西湖大学代表性成果:
19. Su, J.; Chen, K.; Kang, Q.-K.; Shi, H.* Catalytic SNAr Hexafluoroisopropoxylation of Aryl Chlorides and Bromides. Angew. Chem. Int. Ed. 2023, 62, e202302908.
18. Lin, Y.; Shi, H.* Rhodium-Catalyzed Addition of (Trialkylsilyl)arenes to Electrophiles via π‑Coordination-Driven C−Si Bond Activation. J. Am. Chem. Soc. 2023, 145, 22753.
17. Wu, W.-Q.; Lin, Y.; Li, Y.; Shi, H.* “Catalytic dehydrogenative (3 + 2) cycloaddition of alkylbenzenes via π-coordination.” J. Am. Chem. Soc. 2023, 145, 9464.
16. Su, J.; Chen, K.; Kang, Q.-K.; Shi, H.* “Catalytic SNAr hexafluoroisopropoxylation of aryl chlorides and bromides.” Angew. Chem. Int. Ed. 2023, 62, e202302908.
15. Li, K.; Wu, W.-Q.; Shi, H.* “Asymmetric hydrogenation of 1,1-diarylethylenes and benzophenones through a relay strategy.” Nat. Commun. 2023, 2170.
14. Li, Y.; Wu, W.-Q.; Zhu, H.; Kang, Q.-K.; Xu, L.; Shi, H.* "Rhodium-Catalyzed Benzylic Addition Reactions of Alkylarenes to Michael Acceptors." Angew. Chem. Int. Ed. 2022, DOI: 10.1002/anie.202207917.
13. Xu, L.; Shi, H.* "Cobalt-Catalyzed Divergent Functionalization of N-Sulfonyl Amines via β-Carbon Elimination." Sci. China: Chem. 2022, DOI:10.1007/s11426-022-1251-4.
12. Chen, K.+; Kang, Q.-K.+; Li, Y.; Wu, W.-Q.; Zhu, H.; Shi, H.* “Rhodium-Catalyzed Stereoselective Deuteration of Benzylic C–H Bonds via Reversible η6-Coordination” J. Am. Chem. Soc. 2022, 144, 1144.
11. Kang, Q.-K.+; Li, Y.+; Chen, K.; Zhu, H.; Wu, W.-Q.; Lin, Y.; Shi, H.* “Rhodium-Catalyzed Stereoselective Deuteration of Benzylic C–H Bonds via Reversible η6-Coordination” Angew. Chem. Int. Ed. 2022, DOI: 10.1002/anie.202117381.
10. Yan, X.-B.+; Li, L.+; Wu, W.-Q.; Xu, L.; Li, K.; Liu, Y.-C.; Shi, H.* “Ni-Catalyzed Hydroalkylation of Olefins with N-Sulfonyl Amines” Nat. Commun. 2021, 12, 5881.
9. Kang, Q.-K.+; Lin, Y.+; Li, Y.; Xu, L.; Li, K.; Shi, H.* “Catalytic SNAr Hydroxylation and Alkoxylation of Aryl Fluorides” Angew. Chem. Int. Ed. 2021, 60, 20391.
8. Li, L.+; Liu, Y.-C.+; Shi, H.* “Nickel-Catalyzed Enantioselective α‑Alkenylation of N‑Sulfonyl Amines: Modular Access to Chiral α‑Branched Amines” J. Am. Chem. Soc. 2021, 143, 4154.
7. Kang, Q.-K.; Lin, Y.; Li, Y.; Shi, H.* “Ru(II)-Catalyzed Amination of Aryl Fluorides via η6-Coordination” J. Am. Chem. Soc. 2020, 142, 3706.
独立前代表性成果:
6. Shi, H.; Lu, Y.; Weng, J.; Bay, K. L.; Chen, X.; Tanaka, K.; Verma, P.; Houk, K. N.*; Yu, J.-Q.* “Differentiation and functionalization of adjacent, remote C–H bonds” Nature Chemistry 2020, 12, 399.
5. Shi, H.; Herron, A. N.; Shao, Y.; Shao, Q.; Yu, J.-Q. “Enantioselective Remote meta-C‒H Arylation and Alkylation via a Chiral Transient Mediator” Nature 2018, 558, 581.
4. Shi, H.; Wang, P.; Suzuki, S.; Farmer, M. E.; Yu, J.-Q. “Ligand Promoted meta-C−H Chlorination of Anilines and Phenols” J. Am. Chem. Soc. 2016, 138, 14876.
3. Shi, H.; Braun, A.; Wang, L.; Liang, S. H.; Vasdev, N.; Ritter, T. “Synthesis of 18F-Difluoromethylarenes from Aryl (Pseudo) Halides” Angew. Chem. Int. Ed. 2016, 55,10786.
2. Shi, H.; Babinski, D.; Ritter, T. “Modular C−H Functionalization Cascade of Aryl Iodides” J. Am. Chem. Soc. 2015, 137, 3775.
1. Shi, H.; Fang, L.; Tan, C.; Shi, L.; Zhang, W.; Li, C.-C.; Luo, T.; Yang, Z. “Total Syntheses of Drimane-Type Sesquiterpenoids Enabled by a Gold-Catalyzed Tandem Reaction” J. Am. Chem. Soc. 2011, 133, 14944.