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成果及论文

独立以来,代表性研究论文:+为共同一作,*为通讯作者

(25)Defluorinative  Multi-Functionalization  of   Fluoroaryl  Sulfoxides  Enabled  by  Fluorine-Assisted  Temporary  Dearomatization.

Mengjie Hu,Yuchen Liang,Liying Ru,Sheng Ye,  Lei Zhang,  Xin Huang,  Ming Bao,  Lichun Kong,  Bo Peng* Angew. Chem. Int. Ed. 2023, e202306914.


(24) Revisiting  Aromatic  Claisen  Rearrangement  Using  Unstable  Aryl  Sulfonium/Iodonium Species: The Strategy of Breaking Up the Whole into Parts. Yuchen Liang, Bo PengAcc. Chem. Res. 202255,  2103.(Invited Review Article)


(23) Dearomative  di-  and  trifunctionalization  of  aryl  sulfoxides  via  [5,5]-rearrangement.  Mengjie  Hu,+  Yanping Liu,+  Yuchen Liang,+   Taotao Dong,  Lichun Kong,  Ming Bao,  Zhi-Xiang Wang,*  Bo Peng*  Nat Commun 2022, 13, 4719.


(22) Sulfur(IV)-mediated  umpolung  α-heterofunctionalization  of  2-oxazolines. Qifeng Zhang,Yuchen Liang,+  Ruiqi Li,  Ziyi Huang,  Lichun Kong,  Peng Du,  Bo PengChem. Sci. 2022, 13, 5164.


(21)Morita-Baylis-Hillman  Type  [3,3]-Rearrangement:  Switching  fromZ-  toE-selective  α-Arylation  by  New  Rearrangement  Partners. Lei Zhang,+  Wangzhen Bao,+  Yuchen Liang,Wenjing Pan,  Dongyang Li,  Lichun Kong,  Zhi-Xiang Wang,*  Bo PengAngew. Chem. Int. Ed. 2021, 60, 11414.


(20) Z-Selective  α-Arylation  of  α,β-Unsaturated  Nitriles  via  [3,3]-SigmatropicRearrangement.  Mengyuan Chen,+  Yuchen Liang,+  Taotao Dong,  Weijian Liang,  Yanping Liu,  Yage Zhang,  Xin Huang,  Lichun Kong,  Zhi-Xiang Wang,* Bo PengAngew. Chem. Int. Ed. 2021, 60, 2339.


(19) Asymmetric  Iodonio-[3,3]-Sigmatropic  Rearrangement  to  Access  Chiral  α-Aryl  Carbonyl  Compounds. Junsong Tian,Fan Luo,Qifeng Zhang,  Yuchen Liang,  Dongyang Li,  Yaling Zhan,  Lichun Kong,   Zhi-Xiang Wang,*  Bo Peng*  J. Am. Chem. Soc. 2020, 142, 6884.(InsideCover)


(18) Dearomatization  of  Aryl  Sulfoxides: A  Switch  between  Mono-  and  Dual-Difluoroalkylation.  Xin Huang,+  Yage Zhang,+  Weijian Liang,  Qifeng Zhang,  Yaling Zhan,  Lichun Kong, Bo PengChem. Sci. 2020, 11, 3048.


(17) Dearomative  Dual-Functionalization  of  Aryl Iodanes.  Weizhao Zhao,Xin Huang,Yaling Zhan,  Qifeng Zhang,  Dongyang Li,  Yage Zhang,  Lichun Kong,  Bo Peng* Angew. Chem. Int. Ed. 2019, 25, 17210. (Highlighted by X-mol).


(16) Theortho-Difluoroalkylation  of   Aryliodanes  with  Enol  Silyl  Ethers  through  a  Rearrangement  Enabled  by  a  Fluorine  Effect. Xin Huang,+   Yage Zhang,+   Chaoshen Zhang,+   Lei Zhang,  Ying Xu,  Lichun Kong,  Zhi-Xiang Wang,* Bo Peng*Angew. Chem. Int. Ed. 2019, 58,  5956.


(15) [3,3]  and  [5,5]-Sigmatropic  Rearrangement  of  Aryl  Sulfoxides  Using  An  “Assembly/Deprotonation”  Technology.  Lei Zhang,  Mengjie Hu,  Bo PengSynlett2019, 30, 2203. (Invited Synpact Article)


(14) Selective  [5,5]-Sigmatropic  Rearrangement  by  Assembly  of   Aryl  Sulfoxides  with  Allyl  Nitriles.  Lei Zhang,+   Jia-Ni He,Yuchen Liang,+   Mengjie Hu,  Li Shang,  Xin Huang,  Lichun Kong,  Zhi-Xiang Wang,*  Bo Peng*. Angew. Chem. Int. Ed. 2019, 58, 5316.(Highlighted by Synpacts and X-mol).


(13) Selectiveortho  C-H  Cyanoalkylation  of  (Diacetoxyiodo)  arenes  via  [3,3]-Sigmatropic  Rearrangement.  Junsong Tian,  Fan Luo,+   Chaoshen Zhang,+   Xin Huang,*  Yage Zhang,  Lei Zhang,  Lichun Kong,  Xiaochun Hu,  Zhi-Xiang Wang*Bo Peng*   Angew. Chem. Int. Ed. 2018, 57, 9078.


(12) Redox-Neutral  α-Arylation  of  Alkyl  Nitriles  with  Aryl  Sulfoxides:  A  Rapid  Electrophilic  Rearrangement.  Li Shang,+   Yonghui Chang,+   Fan Luo,  Jia-Ni He,  Xin Huang,  Lei Zhang,  Lichun Kong,  Kaixiao Li,  Bo PengJ. Am. Chem. Soc. 2017, 139, 4211. (Highlighted by Synform2017/07, A112–A114 and X-mol).


(11) α-C–H  difluoroalkylation  of   alkyl  sulfoxides  via  intermolecular  Pummerer  reaction.  Xin Huang,+   Weizhao Zhao,+   Yuchen Liang,+   Minghui Wang,   Yalin Zhan,  Yage Zhang,  Lichun Kong,  Zhi-Xiang Wang,*   Bo Peng*   Org. Chem. Front. 2021, 8, 1280.


(10) [3,3]-Sigmatropic  Rearrangement  of  Aryl  Fluoroalkyl  Sulfoxides  with  Alkyl  Nitriles.  Mengjie Hu,  Jia-Ni He,  Yanping Liu,  Taotao Dong,  Mengyuan Chen,  Chao Yan,  Yulu Ye, Bo Peng* Eur. J. Org. Chem. 2020, 193. (YourJOC Talents)


(9) Desulfurization  of  Diaryl(heteroaryl)  Sulfoxides  with  Benzyne.  De-Li Chen,Yan Sun,Mengyuan Chen,  Xiaojin Li,  Lei Zhang,  Xin Huang,  Yihui Bai,  Fang Luo,  Bo Peng*  Org. Lett. 2019, 21, 3986.


(8) Benzyne-mediated  trichloromethylation  of  chiral  oxazolines.  Xin Huang,Weizhao Zhao,+  De-Li Chen,  Yaling Zhan,  Tingting Zeng, Huiquan Jin, Bo PengChem. Commun. 2019, 55,  2070.


(7) Reductiveortho C-H  Cyanoalkylation  of  Aryl(Heteroaryl)  Sulfoxides:  A  General  Approach  to  α-Aryl(Heteroaryl)  Nitriles.  Fan Luo,  Yu Lu,  Mengjie Hu,  Junsong Tian,  Lei Zhang,  Wangzhen Bao,  Chao Yan,  Xin Huang,  Zhi-Xiang Wang*Bo PengOrg. Chem. Front. 2018, 5, 1756. (InsideCover)



(6) Recyclable  Organocatalysts  for  One-pot  Asymmetric  Synthesis  of  2-Fluorocyclohexanols  Bearing  Six  Contiguous  Stereocenters.  Xin Huang,*  Miao Liu,  Jerry P.  Jasinski,  Bo Peng,  Wei Zhang*  Adv. Synth. Catal. 2017, 359, 1919.


(5) Facile  and  Selective  Synthesis  of  Imidazobenzimidazoles  via  a  Copper-Catalysed  Domino  Addition/Cycloisomerisation/Coupling Process.  Bingqing Xu,  Bo Peng,  Bili Cai,  Shishi Wang,  Xiaoxia Wang,  Xin Lv*  Adv. Synth. Catal. 2017, 358, 653.


(4) Synthesis  of  o-Aryloxy  Triarylsulfonium  Salts  via  Aryne  Insertion  into  Diaryl  Sulfoxides.  Xiaojin Li,  Yan Sun,  Xin Huang,  Lei Zhang,  Lichun Kong,  Bo PengOrg. Lett. 2017, 19, 838.


(3) Mild  Ring  Contractions  of  Cyclobutanols  to  Cyclopropyl  Ketones  via  Hypervalent  Iodine  Oxidation.  Yan Sun,  Xin Huang,  Xiaojin Li,  Fan Luo,  Lei Zhang,  Mengyuan Chen,  Shiya Zheng,  Bo PengAdv. Synth. Catal. 2017, 360, 1082.


(2) Mild  Synthesis  of  Triarylsulfonium  Salts  with  Arynes.  Lei Zhang,  Xiaojin Li,  Yan Sun,  Weizhao Zhao,  Fan Luo,  Xin Huang,  Lihui Lin,  Ying Yang,  Bo PengOrg. Biomol. Chem. 2017, 15, 7181.


(1) Recent  progress  in  the  chemistry  of  keteniminium  salts.  Xiaojin Li,  Yan Sun,  Lei Zhang,  Bo PengChin. J. Org. Chem. 2016, 36, 2530.(Review Article)


学术报告


1.彭勃,基于烯酮亚胺盐的亲电重排反应,第十四届全国均相催化学术讨论会,大连,2015.09.22-2015.09.25

2.彭勃,酰胺的亲电重排反应,中国化学会2015年化学青年学术论坛,福州市,2015.12.25-2015.12.28

3.彭勃,无金属参与的有机氰化物的α芳基化,中国化学会第30届学术年会,大连,2016.07.01-2016.07.04

4.彭勃,重排反应制备α-芳基氰化合物,中国化学会第十届全国有机化学学术会议,深圳,2017.12.19-2017.12.21

5.彭勃,Congestion-Accelerated [3,3]-Sigmatropic Rearrangement towards Synthesis of α-Aryl Nitriles,第十五届全国有机合成化学学术研讨会,兰州,2018.8.2-2018.8.5

6.彭勃,Aromatic Cyanoalkylation via Congestion-Accelerated [3,3]-Sigmatropic Rearrangement,第二十届全国金属有机化学学术讨论会,南京,2018.11.01-2018.11.04

7.彭勃,Fluorine Effect Enables [3,3]-Sigmatropic Rearrangement of Aryliodanes with Difluoroenol Silyl Ethers,中国高价碘化学学术研讨会,天津,2019.03.09-2019.03.10

8.彭勃,经由σ重排的芳基亚砜邻、对位选择性C-H键烷基化,全国第十六届有机合成化学学术研讨会,开封,2019.08.08-2019.08.11

9.彭勃,新型芳烃σ重排反应的发现,中国化学会第十一届全国有机化学学术会议,上海,2019.08.31-2019.09.03

10.彭勃,The Rearrangement of Aryl Sulfoxides with Nitriles, 29th International Symposium on the Organic Chemistry of Sulfur, University of Guelph, Canada. 2022.07.17-2022.07.22. (online)

11.彭勃,重访芳烃Claisen重排,中国化学会第十二届全国有机化学学术会议,合肥,2022.09.25-2022.09.29.

12.彭勃,芳烃Claisen重排反应的新机遇,中国化学会第十七届全国有机合成化学学术会议,济南,2022.11.10-2022.11.13


博士及博士后期间代表论文及成果


1.       Peng, B.; Huang, X.; Xie, L.; Maulide, N.* Angew. Chem., Int. Ed. 2014, 53, 8718. (hot paper, inside cover )

2.       Peng, B.; Geerdink, D.; Farès, C.; Maulide, N.* Angew. Chem., Int. Ed. 2014, 53, 5462. (VIP paper)

3.       Peng, B.; Geerdink, D.; Maulide, N.* J. Am. Chem. Soc. 2013, 135, 14968.

4.       Jurberg, I. D.;Peng, B.; Wöstefeld, E.; Wasserloos, M.; Maulide, N.* Angew. Chem., Int. Ed.2012, 51, 1950.

5.       Huang, X.;Peng, B.; Luparia, M.; Gomes, L. F. R.; Veiros, L. F.; Maulide N.* Angew. Chem., Int. Ed.2012, 51, 8886.

6.       Peng, B.; Maulide, N.* Chem. Eur. J. 2013, 19, 13274.

7.       Peng, B.; O’Donovan, D. H.; Jurberg, I. D.; Maulide, N.* Chem. Eur. J. 2012, 18, 16292.

8.       Shaaban, S.;Peng, B.; Maulide N.* Synlett. 2013, 24, 1722.

9.       Maulide, N.;Peng, B.German patent, 2013, 13169588.4.

10.    Peng, B.; Zhang, S.; Yu, X.; Feng, X.; Bao, M.* Org. Lett. 2011, 13, 5402.

11.    Peng, B.; Feng, X.; Zhang, X.; Zhang, S.; Bao, M.* J. Org. Chem. 2010, 75, 2619.

12.    Peng, B.; Feng, X.; Zhang, X.; Ji, L.; Bao M.* Tetrahedron 2010, 66, 6013.