This review summarizes recent progress in catalyst design strategies for solar-driven H₂O₂ production, including surface tailoring, defect engineering, structural manipulation, and heterojunction regulation. Fundamental understanding, underlying catalytic mechanisms, advanced heterogeneous catalysts, current challenges, and perspectives are discussed. This review aims to provide insightful guidance and promote the rapid development of solar-driven H₂O₂ production.

DOI:https://doi.org/10.1002/aenm.202301047