独立以来,代表性研究论文:“+”为共同一作,“*”为通讯作者
(25)Defluorinative Multi-Functionalization of Fluoroaryl Sulfoxides Enabled by Fluorine-Assisted Temporary Dearomatization.
Mengjie Hu,+ Yuchen Liang,+ Liying Ru,+ Sheng Ye, Lei Zhang, Xin Huang, Ming Bao, Lichun Kong, Bo Peng* Angew. Chem. Int. Ed. 2023, e202306914.
(24) Revisiting Aromatic Claisen Rearrangement Using Unstable Aryl Sulfonium/Iodonium Species: The Strategy of Breaking Up the Whole into Parts. Yuchen Liang, Bo Peng* Acc. Chem. Res. 2022, 55, 2103.(Invited Review Article)
(23) Dearomative di- and trifunctionalization of aryl sulfoxides via [5,5]-rearrangement. Mengjie Hu,+ Yanping Liu,+ Yuchen Liang,+ Taotao Dong, Lichun Kong, Ming Bao, Zhi-Xiang Wang,* Bo Peng* Nat Commun 2022, 13, 4719.
(22) Sulfur(IV)-mediated umpolung α-heterofunctionalization of 2-oxazolines. Qifeng Zhang,+ Yuchen Liang,+ Ruiqi Li, Ziyi Huang, Lichun Kong, Peng Du, Bo Peng* Chem. Sci. 2022, 13, 5164.
(21)Morita-Baylis-Hillman Type [3,3]-Rearrangement: Switching fromZ- toE-selective α-Arylation by New Rearrangement Partners. Lei Zhang,+ Wangzhen Bao,+ Yuchen Liang,+ Wenjing Pan, Dongyang Li, Lichun Kong, Zhi-Xiang Wang,* Bo Peng* Angew. Chem. Int. Ed. 2021, 60, 11414.
(20) Z-Selective α-Arylation of α,β-Unsaturated Nitriles via [3,3]-SigmatropicRearrangement. Mengyuan Chen,+ Yuchen Liang,+ Taotao Dong, Weijian Liang, Yanping Liu, Yage Zhang, Xin Huang, Lichun Kong, Zhi-Xiang Wang,* Bo Peng* Angew. Chem. Int. Ed. 2021, 60, 2339.
(19) Asymmetric Iodonio-[3,3]-Sigmatropic Rearrangement to Access Chiral α-Aryl Carbonyl Compounds. Junsong Tian,+ Fan Luo,+ Qifeng Zhang, Yuchen Liang, Dongyang Li, Yaling Zhan, Lichun Kong, Zhi-Xiang Wang,* Bo Peng* J. Am. Chem. Soc. 2020, 142, 6884.(InsideCover)
(18) Dearomatization of Aryl Sulfoxides: A Switch between Mono- and Dual-Difluoroalkylation. Xin Huang,+ Yage Zhang,+ Weijian Liang, Qifeng Zhang, Yaling Zhan, Lichun Kong, Bo Peng* Chem. Sci. 2020, 11, 3048.
(17) Dearomative Dual-Functionalization of Aryl Iodanes. Weizhao Zhao,+ Xin Huang,+ Yaling Zhan, Qifeng Zhang, Dongyang Li, Yage Zhang, Lichun Kong, Bo Peng* Angew. Chem. Int. Ed. 2019, 25, 17210. (Highlighted by X-mol).
(16) Theortho-Difluoroalkylation of Aryliodanes with Enol Silyl Ethers through a Rearrangement Enabled by a Fluorine Effect. Xin Huang,+ Yage Zhang,+ Chaoshen Zhang,+ Lei Zhang, Ying Xu, Lichun Kong, Zhi-Xiang Wang,* Bo Peng*. Angew. Chem. Int. Ed. 2019, 58, 5956.
(15) [3,3] and [5,5]-Sigmatropic Rearrangement of Aryl Sulfoxides Using An “Assembly/Deprotonation” Technology. Lei Zhang, Mengjie Hu, Bo Peng* Synlett. 2019, 30, 2203. (Invited Synpact Article)
(14) Selective [5,5]-Sigmatropic Rearrangement by Assembly of Aryl Sulfoxides with Allyl Nitriles. Lei Zhang,+ Jia-Ni He,+ Yuchen Liang,+ Mengjie Hu, Li Shang, Xin Huang, Lichun Kong, Zhi-Xiang Wang,* Bo Peng*. Angew. Chem. Int. Ed. 2019, 58, 5316.(Highlighted by Synpacts and X-mol).
(13) Selectiveortho C-H Cyanoalkylation of (Diacetoxyiodo) arenes via [3,3]-Sigmatropic Rearrangement. Junsong Tian, Fan Luo,+ Chaoshen Zhang,+ Xin Huang,* Yage Zhang, Lei Zhang, Lichun Kong, Xiaochun Hu, Zhi-Xiang Wang*, Bo Peng* Angew. Chem. Int. Ed. 2018, 57, 9078.
(12) Redox-Neutral α-Arylation of Alkyl Nitriles with Aryl Sulfoxides: A Rapid Electrophilic Rearrangement. Li Shang,+ Yonghui Chang,+ Fan Luo, Jia-Ni He, Xin Huang, Lei Zhang, Lichun Kong, Kaixiao Li, Bo Peng* J. Am. Chem. Soc. 2017, 139, 4211. (Highlighted by Synform2017/07, A112–A114 and X-mol).
(11) α-C–H difluoroalkylation of alkyl sulfoxides via intermolecular Pummerer reaction. Xin Huang,+ Weizhao Zhao,+ Yuchen Liang,+ Minghui Wang, Yalin Zhan, Yage Zhang, Lichun Kong, Zhi-Xiang Wang,* Bo Peng* Org. Chem. Front. 2021, 8, 1280.
(10) [3,3]-Sigmatropic Rearrangement of Aryl Fluoroalkyl Sulfoxides with Alkyl Nitriles. Mengjie Hu, Jia-Ni He, Yanping Liu, Taotao Dong, Mengyuan Chen, Chao Yan, Yulu Ye, Bo Peng* Eur. J. Org. Chem. 2020, 193. (YourJOC Talents)
(9) Desulfurization of Diaryl(heteroaryl) Sulfoxides with Benzyne. De-Li Chen,+ Yan Sun,+ Mengyuan Chen, Xiaojin Li, Lei Zhang, Xin Huang, Yihui Bai, Fang Luo, Bo Peng* Org. Lett. 2019, 21, 3986.
(8) Benzyne-mediated trichloromethylation of chiral oxazolines. Xin Huang,+ Weizhao Zhao,+ De-Li Chen, Yaling Zhan, Tingting Zeng, Huiquan Jin, Bo Peng* Chem. Commun. 2019, 55, 2070.
(7) Reductiveortho C-H Cyanoalkylation of Aryl(Heteroaryl) Sulfoxides: A General Approach to α-Aryl(Heteroaryl) Nitriles. Fan Luo, Yu Lu, Mengjie Hu, Junsong Tian, Lei Zhang, Wangzhen Bao, Chao Yan, Xin Huang, Zhi-Xiang Wang*, Bo Peng* Org. Chem. Front. 2018, 5, 1756. (InsideCover)
(6) Recyclable Organocatalysts for One-pot Asymmetric Synthesis of 2-Fluorocyclohexanols Bearing Six Contiguous Stereocenters. Xin Huang,* Miao Liu, Jerry P. Jasinski, Bo Peng, Wei Zhang* Adv. Synth. Catal. 2017, 359, 1919.
(5) Facile and Selective Synthesis of Imidazobenzimidazoles via a Copper-Catalysed Domino Addition/Cycloisomerisation/Coupling Process. Bingqing Xu, Bo Peng, Bili Cai, Shishi Wang, Xiaoxia Wang, Xin Lv* Adv. Synth. Catal. 2017, 358, 653.
(4) Synthesis of o-Aryloxy Triarylsulfonium Salts via Aryne Insertion into Diaryl Sulfoxides. Xiaojin Li, Yan Sun, Xin Huang, Lei Zhang, Lichun Kong, Bo Peng* Org. Lett. 2017, 19, 838.
(3) Mild Ring Contractions of Cyclobutanols to Cyclopropyl Ketones via Hypervalent Iodine Oxidation. Yan Sun, Xin Huang, Xiaojin Li, Fan Luo, Lei Zhang, Mengyuan Chen, Shiya Zheng, Bo Peng* Adv. Synth. Catal. 2017, 360, 1082.
(2) Mild Synthesis of Triarylsulfonium Salts with Arynes. Lei Zhang, Xiaojin Li, Yan Sun, Weizhao Zhao, Fan Luo, Xin Huang, Lihui Lin, Ying Yang, Bo Peng* Org. Biomol. Chem. 2017, 15, 7181.
(1) Recent progress in the chemistry of keteniminium salts. Xiaojin Li, Yan Sun, Lei Zhang, Bo Peng* Chin. J. Org. Chem. 2016, 36, 2530.(Review Article)
学术报告
1.彭勃,基于烯酮亚胺盐的亲电重排反应,第十四届全国均相催化学术讨论会,大连,2015.09.22-2015.09.25
2.彭勃,酰胺的亲电重排反应,中国化学会2015年化学青年学术论坛,福州市,2015.12.25-2015.12.28
3.彭勃,无金属参与的有机氰化物的α芳基化,中国化学会第30届学术年会,大连,2016.07.01-2016.07.04
4.彭勃,重排反应制备α-芳基氰化合物,中国化学会第十届全国有机化学学术会议,深圳,2017.12.19-2017.12.21
5.彭勃,Congestion-Accelerated [3,3]-Sigmatropic Rearrangement towards Synthesis of α-Aryl Nitriles,第十五届全国有机合成化学学术研讨会,兰州,2018.8.2-2018.8.5
6.彭勃,Aromatic Cyanoalkylation via Congestion-Accelerated [3,3]-Sigmatropic Rearrangement,第二十届全国金属有机化学学术讨论会,南京,2018.11.01-2018.11.04
7.彭勃,Fluorine Effect Enables [3,3]-Sigmatropic Rearrangement of Aryliodanes with Difluoroenol Silyl Ethers,中国高价碘化学学术研讨会,天津,2019.03.09-2019.03.10
8.彭勃,经由σ重排的芳基亚砜邻、对位选择性C-H键烷基化,全国第十六届有机合成化学学术研讨会,开封,2019.08.08-2019.08.11
9.彭勃,新型芳烃σ重排反应的发现,中国化学会第十一届全国有机化学学术会议,上海,2019.08.31-2019.09.03
10.彭勃,The Rearrangement of Aryl Sulfoxides with Nitriles, 29th International Symposium on the Organic Chemistry of Sulfur, University of Guelph, Canada. 2022.07.17-2022.07.22. (online)
11.彭勃,重访芳烃Claisen重排,中国化学会第十二届全国有机化学学术会议,合肥,2022.09.25-2022.09.29.
12.彭勃,芳烃Claisen重排反应的新机遇,中国化学会第十七届全国有机合成化学学术会议,济南,2022.11.10-2022.11.13
博士及博士后期间代表论文及成果
1. Peng, B.; Huang, X.; Xie, L.; Maulide, N.* Angew. Chem., Int. Ed. 2014, 53, 8718. (hot paper, inside cover )
2. Peng, B.; Geerdink, D.; Farès, C.; Maulide, N.* Angew. Chem., Int. Ed. 2014, 53, 5462. (VIP paper)
3. Peng, B.; Geerdink, D.; Maulide, N.* J. Am. Chem. Soc. 2013, 135, 14968.
4. Jurberg, I. D.;Peng, B.; Wöstefeld, E.; Wasserloos, M.; Maulide, N.* Angew. Chem., Int. Ed., 2012, 51, 1950.
5. Huang, X.;Peng, B.; Luparia, M.; Gomes, L. F. R.; Veiros, L. F.; Maulide N.* Angew. Chem., Int. Ed., 2012, 51, 8886.
6. Peng, B.; Maulide, N.* Chem. Eur. J. 2013, 19, 13274.
7. Peng, B.; O’Donovan, D. H.; Jurberg, I. D.; Maulide, N.* Chem. Eur. J. 2012, 18, 16292.
8. Shaaban, S.;Peng, B.; Maulide N.* Synlett. 2013, 24, 1722.
9. Maulide, N.;Peng, B.German patent, 2013, 13169588.4.
10. Peng, B.; Zhang, S.; Yu, X.; Feng, X.; Bao, M.* Org. Lett. 2011, 13, 5402.
11. Peng, B.; Feng, X.; Zhang, X.; Zhang, S.; Bao, M.* J. Org. Chem. 2010, 75, 2619.
12. Peng, B.; Feng, X.; Zhang, X.; Ji, L.; Bao M.* Tetrahedron 2010, 66, 6013.