/C3NR01739G

  50. Yihan Ma, Taishan Wang*, Jingyi Wu, Yongqiang Feng, Hui Li, Li Jiang, Chunying Shu, and Chunru Wang*. Electron Spin Manipulation via Encaged Cluster: Differing Anion Radicals of Y2@C82-Cs, Y2C2@C82-Cs, and Sc2C2@C82-Cs. J. Phys. Chem. Lett.20134, 464-467. https://doi.org/10.1021/jz3020666

  51. Yongqiang Feng, Taishan Wang*, Jingyi Wu, Yihan Ma, Zhuxia Zhang, Li Jiang, Chunhua Ge*, Chunying Shu and Chunru Wang*. Spin-active metallofullerene stabilized by the core of an N-C moiety, Chem. Commun.201349, 2148-2150. https://doi.org/10.1039/C3CC38445D

  52. Taishan Wang, Xiaxia Liao, Jizheng Wang, Chunru Wang, Mei-Yee Chan and Vivian Wing-Wah Yam*, Indan-C60: from a crystalline molecule to photovoltaic application. Chem. Commun.2013, 49, 9923-9925. https://doi.org/10.1039/C3CC46252H

  53. Yihan Ma, Taishan Wang*, Jingyi Wu, Yongqiang Feng, Li Jiang, Chunying Shu and Chunru Wang*. Susceptible electron spin adhering to an yttrium cluster inside an azafullerene C79N, Chem. Commun.2012, 48, 11570-11572. https://doi.org/10.1039/C2CC36435B

  54. Taishan Wang*, Jingyi Wu, Yongqiang Feng, Yihan Ma, Li Jiang, Chunying Shu and Chunru Wang*, Preparation and ESR study of Sc3C2@C80 bis-addition fulleropyrrolidines. Dalton Trans., 2012, 41, 2567-2570. https://doi.org/10.1039/C2DT12162J

  55. Jingyi Wu, Taishan Wang*, Yihan Ma, Li Jiang, Chunying Shu, and Chunru Wang*. Synthesis, Isolation, Characterization, and Theoretical Studies of Sc3NC@C78-C2, J. Phys. Chem. C2011, 115, 23755-23759. https://doi.org/10.1021/jp2081929

  56. Yihan Ma, Taishan Wang*, Jingyi Wu, Yongqiang Feng, Wei Xu, Li Jiang, Junpeng Zheng, Chunying Shu and Chunru Wang*. Size effect of endohedral cluster on fullerene cage: Preparation and structural studies of Y3N@C78-C2, Nanoscale2011, 3, 4955-4957. https://doi.org/10.1039/C1NR11327E

  57. Taishan Wang, Jingyi Wu, Wei Xu, Junfeng Xiang, Xin Lu, Bao Li, Li Jiang, Chunying Shu* and Chunru Wang*. Spin Divergence Induced by Exohedral Modification: ESR Study of Sc3C2@C80 Fulleropyrrolidine. Angew. Chem. Int. Ed.2010, 49, 1786-1789. https://doi.org/10.1002/anie.200906325

  58. Tai-Shan Wang, Lai Feng, Jing-Yi Wu, Wei Xu, Jun-Feng Xiang, Kai Tan, Yi-Han Ma, Jun-Peng Zheng, Li Jiang, Xin Lu*, Chun-Ying Shu*, and Chun-Ru Wang*. Planar Quinary Cluster inside a Fullerene Cage: Synthesis and Structural Characterizations of Sc3NC@C80-Ih. J. Am. Chem. Soc., 2010, 132, 16362-16364. https://doi.org/10.1021/ja107843b

  59. Tai-Shan Wang, Ning Chen, Jun-Feng Xiang, Bao Li, Jing-Yi Wu, Wei Xu, Li Jiang, Kai Tan, Chun-Ying Shu*, Xin Lu* and Chun-Ru Wang*. Russian-Doll-Type Metal Carbide Endofullerene: Synthesis, Isolation, and Characterization of Sc4C2@C80. J. Am. Chem. Soc.2009, 131, 16646-16647. https://doi.org/10.1021/ja9077842

授权专利:    
  1. 金属氮化物内嵌富勒烯及其制备方法,发明专利ZL201911358274.7授权日:2022-12-7,发明(设计)人:王太山;卢羽茜;王春儒。
  2. 一种或双壁碳纳米环材料及其制备方法与应用,发明专利ZL202010497228.1,授权日:2021-10-22,发明(设计)人:王太山;赵冲;王春儒。
  3. 一种金属有机骨架化合物-金属富勒烯复合物及其制备方法, 发明专利ZL201410652890.4,授权日:2018-03-23,发明(设计)人:王春儒;王太山;冯永强;蒋礼。

  4. 金属富勒烯-光活性MOF复合物、其制备方法与应用以及调控金属富勒烯分子磁性的方法发明专利ZL201810456709.0,授权日:2020-10-9,发明(设计)人:王春儒;王太山;蒙海兵。

  5. 一种内嵌金属富勒烯与环苯撑的稳定复合物及其制备方法,发明专利ZL201710728768.4,授权日:2019-10-25,发明(设计)人: 王春儒;王太山;赵冲。

  6. 一种富勒烯复合物及其在清除烟气中自由基的应用,发明专利ZL201710154105.6,授权日:2019-09-13,发明(设计)人:王春儒;王太山;蒙海兵;蒋礼。

  7. 一种金属富勒烯的光磁功能材料及其制备和应用发明专利ZL201811333094.9,授权日:2020-12-31,发明(设计)人:王春儒;王太山;聂明哲。

  8. 一种由纳米材料和外加辐射源组成的实现肿瘤血管阻断的肿瘤治疗药物,发明专利ZL201410366213.6, 授权日:2015-05-18,发明(设计)人:王春儒;甄明明;王太山;舒春英;张国强;邹头君。

  9. 金属富勒烯单晶纳米颗粒在制备特异性肿瘤血管阻断剂中的应用,发明专利ZL201410365005.4,授权日:2016-05-25,发明(设计)人:王春儒;甄明明;舒春英;王太山;李杰;张国强。

代表性论著:

      
  
  
  
  
  
  
  
  
  
  1. Taishan Wang and Chunru Wang*; Chapter 5 Metal Carbide Clusterfullerenes in Endohedral Fullerenes: From Fundamentals to Applications, Yang, S. F. and Wang, C. R. Eds.; World Scientific Publishing: Singapore, 2014; pp 137-152.
  2. Taishan Wang and Chunru Wang*; Chapter 7 Electron Spin Resonance Studies of Metallofullerenes in Endohedral Fullerenes: Electron Transfer and Spin, Alexey A. Popov Ed.; Springer International Publishing: Switzerland, 2017; pp 159-167

  3. 王春儒,王太山,甄明明。金属富勒烯—从基础到应用[M]。北京:化学工业出版社,2018。