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成果及论文

25. Y. He, M. Brjesson, H. Song, Y. Xue, D. Zeng,  M. Ruben*, S. Zhu*, Nickel-Catalyzed ipso/ortho Difunctionalization of Aryl Bromides with Alkynes and Alkyl Bromides via a Vinyl-to-Aryl 1,4-Hydride Shift. J. Am. Chem. Soc. 2021, 143, xxx–xxx.


24. Y. Zhang, J. Ma, J. Chen, L. Meng, Y. Liang*, S. Zhu*, A Relay Catalysis Strategy for Enantioselective Nickel-Catalyzed Migratory Hydroarylation Forming Chiral α-Aryl Alkylboronates. Chem 2021, 7, 3171–3188.


23. L. Meng, J. Yang, M. Duan, Y. Wang*, S. Zhu*, Facile Synthesis of Chiral Arylamines, Alkylamines and Amides by Enantioselective NiH-Catalyzed Hydroamination. Angew. Chem. Int. Ed. 2021, 60, 23584–23589.


22. J. Chen, S. Zhu*, Nickel-Catalyzed Multicomponent Coupling: Synthesis of α-Chiral Ketones by Reductive Hydrocarbonylation of Alkenes. J. Am. Chem. Soc. 2021, 143, 14089–14096.


21. F. Zhou, S. Zhu*, Catalytic Asymmetric Hydroalkylation of α,β-Unsaturated Amides Enabled by Regio-Reversed and Enantiodifferentiating syn-Hydronickellation. ACS Catal. 2021, 11, 8766–8773.

20. Y. He, B. Han, S. Zhu*, Terminal-Selective C(sp3)–H Arylation: NiH-Catalyzed Remote Hydroarylation of Unactivated Internal Olefins. Organometallics 2021, 40, 2253–2264.  (Invited in Organometallic Solutions to Challenges in Cross-Coupling special issue)

19. X. Jiang, B. Han, Y. Xue, M. Duan, Z. Gui, Y. Wang*, S. Zhu*, Nickel-Catalysed Migratory Hydroalkynylation and Enantioselective Hydroalkynylation of Olefins with Bromoalkynes. Nat. Commun. 2021, 12, 3792.



18. Y. He, H. Song, J. Chen, S. Zhu*, NiH-Catalysed Asymmetric Hydroarylation of N-Acyl Enamines to Chiral Benzylamines. Nat. Commun. 2021, 12, 638.


17. J. Liu, H. Gong,* S. Zhu*, BH3 ⋅ Me2S: An Alternative Hydride Source for NiH-Catalyzed Reductive Migratory Hydroarylation and Hydroalkenylation of Alkenes. Eur. J. Org. Chem. 2021, 1543−1546.  (Invited in Special Collections of YourJOC Talents)


16. J. Liu, H. Gong*, S. Zhu*, Nickel-Catalyzed, Regio- and Enantioselective Benzylic Alkenylation of Olefins with Alkenyl Bromide. Angew. Chem. Int. Ed. 2021, 60, 4060–4064.


15. P. Song, S. Zhu*, Nickel-Catalyzed Hydrofluorination of Unactivated Alkenes througha HAT Pathway. ACS Catal.  2020, 10, 13165−13170.


14. Y. Zhang#, J. He#, P. Song, Y. Wang*, S. Zhu*, Ligand-Enabled NiH-Catalyzed Migratory Hydroamination: Chain Walking as a Strategy for Regiodivergent/Regioconvergent Remote sp3 C–H Amination. CCS Chem. 2020, 2, 2259–2268.


13. Y. He, C. Liu, L. Yu, S. S. Zhu*, Enantio- and Regioselective NiH-Catalyzed Reductive Hydroarylation of Vinylarenes with Aryl Iodides. Angew. Chem. Int. Ed. 2020, 59, 21530−21534.


12. Y. He, C. Liu, L. Yu, S. S. Zhu*, Ligand-Enabled Nickel-Catalyzed Redox-Relay Migratory Hydroarylation of Alkenes with Arylborons. Angew. Chem. Int. Ed. 2020, 59, 9186−9191.


11. F. Chen, X. Xu, Y. He, G. Huang, S. Zhu*, NiH-Catalyzed Migratory Defluorinative Cross Olefin-Coupling: Trifluoromethyl-Substituted Alkenes as Acceptor Olefins to Form gem-Difluoroalkenes. Angew. Chem. Int. Ed. 2020, 59, 5398−5402.


10. J. He, Y. Xue, B. Han, C. Zhang, Y. Wang*, S. Zhu*, Nickel-Catalyzed Asymmetric Reductive 1,2-Carboamination of Unactivated Alkenes. Angew. Chem. Int. Ed. 2020, 59, 2328−2332.


9. Y. Zhang, B. Han, S. Zhu*, Rapid Access to Highly Functionalized Alkylboronates via NiH-Catalyzed Remote Hydroarylation of Boron-Containing Alkenes. Angew. Chem. Int. Ed. 2019, 58, 13860.


8. Y. Zhang, X. Xu, S. Zhu*, Nickel-Catalysed Selective Migratory Hydrothiolation of Alkenes and Alkynes with Thiols. Nat. Commun. 2019, 10, 1752.


7. J. He, P. Song, X. Xu, S. Zhu*, Y. Wang*, Migratory Reductive Acylation between Alkyl Halides or Alkenes and Alkyl Carboxylic Acids by Nickel Catalysis. ACS. Catal. 2019, 9, 3253.


6. F. Zhou, Y. Zhang, X. Xu, S. Zhu*, NiH-Catalyzed Remote Asymmetric Hydroalkylation of Alkenes with Racemic α-Bromo Amides. Angew. Chem. Int. Ed. 2019, 58, 1754.


5. J. Xiao, Y. He, F. Ye, S. Zhu*, Remote sp3 C–H Amination of Alkenes with Nitroarenes. Chem 2018, 4, 1645.


4. F. Zhou, J. Zhu, Y. Zhang, S. Zhu*, NiH-Catalyzed Reductive Relay Hydroalkylation: A Strategy for the Remote C(sp3)–H Alkylation of Alkenes. Angew. Chem. Int. Ed. 2018, 57, 4058.


3. F. Chen, K. Chen, Y. Zhang, Y. He, Y.-M. Wang*, S. Zhu*, Remote Migratory Cross-Electrophile Coupling and Olefin Hydroarylation Reactions Enabled by in Situ Generation of NiH. J. Am. Chem. Soc. 2017, 139, 13929.


2. Y. He, Y. Cai, S. Zhu*, Mild and Regioselective Benzylic C−H Functionalization: Ni-Catalyzed Reductive Arylation of Remote and Proximal Olefins. J. Am. Chem. Soc. 2017, 139, 1061.


1. F. Chen, Y. Zhang, L. Yu, S. Zhu*, Enantioselective NiH/Pmrox-Catalyzed 1,2-Reduction of α, β-Unsaturated Ketones. Angew. Chem. Int. Ed. 2017, 56, 2022.