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成果及论文

授权专利:

8. 邓清海李文培,邴得贤,“一种吡啶骨架NCN噁唑啉类配体的合成方法和应用”,专利号:202210949507.6

7. 邓清海成轩,殷权,江岭峰,“一种硝酸酯基转移试剂及其制备方法和应用”,专利号:202210032363.8。

6. 邓清海管笑宇,“一种喹喔啉骨架NN噁唑啉类配体及其合成方法和应用”,专利号:2022105719627.7。

5. 邓清海,任冰涛,刘炎开,江岭峰,“一种NON型手性双噁唑啉类配体及其合成方法和应用”,专利号:202010060616.3。

4. 邓清海,李思源,关振宇,“一种芳基酚类或芳基醚类衍生物的硝化方法”,专利号:201910804741.8。

3. 邓清海,李思源,关振宇,“一种以硝酸盐为硝基源的硝基烯烃衍生物的制备方法”,专利号:201910294607.8。

2. 邓清海,孙健,“一种防倒吸可调压式鼓泡器”,专利号:201710223648.9。

1. 邓清海,刘炎开,吴敦奇,“一种手性噁唑啉类NNP型配体及其合成方法和应用”,专利号:201611080343.9。


代表性论文:

26. Xuan Cheng, Quan Yin, Yi-Fei Cheng, Shao-Hua Wu, Xin-Chang Sun, De-Yi Kong & Qing-Hai Deng* Practical and regioselective halonitrooxylation of olefins to access β-halonitrates. Nat. Commun.202415, 7131.上海师范大学官网介绍上海师范大学化学与材料科学学院官网介绍X-MOL资讯化学加化学深耕堂CBG资讯科学网

25. Ling-Feng Jiang, Shao-Hua Wu, Yu-Xuan Jiang, Hong-Xiang Ma, Jia-Jun He, Yang-Bo Bi, De-Yi Kong, Yi-Fei Cheng, Xuan Cheng & Qing-Hai Deng* Enantioselective copper-catalyzed azidation/click cascade reaction for access to chiral 1,2,3-triazoles. Nat. Commun.202415, 4919.上海师范大学官网介绍上海师范大学化学与材料科学学院官网介绍科学网

24. Cheng-Zhou Lin,† Ling-Feng Jiang,† Guang-Yi Zhang, Fang-Shuai Zhou, Shao-Hua Wu, Jing Cao* and Qing-Hai Deng* Enantioselective synthesis of 3a-azido-pyrroloindolines by copper-catalyzed asymmetric dearomative azidation of tryptamines. Chem. Commun.2023, 59, 7831-7834.

23. Yu-Xuan Chen,† Tao Huo,† Quan Yin,† Ling-Feng Jiang, Xuan  Cheng, Hong-Xiang Ma, Yu-Xuan Jiang, Mei-Zhi Sun,  and Qing-Hai Deng*  Azidobenziodazolones as Azido Sources for the Enantioselective Copper-Catalyzed Azidation of N-Unprotected 3-Trifluoromethylated Oxindoles. Org.  Lett. 2023, 25, 15, 2739–2744.


22. Xuan Cheng, Quan Yin, Yu-Xuan Jiang, Ling-Feng Jiang, Si-Yuan Li, Yi-Fei Cheng, Xin-Chang Sun, Lujun Peng, Cheng Zhong, and Qing-Hai Deng* Simple and Versatile Nitrooxylation: Noncyclic Hypervalent Iodine Nitrooxylating Reagent. Angew. Chem. Int. Ed2023, e.202302521. 上海师范大学官网介绍上海师范大学化学与材料科学学院官网介绍WileyChem介绍CBG资讯“人物与科研”网易转载.


21. Wen-Pei Li,† Guo Cheng,† Si-Yuan Li, Cheng-Zhou Lin, Xiao-Yu Guan, De-Xian Bing, Jing Cao,* Di Zhu, and Qing-Hai Deng* Acid-Free Copper-Catalyzed Electrophilic Nitration of Electron-Rich Arenes with Guanidine Nitrate. J. Org. Chem. 2022, 87, 5, 3834–3840.


20. Fan, Y.-H.;  Guan,X.-Y.;  Li, W.-P.;  Lin, C.-Z.;  Bing, D.-X.;  Sun, M.-Z.;  Cheng, G.; Cao, J.*; Chen J.-J. and Deng, Q.-H.*, Synthesis of amidines via iron-catalyzed dearomative amination of β-naphthols with oxadiazolonesOrg. Chem. Front., 2022,9, 380-385.

19. Li, B.‡; Cheng, X.‡; Guan, Z.-Y.; Li, S.-Y.; Huo, T.; Cheng, G.; Fan, Y.-H.; Zhou, F.-S.; Deng, Q.-H.*, Zinc-catalyzed asymmetric nitrooxylation of β-keto esters/amides with a benziodoxole-derived nitrooxy transfer reagent. Org. Chem. Front. 2020, 7, 3509-3514.

18. Wu,  D.-Q.; Cheng, X.; Liu, Y.-K; Cheng, G.; Guan, X.-Y.; Deng, Q.-H.* A New Class of Chiral Pincer-Type PNN Ligands for Pd-Catalyzed Asymmetric Allylic Alkylation. Chin. J. Org. Chem., 2020, 40(10): 3362-3370.

17. Li, S.-Y.; Guan, Z.-Y.; Xue, J.; Zhang, G.-Y.; Guan, X.-Y.; Deng, Q.-H.*, Practical copper-catalyzed chloronitration of alkenes with TMSCl and guanidine nitrate. Org. Chem. Front. 2020, 7, 2449-2455.

Graphical abstract: Practical copper-catalyzed chloronitration of alkenes with TMSCl and guanidine nitrate

16. Blasius, C. K.; Ren, B.-T.; Bürgy, D.; Liu, Y.-K.; Li, B.; Michalsky, I.; Wadepohl, H.; Deng, Q.-H.*; Gade, L. H.*, Expanding the Boxmi Ligand Family: Synthesis and Application of NON and NSN Ligands.  J. Org. Chem.  2020, 85, 6719-6731.

15. Zhang, G.-Y.; Peng, Y.; Xue, J.; Fan, Y.-H.; Deng, Q.-H.*, Copper-catalyzed nitrene transfer/cyclization cascade to synthesize 3a-nitrogenous furoindolines and pyrroloindolines. Org. Chem. Front. 2019, 6, 3934-3938.

Graphical abstract: Copper-catalyzed nitrene transfer/cyclization cascade to synthesize 3a-nitrogenous furoindolines and pyrroloindolines

14. Mei, Y.-L.; Zhou, W.; Huo, T.; Zhou, F.-S.; Xue, J.; Zhang, G.-Y.; Ren, B.-T.; Zhong, C.; Deng, Q.-H.*, Rhodium-Catalyzed Successive C–H Bond Functionalizations To Synthesize Complex Indenols Bearing a Benzofuran Unit. Org. Lett. 2019, 21, 9598-9602.

Figure 1

13. Peng, Y.; Fan, Y.-H.; Li, S.-Y.; Li, B.; Xue, J.; Deng, Q.-H., Iron-Catalyzed Nitrene Transfer Reaction of 4-Hydroxystilbenes with Aryl Azides: Synthesis of Imines via CC Bond Cleavage. Org. Lett. 2019, 21, 8389-8394.

Figure 1

12. Wang, C.-J.; Sun, J.; Zhou, W.; Xue, J.; Ren, B.-T.; Zhang, G.-Y.; Mei, Y.-L.; Deng, Q.-H., Enantioselective Copper-Catalyzed Electrophilic Dearomative Azidation of β-Naphthols. Org. Lett. 2019, 21, 7315-7319.

Figure 1

11. Ding, W.-P.; Zhang, G.-P.; Jiang, Y.-J.; Du, J.; Liu, X.-Y.; Chen, D.; Ding, C.-H.*; Deng, Q.-H.*; Hou, X.-L.*, Electron-Deficient Alkynes as Dipolarophile in Pd-Catalyzed Enantioselective (3 + 2) Cycloaddition Reaction with Vinyl Cyclopropanes. Org. Lett. 2019, 21, 6805-6810.

Figure 1

10. Jiang, L.-F.; Ren, B.-T.; Li, B.; Zhang, G.-Y.; Peng, Y.; Guan, Z.-Y.; Deng, Q.-H., Nucleophilic Substitution of gem-Difluoroalkenes with TMSNu Promoted by Catalytic Amounts of Cs2CO3J. Org. Chem. 2019, 84, 6557-6564.

Figure 1

9. Ding, W.-P.; Du, J.; Liu, X.-Y.; Chen, D.; Ding, C.-H.*; Deng, Q.-H.*; Hou, X.-L.*, Palladium-Catalyzed [3+2] Cycloaddition of Vinylcyclopropane and Ketones. Synlett 2019, 30, 947-950.

8. Chen, X.-L.; Zhou, S.-H.; Lin, J.-H.; Deng, Q.-H.*; Xiao, J.-C.*, Difluorocarbene-derived trifluoromethylselenolation of benzyl halides. Chem. Commun. 2019, 55, 1410-1413.

7. Liu, Q.; Chen, Q.; Leng, X.; Deng, Q.-H.*; Deng, L.*, Hafnium(II) Complexes with Cyclic (Alkyl)(amino)carbene Ligation. Organometallics 2018, 37, 4186-4188.

6. Wu, D.-Q.; Guan, Z.-Y.; Peng, Y.; Sun, J.; Zhong, C.*; Deng, Q.-H.*, Iron(II) Chloride-Catalyzed Nitrene Transfer Reaction for Dearomative Amination of β-Naphthols with Aryl Azides. Adv. Synth. Catal. 2018, 360, 4720-4725.

image

5. Zhou, W.; Mei, Y.-L.; Li, B.; Guan, Z.-Y.; Deng, Q.-H.*, Synthesis of β-Alkyl 2-Hydroxychalcones by Rhodium-Catalyzed Coupling of N-Phenoxyacetamides and Nonterminal Propargyl Alcohols. Org. Lett. 2018, 20, 5808-5812.

4. Ye, Q.; Jiang, M.*; Deng, Q.-H.*; Liu, J.-T., Copper-catalyzed Intramolecular Carbotrifluoromethylation of Ene-Imines for the Construction of 3-(2,2,2-Trifluoro)ethylated 4-Amino-Chromans. Adv. Synth. Catal. 2018, 360, 1402-1406.

3. Li, Z.-R.; Wu, D.-Q.; Sun, J.; Shen, J.; Deng, Q.-H., Metal-Free Azidoarylation of Vinylcyclopropanes for the Synthesis of N3-Containing Dihydronaphthalenes. Asian J. Org. Chem. 2018, 7, 432-438.

2. Bleith, T.; Deng, Q.-H.; Wadepohl, H.; Gade, L. H., Radical Changes in Lewis Acid Catalysis: Matching Metal and Substrate. Angew. Chem. Int. Ed. 2016, 55, 7852-7856.

1. Li, Z.-R.; Bao, X.-X.; Sun, J.; Shen, J.; Wu, D.-Q.; Liu, Y.-K.; Deng, Q.-H.*; Liu, F.*, Iron-catalyzed trifluoromethylation of vinylcyclopropanes: facile synthesis of CF3–containing dihydronaphthalene derivatives. Org. Chem. Front. 2016, 3, 934-938.