成轩,河南永城
邮箱:c_xuan123@163.com
2015.09—2019.06 河南师范大学 化学教育专业 理学学士(导师:谢明胜教授、郭海明教授)
2019.09—2021.06 上海师范大学 有机化学专业 理学硕士(硕转博,导师:邓清海教授)
2021.09—2024.06 上海师范大学 环境科学与工程专业 工学博士(导师:邓清海教授)
研究方向:
1. 高碘试剂的合成和应用
2. 硝酸酯的绿色不对称合成
3. 新型手性配体的设计与合成
科研与获奖:
10. Yu-Xuan Chen,† Tao Huo,† Quan Yin,† Ling-Feng Jiang, Xuan Cheng, Hong-Xiang Ma, Yu-Xuan Jiang, Mei-Zhi Sun, and Qing-Hai Deng* Azidobenziodazolones as Azido Sources for the Enantioselective Copper-Catalyzed Azidation of N-Unprotected 3-Trifluoromethylated Oxindoles. Org. Lett. 2023, 25, 15, 2739–2744.
9. 一氧化氮供体先导化合物的绿色高效合成:新型高碘硝酸酯基转移试剂的设计及应用(2022年上海师范大学博士研究生拔尖人才培育项目)
8. 邓清海,成轩,殷权,江岭峰;一种硝酸酯基转移试剂的绿色快捷制备方法(ZL202211636307.1)
7. 邓清海,成轩,殷权,江岭峰;一种硝酸酯基转移试剂及其制备方法和应用(ZL202210032363.8)
6. Xuan Cheng, Quan Yin, Yu-Xuan Jiang, Ling-Feng Jiang, Si-Yuan Li, Yi-Fei Cheng, Xin-Chang Sun, Lujun Peng, Cheng Zhong, and Qing-Hai Deng* Simple and Versatile Nitrooxylation: Noncyclic Hypervalent Iodine Nitrooxylating Reagent. Angew. Chem. Int. Ed. 2023, e.202302521. 上海师范大学官网介绍;上海师范大学化学与材料科学学院官网介绍;WileyChem介绍;CBG资讯“人物与科研”;网易转载.
5. Ming-Sheng Xie*, Meng Shan, Ning Li, Yang-Guang Chen, Xiao-Bing Wang, Xuan Cheng, Yin Tian*, Xiao-Xia Wu, Yun Deng, Gui-Rong Qu, and Hai-Ming Guo*. Chiral 4-Aryl-Pyridine-N-oxide Nucleophilic Catalysts: Design, Synthesis, and Application in Acylative Dynamic Kinetic Resolution. ACS Catalysis, 2022, 12, 877-891.
4. 锌催化β-酮酯酰胺的不对称硝酸酯化研究(2021年上海师范大学学生科研项目,重点项目,一等奖)
3. Bin Li‡, Xuan Cheng‡, Zhen-Yu Guan, Si-Yuan Li, Tao Huo, Guo Cheng, Yan-Hui Fan, Fang-Shuai Zhou and Qing-Hai Deng*. Zinc-catalyzed asymmetric nitrooxylation of β-keto esters/amides with a benziodoxole-derived nitrooxy transfer reagent. Org. Chem. Front. 2020, 7, 3509-3514.
2. Dun-Qi Wu, Xuan Cheng, Yan-Kai Liu, Guo Cheng, Xiao-Yu Guan and Qing-Hai Deng. * A New Class of Chiral Pincer-Type PNN Ligands for Pd-Catalyzed Asymmetric Allylic Alkylation. Chin. J. Org. Chem., 2020, 40(10): 3362-3370.
1. Ming-Sheng Xie*, Xuan Cheng, Yang-Guang Chen, Xiao-Xia Wu, Gui-Rong Qu and Hai-Ming Guo* Efficient synthesis of tetrazole hemiaminal silyl ethers via three-component hemiaminal silylation. Org. Biomol. Chem., 2018, 16, 6890. (除导师外一作)