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成果及论文

229.“Copper-catalysed asymmetric hydroboration of alkenes with 1,2-benzazaborines to access chiral naphthalene isosteres”, Wanlan Su, Jide Zhu, Yu Chen, Xu Zhang, Weihua Qiu, Kai Yang*, Peiyuan Yu* and Qiuling Song*Nat. Chem. 202416, 1312-1319. doi: https://doi.org/10.1038/s41557-024-01505-0

228. “Ni-catalysed assembly of axially chiral alkenes from alkynyl tetracoordinate borons via 1,3-metallate shift”, Xingxing MaMengwei TanLuo LiZihao ZhongPuhui LiJinchao Liang and Qiuling Song *Nat. Chem. 202416, 42–53  doi: https://doi.org/10.1038/s41557-023-01396-7.

227.“Enantioselective construction of C-B axially chiral alkenylborons by nickel-catalyzed radical relayed reductive coupling”, Weihua QiuRencai TaoYong HeYao ZhouKai Yang* and Qiuling Song*Nat. Commun. 15, 10432 (2024).doi: https://doi.org/10.1038/s41467-024-54597-0

226.“Pd-Catalyzed B–H Aryl/Alkenylation of 1,2-Azaborines”, Zhen Zhang, Dandan Jiang, Peiwen Su, Kai Yang*, Peiyuan YuQiuling Song*, ACS Catal. 2024, 14, 16996−17003.doi: https://doi.org/10.1021/acscatal.4c04576

225.“Interception of Alkynyl Tetracoordinate Borons with Sulfur Electrophiles beyond the Zweifel Pathway”, Xingxing MaYuanbiao AnLuo LiMeihui CaiQiuling Song*, Angew. Chem. Int. Ed. 2024, e202416579. doi: https://doi.org/10.1002/anie.202416579

224.“Cu-catalyzed enantioselectivee assembly of axially chiral allylic boronates”, Shuai Wang, Jianbo Liu, Wenyue Ma, Qiuling Song*, Sci. China Chem., 2024, doi: https://doi.org/10.1007/s11426-024-2315-1

223.“Photo-induced decarboxylative C-S bond formation to access sterically hindered unsymmetric S-alkyl thiosulfonates and SS-alkyl thiosulfonates”, Yu Guo, Guotao Lin, Mengjie Zhang, Jian Xu and Qiuling Song*, Nat. Commun. (2024) 15,7313, doi: https://doi.org/10.1038/s41467-024-51334-5  

222.“Fluorinating electrophilic interception in the oxidation or protonation of alkynyl tetracoordinate borons”, Xingxing Ma, Zihao Zhong, Qiuling Song*, Chem, 2024, 11, 1–15, doi: https://doi.org/10.1016/j.chempr.2024.07.034

221.“Copper- and Palladium-Cocatalyzed Chemo-, Regio-, Stereo-, and Atroposelective Arylboration of 1,3-Enynes”, Wangyang Li, Haohua Chen, Yanping Zheng, Yong Lu, Jinhui Xie, Shanglin Chen, Yu Lan*, and Qiuling Song* ACS Catal. 2024, 14, 11318−11331, doi: https://doi.org/10.1021/acscatal.4c03301

220.“Chemo-, regio- and stereoselective access to polysubstituted 1,3-dienes via Nickel-catalyzed four-component reactions”, Shanglin Chen, Ya-Nan Wang, Jinhui Xie, Wangyang Li , Mingxing Ye, Xingxing Ma, Kai Yang, Shijun Li, Yu Lan* and Qiuling Song*, Nat. Commun. (202415, 5479 doi: https://doi.org/10.1038/s41467-024-49870-1


219.“Difluorocarbene-induced [1,2]- and [2,3] rearrangement of tertiary amines”, Jianke Su, Yu Guo, Chengbo Li and Qiuling Song*, Nat Commun 15, 4794 (2024). doi: https://doi.org/10.1038/s41467-024-49054-x

218.“Unlocking Diverse π‑Bond Enrichment Frameworks by the Synthesis and Conversion of Boronated Phenyldiethynylethylenes”, Jinhui Xie, Wangyang Li, Yong Lu, Yanping Zheng, Yanying Huang, Shanglin Chen, and Qiuling Song*, J. Am. Chem. Soc. 2024, 146, 10167–10176, doi: https://doi.org/10.1021/jacs.4c01989.

217.“N -Heterocycle-Editing to Access Fused-BN-Heterocycles via Ring-Opening/C-H Borylation/Reductive C-B Bond Formation”, Xu Zhang, Wanlan Su, Huosheng Guo, Pengyuan Fang, Kai Yang* and Qiuling Song*Angew. Chem. Int. Ed2024, 63, e202318613, doi: https://doi.org/10.1002/anie.202318613

216.“Palladium-Catalyzed Difluorocarbene Transfer Enabled Divergent Synthesis of γ-Butenolides and Ynones from Iodobenzene and Terminal Alkynes”, Heyun Sheng, Zhiwei Chen, and Qiuling Song*, J. Am. Chem. Soc. 2024, 146, 1722–1731https://doi.org/10.1021/jacs.3c13044

215.“Enantio- and regioselective [2 + 2 + 2] cycloaddition of BN-diynes for construction of C-B axial chirality”,Hao Wang, Bolin Qiao, Jide Zhu, Huosheng Guo, Zhen Zhang, Kai Yang*, Shi-Jun Li, Yu Lan*, Qiuling Song*Chem, 2024 10, 317-329, doi: http://doi.org/10.1016/j.chempr.2023.09.017

214.“Enantioselective copper-catalyzed B–H bond insertion reaction of α-diazo phosphonates to access chiral α-boryl phosphonates”, Longlong Li, Kui Yu, Hejun An, Xinping Cai and Qiuling Song*Chem. Sci., 2024,15, 7130-7135, doi: https://doi.org/10.1039/d4sc01271b.

213.“Remote Boryl and Alkenyl Radical Migration of Olefin-bearing Aryl Bromides”, Chaokun Li, Nan Chen, Tangfeng Yao, Chenchen Zhao, Shangteng Liao and Qiuling Song*, CCS Chem2024; 0: 1-14 doi: https://doi.org/10.31635/ccschem.024.202404075


212.“Brønsted acid-mediated selective α-alkenylation of 3,4-dihydro-2H-pyrans”, Nan Chen, Chaokun Li, Shangteng Liao, Jinglong Chen,* Xingxing Ma and Qiuling Song*, Org. Chem. Front., 2024, doi: https://doi.org/10.1039/D4QO00541D

211.“Difluorocarbene Enables Access to 2,2-Difluorohydrobenzofurans and 2-Fluorobenzofurans from ortho-Vinylphenols”, Yahao Wang, Shuai Wang, Jianbo Liu, and Qiuling Song*, Org. Lett. 2024, 263744−3749. doi: https://doi.org/10.1021/acs.orglett.4c00779.   

210.“Highly Stereoselective Synthesis of Multisubstituted Olefins from Alkynyl Tetracoordinate Borons and Iodonium Ylides via a Cyclic Intermediate”, Jinchao Liang, Xin Chen, Jinglong Chen*, Xingxing Ma, and Qiuling Song*Org. Lett. 2024, 26, 18, 3872–3877. doi: https://doi.org/10.1021/acs.orglett.4c01031.

209.“1,1-Oxycarbonation of Terminal Alkynes via Sequential Borylation, 1,2-Migration, and Oxidation with Oxone”, Guan Zhang, Bofan Feng, Yutong Wang, Jinglong Chen*, Xingxing Ma, and Qiuling Song*Org. Lett. 2024, 26,  3109–3113, doi: https://doi.org/10.1021/acs.orglett.4c00738.

208.“Recent progress in the catalytic enantioselective reactions of 1,1-diborylalkanes”, Xin Li, Jinglong Chen* and Qiuling Song*Chem. Commun., 202460, 2462–2471, doi: https://doi.org/10.1039/d3cc06165e


207.“Single-atom skeletal editing of 2H-indazoles enabled by difluorocarbene”, Yao ZhouFuling ChenZiru LiJunjie DongJingnan LiBohao Zhang and Qiuling Song*Sci. China Chem. 66, 1975-1981 (2023). doi:https://doi.org/10.1007/s11426-023-1599-4

206.“Palladium-Catalyzed Atroposelective Kinetic C−H Olefination and Allylation for the Synthesis of C-B Axial Chirality”, Jie XuWeihua QiuXu ZhangZhihan WuZhen ZhangKai YangQiuling Song*Angew. Chem. Int. Ed2023, e202313388, doi: http://doi.org/10.1002/anie.202313388

205.“Decarboxylation of β-boryl NHPI esters enables radical 1,2-boron shift for the assembly of versatile organoborons”, Yu GuoXiaosha WangChengbo LiJianke SuJian Xu* and Qiuling Song*Nat Commun 14, 5693 (2023), doi: https://doi.org/10.1038/s41467-023-41254-1.

204.“Transition-metal-free C(sp2)–C(sp3) cross-coupling of α-(pseudo)halo aliphatic ketones with boronic acids via a 1,4-metallate shift”, Xue Li, Haohua Chen, Hao Wang, Qiaohui Zhang, Heyun Sheng, Yu Lan* and Qiuling Song*Nat. Synth 2, 1211–1221 (2023). doi: https://doi.org/10.1038/s44160-023-00373-9

203.“Construction of C-B axial chirality via dynamic kinetic asymmetric cross-coupling mediated by tetracoordinate boron”, Kai Yang, Yanfei Mao, Zhihan Zhang, Jie Xu, Hao Wang, Yong He, Peiyuan Yu* and Qiuling Song*Nat Commun 14, 4438 (2023), doi: https://doi.org/10.1038/s41467-023-40164-6.

202.“Cu(I)-Catalyzed Highly Diastereo- and Enantioselective Constructions of Boron/Carbon Vicinal Stereogenic Centers via Insertion Reaction”, Guan Zhang, Xinping Cai, Junyi Jia, Bofan Feng, Kai Yang, and Qiuling Song*ACS Catal. 202313, 9502-9508, doi: https://doi.org/10.1021/acscatal.3c02093.

201.“Modular assembly of versatile tetrasubstituted alkenyl monohalides from alkynyl tetracoordinate borons”, Xingxing Ma, Luo Li, Mengwei Tan, Zihao Zhong, Jinchao Liang, Puhui Li and Qiuling Song*Chem 20239, 1164-1181, doi: https://doi.org/10.1016/j.chempr.2023.01.005.

 

200.“Unconventional Transformations of Difluorocarbene with Amines and Ethers”, Xingxing Ma, Jianke Su and Qiuling Song*Acc. Chem. Res. 202356, 592–607, doi: https://doi.org/10.1021/acs.accounts.2c00830.

 

199.Synthesis of axially chiral alkenylboronates through combined copper- and palladium-catalysed atroposelective arylboration of alkynes”, Wangyang Li, Shanglin Chen, Jinhui Xie, Zhenwei Fan Kai Yang and Qiuling Song*Nat. Synth 2, 140-151(2023), doi: https://doi.org/10.1038/s44160-022-00201-6.

198.“Design, Synthesis, and Applications of ortho-Sulfur Substituted Arylphosphanes”, Yu Guo, Ying Luo, Shiqiang Mu, Jianke Su, Jian Xu and Qiuling Song*, CCS Chem. 2023, 5, 1353-1364, DOI:10.31635/ccschem.022.202201944


197.Synthesis of 10B-enriched 2,1-borazaronaphthalenes from o-aminostyrenes and 10BF3”,Weihua QiuJide ZhuRencai Tao,  Kai Yang* and  Qiuling Song*, Org. Chem. Front., 2024, 11, 2733. DOI: http://doi.org/10.1039/d4qo00176a

196.“Synthesis of Phosphachromones by Cyclized Coupling of Ethyl Hydrogen (Phenylethynyl)phosphonate with Arynes”, Yu Guo, Jianke Su, Jian Xu*, and Qiuling Song*, Org. Lett. 2023256459−6463doi: http://doi.org/10.1021/acs.orglett.3c01938

195.“4CzIPN-catalyzed radical-initiated cascade cyclization for the photosynthesis of polysubstituted quinolin-3-amines”, Shiqiang Mu, Yu Guo, Xiujuan Huang, Ying Luo, Menghan Chen, Jian Xu* and Qiuling Song*,  Org. Chem. Front., 202310, 3259–3263,doi: https://doi.org/10.1039/D3QO00537B.

194.“Divergent Synthesis of 1,1-Carbonyl Amino Alkyl Borons from Indoles”, Mengyuan Hou, Yahao Wang, Puhui Li, Xingxing Ma, Guan Zhang and Qiuling Song*Org. Lett. 2023, 25, 4038−4043, doi: https://doi.org/10.1021/acs.orglett.3c01190.

193.“Synthesis of α-Haloboronates by the Halogenation of gem-Diborylalkanes via Tetracoordinate Boron Species”, Shangteng Liao, Jinchao Liang Chaokun Li, Nan Chen, Kai Yang, Jinglong Chen*, and Qiuling Song*Org. Lett. 202325, 2928−2933, doi: https://doi.org/10.1021/acs.orglett.3c00982.


192.Copper-Catalyzed Radical Addition of Alkynols to Synthesize Difluoroheterocyclic Compounds” Fumei Ke, Changjiang Yu, Xin Li, Heyun Sheng, and Qiuling Song*, Org. Lett. 2023, 25, 15, 2733–2738, doi: https://doi.org/10.1021/acs.orglett.3c00968

191.“Rhodium-Catalyzed Intramolecular Cyclization to Synthesize 2-Aminobenzofurans via Carbene Metathesis Reactions” Xue Li, Heyun Sheng, and Qiuling Song*Org. Lett. 202325, 12, 2113–2117, doi: https://doi.org/10.1021/acs.orglett.3c00539.

190.“Arylation of Terminal Alkynes: Transition-Metal-Free Sonogashira-Type Coupling for the Construction of C(sp)–C(sp2) Bonds”, Mingxing Ye, Mengyuan Hou, Yahao Wang, Xingxing Ma, Kai Yang, and Qiuling Song*Org. Lett. 202325, 10, 1787–1792, doi: https://doi.org/10.1021/acs.orglett.3c00586.

189.“Recent advances in the construction of tetracoordinate boron compounds”Xue Li,  Guan Zhang and  Qiuling Song*Chem. Commun.202359, 3812-3820, doi: https://doi.org/10.1039/D2CC06982B.


188.“Deaminative Arylation or Alkenylation of Aliphatic Tertiary Amines with Aryl or Alkenylboronic Acids via Nitrogen Ylides”, Jianke Su, Chengbo Li, Xinyuan Hu, Yu Guo and Qiuling Song*, Angew. Chem. Int. Ed. 2022, 61, e2022127, doi: 10.1002/anie.202212740.

 

187.“Cu-catalyzed three component cascade synthesis of 1,3-benzothiazines from ortho-aminohydrazones and bromodifluoroacetamides”, Changjiang Yu, Fumei Ke, Jianke Su, Xingxing Ma, Xin Li and Qiuling Song*, Org. Lett. 202224, 7861–7865.doi: https://doi.org/10.1021/acs.orglett.2c03399

  


186.“Enantioselective Copper-Catalyzed sp2/sp3 Diborylation of 1,1-Chloro-Trifluoromethyl– 2-alkenes”, Zhenwei Fan, Mingxing Ye, Yahao Wang, Jian Qiu, Wangyang Li, Xingxing Ma, Kai Yang and Qiuling Song*ACS Cent. Sci. 2022, 8, 8, 1134–1144, doi: 10.1021/acscentsci.2c00339.

 

185.“Enantioselective copper-catalyzed double hydroboration of alkynes to access chiral gem-diborylalkanes”, Shengnan Jin, Jinxia Li, Kang Liu, Weiyi Ding, Shuai Wang, Xiujuan Huang, Xue Li, Peiyuan Yuand Qiuling Song*Nat. Commun. 202213, 3524-3536, doi: 10.1038/s41467-022-31234-2

 

184.“Construction of boron-stereogenic compounds via enantioselective Cu-catalyzed desymmetric B–H bond insertion reaction”, Guan Zhang, Zhihan Zhang, Mengyuan Hou, Xinping Cai, Kai Yang, Peiyuan Yu* and Qiuling Song*Nat. Commun. 202213, 2624, doi: 10.1038/s41467-022-30287-7

 

183.“Synthesis of α-Aminosilanes by 1,2-Metalate Rearrangement Deoxygenative Silylation of Aromatic Amides”, Lu Zhou, Jian Qiu, Cece Wang, Feng Zhang and Qiuling Song*Org. Lett. 202224, 3249-3253. 

 

182.“Construction and transformations of 2,2-difluoro-2,3-dihydrofurans from enaminones and diflurocarbene”, Heyun Sheng, Zhiwei Chen, Xue Li, Jianke Su and Qiuling Song*Org. Chem. Front. 20229, 3000-3005

 

181.“Design, synthesis, and applications of stereospecific 1,3-diene carbonyls”, Qiang Feng, Shihui Wang, Xingxing Ma, Changqing Rao and Qiuling Song*Science China Chem.  2022. doi: 10.1007/s11426-021-1204-5

 

180.“Ni-Catalyzed Radical-Promoted Defluoroalkylborylation of Trifluoromethyl Alkenes To Access gem-Difluorohomoallylic Boronates”, Jian Qiu , Cece Wang, Lu Zhou, Yixian Lou, Kai Yang and Qiuling Song*Org. Lett. 202224, 2446–2451

 

179.“Base-promoted anaerobic intramolecular cyclization synthesis of 4,5-disubstituted-1,2,3-thiadiazoles”, Cong Dong, Shaoyu Mai, Shuai Wang, Xin Li and Qiuling Song*, Org. Chem. Front. 2022, doi: 10.1039/d2qo00351a

 

178.“Difluorocarbene Enabled to Access 1,3-oxazin-6-ones from Enamides”, Shuai Wang, Xin Li, Shengnan Jin, Kang Liu, Cong Dong, Jianke Su and Qiuling Song*Org. Chem. Front. 2022, 9, 1282-1287

 

177.“Advances in the Construction of Fluorinated Organoboron Compounds”, Xingxing Ma, Zhijie Kuang and Qiuling Song*JACS Au20222, 261–279, doi: 10.1021/jacsau.1c00129

 

176.“Photo-induced trifunctionalization of bromostyrenes via remote radical migration reactions of tetracoordinate boron species”, Chaokun Li, Shangteng Liao, Shanglin Chen, Nan Chen, Feng Zhang, Kai Yang and Qiuling Song*Nat Commun 13, 1784 (2022), doi: 10.1038/s41467-022-29466-3

 

175.[4+1] Cyclization of Benzohydrazide and ClCF2COONa Enables 1,3,4-Oxadiazoles and 1,3,4-Oxadiazoles-d(5)”, Ya Wang, Shiqiang Mu, Xin Li, Qiuling Song*Chin. Chem. Lett. 202233, 1511-1514

 

174.“Deconstructive Difunctionalizations of Carbon-Oxygen Cleavage in Cyclic Ethers Enabled by Difluorocarbene to Access Difluoromethyl Ethers”, Heyun Sheng, Jianke Su, Xue Li and Qiuling Song*CCS Chem. 2022, doi: 10.31635/ccschem.022.202101576

 

173.“Chemoselective Reduction of Exo-, Endo-Cyclic and Acyclic α,β-Unsaturated Ketones Under Catalyst Free Conditions”, Kaixia Jian, Bingnan Li, Shuxian Zhu, Qingqing Xuan and Qiuling Song*Org. Chem. Front. 20229, 1109-1114 

 

172.“Rh-Catalyzed Diastereoselective Addition of Arylboronic Acids to α-Keto N-tert-Butane sulfinyl Aldimines: Synthesis of α-Amino Ketones”, Cece Wang, Lu Zhou, Jian Qiu, Kai Yang and Qiuling Song*Org. Chem. Front. 2022, 9, 1016-1022

 

171.Photoinduced Decarboxylative Phosphorothiolation of N-Hydroxyphthalimide Esters”, Yu Guo, Ying Luo, Shiqiang Mu, Jian Xu* and Qiuling Song*Org. Lett. 202123, 6729-6734

 

170.“Regioselective Cross-Coupling of Isatogens with Boronic Acids to Construct 2,2-Disubstituted Indolin-3-one Derivatives”, Hetao Xu, Mingxing Ye, Kai Yang and Qiuling Song*Org. Lett. 202123, 7776-7780

 

169.“Modular Synthesis of Polysubstituted Quinolin-3-Amines by Oxidative Cyclization of  2-(2-Isocyanophenyl)acetonitriles with Organoboron Reagents”, Shihui Wang, Jian Xu and Qiuling Song*Org. Lett. 202123, 6789-6794

 

168.“Pyridinium-catalyzed decarboxylative borylation of benzoyl peroxides”, Shuxian Zhu , Jianxiang Yan , Yao Zhou , Kai Yang  and Qiuling Song*, Green Synth. Catal.20212, 299-302

 

167.“Double Capture of Difluorocarbene by 2-Aminostyrenes Enables the Construction of 3-(2,2-Difluoroethyl)-2-Fluoroindoles”, Heyun Sheng, Jianke Su, Xin Li, Xue Li and Qiuling Song*Org. Lett. 202123, 7781-7786

 

166.“An Olefinic 1,2-α-Boryl Migraion Enables 1,2-Bis(boronic esters) via Radical-polar Crossover Reaction”, Feng Zhang, Shangteng Liao, Lu Zhou, Kai Yang, Chenglan Wang, Yixian Lou, Cece Wang and Qiuling Song*Chin. J. Chem. 2021,40, 582-588

 

165.“Modular Synthesis of Polysubstituted Quinolin-3-Amines by Oxidative Cyclization of 2-(2-Isocyanophenyl)acetonitriles with Organoboron Reagents”, Shihui Wang, Jian Xu and Qiuling Song*Org. Lett. 202123, 6789-6794

 

164.“Copper-catalyzed 1,6-conjugate addition of para-quinone methides with 1,1-diborylmethane”, Xin Li, Guoliang Gao, Songtao He and Qiuling Song*, Org. Chem. Front.20218, 4543-4548

 

163.“Palladium-catalyzed Three-component Synthesis of Phosphine-containing Tetrasubstituted Acyclic Unsymmetric Allcarbon Olefins”, Xingxing Ma, Puhui Li, Jinchao Liang, Hejun An, Kai Yang, and Qiuling Song *, Cell Reports Physical Science20212, 100629

 

162.“C-F bond activation under transition-metal-free conditions”, Han-Jun Ai, Xingxing Ma, Qiuling Song and Xiao-Feng Wu*Science China Chemistry202164, 1630-1659 

 

161.“Difluorocarbene enables to access 2-fluoroindoles from ortho-vinylanilines”Jianke Su, Xinyuan Hu, Hua Huang, Yu Guo and Qiuling Song*Nat. Commun202112, 4986

 

160.Enantioselective Cobalt-Catalyzed Cascade Hydrosilylation and Hydroboration of Alkynes to Access Enantioenriched 1,1-Silylboryl Alkanes”, Shengnan Jin, Kang Liu, Shuai Wang, and Qiuling Song*J. Am. Chem. Soc. 2021143, 13124-13134

 

159.“Construction of Axially Chiral Arylborons via Atroposelective Miyaura Borylation”, Kai Yang, Yanfei Mao, Jie Xu, Hao Wang, Yong He, Wangyang Li and Qiuling Song*J. Am. Chem. Soc. 2021143, 10048-10053

 

158.“Atom Recombination of Difluorocarbene Enables 3-Fluorinated Oxindoles from 2-Aminoarylketones”, Guan Zhang, Qianqian Shi, Mengyuan Hou, Kai Yang, Shihui Wang, Shuai Wang, Wangyang Li, Chaokun Li, Jian Qiu, Hetao Xu, Lu Zhou, Cece Wang, Shi-Jun Li, Yu Lan,* and Qiuling Song*CCS Chemistry 20224, 1671-1679, doi:10.31635/ccschem.021.202100979

 

157.“Tetracoordinate Boron Intermediates Enabled Unconventional Transformations”, Kai Yang and Qiuling Song*Acc. Chem. Res.,202154, 2298-2312

 

156.“Catalytic Atroposelective Catellani Reaction Enables to Construct Axially Chiral Biaryl Monophosphine Oxides”, Qiang Feng, Xingxing Ma, Wen Bao, Shi-Jun Li, Yu Lan, and Qiuling Song*CCS Chemistry. 2021, 3, 377-387

 

155. “Passerini-Type Reaction of Boronic Acids Enables α-Hydroxyketones”, Kai Yang, Feng Zhang, Tongchang Fang, Chaokun Li, Wangyang Li, and Qiuling Song*Nat. Commun2021, 12, 441

 

154. “Solvent-Dependent Cyclization of 2-Alkynylanilines and ClCF2COONa for the Divergent Assembly of N-(Quinolin-2-yl)amides and Quinolin-2(1H)-ones”, Ya Wang, Yao Zhou, Xingxing Ma, and Qiuling Song*Org. Lett. 2021, 23,  5599–5604

 

153. “Ni-Catalyzed Reductive Allylation of α-Chloroboronates to Access Homoallylic Boronates”,Yixian Lou, Jian Qiu, Kai Yang, Feng Zhang and Qiuling Song*Org. Lett. 202123, 4564–4569

 

 152.“通过炔丙醇的自由基氧化重排反应合成二亚甲基茚酮和苯并噻吩酮类化合物的反应研究”, 晏建祥,朱舒娴,高超, 宋秋玲*, 分子科学学报(约稿), 202137, 154-161

 

151.“Cu-Catalyzed Chemoselective Reduction of N-Heteroaromatics with NH3·BH3 in Aqueous Solution”, Chao Gao, Qingqing Xuan and Qiuling Song*Chin. J Chem2021, 39, 2504-2508

 

150.“N2H4-H2O Enabled Umpolung Cyclization of o-Nitro Chalcones for the Construction of Quinoline N-oxides”, Guan Zhang, Kai Yang, Shihui Wang, Qiang Feng and Qiuling Song*, Org. Lett. 202123, 595-600

 

149.“Rapid incorporation of difluoroacetate radical into para-quinone methides via radical 1,6-conjugate addition”, Xin Li, Songtao He and Qiuling Song*Chem. Commun. 202157, 6035-6038

 

 148.“Dialkylzincs Mediated Radical 1,2-Addition of Alkenes and Alkynes”, Xin Li, Songtao He, and Qiuling Song*Org. Lett. 202123, 2994-2999

 

 147.“Photoinduced NaI-Promoted Radical Borylation of Alkyl Halides and Pseudohalides”, Chenglan Wang, Lu Zhou, Kai Yang, Feng Zhang and Qiuling Song*Chin. J. Chem. 202139, 1825-1830

 

146.“Pd-Catalyzed Assembly of Fluoren-9-ones by Merging of C-H activation and Difluorocarbene Transfer”, Xiaobing Liu, Heyun Sheng, Yao Zhou and Qiuling Song*Org. Lett. 202123, 2543-2547

 

145.“Photo-Induced Weak Base-Catalyzed Synthesis of α-Haloboronates from Vinylboronates and Polyfluoroalkyl Halides”, Tongchang Fang, Jian Qiu, Kai Yang, and Qiuling Song*Org. Chem. Front.20218, 1991-1996

 

144.“Biomimetic Carbene Cascades Enabled Imine Derivative-migration from Donor, Donor-Carbene-Bearing Thiocarbamates”, Xue Li, Haohua Chen, Shaoyu Mai, Yu Lan* and Qiuling Song*Org. Lett. 202123, 3518-3523

 

143.“Preparation of Anthranils via Chemoselective Oxidative Radical Cyclization of 3-(2-Azidoaryl) Substituted Propargyl Alcohols”, Chao Gao, Jian Xu, Shuxian Zhu, Kaixia Jian, Qingqing Xuan* and Qiuling Song*Chem. Commun. 2021572037-2040 

 

142. “Transition-Metal-Free Double Insertive Coupling of Isocyanides with Arylboronic Acids Enabled Diarylmethanamines”, Kai Yang, Xiaoxiao Hu, Wangyang Li, Jian Qiu, Qiang Feng, Shihui Wang, Guan Zhang, Zhijie Kuang, Peiyuan Yu* and Qiuling Song*Cell Reports Physical Science20201, 100268

 

141. “Recent Progress on Selective Deconstructive Modes of Halodifluoromethyl and Trifluoromethyl-containing Reagents”, Xingxing Ma and Qiuling Song*Chem. Soc. Rev.2020, 49, 9197-9219

 

140. “Elemental sulfur enabled divergent synthesis of disulfides, diselenides and polythiophenes from β-CF3-1,3-enynes”, Shengnan Jin, Shi-Jun L, Xingxing Ma, Jianke Su, Haohua Chen, Yu Lan and Qiuling Song*Angew. Chem. Int. Ed. 202060, 881-888

 

139.“Deconstructive Functionalizations of Unstrained Carbon−Nitrogen Cleavage Enabled by Difluorocarbene”, Jianke Su, Xingxing Ma, Zongliang Ou, Qiuling Song*, ACS Central Science  2020, 6, 1819-1826

 

138.“Cu-catalyzed regio- and stereodivergent chemoselective sp2/sp3 1,3- and 1,4-diborylations of CF3-containing 1,3-enynes”, Zhijie Kuang, Haohua Chen, Jian Qiu, Zongliang Ou, Yu Lan* and Qiuling Song*Chem. 20206, 2347-2363

 

137.Palladium-Catalyzed Desulfurative Amide Formation from Thioureas and Arylboronic Acids, Jianke Su, Wendong Li, Xin Li, Jian Xu and Qiuling Song*ChemCatChem202012, 5664-5668 

 

136.“Palladium-Catalyzed Cyanation of Aryl Halides with in situ Generated CN- from ClCF2H and NaNH2”, Changjiang Yu, Xingxing Ma and Qiuling Song*Org. Chem. Front.20207, 2950-2954

 

135.Cu-Catalyzed o-Amino Benzofuranthioether Formation from N-Tosylhydrazone-Bearing Thiocarbamates and Arylative Electrophiles”, Xue Li, Shaoyu Mai, Xin Li, Jian Xu, Hetao Xu, and Qiuling Song*Org. Lett. 2020227874–7878

 

134.“Synthesis of Thiazoles and Isothiazoles via Three-Component Reaction of Enaminoesters, Sulfur, and Bromodifluoroacetamides/Esters”, Xingxing Ma, Xiaoxia Yu, Hua Huang and Qiuling Song*, Org. Lett. 202022, 5284–5288

 

133.“Enantio- and Diastereoselective Diarylmethylation of 1,3-Dicarbonyl Compounds”, Xin Li, Songtao He and Qiuling Song*Chem. Sci. 202011, 5969-5973

 

132.“Base-Promoted Domino-Borylation- Protodeboronation Strategy”, Zhijie Kuang, Kai Yang, Yao Zhou and Qiuling Song*Chem. Commun. 202056, 6469-6479

 

131.“[3+1+1] Type Cyclization of ClCF2COONa for the Assembly of Imidazoles and Tetrazoles via In-Situ Generated Isocyanides”, Ya Wang, Yao Zhou and Qiuling Song*Chem. Commun. 2020566106-6109

 

130.“Michael Reaction Inspired Atroposelective Construction of Axially Chiral Biaryls”, Shengyi Yan, Wang Xia, Shaoyu Li, Qiuling Song*, Shaohua Xiang, Bin Tan*J. Am. Chem. Soc.2020142, 7322-7327

 

129.“Palladium-Catalyzed C-H Bond Activation for the Assembly of N-Aryl Carbazoles with Aromatic Amines as Nitrogen Sources”, Xiaobing Liu, Heyun Sheng, Yao Zhou and Qiuling Song*Chem. Commun. 202056, 1665-1668

 

128.“Precise Construction of SCF2H or SeCF2H Groups on Heteroarenes Generated in situ from CF3-Containing 1,3-Enynes”, Shengnan Jin, Zhijie Kuang and Qiuling Song*Org. Lett. 202022, 615-619

 

127.“Cu-Catalyzed C-N Bond Cleavage of 3-Aminoindazoles for C-H Arylation of Enamines”, Yao Zhou, Ya Wang, Zhiyi Song, Tamaki Nakano and Qiuling Song*Org. Chem. Front. 2020, 7, 25-29.

 

126.“Synthesis of CF2H-Containing Oxime Ethers Derivatives from ClCF2H tert-Butyl Nitrile and Indoles”, Xingxing Ma, Hua Huang, Jianke Su, Zhiyi Song, Tamaki Nakano and Qiuling Song*Chin. J.  Chem.  202038, 63-68.

 

125.“Radical-Induced 1,2-Boron Shift, Enabling 1,3-Difunctionalization of Allylboronic Esters”, Kai Yang, Zhijie Kuang, Qiuling Song*Chem20206, 330-331.

 

124.“Chiral Brønsted Acid from Chiral Phosphoric Acid Boron Complex and Water: Asymmetric Reduction of Indoles”, Kai Yang,  Yixian Lou, Chenglan Wang, Liang-Wen Qi, Tongchang Fang, Feng Zhang, Hetao Xu, Lu Zhou, Wangyang Li, Peiyuan, Yu,* Qiuling Song*Angew. Chem. Int. Ed. 202059, 3294-3299, DOI: 10.1002/anie.201913656.

 

123.“Cu-Catalyzed Aromatic Metamorphosis of 3-Aminoindazoles”, Yao Zhou, Lu Lin, Ya Wang, Yixian Lou, Jun Zhu* and Qiuling Song*Org. Lett. 201921, 7630-7634.

 

122.“Synthesis of anti-vicinal diboronates from diarylethynes and B(2)pin(2)”, Zhijie Kuang, Shaoyu Mai, Kai Yang and Qiuling Song*Science Bulletin201922, 1685-1690.

 

121.“Tert-Butyl Nitrite Mediated Synthesis of Fluorinated O-Alkyloxime Ethers Derivatives”, Xingxing Ma and Qiuling Song*Org. Lett. 201921, 7375-7379

 

 120.“Cu-Catalyzed Denitrogenative Transannulation of 3-Aminoindazoles to Assemble 1-Aminoisoquinolines and 3-Aminobenzothiophene”, Yao Zhou, Ya Wang, Yixian Lou and  Qiuling Song*Org. Lett. 2019, 21, 8869-8873

 

119.“Palladium-catalyzed Suzuki-Miyaura coupling of thioureas or thioamides", Shaoyu Mai, Wendong Li, Xue Li, Yingwei Zhao & Qiuling Song*Nature Commun., 2019, 10, 5709, DOI:10.1038/s41467-019-13701-5

 

118.“Stereospecific 1,4-Metallate Shift Enables Stereoconvergent Synthesis of Ketoximes”, Kai Yang, Feng Zhang, Tongchang Fang, Guan Zhang,and Qiuling Song*Angew. Chem. Int. Ed. 201958, 13421.DOI:10.1002/anie.201906057

 

117.“Base-catalyzed Diborylation of Alkynes: Synthesis and Applications of cis-1,2-Bis(boryl)alkenes”, Zhijie Kuang, Guoliang Gao and Qiuling Song*Science China Chem. 201962(1), 62-66

 

116.“Difluoromethylation of Tosylhydrazone Compounds with Chlorodifluoromethane under Mild Conditions”, Changjiang Yu, Jianke Su, Xingxing Ma, Yao Zhou and Qiuling Song*, (invited article for special issue "Organofluorine Chemistry" (Guest Editors: Gavin Chit Tsui and Jinbo Hu)) , Asian J. Org. Chem.,20198, 694-697.

 

115.“Chlorodifluoromethane as a Novel C1 Synthon in the Assembly of N-containing Compounds”, Xingxing Ma, Jianke Su, Xingang Zhang* and Qiuling Song*iScience201919, 1-13, 10.1016/j.isci.2019.07.005

 

114.“Metal-free Cyclization of Unsaturated Hydrazones for the Divergent Assembly of Pyrazolones and Pyrazolines” Xiaobin Liu, Yao Zhou and Qiuling Song*, Chem. Commun201955, 8943-8946

113.“Synthesis of Furoxans and Isoxazoles via Divergent [2+1+1+1] Annulations of Sulfoxonium Ylides and tBuONO”, Zhonghe Tang, Yao Zhou and Qiuling Song*Org. Lett. 201921, 5273-5276

 

112.“Transition metal-free quadruple cleavage of ethyl bromodi-fluoroacetate for the assembly of 1,3,5-triazines”, Xiaoxia Yu, Yao Zhou, Xingxing Ma and Qiuling Song*Chem. Commun201955, 8079-8082

 

111.“3-Aminoindole Synthesis: CAr-N Bond Construction along with the Indole Ring Formation”, Guan Zhang, Lu Lin, Kai Yang, Shihui Wang, Qiang Feng, Jun Zhu*, Qiuling Song*Adv. Synth. Catal. 2019361, 3718-3722

 

110.“自由基促进硫甲基取代的炔酮的环化反应”, 许健, 张世樊, 罗滢,   张荔, 张帆, 黄挺菁,宋秋玲*, 化学学报(约稿), 201977, 932-938

 

109.“Oxidant-controlled divergent transformations of 3-aminoindazoles for the synthesis of pyrimido [1,2-b]-indazoles and aromatic nitrile-derived dithioacetals”, Yao Zhou, Yixian Lou, Ya Wang and Qiuling Song*Org. Chem. Front. 20196, 3355-3359

  

108.“S8-Catalyzed triple cleavage of bromodifluoro compounds for the assembly of N-containing heterocycles ”, Shuilin Deng, Haohua Chen, Xingxing Ma, Yao Zhou, Kai Yang, Yu Lan  and Qiuling Song* , Chem. Sci., 2019, 10,6828–6833

 

107.“Radical Promoted C(sp2)-S Formation and C(sp3)-S Bond Cleavage: Access to 2-Subsituted-Thiochromones”,  Jian Xu, Fan Zhang, Shifan Zhang, Li Zhang, Xiaoxia Yu, Jianxiang Yan and Qiuling Song* , Org. Lett. 201921, 1112–1115

 

106.“Gold catalyzed radical-involved intramolecular cyclization of internal N-propargylamides for the synthesis of 5-oxazole ketones”,  Hejun An, Shaoyu Mai, Qingqing Xuan, Yao Zhou and Qiuling Song*J. Org. Chem. 201984, 401-408

 

105.“Reductive N-Alkylation of Primary and Secondary Amines Using Carboxylic Acids and Borazane under Metal-free Conditions”, Yahui Wei, Qingqing Xuan and Qiuling Song*Org. Chem. Front. 20185, 3510-3514, inside front cover.

 

104.“Oxidative Rearrangement of 3-Aminoindazoles for the Construction of 1,2,3-Benzotriazine-4(3H)-ones at Ambient Temperature”, Yao Zhou, Ya Wang, Yixian Lou and Qiuling Song*, Org. Lett. 201820, 6494-6497.

 

103.“碱催化的含氮杂环的N-H和O-H二氟甲基化反应”, 马星星,轩晴晴,宋秋玲*,化学学报(约稿), 201876, 972-976.

 

102.“Cu-Catalyzed Denitrogenative Ring-Opening of 3-Aminoindazoles for the Synthesis of Aromatic Nitrile-containing (Hetero)Arenes”, Yao Zhou, Shuilin Deng, Shaoyu Mai and  Qiuling Song*Org. Lett. 201820, 6161-6165

 

101.“Halodifluoroacetates as Formylation Reagents with Various Amines via Double C(sp3)-F Bond Cleavage”, Xingxing Ma, Shuilin Deng and  Qiuling Song*Org. Chem. Front. 20185, 3505-3509, front cover.

 

100.“Metal-Free Ring-Opening of 3-Aminoindazoles for the Synthesis of 2-Aminobenzoates”, Yao Zhou and Qiuling Song*, Org. Chem. Front. 20185, 3245-3249.

 

99.“Four-Coordinate Triarylborane Synthesis via Cascade B-Cl/C-B Cross-Metathesis and C-H Bond Borylation”, Kai Yang, Guan Zhang and Qiuling Song*Chem. Sci. 2018, 9,7666-7672,

 

98.“Copper-Catalyzed Intermolecular Reductive Radical Difluoroalkylation-Thiolation of Aryl Alkenes”, Weiguang Kong, Changjiang Yu, Hejun An and Qiuling Song*Org. Lett. 2018, 204975–4978.

 

97.“Diversity-oriented Synthesis of Imidazo[2,1-a]isoquinolines”, Shaoyu Mai, Yixin Luo, Xianyun Huang, Zhenghao Shu, Bingnan Li, Yu Lan, and Qiuling Song*, Chem. Commun. 201854, 10240-10243front cover.

 

96.“Base-catalyzed Borylation/B-O Elimination of Propynols and B2pin2 Delivering Tetrasubstituted Alkenylboronates”, Zhijie Kuang, Haohua Chen, Jianxiang Yan, Kai Yang, Yu Lan and Qiuling Song*Org. Lett. 2018, 20, 5153-5157 

 

95.“Base-catalyzed Diborylation of Alkynes: Synthesis and Applications of cis-1,2-Bis(boryl)alkenes”, Zhijie Kuang, Guoliang Gao and Qiuling Song*Science China Chem. 2018doi : 10.1007/s11426-018-9344-4

 

94.“Synthesis of β-Aminoenones via Cross-Coupling of in situ Generated Isocyanides with 1,3-Dicarbonyl Compounds”, Xingxing Ma, Yao Zhou and Qiuling Song*Org. Lett. 2018, 204777–4781.

 

93.“Divergent Synthesis of α-Aryl Ketones/Esters via Rhodium-Catalyzed Selective Deesterification and Decarbonylation of the Diazo Compounds”, Zhonghe Tang, Shaoyu Mai, Yao Zhou and Qiuling Song*Org. Chem. Front. 2018, 5, 2583-2587.

 

92.“A Facile Synthesis of Diverse 5-Arylated Triazoles via Cu-Catalyzed Oxidative Interrupted Click Reaction with Arylboronic Acids under Air Conditions”, Xiaoxia Yu, Jian Xu, Yao Zhou and Qiuling Song*Org. Chem. Front. 20185, 2463-2467.

 

91.“Dual Roles of Ethyl Bromodifluoroacetate in the Formation of Fluorine-containing Heteroaromatic Compounds”, Xingxing Ma, Shaoyu Mai, Yao zhou, Gui-Juan Cheng and Qiuling Song*Chem. Commun. 2018548960-8963, front cover

 

90.Functionalized Geminal-Diborylalkanes from Various Alkynes”, Guoliang Gao, Zhijie Kuang and Qiuling Song*Org. Chem. Front. 2018, 5, 2249-2253.

 

89.“Copper/Diboron-Mediated Intramolecular Oxygenation and Allylation/Benzylation of Nitroalkynes for the Synthesis of C2-Quaternary Indolin-3-ones”, Wenqiang Fu, Yao Zhou and Qiuling Song*Chem. Asian  J. 2018, 2511-2515, inside front cover, invited contribution to special issue for “Homogeneous Catalysis from Young Investigators in Asia”.

 

88.“Rh(II)/Phosphine-Cocatalyzed Synthesis of Dithioketal Derivatives from Diazo Compounds Through Simultaneous Construction of Two Different C-S Bonds”, Changqing Rao, Shaoyu Mai and Qiuling Song*Chem. Commun. 2018, 54, 5964-5967, back cover

 

87. “Lewis-acid Promoted Highly Chemoselective Condensation of 2-Aminobenzimidazoles or 3-Aminoindazoles to Construct Fused Nitrogen Heterocycles”, Weiguang Kong, Yao Zhou and Qiuling Song*Adv. Synth. Catal. 2018360, 1943-1948

 

86.“Synthesis of Fused-benzimidazoles via Successive Nucleophilic Additions of Benzimidazole Derivatives to Arynes under Metal-free Conditions”, Bingnan Li, Shaoyu Mai, Jinglong Chen and Qiuling Song*Org. Chem. Front. 2018, 5, 1639-1642.

85.“Photoredox-Catalyzed Cascade Annulation of Methyl(2-(phenylethynyl) phenyl) sulfane and Me-thyl(2(phenylethynyl) phenyl) selane with Sulfonyl Chlorides: Synthsis of Benzothiophenes and Benzoselenophenes”, Jianxiang Yan, Jian Xu, Yao Zhou, Jinglong Chen and Qiuling Song*Org. Chem. Front. 20185, 1483 - 1487.

 

84.“Thiocarbamate-Directed Tandem Olefination−Intramolecular Sulfuration of Two ortho C−H Bonds: Application to Concise Synthesis of a COX-2 Inhibitor”, Wendong Li, Yingwei Zhao, Shaoyu Mai and Qiuling Song*Org. Lett. 201820, 1162-1166

 

83.“Photoredox-Catalyzed Decarboxylative Alkylation of Silyl Enol Ethers to Synthesize Functionalized Aryl Alkyl Ketones”, Weiguang Kong, Changjiang Yu, Hejun An and Qiuling Song*Org. Lett. 201820, 349-352 

 

82.“Copper-Catalyzed Radical Difluoroalkylation and Redox Annulation of Nitroalkynes for the Construction of C2-Quaternary Indolin-3-ones”, Wenqiang Fu and Qiuling Song*Org. Lett. 201820, 393-396

 

81.Recent Advances in Asymmetric Reactions Catalyzed by Chiral Phosphoric Acids”, Xin Li and Qiuling Song*Chin. Chem.  Lett. 201829, 1181-1192, invited review.

 

80.“Cu/Pd Cooperatively Catalyzed Tandem Intramolecular anti-Markovnikov Hydroarylation of Unsaturated Amides: Facile Construction of 2-Quinolones via Borylation/Intramolecular C(sp3)-C(sp2) Cross Coupling”, Zhijie Kuang, Bingnan Li and Qiuling Song*, Chem. Commun. 201854, 34-37, back cover

 

79.“Divergent Synthesis of Disulfanes and Benzenesulfonothioates Bearing 2-Aminofurans From N-Tosylhydrazone-Bearing Thiocarbamates”, Shaoyu Mai and Qiuling Song*Angew. Chem. Int. Ed. 20177952-7957

 

78.“Synthesis of 3-Arylsulfonyl-Benzothiophenes and Benzoselenophenes via TBHP-Initiated Radical Cyclization of 2-Alkynyl Thioanisoles or Selenoanisoles with Sulfinic Acids”, Jian Xu, Xiaoxia Yu, Jianxiang Yan and Qiuling Song*, Org. Lett. 201719, 6292-6295

 

77.“Expedient Chemoselective and Catalyst-free Synthesis of 3, 3-Difluorochroman-4-ones from o-hydroxyarylenaminones and Selectfluor”, Jian Xu, Zhijie Kuang and Qiuling Song*Chin. Chem. Lett. 2017, 10.1016/j.cclet.2017.10.027

 

76.“An Expedient and Novel Strategy for Reductive Amination by Employing H2O as Both Hydrogen Source and Solvent via B2(OH)4/H2O Systems”, Yahui Wei, Cong Zhao, Qingqing Xuan, Qiuling Song*Org. Chem. Front. 2017, 4, 2291-2295, inside front cover picture

 

75.“Cu/Pd Cooperatively Catalyzed Tandem Intramolecular anti-Markovnikov Hydroarylation of Unsaturated Amides: Facile Construction of 2-Quinolones via Borylation/Intramolecular C(sp3)-C(sp2) Cross Coupling”, Zhijie Kuang, Bingnan Li and Qiuling Song*, Chem. Commun. 201854, 34-37

 

74. “Merging gold catalysis and organocatalytic oxidation for chemodivergent synthesis of functionalized oxazoles from N-propargylamides”, Shaoyu Mai, Changqing Rao, Ming Chen, Jihu Su, Jiangfeng Du and Qiuling Song*Chem. Commun. 201753, 10366-10369

 

73.“Cu-Catalyzed Synthesis of 3-Formyl imidazo[1,2-a]pyridines and Imidazo[1,2-a]pyrimidines by Employing Ethyl Tertiary Amines as Carbon Sources”, Changqing Rao, Shaoyu Mai and Qiuling Song*, Org. Lett. 2017, 19, 4726-4729

 

72.“Gold(I)-Catalyzed Synthesis of 2-Substituted Indoles from 2-Alkynylnitroarenes with Diboron as Reductant”, Wenqiang, Fu, Kai Yang, Jinglong Chen and Qiuling Song*Org. Biomol. Chem. 2017, 15, 8354 - 8360

 

71.“Co-Catalyzed Highly Chemo- and Regio-selective C(sp3)-H Nitration”, Yao Zhou, Zhonghe Tang and Qiuling Song*, Chem. Commun. 2017, 53, 8972-8975

 

70.“Visible-Light-Induced Thiotrifluoromethylation of Terminal Alkenes with Sodium Triflinate and Benzenesulfonothioates”, Weiguang Kong, Hejun An and Qiuling Song*Chem. Commun. 2017, 53, 8968-8971

 

69.“3,3- 二氟-2- 羰基吲哚类化合物的制备及应用”, 宋秋玲*和柯淼林, 中国医药工业杂志,201748(06), 787-794

68.“Spiro(phosphoamidite) ligand (SIPHOS)/Cu(OTf)2-catalyzed highly regio- and stereo-selective hydroborations of internal alkynes with diborane in water”, Qingqing Xuan, Yahui Wei and Qiuling Song*Chin. Chem. Lett. 201728, 1163-1166.

 

67.“Copper(I)-Catalyzed Chemoselective Reduction of Benzofuran-2-yl Ketones to Alcohols with B2pin2 via a Domino-Borylation-Protodeboronation (DBP) Strategy”, Qingqing Xuan, Weiguang Kong, Qiuling Song*J. Org. Chem. 2017827602-7607

 

66.“Umpolung of Proton from H2O: A Metal-free Selective Reduc-tion of Carbonyl Compounds Mediated by Diboron Reagents”, Qingqing Xuan, Cong Zhao and Qiuling Song*, Org. Biomol. Chem. 201715, 5140-5144, inside front cover picture

 

65.“Expedient E-Stereoselective Synthesis of Multi-substituted Functionalized Allylic Boronates from Morita−Baylis−Hillman Alcohols”, Qingqing Xuan, Yahui Wei and Qiuling Song*Org. Chem. Front. 2017, 4, 1220-1223, inside front cover picture

 

64.“Pd-Catalyzed Regioselective 1,2-Difunctionalization of Vinylarenes with Alkeneyl Triflates and Aryl Boronic Acids at Ambient Temperature”, Zhijie Kuang, Kai Yang and Qiuling Song*Org. Lett. 201719, 2702-2707

 

63.“Chemical Constituents of The Seahorse Hippocampus trimaculatus from East China Sea”, Jingna Wu, Zhiyu Liu*, Jie Su, Haixia Lu, Dengyuan Liao and Qiuling Song*Chemistry of Natural Compound s201753, 982-983

62.“Pd-Catalyzed 1,2-Diarylation of Vinylnaphthalenes at Ambient Temperature”, Zhijie Kuang, Kai Yang and Qiuling Song*, Org. Chem. Front. 20174, 1224-1228

 

61.“Lewis-acid Mediated [3+3] Annulation for the Construction of Substituted Pyrimidine and Pyridine Derivatives And Further C-H Activation Studies with Pyrimidine as A Directing Group”, Yao Zhou, Zhonghe Tang and Qiuling Song*, Adv. Synth. Catal2017359, 952-958

 

60.Synthesis of Fully-substituted 1,2,3-triazoles via Copper(I)-Catalyzed Three-Component Coupling of Sulfoximines, Alkynes and Azides”, Jian Xu and Qiuling Song*, Org. Chem. Front. 20174, 938-942, front cover picture

 

59.“Anti-inflammatory activity of 3β-hydroxycholest-5-en-7-one isolated from Hippocampus trimaculatus leach iva inhibiting iNOS, TNF-α, and 1L-1β of LPS induced RAW 264.7 macrophage cells”, Jingna Wu, Zhiyu Liu,* Jie Su, Nan Pan and Qiuling Song*, Food & Function20178, 788-795

 

58.“Silver-Catalyzed Radical Involved Cascade Cyclization of Diphenylphosphine with CinnamamidesEfficient Access to 2-Phosphinoyl-3H-Pyrrolo[1,2-a]indoles”,Jiang Xu, Xiaoxia Yu, Qiuling Song*, Org. Lett. 2017, 19, 980-983

57.“Copper/B2pin2-Catalyzed C-H Difluoroacetylation -Cycloamidation of Anilines Leading to the Formation of 3,3-Difluoro-2-oxindoles”, Miaolin Ke and Qiuling Song*, Chem. Commun201753, 2222 – 222

 

56.“Copper/B2pin2-Catalyzed 1, 6-HydroDifluoroacetylation of para-Quinone Methides”, Miaolin Ke and Qiuling Song*, Adv. Synth. Catal2017359, 384-389

 

55.“Aerobic Oxidative Decyanation-Amidation of Arylacetonitriles with Urea as Nitrogen Source”, Xuezhao Xu, Bingnan Li, Yingwei Zhao and Qiuling Song*Org. Chem. Front. 20174, 331-334, front cover picture

 

54. “Divergent Synthesis of Disulfanes and B enzenesulfonothioates Bearing 2-Aminofurans From N-Tosylhydrazone-Bearing Thiocarbamates”, Shaoyu Mai, Prof.Dr. Qiuling SongAngew. Chem. Int. Ed201756, 7952 –7957

 

53.“Base-controlled highly selective synthesis of alkyl 1,2-bis(boronates) or 1,1,2-tris(boronates) from terminal alkynes”, Guoliang Gao, Jianxiang Yan, Kai Yang, Fener Chen and Qiuling Song *Green Chem.201719, 39974001

 

52.“Copper/B2pin2-catalyzed C–H difluoroacetylation– cycloamidation of anilines leading to the formation of 3,3-difluoro-2-oxindoles”, Miaolin Ke and Qiuling Song*, Chem. Commun., 201753, 2222--2225

 

51.“Pd-Catalyzed Regioselective Arylboration of Vinylarenes”, Kai Yang and Qiuling Song*Org. Lett. 2016, 185460-5463

50.“Fe-catalyzed Aerobic Oxidative C-CN Bond Cleavage: in-situ Generated Acyl Groups from Arylacetonitriles Serving as Electrophiles Leading to Various Esters”, Weiguang Kong, Bingnan Li, Xuezhao Xu and Qiuling Song*J. Org. Chem.201681, 8436-8443

 

49.“Diborane-Mediated Deoxygenation of o-Nitrostyrenes to form Indoles”, Kai Yang, Fei Zhou, Zhijie Kuang, Guoliang Gao, Tom G Driver* and Qiuling Song*, Org. Lett. 2016, 184088-4091

 

48. “Diboron-Assisted Palladium-Catalyzed Transfer Hydrogenation of N-heteroaromatics with Water as Hydrogen Donor and Solvent”, Qingqing Xuan and Qiuling Song*Org. Lett. 2016, 184250-4253

 

47.“(Z)-Selective Synthesis of γ,δ-Unsaturated Ketones via Pd-Catalyzed Ring-Opening of 2-Alkylenecyclobutanones with Arylboronic Acids”, Yao Zhou, Changqing Rao and Qiuling Song*Org. Lett. 2016, 18, 4000-4003

 

46.“Palladium-Catalyzed Nitration of Meyer−Schuster Intermediates with tBuONO as Nitrogen Source at Ambient Temperature”, Yuanguang Lin, Weiguang Kong and Qiuling Song*Org. Lett. 201618, 3702-3705

 

45.“Catalyst-Induced Divergent Acylation of Benzimidazoles from 2-Halo Substituted Phenylacetic Acids via Aerobic Oxidative Decarboxylative Tandem Process”, Shaoyu Mai, Yingwei Zhao and Qiuling Song*, Org. Biomol. Chem. 201614, 8685-8690, front cover picture

 

44.“Carbon-Carbon Triple Bond Cleavage of Arylacetylenes for the Synthesis of Arylnitriles without Metal-Catalyst”, Yuanguang Lin and Qiuling Song*Eur. J. Org. Chem. 2016, 18, 3056-3059

 

43.Radical Promoted Difunctionalization of Unsaturated Carbon-Carbon Bonds in the Presence of Dioxygen”, Jian Xu and Qiuling Song*, Chin. J. Org. Chem. 2016, 36(6), 1151, invited review, front cover picture

 

42.“Copper-Catalyzed C(sp2)-H Difluoroalkylation of Aldehyde-Derived Hydrazones with Diboron as Reductant”, Miaolin Ke and Qiuling Song*, J. Org. Chem.201681 (9), 3654–3664

 

41.“Substituents-Controlled Chemoselective Cleavage C=C or Csp2-C(CO) Bond of α,β-Unsaturated Carbonyl Compounds Leading to β-Ketophosphonates”, Yao Zhou, Changqing Rao, Shaoyu Mai and Qiuling Song*, J. Org. Chem. 201681, 2027–2034

 

40.“Palladium-Catalyzed Arylboration of Bicyclic Alkenes”, Kai Yang and Qiuling Song*J. Org. Chem. 201681, 1000–1005

 

39.“Transition-Metal-Free Regio-selective Synthesis of Alkylboronates from Arylacetylenes or Vinyl Arenes”, Kai Yang and Qiuling Song*Green Chem. 201618, 932–936

 

38.“Copper-Catalyzed Tandem A3-Coupling–Isomerization–Hydrolysis Reactions of Aldehydes and Terminal Alkynes Leading to Chalcones”, Zhao Yingwei and Qiuling Song*Org. Chem. Front. 20163, 294–297, front cover picture

 

37.“Cu-Catalyzed Hydrofluoroacetylation of Alkynes or Alkynyl Carboxylic Acids Leading to Highly Stereoselective Difluoroacetylated Alkenes”, Miaolin Ke, Qiang Feng, Kai Yang and Qiuling Song*, Org. Chem. Front. 20163, 150–155, front cover picture

 

36.“β-Ketophosphonates Formation via Deesterification or Deamidation of Cinnamyl/Alkynyl Carboxylates or Amides with H-phosphonates”, Yao Zhou, Mingxin Zhou, Ming Chen, Jihu Su, Jiangfeng Du and Qiuling Song*RSC Advances20155, 103977–103981 

 

35.“Molecular Oxygen Promoted Cu-Catalyzed Oxidative Direct Amidation of Unactivated Carboxylic Acids with Azoles”, Wen Ding, Shaoyu Mai and Qiuling Song*Beilstein. J. Org. Chem. 201511, 2158–2165 (invited paper)

 

34.“Chemoselective Catalytic Reduction of Conjugated α, β-Unsaturated Ketones to Saturated Ketones via Hydroboration/ Protodeboronation Strategy", Wen Ding and Qiuling Song*Org. Chem.Front.20163, 14–18, front cover picture

 

33. “Highly selective copper-catalyzed trifunctionalization of alkynyl carboxylic acids: an efficient route to bis-deuterated β-borylated α, β-styrene", Qiang Feng, Kai Yang and Qiuling Song*, Chem.Common 2015,51,15394-15397

 

32.“Palladium-Catalyzed Aerobic Oxidative Cross-Coupling of Arylhydrazines with Terminal Alkynes”, Yingwei Zhao and Qiuling Song*, Chem. Commun. 201551, 13272-13274, Back cover

 

31.“Cu/Fe-Cocatalyzed Formation of b-Ketophosphonates by a Domino Knoevenagel–Decarboxylation–Oxyphosphorylation Sequence from Aromatic Aldehydes and H-Phosphonates”, Mingxin Zhou, Yao Zhou and Qiuling Song*, Chem.Eur. J. 201521, 10654-0659

 

30.“Cu-Catalyzed Aerobic Oxidative Amidation of Aryl Alkyl Ketones with Azoles to Afford Tertiary Amides via Selective C-C bond Cleavage”, Wen Ding and Qiuling Song*, Organic Chemistry Frontiers2015, 2, 765-770, front cover picture

 

29.“β-Ketophosphonates Formation via Aerobic Oxyphosphorylation of Alkynes or Alkynyl Carboxylic Acids with H-Phosphonates”, Mingxin Zhou, Ming Chen, Yao Zhou, Kai Yang, Jihu Su, Jiangfeng Du and Qiuling Song*, Org. Lett. 201517, 1786–1789

 

28.Cu-Catalyzed Aerobic Oxidative Esterification of Acetophe-nones with Alcohols to a-Ketoesters”, Xuezhao Xu, Wen Ding, Yuanguang Lin and Qiuling Song*Org. Lett. 201517, 516-519

 

27.“Styryl Ether Formation from Benzylic Alcohols under Transition-Metal-Free Basic DMSO Conditions”, Kai Yang and Qiuling Song*, Org. Biomol. Chem. 2015, 13, 2267-2272, front cover picture

 

26.Sulfonamides Formation from Sodium Sulfinates and Amines or Ammonia under Metal-Free Conditions at Ambient Temperature”, Kai Yang, Miaolin Ke, Yuanguang Lin and Qiuling Song*Green Chem. 2015, 17, 1395 - 1399

25.Fe -Catalyzed Double Cross-Dehydrogenative Coupling of 1, 3-Dicarbonyl Compounds and Arylmethanes”, Kai Yang and Qiuling Song*Org. Lett. 201517, 548-551

 

24.“Chemoselective Acylation of Benzothiazoles with Aryl Methyl Ketones under N2 Atmosphere”, Qiang Feng and Qiuling Song*Adv. Synth. Catal. 2014356, 2445-2452

 

23.“Synthesis of α-Ketoamides from Aryl Methyl Ketone and DMF via Copper-Catalyzed Aerobic Oxidative Coupling”, Mingxin Zhou and Qiuling Song*, Synthesis2014, invited theme paper, 46, 1853-1858

 

22.“Copper-Catalyzed Decarboxylative C-N Triple Bond Formation: Direct Synthesis of Benzonitriles from Phenylacetic Acids Under O2 Atmosphere”, Qiang Feng and Qiuling Song*, Adv. Synth. Catal. 2014, 356, 1697-1702, front cover picture

 

21.A catalyst-free, facile and efficient approach to cyclic ester: synthesis of 4H-benzo[d][1,3]dioxin-4-ones,  Feng Lin, Qiuling Song, Yuyu Gao and Xiuling Cui, RSC Adv., 20144, 19856-19860

 

20.“Aldehydes and Ketones Formation: Copper-Catalyzed Aerobic Oxidative Decarboxylation of Phenylacetic Acids and α-Hydroxyphenylacetic Acids”, Qiang Feng and Qiuling Song*, J. Org. Chem. 201479, 1867-1871

 

19.“Synthesis of Primary Amides via Copper Catalyzed Aerobic Decarboxylative Ammoxidation of Phenylacetic Acids and α-Hydroxyphenylacetic Acids with Ammonia in Water”, Qiuling Song*, Qiang Feng and Kai Yang, Org. Lett. 201416, 624-627

 

18.“KI-catalyzed arylation of benzothiazoles from the coupling of aryl aldehydes with benzothiazoles in neat water”,Yuyu Gao, Qiuling Song, Guolin Cheng and Xiuling Cui, Org. Biomol. Chem. 201412, 1044-1047

 

17.“Copper-Catalyzed Oxidative Decarboxylative Arylation of Benzothiazoles with Phenylacetic Acids and a-Hydroxyphenylacetic Acids with O2 as the Sole Oxidant”, Qiuling Song*, Qiang Feng and Mingxin Zhou, Org. Lett. 201315, 5990-5993

 

16.“Synthesis of esters from aldehydes or carboxylic acids with dichloromethane, dichloroethan or dichloropropane under mild conditions”, Feng Lin, Qiang Feng, Xiuling Cui*, Qiuling Song*RSC Adv., 20133, 20246-20253

15.“Carbonylation of 1-Lithiobutadiene with Carbon Monoxide Followed by Intramolecular Acyllithiation of C=C Double Bond and Intermolecular Acylation with Acid Chloride: Scope, Applications and Mechanistic Aspects”, Heng Li,  Lantao Liu, Fei Zhao, Congyang Wang, Chao Wang, Qiuling Song, Wen-Xiong Zhang, and Zhenfeng Xi*, J. Org. Chem. 201277, 4793-4800 

14.“The supertristeroids: large, chiral, molecular bowls prepared by trimerization of pentacyclic steroidal ketones”, Qiuling Song, Douglas M. Ho, and Robert A. Pascal, Jr.*, J. Org. Chem. 2007, 72, 4449-4453 

13.“Polyphenyl macrocyclic oligophenylenes”, Qiuling Song, Christopher W. Lebeis, Xianfeng Shen, Douglas M. Ho, and Robert A. Pascal, Jr*. J. Am. Chem. Soc. 2005127, 13732-13737 

12.“Sterically congested in-methylcyclophanes”, Qiuling Song, Douglas M. Ho, and Robert A. Pascal, Jr.* J. Am. Chem. Soc2005127, 11246-11247 

11.“Concise synthesis of stereodefined dienols and cyclopentadienes via direct addition of 1-bromomagnesiobutadienes and 1-lithiobutadienes to carbonyl compounds”, Hongyun Fang, Qiuling Song, Zhihui Wang, and Zhenfeng Xi*, Tetrahedron Lett. 200445, 5159-5162  

10.“Reactions of 1,4-dilithiobutadienes with isothiocyanates: preparation of iminocyclopentadiene derivatives via cleavage of the C=S double bond of a RN=C=S molecule”, Congyang Wang, Qiuling Song, and Zhenfeng Xi*, Tetrahedron 2004, 60, 5207-5214  

9.“Preparation of S-containing heterocycles via novel reaction patterns of carbon disulfide with 1-lithiobutadienes and 1,4-dilithiobutadienes”, Congyang Wang, Jinglong Chen, Qiuling Song, Zhiping Li, and Zhenfeng Xi*, ARKIVOC 2003 (ii) 155-164

8.“Acyl-lithiation of olefins: Formation of cyclopentenones from 1-lithio-butadienes and CO”, Qiuling Song, Zhiping Li, Jinglong Chen, Congyang Wang, and Zhenfeng Xi*, Org. Lett. 2002, 4, 4627-4629 

7.“Stereoselective synthesis of polysubstituted 2,5-dihydrofurans from reaction of 1,4-dilithio-1,3-dienes with aldehydes”, Jinglong Chen, Qiuling Song, Pixu Li, Hairong Guan, Xianglin Jin, and Zhenfeng Xi*, Org. Lett. 2002, 4, 2269-2271  

6. “Novel cycloaddition of nitriles with monolithio- and dilithiobutadienes, Jinglong Chen, Qiuling Song, Congyang Wang, and Zhenfeng Xi*, J. Am. Chem. Soc. 2002124, 6238-6239 

5. “Novel reaction patterns of carbon disulfide with organolithium compounds via cleavage of C=S bonds or via cycloaddition reactions”, Jinglong Chen, Qiuling Song, and Zhenfeng Xi, Tetrahedron Lett. 2002, 43, 3533-3535  

4. “Novel synthetic methodologies based on selective cleavage of C=O bonds mediated by organometallic compounds”, Zhenfeng Xi*, Pixu Li, Qiuling Song, and Jinglong Chin. J. Org. Chem. 2001 Vol. 21 (11): 824-832 

3.“Highly regio- and stereoselective 1,1-cycloaddition of carbon monoxide with 1,4-dilithio-1,3-dienes. Novel synthetic methods for 3-cyclopenten-1-one derivatives”, Qiuling Song, Jinglong Chen, Xianglin Jin, and Zhenfeng Xi*, J. Am. Chem. Soc. 2001, 123, 10419-10420 

2.“Dialkenylation carbonyl groups by alkenyllithium compounds: Formation of cyclopentadiene derivatives by the reaction of 1,4-dilithio-1,3-dienes with ketones and aldehydes”, Zhenfeng Xi, Qiuling Song,Jinglong Chen, Hairong Guan, and Pixu Li*, Angew. Chem. Int. Ed. 2001, 40, 1913-1916

1.“Efficient synthesis of cyclopentadienone derivatives by the reaction of carbon dioxide with 1,4-dilithio-1,3-dienes”, Zhenfeng Xi*, and Qiuling SongJ. Org. Chem. 2000, 65, 9157-9159