2024
70. Photocatalyst-Free Transformation of C(sp3)−H Bonds to Oxime 2 Ethers via Photoinduced Hydrogen Atom Transfer
Yu-Lian Zhao,§ Xuehong Min,§ Lijing Li, Xiao-Le Han,* Yi Wei,* and Xiao-Qiang Hu*
Org. Lett. 2024, 10.1021/acs.orglett.4c03653
69. Decarboxylative Aminomethylation of Indole-3-carboxylic Acids via Strain Release-Driven Ring Opening of 1,2-Oxazetidines
Zi-Kui Liu, Yun Liu, Xiao-Qiang Hu,* and You-Quan Zou*
Org. Lett. 2024, 26, 8934−8938
68. Modular Assembly of Six-Membered Carbocyclic Spirooxindoles via Peterson Olefination/Michael Addition/C(sp3) Arylation Cascade
Feng-Cheng Jia, Zi-Yi Yuan, Na Luo, Shuang-Xi Gu,* and Xiao-Qiang Hu*
Chin. J. Chem. 2024, 42, 2614-2620
67. Expedient access to polysubstituted acrylamides via strain-release-driven dual phosphine and palladium catalysis
Yu-Xiang Yao, Jing Zhang, Xuehong Min, Lan Qin, Yi Wei, Yang Gao and Xiao-Qiang Hu*
Chem. Commun., 2024, DOI:10.1039/D4CC01968G
66. Metal-Free Cyanation of gem-Difluoroalkenes via Azide-Mediated C−C Double Bond Fragmentation
Hui Wang, Yuan-Yuan He, Jianwei Han, Zhong-Qiang Zhou*, and Xiao-Qiang Hu*
J. Org. Chem. 2024, DOI:10.1021/acs.joc.4c00281
65. Iron-Catalyzed Photochemical Synthesis of Sulfinamides from Aliphatic Hydrocarbons and Sulfinylamines
Guang-Da Xia, Run Li, Long Zhang, Yi Wei*, and Xiao-Qiang Hu*
Org. Lett. 2024, 26, 3703–3708
64. Radical-Mediated Decarboxylative C−C and C−S Couplings of Carboxylic Acids via Iron Photocatalysis
Li-Jing Li, Yi Wei*, Yu-Lian Zhao, Yang Gao, and Xiao-Qiang Hu*
Org. Lett. 2024, 26, 1110–1115
63. Ag-Catalyzed Practical Synthesis of N‑Acyl Anthranilic Acids from Anthranils and Carboxylic Acids
Changshu Wu, Yang Gao*, Yanping Huo, Xianwei Li, Qian Chen, and Xiao-Qiang Hu
J. Org. Chem. 2024, 89, 3150–3160
62. Copper-Catalyzed C(sp)−H Aryl amination Enables Modular Synthesis of Quinolines and 2-Quinolinones
Yang Gao*, Haixia Li, Simin Yang, Yanping Huo, Qian Chen, Xianwei Li, Zhe Wang and Xiao-Qiang Hu *
Sci. China Chem. 2024, 67, 595–603
2023
61. Strain-Release-Driven Phosphine and Rhodium Catalysis: Facile Synthesis of Unsymmetrical Tetrasubstituted Alkenes
Jing Zhang, Zhiyong Hu, Lan Qin, Yang Gao* and Xiao-Qiang Hu *
ACS Catal. 2023, 13, 10425−10434
60. Radical phosphorylation of aliphatic C–H bonds via iron photocatalysis
Guang-Da Xia,§ † Zi-Kui Liu,§ † Yu-Lian Zhao,† Feng-Cheng Jia* and Xiao-Qiang Hu *
Org. Lett. 2023, 25, 5279–5284
59. Tf2O‑Promoted Chemoselective C3 Functionalization of Anthranils with Phenols and Thiophenols
Yupeng Zhao, Yang Gao,* Zhongke Xie, Shuwei Liao, Jiebin Huang, Yanping Huo, Qian Chen,
Xianwei Li and Xiao-Qiang Hu
J. Org. Chem. 2023, 88, 10257–10265
58. Efficient synthesis of quinolones enabled by cheap copper catalysis
Li Yifei，Zhang Jing，Hu Xiao-Qiang*
Journal of South-Central Minzu University（Natural Science Edition）
中南民族大学学报, 2023, Doi：10.20056/j.cnki.ZNMDZK.20230302
57. Merging Ullmann-type cyclization and ring-expansion: a facile assembly of pyrimidinefused
quinazolinones by copper catalysis
Zhen-Wei Sun, Na Luo, Xiang Zhang, Wen-Jun Tuo, Xiao-Qiang Hu * and Feng-Cheng Jia *
Org. Chem. Front. 2023,10, 2002-2006
56. Nitrene transfer reaction with hydroxylamine derivatives
Yang Gao, * Haixia Li, Yupeng Zhao and Xiao-Qiang Hu*
Chem. Commun. 2023, 59, 1889-1906
55. Organo-cyanamides: convenient reagents for catalytic amidation of carboxylic acids
Li-Jing Li, Zhong-Qiang Zhou,* Zi-Kui Liu, Yuan-Yuan He, Feng-Cheng Jia * and Xiao-Qiang Hu*
Chem. Commun. 2023, 59, 438.
54. Practical synthesis of isocoumarins via Rh(III)-catalyzed C–H activation/annulation cascade
Qian-Ci Gao, Yi-Fei Li, Jun Xuan* and Xiao-Qiang Hu*
Beilstein J. Org. Chem. 2023, 19, 100.
2022
53. NiH-Catalyzed Proximal-Selective Hydroamination of Unactivated Alkenes with Anthranils
Yushan Cui, Yang Gao,* Wanxuan Zhao, Yinglin Luo, Haiyi Xie, Yanping Huo,* and Xiao-Qiang Hu*
J. Org. Chem. 2022, 87, 14861.
Yuan-Yuan He, Mei-Shan Zhu, Yang Gao * and Xiao-Qiang Hu*
Chem. Commun., 2022, 58, 11272
51. Deoxygenative gem-difluorovinylation of aliphatic alcohols
Guang-Da Xia, Yuan-Yuan He, Jing Zhang, Zi-Kui Liu, Yang Gao * and Xiao-Qiang Hu*
Chem. Commun. 2022, 58, 6733-6736.
50. Divergent synthesis of fused N-heterocycles via rhodium-catalysed [4+2] cyclization of pyrazolidinones with iodonium ylides
Run Li,# Ye-Xing Hou,#（共同一作） Ji-Hang Xu, Yang Gao* and Xiao-Qiang Hu*
Org. Chem. Front., 2022, 9, 2181-2186
49. Merging strain-release and copper catalysis: the selective ring-opening cross-coupling of 1,2-oxazetidines with boronic acids
Ji-Hang Xu, Zi-Kui Liu, Yan-Liu Tang, Yang Gao* and Xiao-Qiang Hu*
Chem. Commun., 2022, 58, 4180-4183.
48. Practical synthesis of 3-aryl anthranils via an electrophilic aromatic substitution strategy
Yang Gao,* Simin Yang, Minwei She, Jianhong Nie, Yanping Huo, Qian Chen, Xianwei Li and Xiao-Qiang Hu
Chem. Sci., 2022, 13, 2105-2114
2021
47. Strain-release enabled [3+2] annulation of 3-aminooxetanes with simple C-N bonds: facile synthesis of imidazolidines
Jing Zhang, Yi-Fei Li, Feng-Cheng Jia,* Yang Gao and Xiao-Qiang Hu*
Org. Chem. Front., 2021, 8, 6616-6621
46. A transition-metal-free, base-promoted annulation/ring-cleavage/ring-reconstruction cascade reaction: a facile access to N-protection free indole-indenones
Na Luo, Zhen-Wei Sun, Xing-Xin Xu, Xiao-Qiang Hu* and Feng-Cheng Jia*
Org. Chem. Front., 2021, 8, 6591-6596
45. Recent advances in catalytic synthesis of medium-ring lactones and their derivatives
Zi-Kui Liu, Yang Gao* and Xiao-Qiang Hu*
Catal. Sci. Technol., 2021, 11, 6931-6946
44. Nickel-Catalyzed Hydroamination of Olefins with Anthranils
Yang Gao*, Yushan Cui, Yanping Huo, Jinhong Chen, Minwei She, Xianwei Li, Qian Chen, and Xiao-Qiang Hu
J. Org. Chem., 2021, 86, 12107–12118
43. Merging C–H Activation and Strain–Release in Ruthenium-Catalyzed Isoindolinone Synthesis
Xiao-Qiang Hu*, Zi-Kui Liu, Ye-Xing Hou, Ji-Hang Xu, and Yang Gao*
Org. Lett., 2021, 23, 6332–6336
42. Chiral Ru(II)/Carboxylic Acid Catalyzed Asymmetric C—H Functionalization: Synthesis of Sulfur-Stereogenic Sulfoximines
Ye-Xing Hou, Xiao-Qiang Hu*
Chin. J. Org. Chem., 2021, 41, 2920-2922
41. NiH-Catalyzed Hydroamination/Cyclization Cascade: Rapid Access to Quinolines
Yang Gao*, Simin Yang, Yanping Huo, Qian Chen, Xianwei Li, and Xiao-Qiang Hu*
ACS Catal., 2021, 11, 7772–7779
40. Transition-metal-free decarboxylative ipso amination of aryl carboxylic acids
Jing Zhang#, Ye-Xing Hou#（共同一作）, Yan-Liu Tang, Ji-Hang Xu, Zi-Kui Liu, Yang Gao and Xiao-Qiang Hu*
Org. Chem. Front., 2021, 8, 3434-3439
39. Directing group strategies in catalytic sp2 C–H cyanations: scope, mechanism and limitations
Hui-cheng Cheng,* Peng-hu Guo, Jiao-li Ma* and Xiao-Qiang Hu*
Catal. Sci. Technol., 2021, 11, 3308-3325
38. Ruthenium-catalysed C–H/C–N bond activation: facile access to isoindolinones
Xiao-Qiang Hu*, Ye-Xing Hou, Zi-Kui Liu and Yang Gao*
Org. Chem. Front., 2021, 8, 915-921
37. Ru-catalysed C(sp2)–H vinylation/annulation of benzoic acids and alkynes: rapid access to medium-sized lactones
Xiao-Qiang Hu*, Zi-Kui Liu, Ye-Xing Hou, Guodong Zhang* and Yang Gao*
Chem. Commun., 2021, 57, 1113-1116
36. Organic Azides: Versatile Synthons in Transition Metal-Catalyzed C(sp2)−H Amination/Annulation for N-Heterocycle Synthesis
Zi-Kui Liu#, Quan-Qing Zhao,#（共同一作） Yang Gao, Ye-Xing Hou, Xiao-Qiang Hu*
Adv. Synth. Catal., 2021, 2, 411-424
2020
35. Radical chemistry of nitrosoarenes: concepts, synthetic applications and directions
Yang Gao,* Simin Yang, Wenping Xiao, Jianhong Nie and Xiao-Qiang Hu*
Chem. Commun., 2020, 56, 13719-13730
34. Recent Advances in Catalytic Synthesis of Benzosultams
Quan-Qing Zhao and Xiao-Qiang Hu*
Molecules., 2020, 25, 4367
33. Recent Progress on Reductive Coupling of Nitroarenes by Using Organosilanes as Convenient Reductants
Yang Gao*, Simin Yang, Yanping Huo, Xiao-Qiang Hu
Adv. Synth. Catal., 2020, 19, 3971-3986
32. Radical Carbonylative Synthesis of Heterocycles by Visible Light Photoredox Catalysis
Xiao-Qiang Hu* , Zi-Kui Liu and Wen-Jing Xiao*
Catalysts., 2020, 10, 1054
31. Recent advances in phosphoranyl radical-mediated deoxygenative functionalisation
Xiao-Qiang Hu* , Ye-Xing Hou, Zi-Kui Liu and Yang Gao*
Org. Chem. Front., 2020, 7, 2319-2324
30. Copper-Catalyzed Electrophilic Amination of Arylboronic Acids with Anthranils: An Access to N-Aryl-2-aminophenones
Yang Gao*, Simin Yang, Yibiao Li, Yanping Huo*, Zongyi Huang, Zumin Chen, and Xiao-Qiang Hu*
J. Org. Chem., 2020, 85, 10222–10231
29. Single Electron Activation of Aryl Carboxylic Acids
Xiao-Qiang Hu*, Zi-Kui Liu, Ye-Xing Hou, Yang Gao*
iScience., 2020, 23, 101266
28. TFA/TBHP-promoted oxidative cyclisation for the construction of tetracyclic quinazolinones and rutaecarpine
Feng-Cheng Jia,* Tian-Zhi Chen and Xiao-Qiang Hu*
Org. Chem. Front., 2020, 7, 1635-1639
27. Anthranils: versatile building blocks in the construction of C–N bonds and N-heterocycles
Yang Gao,* Jianhong Nie, Yanping Huo and Xiao-Qiang Hu*
Org. Chem. Front., 2020, 7, 1177-1196
26. Rh-Catalyzed C–H Amination/Annulation of Acrylic Acids and Anthranils by Using −COOH as a Deciduous Directing Group: An Access to Diverse Quinolines
Yang Gao*, Jianhong Nie, Yibiao Li, Xianwei Li, Qian Chen, Yanping Huo, and Xiao-Qiang Hu*
Org. Lett. 2020, 22, 2600–2605
25. Rh(III)-Catalyzed Selective ortho-C−H Amination of Benzoic Acids with Anthranils: A Facile Access to Anthranilic Acid Derivatives (AAs)
Yang Gao*, Jianhong Nie, Yibiao Li, Guilan Liao, Yanping Huo, Xiao-Qiang Hu*
ChemCatChem., 2020, 10, 1054
Before South-Central Minzu University
2019
24. Ylide-Functionalized Phosphine (YPhos)–Palladium Catalysts: Selective Monoarylation of Alkyl Ketones with Aryl Chlorides
Xiao-Qiang Hu, Dominik Lichte, Ilja Rodstein, Philip Weber, Ann-Katrin Seitz, Thorsten Scherpf, Viktoria H. Gessner*, and Lukas J. Gooßen*
Org. Lett., 2019, 21, 18, 7558–7562
23. Ring-Opening Ortho-C–H Allylation of Benzoic Acids with Vinylcyclopropanes: Merging Catalytic C–H and C–C Activation Concepts
Zhiyong Hu, Xiao-Qiang Hu, Guodong Zhang, and Lukas J. Gooßen*
Org. Lett.. 2019, 21, 17, 6770–6773
22. Oxygen Heterocycles: Eosin Derivatives
Wen-Jing Xiao*, Xiao-Qiang Hu and Jia-Rong Chen (Book Chapter)
Photoorganocatalysis in Organic Synthesis, pp. 243-286 (2019), https://doi.org/10.1142/9781786346056_0006
2018
21. Synergistic CO2 Mediation and Photocatalysis for α-Alkylation of Primary Aliphatic Amines
Xiao-Qiang Hu , Jia-Rong Chen, Wen-Jing Xiao*
Chem., 2018, 4, 2274-2277
20. Catalytic C–N and C–H Bond Activation: ortho-Allylation of Benzoic Acids with Allyl Amines
Xiao-Qiang Hu, Zhiyong Hu, Guodong Zhang, Nardana Sivendran, and Lukas J. Gooßen*
Org. Lett., 2018, 20, 14, 4337–4340
19. Carboxylate-directed C–H allylation with allyl alcohols or ethers
Xiao-Qiang Hu, Zhiyong Hu, A. Stefania Trita, Guodong Zhang and Lukas J. Gooßen*
Chem. Sci., 2018, 9, 5289-5294
2017
18. Controllable Remote C-H Bond Functionalization by Visible-Light Photocatalysis
Xiao-Qiang Hu, Jia-Rong Chen*, Wen-Jing Xiao*
Angew. Chem. Int. Ed., 2017, 56, 1960-1962
2016
17. Exploration of Visible-Light Photocatalysis in Heterocycle Synthesis and Functionalization: Reaction Design and Beyond
Jia-Rong Chen, Xiao-Qiang Hu, Liang-Qiu Lu, and Wen-Jing Xiao*
Acc. Chem. Res., 2016, 49, 1911–1923
16. Organophotocatalytic Generation of N- and O-Centred Radicals Enables Aerobic Oxyamination and Dioxygenation of Alkenes
Xiao-Qiang Hu, Jun Chen, Jia-Rong Chen*, Dong-Mei Yan, Wen-Jing Xiao
Chem. Eur. J., 2016, 22, 14141-14146
15. Catalytic N-radical cascade reaction of hydrazones by oxidative deprotonation electron transfer and TEMPO mediation
Xiao-Qiang Hu, Xiaotian Qi, Jia-Rong Chen*, Quan-Qing Zhao, Qiang Wei, Yu Lan, Wen-Jing Xiao
Nat. Commun., 2016, 7, 11188
14. Visible light photoredox-controlled reactions of N-radicals and radical ions
Jia-Rong Chen*, Xiao-Qiang Hu, Liang-Qiu Lua and Wen-Jing Xiao*
Chem. Soc. Rev., 2016, 45, 2044-2056
13. A visible-light photocatalytic N-radical cascade of hydrazones for the synthesis of dihydropyrazole-fused benzosultams
Quan-Qing Zhao, Xiao-Qiang Hu, Meng-Nan Yang, Jia-Rong Chen* and Wen-Jing Xiao*
Chem. Commun., 2016, 52, 12749-12752
2015
12. Photocatalytic Radical Trifluoromethylation/Cyclization Cascade: Synthesis of CF3-Containing Pyrazolines and Isoxazolines
Qiang Wei, Jia-Rong Chen*, Xiao-Qiang Hu, Xiao-Chen Yang, Bin Lu, and Wen-Jing Xiao
Org. Lett., 2015, 17, 4464–4467
11. Formal [4+1] Annulation Reactions in the Synthesis of Carbocyclic and Heterocyclic Systems
Jia-Rong Chen*, Xiao-Qiang Hu, Liang-Qiu Lu, and Wen-Jing Xiao*
Chem. Rev., 2015, 115, 5301–5365
10. PhI(OAc)2-mediated functionalisation of unactivated alkenes for the synthesis of pyrazoline and isoxazoline derivatives
Xiao-Qiang Hu, Guoqiang Feng, Jia-Rong Chen,* Dong-Mei Yan, Quan-Qing Zhao, Qiang Wei and Wen-Jing Xiao*
Org. Biomol. Chem., 2015,13, 3457-3461
9. Recent advances in catalytic asymmetric synthesis of pyrazoline and pyrazolidine derivatives
in “Targets in Heterocyclic Synthesis, Chemistry and Properties”, （Book Chapter）
Xiao-Qiang Hu, Jia-Rong Chen,* and Wen-Jing Xiao*
Attanasi, O., Noto, R., Spinelli, D., Eds. Italian Society of Chemistry, 2015, pp 87-112.
2014
8. Photocatalytic Generation of N-Centered Hydrazonyl Radicals: A Strategy for Hydroamination of β,γ-Unsaturated Hydrazones
Xiao-Qiang Hu, Jia-Rong Chen* ,Qiang Wei,Feng-Lei Liu,Qiao-Hui Deng, André M. Beauchemin, Wen-Jing Xiao*
Angew. Chem. Int. Ed., 2014, 53, 12163-12167
7. Efficient Synthesis of Dihydropyrazoles by Halocyclization of β,γ-Unsaturated Hydrazones
Xiao-Qiang Hu,Jia-Rong Chen* ,Qiang Wei,Feng-Lei Liu,Qiao-Hui Deng, You-Quan Zou,Wen-Jing Xiao*
Eur. J. Org. Chem., 2014, 15, 3082-3086
6. Metal-Containing Carbonyl Ylides: Versatile Reactants in Catalytic Enantioselective Cascade Reactions
Jia-Rong Chen*, Xiao-Qiang Hu, and Wen-Jing Xiao*
Angew. Chem. Int. Ed., 2014, 53, 4038-4040
5. Enantioselective organocatalytic oxa-Michael addition of oximes to β-CF3-β-disubstituted nitroalkenes: efficient synthesis of β-amino-α-trifluoromethyl alcohols
Feng-Lei Liu, Jia-Rong Chen,* Bin Feng, Xiao-Qiang Hu, Li-Hua Ye, Liang-Qiu Lu and Wen-Jing Xiao*
Org. Biomol. Chem., 2014, 12, 1057-1060
2013
4. Copper-Catalyzed Enantioselective Inverse Electron-Demand Hetero-Diels–Alder Reactions of Diazadienes with Enol Ethers: Efficient Synthesis of Chiral Pyridazines
Shuang Gao, Jia-Rong Chen, Xiao-Qiang Hu, Hong-Gang Chen, Liang-Qiu Lu, Wen-Jing Xiao*
Adv. Synth. Catal., 2013, 335, 3539-3544
3. Formal [4+1] cycloaddition of camphor-derived sulfonium salts with aldimines: enantioselective synthesis of 2,3-dihydrobenzofurans
Ying Cheng, Xiao-Qiang Hu, Shuang Gao, Liang-Qiu Lu, Jia-Rong Chen, Wen-Jing Xiao*
Tetrahedron, 2013, 69, 3810-3816
2. [4+3] Cycloaddition of in situ generated azoalkenes with C,N-cyclic azomethineimines: efficient synthesis of tetrazepine derivatives
Xiao-Qiang Hu, Jia-Rong Chen,* Shuang Gao, Bin Feng, Liang-Qiu Lu and Wen-Jing Xiao*
Chem. Commun., 2013, 49, 7905-7907
2012
1. Visible light induced intermolecular [2+2]-cycloaddition reactions of 3-ylideneoxindoles through energy transfer pathway
You-Quan Zou, Shu-Wen Duan, Xiang-Gao Meng, Xiao-Qiang Hu, Shuang Gao, Jia-Rong Chen, Wen-Jing Xiao*
Tetrahedron, 2012, 68, 6914-6919
