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成果及论文

授权专利:

7.  邓清海成轩,殷权,江岭峰,“一种硝酸酯基转移试剂及其制备方法和应用”,专利号:202210032363.8。

6. 邓清海管笑宇,“一种喹喔啉骨架NN噁唑啉类配体及其合成方法和应用”,专利号:2022105719627.7。

5. 邓清海,任冰涛,刘炎开,江岭峰,“一种NON型手性双噁唑啉类配体及其合成方法和应用”,专利号:202010060616.3。

4. 邓清海,李思源,关振宇,“一种芳基酚类或芳基醚类衍生物的硝化方法”,专利号:201910804741.8。

3. 邓清海,李思源,关振宇,“一种以硝酸盐为硝基源的硝基烯烃衍生物的制备方法”,专利号:201910294607.8。

2. 邓清海,孙健,“一种防倒吸可调压式鼓泡器”,专利号:201710223648.9。

1. 邓清海,刘炎开,吴敦奇,“一种手性噁唑啉类NNP型配体及其合成方法和应用”,专利号:201611080343.9。


代表性论文:

24. Cheng-Zhou Lin,† Ling-Feng Jiang,† Guang-Yi Zhang, Fang-Shuai Zhou, Shao-Hua Wu, Jing Cao* and Qing-Hai Deng* Enantioselective synthesis of 3a-azido-pyrroloindolines by copper-catalyzed asymmetric dearomative azidation of tryptamines. Chem. Commun.2023, 59, 7831-7834.

23. Yu-Xuan Chen,† Tao Huo,† Quan Yin,† Ling-Feng Jiang, Xuan  Cheng, Hong-Xiang Ma, Yu-Xuan Jiang, Mei-Zhi Sun,  and Qing-Hai Deng*  Azidobenziodazolones as Azido Sources for the Enantioselective Copper-Catalyzed Azidation of N-Unprotected 3-Trifluoromethylated Oxindoles. Org.  Lett. 2023, 25, 15, 2739–2744.


22. Xuan Cheng, Quan Yin, Yu-Xuan Jiang, Ling-Feng Jiang, Si-Yuan Li, Yi-Fei Cheng, Xin-Chang Sun, Lujun Peng, Cheng Zhong, and Qing-Hai Deng* Simple and Versatile Nitrooxylation: Noncyclic Hypervalent Iodine Nitrooxylating Reagent. Angew. Chem. Int. Ed2023, e.202302521. 上海师范大学官网介绍上海师范大学化学与材料科学学院官网介绍WileyChem介绍CBG资讯“人物与科研”网易转载.


21. Wen-Pei Li,† Guo Cheng,† Si-Yuan Li, Cheng-Zhou Lin, Xiao-Yu Guan, De-Xian Bing, Jing Cao,* Di Zhu, and Qing-Hai Deng* Acid-Free Copper-Catalyzed Electrophilic Nitration of Electron-Rich Arenes with Guanidine Nitrate. J. Org. Chem. 2022, 87, 5, 3834–3840.


20. Fan, Y.-H.;  Guan,X.-Y.;  Li, W.-P.;  Lin, C.-Z.;  Bing, D.-X.;  Sun, M.-Z.;  Cheng, G.; Cao, J.*; Chen J.-J. and Deng, Q.-H.*, Synthesis of amidines via iron-catalyzed dearomative amination of β-naphthols with oxadiazolonesOrg. Chem. Front., 2022,9, 380-385.

19. Li, B.‡; Cheng, X.‡; Guan, Z.-Y.; Li, S.-Y.; Huo, T.; Cheng, G.; Fan, Y.-H.; Zhou, F.-S.; Deng, Q.-H.*, Zinc-catalyzed asymmetric nitrooxylation of β-keto esters/amides with a benziodoxole-derived nitrooxy transfer reagent. Org. Chem. Front. 2020, 7, 3509-3514.

18. Wu,  D.-Q.; Cheng, X.; Liu, Y.-K; Cheng, G.; Guan, X.-Y.; Deng, Q.-H.* A New Class of Chiral Pincer-Type PNN Ligands for Pd-Catalyzed Asymmetric Allylic Alkylation. Chin. J. Org. Chem., 2020, 40(10): 3362-3370.

17. Li, S.-Y.; Guan, Z.-Y.; Xue, J.; Zhang, G.-Y.; Guan, X.-Y.; Deng, Q.-H.*, Practical copper-catalyzed chloronitration of alkenes with TMSCl and guanidine nitrate. Org. Chem. Front. 2020, 7, 2449-2455.

Graphical abstract: Practical copper-catalyzed chloronitration of alkenes with TMSCl and guanidine nitrate

16. Blasius, C. K.; Ren, B.-T.; Bürgy, D.; Liu, Y.-K.; Li, B.; Michalsky, I.; Wadepohl, H.; Deng, Q.-H.*; Gade, L. H.*, Expanding the Boxmi Ligand Family: Synthesis and Application of NON and NSN Ligands.  J. Org. Chem.  2020, 85, 6719-6731.

15. Zhang, G.-Y.; Peng, Y.; Xue, J.; Fan, Y.-H.; Deng, Q.-H.*, Copper-catalyzed nitrene transfer/cyclization cascade to synthesize 3a-nitrogenous furoindolines and pyrroloindolines. Org. Chem. Front. 2019, 6, 3934-3938.

Graphical abstract: Copper-catalyzed nitrene transfer/cyclization cascade to synthesize 3a-nitrogenous furoindolines and pyrroloindolines

14. Mei, Y.-L.; Zhou, W.; Huo, T.; Zhou, F.-S.; Xue, J.; Zhang, G.-Y.; Ren, B.-T.; Zhong, C.; Deng, Q.-H.*, Rhodium-Catalyzed Successive C–H Bond Functionalizations To Synthesize Complex Indenols Bearing a Benzofuran Unit. Org. Lett. 2019, 21, 9598-9602.

Figure 1

13. Peng, Y.; Fan, Y.-H.; Li, S.-Y.; Li, B.; Xue, J.; Deng, Q.-H., Iron-Catalyzed Nitrene Transfer Reaction of 4-Hydroxystilbenes with Aryl Azides: Synthesis of Imines via CC Bond Cleavage. Org. Lett. 2019, 21, 8389-8394.

Figure 1

12. Wang, C.-J.; Sun, J.; Zhou, W.; Xue, J.; Ren, B.-T.; Zhang, G.-Y.; Mei, Y.-L.; Deng, Q.-H., Enantioselective Copper-Catalyzed Electrophilic Dearomative Azidation of β-Naphthols. Org. Lett. 2019, 21, 7315-7319.

Figure 1

11. Ding, W.-P.; Zhang, G.-P.; Jiang, Y.-J.; Du, J.; Liu, X.-Y.; Chen, D.; Ding, C.-H.*; Deng, Q.-H.*; Hou, X.-L.*, Electron-Deficient Alkynes as Dipolarophile in Pd-Catalyzed Enantioselective (3 + 2) Cycloaddition Reaction with Vinyl Cyclopropanes. Org. Lett. 2019, 21, 6805-6810.

Figure 1

10. Jiang, L.-F.; Ren, B.-T.; Li, B.; Zhang, G.-Y.; Peng, Y.; Guan, Z.-Y.; Deng, Q.-H., Nucleophilic Substitution of gem-Difluoroalkenes with TMSNu Promoted by Catalytic Amounts of Cs2CO3J. Org. Chem. 2019, 84, 6557-6564.

Figure 1

9. Ding, W.-P.; Du, J.; Liu, X.-Y.; Chen, D.; Ding, C.-H.*; Deng, Q.-H.*; Hou, X.-L.*, Palladium-Catalyzed [3+2] Cycloaddition of Vinylcyclopropane and Ketones. Synlett 2019, 30, 947-950.

8. Chen, X.-L.; Zhou, S.-H.; Lin, J.-H.; Deng, Q.-H.*; Xiao, J.-C.*, Difluorocarbene-derived trifluoromethylselenolation of benzyl halides. Chem. Commun. 2019, 55, 1410-1413.

7. Liu, Q.; Chen, Q.; Leng, X.; Deng, Q.-H.*; Deng, L.*, Hafnium(II) Complexes with Cyclic (Alkyl)(amino)carbene Ligation. Organometallics 2018, 37, 4186-4188.

6. Wu, D.-Q.; Guan, Z.-Y.; Peng, Y.; Sun, J.; Zhong, C.*; Deng, Q.-H.*, Iron(II) Chloride-Catalyzed Nitrene Transfer Reaction for Dearomative Amination of β-Naphthols with Aryl Azides. Adv. Synth. Catal. 2018, 360, 4720-4725.

image

5. Zhou, W.; Mei, Y.-L.; Li, B.; Guan, Z.-Y.; Deng, Q.-H.*, Synthesis of β-Alkyl 2-Hydroxychalcones by Rhodium-Catalyzed Coupling of N-Phenoxyacetamides and Nonterminal Propargyl Alcohols. Org. Lett. 2018, 20, 5808-5812.

4. Ye, Q.; Jiang, M.*; Deng, Q.-H.*; Liu, J.-T., Copper-catalyzed Intramolecular Carbotrifluoromethylation of Ene-Imines for the Construction of 3-(2,2,2-Trifluoro)ethylated 4-Amino-Chromans. Adv. Synth. Catal. 2018, 360, 1402-1406.

3. Li, Z.-R.; Wu, D.-Q.; Sun, J.; Shen, J.; Deng, Q.-H., Metal-Free Azidoarylation of Vinylcyclopropanes for the Synthesis of N3-Containing Dihydronaphthalenes. Asian J. Org. Chem. 2018, 7, 432-438.

2. Bleith, T.; Deng, Q.-H.; Wadepohl, H.; Gade, L. H., Radical Changes in Lewis Acid Catalysis: Matching Metal and Substrate. Angew. Chem. Int. Ed. 2016, 55, 7852-7856.

1. Li, Z.-R.; Bao, X.-X.; Sun, J.; Shen, J.; Wu, D.-Q.; Liu, Y.-K.; Deng, Q.-H.*; Liu, F.*, Iron-catalyzed trifluoromethylation of vinylcyclopropanes: facile synthesis of CF3–containing dihydronaphthalene derivatives. Org. Chem. Front. 2016, 3, 934-938.