Publications (corresponding author papers only):
2023
90. Asymmetric N-Alkylation of 1H-Indoles via Carbene Insertion Reaction. Peng, Q.; Huang, M.; Xu, G.; Zhu, Y.; Shao, Y.; Tang, S.; Zhang, X.; Sun, J. Angew. Chem. Int. Ed. 2023, e202313091.
89. Phosphoric Acid-Catalyzed Asymmetric N-propargylation of Pyridazinones and 2-Pyridones. Li, Q.; Chen, T.; Sun, J. Org. Chem. Front. 2023, 10, 4665.
88. Iridium-Catalyzed C5-Regioselective Esterification of Dienyl Alcohols with Carboxylic Acids. Chen, J.; Zhang, Y.; Tang, S.; Shao, Y.; Sun, J. Eur. J. Org. Chem. 2023, 26, e202300605.
87. Gold-Catalyzed Tandem Reaction of o-Alkynylphenols with Diazo Compounds: Access to 2,3-Disubstituted Benzofurans. Huang, T.; Shao, Y.; Tang, S.; Sun, J. Org. Biomol. Chem. 2023, 21, 5752.
86. Atroposelective Synthesis of N-N Axially Chiral Bipyrroles via Rhodium-Catalyzed C-H Insertion Reaction. Wang, C.; Sun, J. Org. Lett. 2023, 25, 4808.
85. Iri;dium-Catlayzed Diastereo- and Enantioselective [4+1] Cycloaddition of Hydroxyallyl Anilines with Sulfoxonium Ylides. He, C.; Tang, Y.; Tang, S.; Sun, J. Org. Lett. 2023, 25, 4621.
84. Rhodium-Catalyzed Dearomative 1,4-Acyl Rearrangement of 2-Oxypyridines with Hydrazones: Access to N-Substituted 2-Pyridones. Ni, Y.; Sun, J. Eur. J. Org. Chem. 2023, 26, e202300368.
83. Copper-Catalyzed Reaction of Benzoxazinanones with Sulfilimines: Access to 2-Ethynyl-benzoimidazoles via an Abnormal Skeletal Rearrangement. Zhang, T.; Ni, Y.; Sun, J. Org. Biomol. Chem. 2023, 21, 4583.
82. Access to Chiral Tetrahydroquinazolines/1,3-Benzoxazines via Iridium-Catalyzed Asymmetric [4+2]-Cycloaddition. Tang, S.; Cheng, Z.; Zhang, P.; Shao, Y.; Sun, J. Org. Lett. 2023, 25, 3639.
81. Catalytic Aminomethylative Etherification of N-Allenamides with N,O-Acetals Enabled by Lewis/Bonsed Acid Catalysis. Zhang, T.; Ji, D.; Sun, J. Org. Biomol. Chem. 2023, 21, 3340.
80. Rhodium-Catalyzed N-Arylation of 2-Pyridones Enabled by 1,6-Acyl Migratory Rearrangement of 2-Oxypyridines. Su, J.; Yan, Z.; Sun, J. Org. Lett. 2023, 25, 1974.
79. Forming All-Carbon Quaternary Centers by Geminal Difunctionalization of Diazo Compounds with N,N-Substituted Anilines and Allylic Carbonates. Chen, Q.; Huang, T.; Shao, Y.;* Tang, S.; Sun, J.* J. Org. Chem. 2023, 88, 3308.
78. Copper-catalyzed dearomative 1,4-carboxylate rearrangement of 2-carbonateindoles. Zhu, Y.; Shao, Y.; Tang, S.; Sun, J.* Org. Chem. Front. 2023, 10, 99.
2022
77. Rhodium-Catalyzed Formal C_O Bond Insertion and Sequential2 Acyl 1,4-N-to-O Migratory Rearrangement. Li, Q.; He, C.; Su, J.; Shao, Y.; Tang, S.; Sun, J.* J. Org. Chem. 2022, 87, 16937-16940.
76. Atroposelective Synthesis of N-Arylindoles via Enantioselective N-H Bond Insertion. Niu, C.; Zhou, Y.; Chen, Q.; Zhu, Y.; Tang, S.; Yu, Z.;* Sun, J.* Org. Lett. 2022, 24, 7428-7433.
75. Atroposelective Synthesis of Axially Chiral C2-Arylindoles via Rhodium-Catalyzed Asymmetric C-H Bond Insertion. Liu, J.; Li, Q.; Shao, Y.; Sun, J.*Org. Lett. 2022, 24, 4670-4674.
74. Enyne Diketones: A New Classes Substrate in Asymmetric Nazarov Cyclization for Construction of Chiral Allene Cyclopentenone. Tang, S.;* Zhang, P.; Shao, Y.; Sun, J.* Nat. Commun. 2022,13, 3146.
73. Diastereoselective Formation of b-Lactams via a Three-Component Reaction. Shang, Y.;* Tian, S.; Zhu, J.; Tang, S.; Sun, J.* New. J. Chem. 2022, 46, 9989-9993.
72. Asymmetric Arylation of Diazoesters with Anisoles Enabled by Cooperative Gold and Phosphoric Acid Catalysis. Xu, G.;† Huang, M.;† Zhang, T.; Shao, Y.; Tang, S.; Cao, H.; Zhang, X.;* Sun, J.* Org. Lett. 2022, 24, 2809-2814.
71. Catalytic Transformation of 2-Pyridones by Rhodium Mediated Carbene Transfer. Su, J.; Li, Q.; Shao, Y.; Sun, J.* Org. Lett. 2022, 24, 1637-1641.
70. Rhodium-Catalyzed Dearomative Rearrangement of 2-Oxypyridines with Cyclopropenes: Access to N-Alkylated 2-Pyridones. Cui, H.; Xu, G.; Zhu, J.; Sun, J.* Org. Chem. Front. 2022, 9, 1295-1299.
2021
69. [4+3]-Cycloaddition Reaction of Sulfilimines with Cyclobutenones: Access to Benzazepinones. Xie, X.; Sun, J.* Org. Lett. 2021, 23, 8921-8925.
68. Construction of C-C Axial Chirality via Asymmetric Carbene Insertion into Arene C-H Bonds. Li, Z.;† Chen, Y.;† Wang, C.; Xu, G.; Shao, Y.; Zhang, X.;* Tang, S.; Sun, J.* Angew. Chem. Int. Ed. 2021, 60, 25714-25718. (Hot paper)
67. Iridium-Catalyzed Regio- and Enantioselective Allylic Esterification of Secondary Allylic Alcohols with Carboxylic Acids. Tang, S.;* Zhang, P.; Wang, C.; Shao, Y.; Sun, J.* Chem. Commun. 2021, 57, 11080-11083.
66. Asymmetric [3 + 1]-Cycloaddition Reaction via Diazo Discrimination. Xu, Y.; Wang, Z.; Sun, J.* Org. Lett. 2021, 23, 7613-7617.
65. Copper-Catalyzed Tandem Cross-Coupling and Alkynylogous Aldol Reaction: Access to Chiral Exocyclic a-Allenol. Xu, G.; Wang, Z.; Shao, Y.; Sun, J.* Org. Lett. 2021, 23, 5175-5179.
64. Chemo- and Enantioselective Insertion of Furyl Carbene into the N-H Bond of 2-Pyridones. Wang K.; † Liu, Z.;† Xu, G.; Shao, Y.; Tang, S.; Chen, P.; Zhang, X.;* Sun, J.*. Angew. Chem. Int. Ed. 2021, 60, 16942-16946.
63. Copper-Catalyzed 1,1-Boroalkylation of Terminal Alkynes: Access toAlkenylboronates via a Three-Component Reaction. Li, Z.; Sun, J.* Org. Lett. 2021, 23, 3706-3711.
62. Ruthenium-Catalyzed Chemoselective N−H Bond Insertion Reactions of 2‑Pyridones/7-Azaindoles with Sulfoxonium Ylides, Liu, X.; Shao, Y.; Sun, J.* Org. Lett. 2021, 23, 1038-1043.
61. Gold-Catalyzed Cascade Cyclization and 1,3-Difunctionalization To Access Polysubstituted Furans, Xu, Y.; Sun, J.* Org. Lett. 2021, 23, 853-857.
60. Scandium-catalyzed highly selective N2-alkylation of benzotriazoles with cyclohexanones, Tang, S.;* Yu, J.; Shao, Y.; Sun, J.* Org. Chem. Front. 2021, 8, 278-282.
2020
59. Dearomative Migratory Rearrangement of 2-Oxypyridines Enabled by α-Imino Rhodium Carbene, Xu, G.; Shao, Y.; Tang, S.; Chen, Q.;* Sun, J.* Org. Lett. 2020, 22, 9303-9307.
58. Site-Selective Functionalization of 7-Azaindoles via Carbene Transfer and Isolation of N-Aromatic Zwitterions, Liu, J.; Xu, G.; Tang, S.; Chen, Q.;* Sun, J.* Org. Lett. 2020, 22, 9376-9380.
57. Forming All-Carbon Quaternary Stereocenters by Organocatalytic Aminomethylation: Concise Access to β2,2-Amino Acids, Wang, K.; Yu, J.; Shao, Y.; Tang, S.; Sun, J.* Angew. Chem. Int. Ed. 2020, 59, 23516-23520.
56. Gold-Catalyzed Intermolecular Formal [4+2+2]-Cycloaddition of Anthranils with Allenamides, Wang, C.; Xu, G.; Shao, Y.; Tang, S.; Sun, J.* Org. Lett. 2020, 22, 5990-5994.
2019
55. Gold-Catalyzed Highly Diastereoselective Oxy-Propargylamination of Allenamides with C-Alkynyl N-Boc N,O-Acetals, Chen, L.; Yu, J.; Tang, S.; Shao, Y.; Sun, J.* Org. Lett. 2019, 21, 9050-9054.
54. Copper-Catalyzed Amino-oxymethylation of Ynamides with N,O-Acetals, Yu, J.; Xu, G.; Tang, S.; Shao, Y.; Sun, J.* Org. Lett. 2019, 21, 9076-9079.
53. Catalyst-Controlled Selective Alkylation/Cyclopropanation of Indoles with Vinyl Diazoesters, Wang, Z.; Xu, G.; Tang, S.; Shao, Y.; Sun, J.* Org. Lett. 2019, 21, 8488-8491.
52. Ir-Catalyzed Regiocontrolled Allylic Amination of Di-/Trienyl Allylic Alcohols with Secondary Amines, Tang, S.; Li, Z.; Shao, Y.; Sun, J.* Org. Lett. 2019, 21, 7228-7232.
51. B(C6F5)3-Catalyzed Formal (4+1)-Annulation of ortho-Quinone Methides with Diazoacetates: Access to 2,3-Dihydrobenzofurans, Xu, G.; Tang, S.; Shao, Y.; Sun, J.* Chem. Commun. 2019, 55, 9096-9099.
50. Rhodium-Catalyzed C=N Bond Formation through a Rebound Hydrolysis Mechanism and Application in β-lactam Synthesis, Chen, L.;† Zhang, L.;† Shao, Y.; Xu, G.; Zhang, X.;* Tang, S.; Sun, J.* Org. Lett. 2019, 21, 4124-4127.
49. Stereoselective Synthesis of Fully Substituted β-Lactams via Metal-Organo Relay Catalysis, Chen, L.; Wang, K.; Shao, Y.; Sun, J.* Org. Lett. 2019, 21, 3804-3807.
48. Copper-Catalyzed Oxy-aminomethylation of Diazo Compounds with N,O-Acetals, Yu, J.;† Chen, L.;† Sun, J.* Org. Lett. 2019, 21, 1664-1667.
47. Access to N-Substituted 2-Pyridones by Catalytic Intermolecular Dearomatization and 1,4-Acyl Transfer, Xu, G.;† Chen, P.;† Liu, P.; Tang, S.; Zhang, X.;* Sun, J.* Angew. Chem. Int. Ed. 2019, 58, 1980-1984. (VIP)
2018
46. Tandem Reaction of Allenoate Formation and Cyclization: Divergent Synthesis of Four to Six-Membered Heterocycles, Ji, D.; Liu, K. Sun, J.* Org. Lett. 2018, 20, 7708-7011.
45. Rhodium-Catalyzed Regioselective N2-Alkylation of Benzotriazoles with Diazo Compounds/Enynones via a Nonclassical Pathway, Wang, K.;† Chen, P.;† Ji, D.; Zhang, X.;* Xu, G.; Sun, J.* Angew. Chem. Int. Ed. 2018, 57, 12489-12493.
44. Asymmetric [4+2]-Cycloaddtion of Copper-Allenylidenes with Hexahydro-1,3,5-Triazines: Access to Chiral Tetrahydroquinazolines, Ji, D.; Wang, C.; Sun, J.* Org. Lett. 2018, 20, 3710-3713.
43. Rhodium-Catalyzed Asymmetric Dearomative [4+3]-Cycloaddition of Vinylindoles with Vinyldiazoacetates: Access to Cyclohepta[b]indoles, Xu, G.; Chen, L.; Sun, J.* Org. Lett. 2018, 20, 3408-3412.
42. Gold-Catalyzed Friedel-Crafts C-H Alkylation of Indolines and Sequential Oxidative Aromatization: Access to C5-Functionalized Indoles, Zhang, W.; Xu, G.; Qiu, L.; Sun, J.* Org. Biomol. Chem. 2018, 16, 3889.
41. [3+2]-Cycloaddition of Azaoxyallyl Cations with Hexahydro-1,3,5-Triazines: Access to 4-Imidazolidinones, Ji, D.; Sun, J.* Org. Lett. 2018, 20, 2745-2748.
40. Lewis Acid-Mediated Room-Temperature Cascade Reaction of 3‑Hydroxyisoindolin-1-one with Alkyne, Li, J.;* Li, Y.; Wang, Z.; Bian, Y.; Bai, S.; Liu, L.; Sun, J.* J. Org. Chem. 2018, 83, 4257.
39. Catalyst-Free Synthesis of Tetrahydropyrimidines via Formal [3+3]-Cycloaddition of Imines with 1,3,5-Hexahydro-1,3,5-Triazines, Chen, L.; Liu, K.; Sun, J.* RSC Adv. 2018, 8, 5532.
38. Gold-Catalyzed Stereoselective Dearomatization/Metal-Free Aerobic Oxidation: Access to 3-Substituted Indolines/Oxindoles, Liu, K.; Xu, G.; Sun, J.* Chem. Sci. 2018, 9, 634-639.
37. Gold-Catalyzed Controllable C2-Functionalization of Benzofurans with Aryl Diazoester, Xu, G.; Liu, K.; Sun, J.* Org. Lett. 2018, 20, 72-75.
2017
36. Divergent Synthesis of Fused Tricyclic Compounds via a Tandem Reaction from Alkynyl-cyclohexadienones and Diazoesters, Xu, G.; Liu, K.; Sun, J.* Org. Lett. 2017, 19, 6440-6443.
35. Gold-Catalyzed [2+2+2+2]-Cycloaddition of 1,3,5-Hexahydro-1,3,5-triazines with Alkoxyallenes, Peng, S.; Ji, D.; Sun, J.* Chem. Commun. 2017, 53, 12770-12773.
34. Iron-Catalyzed Intermolecular Cycloaddition of Diazo Surrogates with Hexahydro-1,3,5-Triazines, Liu, P.; Zhu, C.; Xu, G.; Sun, J.* Org. Biomol. Chem. 2017, 15, 7743.
33. Stereoselective Synthesis of Tetrasubstituted Furylalkenes via Gold-Catalyzed Cross-Coupling of Enynones with Diazo Compounds, Liu, P.; Sun, J.* Org. Lett. 2017, 19, 3482-3485.
32. Synthesis of seven-membered heterocycles via copper-catalyzed cross-coupling of terminal alkynes with diazo compounds and sequential Michael addition, Yan, S.; Cao, S.; Sun, J.* Org. Biomol. Chem. 2017, 15, 5272.
31. Synthesis of Six-Membered Carbo-/Heterocycles by Copper-Catalyzed Cascade Reaction of Alkynes and Diazo Compounds, Min, J.; Xu, G.; Sun, J.* J. Org. Chem. 2017, 82, 5492.
30. Controlled Selective Synthesis of Dihydropyrans through Tandem Reaction of Alkynes with Diazo Compounds, Min, J.; Xu, G.; Sun, J.* Chem. Commun. 2017, 53, 4350-4353.
29. Metal-Free [2+1+2]-Cycloaddition of Tosylhydrazones with Hexahydro-1,3,5-triazines to Form Imidazolidines, Liu, P.; Xu, G.; Sun, J.* Org. Lett. 2017, 19, 1858-1861.
28. Gold/Silver-Catalyzed Controllable Regioselective Vinylcarbene Insertion into O-H Bonds, Xu, G.; Liu, K.; Dai, Z.*; Sun, J.* Org. Biomol. Chem. 2017, 15, 2345.
27. Gold-Catalyzed Highly Regio- and Enantioselective Vinylcarbene Insertion into O-H Bonds of 2-Pyridones, Huang, D.; Xu, G.; Peng, S.; Sun, J.* Chem. Commun. 2017, 53, 3197-3200.
26. Gold-Catalyzed Regiodivergent [2 + 2 + 2]-Cycloadditions of Allenes with Triazines, Peng, S.; Cao, S.; Sun, J.* Org. Lett. 2017, 19, 524-527.
25. Gold-catalyzed sequential annulations towards 3,4-fused bi/tri-cyclic furans involving a [3+2+2]-cycloaddition, Liu, S.; Yang, P.; Peng, S.; Zhu, C.; Cao, S.; Li, J.; Sun, J.* Chem. Commun. 2017, 53, 1152-1155.
24. Gd(III)-induced Supramolecular Hydrogelation with Enhanced Magnetic Resonance Performance for Enzyme Detection, Hua, Y.; Pu, G.; Ou, C.; Zhang, X.; Wang, L.; Sun, J.;* Yang, Z.;* Chen, M.* Sci. Rep. 2017, 7, 40172.
2016
23. Gold-Catalyzed Formal [4+1]/[4+3]-Cycloadditions of Diazo Esters with Triazines, Zhu, C.; Xu, G.; Sun, J.* Angew. Chem. Int. Ed. 2016, 55, 11868-11871.
2015
22. Rhodium-Catalyzed Multiple C-H Bond Activation and Oxidative Annulation: Application on the Synthesis of Polyheteromatic Compounds, Peng, S.; Liu, S.; Zhang, S.; Cao, S.; Sun, J.* Org. Lett. 2015, 17, 5032-5035.
21. Stereodivergent Synthesis of N-Heterocycles via Catalyst-Controlled, Activity-Directed Tandem Annulation of Diazo Compounds with Amino-Alkynes, Liu, K.; Zhu, C.; Min, J.; Peng, S.; Xu, G.; Sun, J.* Angew. Chem. Int. Ed. 2015, 54, 12962-12967.
20. Copper-Catalyzed Intermolecular Coupling of Diazo Compounds: An Efficient and Practical Approach towards Tetra-Substituted Olefins, Zhu, C.; Xu, G.; Peng, S.; Li, J.; Sun, J.* Org. Lett. 2015, 17, 4244-4247.
19. Base-Promoted/Gold-Catalyzed Intramolecular Highly Selective and Controllable De-tosylative Cyclization, Zhu, C.; Qiu, L.; Xu, G.; Li, J.; Sun, J.* Chem. Eur. J. 2015, 21, 12871-12875.
18. Gold-Catalyzed Intramolecular Diazo Coupling: An Efficient Macrocyclization towards Cyclic Olefins, Zhu, C.; Xu, G.; Liu, K.; Qiu, L.; Peng, S.; Sun, J.* Chem. Commun. 2015, 51, 12768-12770.
17. An Efficient Synthesis of Isoquinolines via Rhodium-Catalyzed Direct C-H Functionalization of Arylhydrazines, Zhang, S.; Huang, D.; Xu, G.; Cao, S.; Wang, R.; Peng, S.; Sun, J.* Org. Biomol. Chem. 2015, 13, 7920-7923.
16. Realized C-H Functionalization of Aryldiazo Compounds via Rhodium Relay Catalysis, Qiu, L.; Huang, D.; Xu, G.; Dai, Z.; Sun, J.* Org. Lett. 2015, 17, 1810-1813.
15. Copper-catalyzed 1,3-dipolar cycloaddition of methyleneindolinones and N,N’-cyclic azomethine imines, Zhang, D.; Zhang, D.; Xu, G.; Sun, J.* Chin. Chem. Lett. 2015, 26, 301-303.
14. Gold(I)-Catalyzed Diazo Cross-Coupling: A Selective and Ligand-Controlled Denitrogenation/Cyclization Cascade, Xu, G.; Zhu, C.; Gu, W.; Li, J.; Sun, J.* Angew. Chem. Int. Ed. 2015, 54, 883-887.
2014
13. Gold(I)-Catalyzed Diazo Coupling: Strategy toward Alkene Formation and Tandem Benzannulation, Zhang, D.; Xu, G.; Ding, D.; Zhu, C.; Li, J.; Sun, J.* Angew. Chem. Int. Ed. 2014, 53, 11070-11074.
12. A supramolecular hydrogel for the delivery of bortezomib, Pu, G.; Ren, C.; Li, D.; Wang, L.;* Sun, J.* RSC Adv. 2014, 4, 50145-50147.
11. Metal-Free, Visible-Light Photoredox Catalysis: Transformation of Arylmethyl Bromides to Alcohols and Aldehyde, Li, J.; Wang, H.; Liu, L.; Sun, J.* RSC Adv. 2014, 4, 49974-49978.
10. A Highly Efficient DBU-Catalyzed Green Synthesis of Spirooxindole, Wang, L.; Zhang, D.; Li, J.; Xu, G.; Sun, J.* RSC Adv. 2014, 4, 44193-44196.
9. Photo-assisted Multi-Component Reaction (MCR): A New Entry to 2-Pyrimidine-thiones, Guo, H.; Zhu, C.; Li, J.; Xu, G.; Sun, J.* Adv. Synth. Catal. 2014, 356, 2801-2806.
8. When Aryldiazonium Salts Meet Vinyl Diazoacetates: A Cobalt-Catalyzed Regiospecific Synthesis of N-Arylpyrazoles, Guo, H.; Zhang, D.; Zhu, C.; Li, J.; Xu, G.; Sun, J.* Org. Lett. 2014, 16, 3110-3113.
7. Pd-Catalyzed Cascade Reaction of N-H Insertion and Oxidative Dehydrogenative Aromatization: A New Entry to 2-Amino-phenols, Ding, D.; Lv, X.; Li, J.; Qiu, L.; Xu, G.; Sun, J.* Org. Biomol. Chem. 2014, 12, 4084-4088.
6. Copper-catalyzed N-H Insertion and Oxidative Aromatization Cascade: Facile Synthesis of 2-Arylamino-Phenols, Ding, D.; Lv, X.; Li, J.; Xu, G.; Ma, B.; Sun, J.* Chem. Asian. J. 2014, 9, 1539-1542.
5. Palladium Catalyzed N-H Bond Insertion and Intramolecular Cyclization Cascade: The Divergent Synthesis of Heterocyclics, Ding, D.; Liu, G.; Xu, G.; Li, J.; Wang, G.; Sun, J.* Org. Biomol. Chem. 2014, 12, 2533-2537.
4. Copper-Catalyzed Annulation of α-Substituted Diazoacetates with 2-Ethynylanilines: The Direct Synthesis of C2-Functionalized Indoles, Liu, G.; Xu, G.; Li, J.; Ding, D.; Sun, J.* Org. Biomol. Chem. 2014, 12, 1387-1390.
2013
3. CuI-catalyzed cross-coupling of diazoacetamide with terminal alkynes: an approach to synthesizing substituted dienamides and 3-butynamides, Li, J.; Ding, D.; Liu, L.; Sun, J.* RSC Adv. 2013, 3, 21260-21266.
2. Palladium-catalyzed carbenoid based N–H bond insertions: application to the synthesis of chiral α-amino esters, Liu, G.; Li, J.; Qiu, L.; Liu, L.; Xu, G.; Ma, B.; Sun, J.* Org. Biomol. Chem. 2013, 11, 5998-6002.
1. A highly enantioselective Darzens reaction between diazoacetamides and aldehydes catalyzed by a (+)-pinanediol–Ti(OiPr)4 system, Liu, G.; Zhang, D.; Li, J.; Xu, G.; Sun, J.* Org. Biomol. Chem. 2013, 11, 900-904.
