At HZNU  

19. Yanchuang Zhao, Jing Zhang, Shao-Fei Ni* and Xinxin Shao*. Synthesis of Azo-substituted BCPs via Base-promoted Halogen Atom Transfer. Org. Lett.  2024, 26, 4406-4410. https://pubs.acs.org/doi/10.1021/acs.orglett.4c01546.

18. Qiujin Fan, Yanchuang Zhao, Jintao Liang, Yan Zhang, Yuenian Xu, Qingqing Zhang, Hua Zhu, Min Jiang* and Xinxin Shao*. Nickel-free Cross-electrophile Coupling of Unactivated Alkyl Bromides with Thiosulfonates and Sulfinyl Sulfones. Org. Chem. Front. 2024, ASAP. https://pubs.rsc.org/en/content/articlelanding/2024/qo/d4qo00023d.

17. Jing Zhang#, Yanchuang Zhao#, Yu-Yi Zhu#, Peng Lei#, Hanru Liu, Chang-Sheng Wang, Shuya Xing, Yong Liu,  Shao-Fei Ni*, Thomas Castanheiro*, Li-Wen Xu and Xinxin Shao* (#: Co-first author). Base-induced Azofluoroalkylation of Unactivated Alkenes via Halogen Atom Transfer. Org. Chem. Front. 2024, ASAP. https://pubs.rsc.org/en/content/articlelanding/2024/qo/d3qo02114a.

This paper is chosen as "Hot paper".  

16. Wen Liu#, Huilin Lan#, Jia-Bo Huang, Wenting Liu, Ke-Zhi Jiang, Xuqiong Xiao, Shao-Fei Ni*, Jingsong Liu*, Ying Bai*, and Xinxin Shao* and Dianhu Zhu* (#: Co-first author). Benzyl Deuteriodifluoromethyl Sulfoxide: An Easily Accessible and Stable Reagent for Direct Deuterodifluoromethylthiolation. Org. Lett.  2024, 26, 687–691. https://pubs.acs.org/doi/10.1021/acs.orglett.3c04082.

15. Yilong Li, Lulu Liu, Dingjian Shan, Fangcan Liang, Shuo Wang, Le Yu, Ji-Quan Liu, Qingling Wang*, Xinxin Shao* and Dianhu Zhu*. Exploration on Metal-Catalytic Conversion of Sulfinyl Sulfones. ACS. Catal.  2023, 4, 13474–13483. https://pubs.acs.org/doi/10.1021/acscatal.3c03663?ref=PDF.

14. Yan Zhang, Qiujin Fan, Zhiyong Ye, Yuenian Xu, Yuhan Cao, Yong Liu, Wen Liu, and Xinxin Shao*. Zinc-induced One-pot Coupling of Alkyl Halides and Alcohols to Access CD₃-labeled Alkyl Sulfides. Cell Rep Phys. Sci. 2023, 4, 101696. https://www.cell.com/cell-reports-physical-science/fulltext/S2666-3864(23)00527-1#.

13. Yuenian Xu, Yan Zhang, Yong Liu, Wen-Wu Sun, Jie Huang, Hui He, Yingjie Wu, Wen Liu, Shao-Fei Ni*, Xu-Qiong Xiao and Xinxin Shao*. Bioinspired Zinc-mediated Umpolung Thiolation of Alkyl Electro-philes: Reaction Development, Scope and Mechanism.  Sci China Chem. 2024, 67, 898-907. https://www.sciengine.com/SCC/doi/10.1007/s11426-023-1795-9.

12. Wen Liu, Yan Zhang, Shuya Xing, Huilin Lan, Xinrui Chen, Ying Bai* and Xinxin Shao*. β-Trifluorosulfinylesters: tuneable reagents for switchable trifluoromethylsulfinylation and C–H trifluoromethylthiolation. Org. Chem. Front. 2023, 10. 2186-2192. https://pubs.rsc.org/en/content/articlelanding/2023/qo/d3qo00013c.

11. Yuenian Xu, Yong Liu, Yan Zhang, Kefang Yang, Yan Wang, Jiajian Peng, Xinxin Shao* and Ying Bai*. Nonbasic Synthesis of Thioethers via Nickel-catalyzed Reductive Thiolation Utilizing NBS-like N-Thioimides as Electrophilic Sulfur Donors. J. Org. Chem. 2023, 88, 2273. https://pubs.acs.org/doi/10.1021/acs.joc.2c02360.

10. Wen Liu, Shuya Xing,  Shao-Fei Ni*, Cheng Ma, Qiujin Fan, Zhiyong Ye, Yanchuang Zhao, Ting Ouyang, Ying Bai*, Xinxin Shao. Lewis Base-catalyzed Trifluoromethylsulfinylation of Alcohols and Phenols: Modular Synthesis of Trifluoromethanesulfinate Esters.  Org. Chem. Front. 2023, 10.  3522-3529. https://pubs.rsc.org/en/content/articlelanding/2023/qo/d3qo00500c.

9. Shuya Xing, Cheng Ma, Wen Liu, Shao-Fei Ni*, Dianhu Zhu*, Li-Wen Xu, Xinxin Shao*. Lewis Base-Catalyzed Trifluoromethylsulfinylation of Allylic Alcohols: Stability-Oriented Divergent Synthesis. Org. Lett. 2023, 25, 1066. DOI: 10.1021/acs.orglett.2c04243. https://pubs.acs.org/doi/10.1021/acs.orglett.2c04243.

8. Jing Zhang, Min Jiang, Chang-Sheng Wang*, Kai Guo*, Quan-Xin Li, Cheng Ma, Shao-Fei Ni, Gen-Qiang Chen, Yan Zong, Hua Lu*, Li-Wen Xu and Xinxin Shao*. Transition-metal free C–N bond formation from alkyl iodides and diazonium salts via halogen-atom transfer. Nat. Commun. 2022, 13, 6961.  https://www.nature.com/articles/s41467-022-35613-7

7. Yong Liu, Yuenian Xu, Yan Zhang, Wen-Chao Gao and Xinxin Shao*. “Thiol-free synthesized” and sustainable thiolating synthons for nickel-catalyzed reductive assembly of sulfides with high efficiency. Org. Chem. Front. 2022, 9, 6490. DOI：10.1039/D2QO01317G.  https://pubs.rsc.org/en/content/articlelanding/2022/qo/d2qo01317g.

6. Yan Zhang, Wen Liu, Yuenian Xu, Yong Liu, Jiajian Peng, Minyan Wang, Ying Bai, Hua Lu, Zhuangzhi Shi*, and  Xinxin Shao*.   S-(Methyl-d3) Arylsulfonothioates: A Family of Robust, Shelf-Stable, and Easily Scalable Reagents for Direct Trideuteromethylthiolation. Org. Lett. 2022, 24, 6794-6799. https://pubs.acs.org/doi/10.1021/acs.orglett.2c02680.

This paper is chosen as "Editor's choise".  
 

5. Na Xu, Han Gao, Sisi Wang, Lizhi Gai, Jiangwei Tian, Xinxin Shao*, Hua Lu*. A near-infrared photoacoustic probe for specific detection of fluoride ionin vivo. Dye and Pigments. 2022, 205, 110536. DOI：10.1016/j.dyepig.2022.110536. https://www.sciencedirect.com/science/article/pii/S0143720822004582.

• 4. Wengui Wang,
*
• Shuna Gao, Zhiying Ding, Weirui Zhu, Shuya Xing
, Shuai Zhao ,  Xinxin Shao * and Shoufeng Wang* .  Visible light-promoted carbodi(tri)fluoromethylthiolation of alkenes. J. Fluorine Chem. 2022, 254, 109949 . 

• 3. Shuya Xing
, 
• Yu-Yi Zhu
, 
• Wen Liu
, 
• Yong Liu
, 
• Jing Zhang
, 
• Huarong Zhang
, 
• Yan Wang
, 
• Shao-Fei Ni*
, and  Xinxin Shao *. C –H Fluoroalkylsulfinylation/Intramolecular Rearrangement for Precise Synthesis of Fluoroalkyl Sulfoxides . Org. Lett. 2022, 24, 3378. DOI： 10.1021/acs.orglett.2c01151 . https://pubs.acs.org/doi/10.1021/acs.orglett.2c01151

2. Yong Liu, Shuya Xing, Jing Zhang, Wen Liu, Yuenian Xu, Yan Zhang, Kefang Yang, Lei Yang, Kezhi Jiang and Xinxin Shao*. Construction of diverse C–S/C–Se bonds via nickel catalyzed reductive coupling employing thiosulfonates and a selenosulfonate under mild conditions. Org. Chem. Front. 2022, 9, 1375. DOI：10.1039/D1QO01873F.  https://pubs.rsc.org/en/content/articlelanding/2022/qo/d1qo01873f

1. Pengfei Zhou, Xinxin Shao*, and Steven J. Malcolmson*. A Diastereodivergent and Enantioselective Approach to syn- and anti-Diamines: Development of 2-Azatrienes for Cu-Catalyzed Reductive Couplings with Imines That Furnish Allylic Amines. .J. Am. Chem. Soc, 2021, 143, 13999. https://pubs.acs.org/doi/10.1021/jacs.1c07707. This work was highlighted by JACS Spotlight. 

Pre-HZNU (代表性论文)

1. Xinxin Shao.; Kangnan Li.; Steven. Malcolmson*. Enantioselective Synthesis of anti-1,2-Diamines by Cu-Catalyzed Reductive Couplings of Azadienes with Aldimines and Ketimines. J. Am. Chem. Soc, 2018, 140, 7083.

2. Kangnan Li#.; Xinxin Shao#.; Steven. Malcolmson*. 2-Azadienes as Reagents for Preparing Chiral Amines: Synthesis of 1,2-Amino Tertiary Alcohols by Cu-Catalyzed Enantioselective Reductive Couplings with Ketones. J. Am. Chem. Soc, 2018, 140, 598.(#: Co-first author)

3.Dianhu Zhu#, Xinxin Shao#, Long Lu*, Qilong Shen*.PhSO2SCF2H: A Shelf-Stable, Easily Scalable Reagent for Radical Difluoromethylthiolation. Angew. Chem. Int. Ed. 2016, 55, 15807.(#: Co-first author)

4. Xinxin Shao#, Chunfa Xu#. Long Lu*, Qilong Shen*. Shelf-Stable Electrophilic Reagents for Trifluoromethylthiolation. Acc. Chem. Res., 2015, 48, 1227. (#Co-first author) (ESI top 1% paper)

5. Feng Hu#, Xinxin Shao#, Dianhu Zhu, Long Lu, Qilong Shen*. Silver-catalyzed Decarboxylative Trifluoromethylthiolation of Aliphatic Carboxylic Acids in Aqueous Emulsion.Angew. Chem. Int. Ed. 2014, 53, 6105. (#: Co-first author)

6. Xinxin Shao, Xueqiang Wang, Tao Yang, Long Lu*, Qilong Shen*. An Electrophilic Hypervalent Iodine Reagent for Trifluoromethylthiolation. Angew. Chem. Int. Ed. 2013, 52, 3457. (Back Cover, ESI top 1% paper)

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