发表论著与发明专利

近年，针对水处理高能耗低效率瓶颈，在国际上首次提出突破经典芬顿原理的双反应中心（DRC）水处理技术原理并成功构建DRC水处理体系，实现污染物高效低耗转化和去除，并系统研究“DRC催化剂-污染物-H2O/O2/复杂环境因子”多介质界面过程和水自净化机制，在《美国国家科学院院刊（PNAS）》、Nature旗下水资源领域顶刊NPJ Clean Water和环境领域顶尖期刊Environmental Science & Technology、Applied Catalysis B: Environmental等国际权威刊物发表高水平学术论文80余篇，申请发明专利50余项（已获授权37余项），相关成果被中试应用。

代表性论著：

[1] Wenrui Cao, Chun Hu, Peng Zhang, Ting Qiu, Shuguang Wang, Guohe Huang, Lai Lyu*. Salinity-mediated water self-purification via bond network distorting of H2O molecules on DRC-surface. Proceedings of The National Academy of Sciences of The United States of America (Proc. Natl. Acad. Sci. USA), 2023, 120(45), e2311920120 (JCR-Q1,世界四大顶刊之一)

[2] Yingtao Sun, Chun Hu, Lai Lyu*. New sustainable utilization approach of livestock manure: Conversion to dual-reaction-center Fenton-like catalyst for water purification. NPJ Clean Water, 2022, 5, 53. (JCR-Q1, Nature旗下水资源领域顶刊, IF=12.190)

[3] Wenrui Cao, Zhongkai Wang, Peng Zhang, Yingtao Sun, Zhiju Xie, Chun Hu, Shuguang Wang, Guohe Huang, Lai Lyu*. Water self-purification with zero-external consumption by livestock manure resource utilization. Environmental Science & Technology, 2023, 57, 2837-2845. (JCR-Q1, 环境领域顶刊, IF=11.357)

[4] Sihui Zhan, Hongxiang Zhang, Xueyue Mi, Yubao Zhao, Chun Hu, Lai Lyu*. Efficient Fenton-like process for pollutant removal in electron-rich/poor reaction sites induced by surface oxygen vacancy over cobalt-zinc oxides. Environmental Science & Technology, 2020, 54, 8333-8343. (JCR-Q1, 环境领域顶刊, IF=11.357)

[5] Lai Lyu, Guangfei Yu, Lili Zhang, Chun Hu*, Yong Sun. 4-Phenoxyphenol -functionalized reduced graphene oxide nanosheets: A metal-free Fenton-like catalyst for pollutant destruction. Environmental Science & Technology, 2018, 52, 747-756. (JCR-Q1, 环境领域顶刊, IF=11.357, Online Cover Paper, 2019.7/8-ESI高被引论文)

[6] Lai Lyu, Dengbiao Yan, Guangfei Yu, Wenrui Cao, Chun Hu*. Efficient destruction of pollutants in water by a dual-reaction-center Fenton-like process over carbon nitride compounds-complexed Cu(II)-CuAlO2. Environmental Science & Technology, 2018, 52, 4294-4304. (JCR-Q1, 环境领域顶刊, IF=11.357, 2020.1/2, 2020.5/6-ESI高被引论文)

[7] Lai Lyu, Lili Zhang, Qiyuan Wang, Yulun Nie, Chun Hu*. Enhanced Fenton catalytic efficiency of γ-Cu-Al2O3 by σ-Cu2+-ligand complexes from aromatic pollutant degradation. Environmental Science & Technology, 2015, 49, 8639-8647. (JCR-Q1, 环境领域顶刊, IF=11.357)

[8] Chao Lu, Chun Hu, Hongwei Rong,  Lai Lyu*.  Low-consumption water purification: Trace H2O2 triggering H2O2 generation through pollutant utilization on non-equilibrium ZnS surface. Applied Catalysis B: Environmental, 2023, 338, 123051. (JCR-Q1, IF=24.319)

[9] Lai Lyu, Chao Lu, Yingtao Sun, Wenrui Cao, Tingting Gao, Chun Hu*. Low consumption Fenton-like water purification through pollutants as electron donors substituting H2O2 consumption via twofold cation-π over MoS2 cross-linking g-C3N4 hybrid. Applied Catalysis B: Environmental, 2023, 320, 121871. (JCR-Q1, IF=24.319)

[10] Hongxiang Zhang, Chenwei Li, Lai Lyu*, Chun Hu. Surface oxygen vacancy inducing peroxymonosulfate activation through electron donation of pollutants over cobalt-zinc ferrite for water purification. Applied Catalysis B: Environmental, 2020, 270, 118874. (JCR-Q1, IF= 24.319, ESI高被引论文)

[11] Liang Wang, Xuan Huang, Muen Han, Lai Lyu*, Tong Li, Yaowen Gao, Qingyi Zeng, Chun Hu. Efficient inhibition of photogenerated electron-hole recombination through persulfate activation and dual-pathway degradation of micropollutants over iron molybdate. Applied Catalysis B: Environmental, 2019, 257, 117904. (JCR-Q1, IF= 24.319)

[12] Congfeng Xu, Zheng Bao, Chun Hu, Lai Lyu*. Surface electron-polarized biochar-enhanced anaerobic digestion mechanism revealed by metagenomic binning strategy. Chemical Engineering Journal, 2023, 144474. (JCR-Q1, IF= 16.744)

[13] Lai Lyu, Lili Zhang, Chun Hu*. Enhanced Fenton-like degradation of pharmaceuticals over framework copper species in copper-doped mesoporous silica microspheres. Chemical Engineering Journal, 2015, 274, 298-306. (JCR-Q1, IF= 16.744)

[14] Lai Lyu, Lili Zhang, Guangzhi He, Hong He, Chun Hu*. Selective H2O2 conversion to hydroxyl radicals in electron-rich area of hydroxylated C-g-C3N4/CuCo-Al2O3. Journal of Materials Chemistry A, 2017, 5, 7153-7164. (JCR-Q1, IF=14.511, 入选2017 JMCA HOT Papers)

[15] Lai Lyu, Lili Zhang, Chun Hu*, Min Yang. Enhanced Fenton-catalytic efficiency by highly accessible active sites on dandelion-like copper–aluminum–silica nanospheres for water purification. Journal of Materials Chemistry A, 2016, 4, 8610-8619. (JCR-Q1, IF=14.511, 入选2016 JMCA HOT Papers)

[16] Wenrui Cao, Lai Lyu*, Kanglan Deng, Chao Lu, Chun Hu. L-ascorbic acid oxygen-induced micro-electronic field over metal-free polyimide for peroxymonosulfate activation to realize efficient multi-pathway destruction of contaminants. Journal of Materials Chemistry A, 2020, 8, 810-819. (JCR-Q1, IF=14.511)

[17] Lai Lyu, Wenrui Cao, Guangfei Yu, Dengbiao Yan, Kanglan Deng, Chao Lu, Chun Hu*. Enhanced polarization of electron-poor/rich micro-centers over nZVCu-Cu(II)-rGO for pollutant removal with H2O2. Journal of Hazardous Materials, 2020, 383, 121182. (JCR-Q1, IF= 14.224)

[18] Wenrui Cao, Yongxiang Luo, Xuanying Cai, Shuguang Wang, Chun Hu, Lai Lyu*. π-π conjugation driving peroxymonosulfate activation for pollutant elimination over metal-free graphitized polyimide surface. Journal of Hazardous Materials, 2021, 412, 125191. (JCR-Q1, IF= 14.224)

[19] Tingting gao, Chao Lu, Chun Hu, Lai Lyu*. H2O2 inducing dissolved oxygen activation and electron donation of pollutants over Fe-ZnS quantum dots through surface electron-poor/rich microregion construction for water treatment. Journal of Hazardous Materials, 2021, 420, 126579. (JCR-Q1, IF= 14.224)

[20] Xueci Xing#, Lai Lyu#, Zhen Yan#, Han Zhang, Tong Li, Muen Han, Zesong Li, Fagen Zhang, Zhu Wang, Shuguang Wang, Yiguo Hong, Chun Hu*. Self-purification of actual wastewater via microbial-synergy driving of catalyst-surface microelectronic field: A pilot-scale study. Journal of Hazardous Materials, 2023, 457, 131744. (JCR-Q1, IF= 14.224)

[21] Han Zhang#, Lai Lyu#, Chun Hu*, Tong Ren, Fan Li, Yuhao Shi, Muen Han, Yingtao Sun, Fagen Zhang. Enhanced purification of kitchen-oil wastewater driven synergistically by surface microelectric fields and microorganisms. Environment International, 2023, 174, 107878. (JCR-Q1, IF=13.352)

[22] Wenrui Cao, Muen Han, Lai Lyu*, Chun Hu, Feng Xiao. Efficient Fenton-like process induced by fortified electron-rich O microcenter on the reduction state Cu-doped CNO polymer. ACS Applied Materials & Interfaces, 2019, 11, 16496-16505. (JCR-Q1, IF=10.383)

[23] Muen Han, Lai Lyu*, Yinmei Huang, Junrong Liang, Meimei Xue, Tao Wu, Jiyi Li, Meiping Chen, Chun Hu. In situ generation and efficient activation of H2O2 for pollutant degradation over CoMoS2 nanosphere-embedded rGO nanosheets and its interfacial reaction mechanism. Journal of Colloid and Interface Science, 2019, 543, 214-224. (JCR-Q1, IF=9.965)

[24] Liang Wang, Dengbiao Yan, Lai Lyu*, Chun Hu, Ning Jiang, Lili Zhang. Notable light-free catalytic activity for pollutant destruction over flower-like BiOI microspheres by a dual-reaction-center Fenton-like process. Journal of Colloid and Interface Science, 2018, 527, 251-259. (JCR-Q1, IF=9.965, Cover Paper)

[25] Xuejian Zhang#, Junrong Liang#, Yong Sun, Fagen Zhang, Chenwei Li, Chun Hu, Lai Lyu*. Mesoporous reduction state cobalt species-doped silica nanospheres: An efficient Fenton-like catalyst for dual-pathway degradation of organic pollutants. Journal of Colloid and Interface Science, 2020, 576, 59-67. (JCR-Q1, IF=9.965)

[26] Yumeng Wang, Qian Fang, Zhiju Xie, Chun Hu, Lai Lyu*. Enhanced Fenton-like porcesss via interfacial electron donating of pollutants over in situ cobalt-doped graphitic carbon nitride. Journal of Colloid and Interface Science, 2022, 608, 673-682. (JCR-Q1, IF=9.965)

[27] Chenwei Li#, Xuanying Cai#, Qian Fang#, Yongxiang Luo#, Peng Zhang, Chao Lu, Muen Han, Chun Hu, Lai Lyu*. Peroxymonosulfate as inducer driving interfacial electron donation of pollutants over oxygen-rich carbon-nitrogen graphene-like nanosheets for water treatment. Journal of Colloid and Interface Science, 2022, 622, 272-283. (JCR-Q1, IF=9.965)

[28] Lai Lyu, Muen Han, Wenrui Cao, Yaowen Gao, Qingyi Zeng, Guangfei Yu, Xuan Huang, Chun Hu*. Efficient Fenton-like process for organic pollutant degradation on Cu-doped mesoporous polyimide nanocomposites. Environmental Science: Nano, 2019, 6, 798-808. (JCR-Q1, IF=9.473, Environmental Science: Nano Recent HOT Articles)

[29] Lai Lyu, Lili Zhang, Chun Hu*. Galvanic-like cells produced by negative charge nonuniformity of lattice oxygen on d-TiCuAl-SiO2 nanospheres for enhancement of Fenton-catalytic efficiency. Environmental Science: Nano, 2016, 3, 1483-1492. (JCR-Q1, IF=9.473)

[30] Kanglan Deng#, Tingting Gao#, Qian Fang, Feiyun Wu, Chao Lu, Fan Zhang, Wenrui Cao, Muen Han, Chun Hu, Lai Lyu*. Vanadium tetrasulfide cross-linking graphene-like carbon driving a sustainable electron supply chain from pollutants through the activation of dissolved oxygen and hydrogen peroxide. Environmental Science: Nano, 2021, 8, 86-96. (JCR-Q1, IF=9.473, Environmental Science: Nano Recent HOT Articles, 封面论文)

[31] Yingtao Sun#, Ruixin Yi#, Chun Hu, Lai Lyu*. Enhanced purification efficiency of pharmaceutical wastewater through pollutant-mediated H2O2 activation pathway over CuZnS nano-aggregated particles. Environmental Science: Nano, 2022, 9, 4317-4324. (JCR-Q1, IF=9.473)

[32] Muen Han, Guoyu Liang, Su Zhou, Zitong Liao, Yingtao Sun, Meiyi Li, Chun Hu, Lai Lyu*. Zero-added conversion of chicken manure into dual-reaction-center catalyst for pollutant degradation triggered by peroxymonosulfate. Separation and Purification Technology, 2023, 123763. (JCR-Q1, IF=9.136)

[33] Yuting Gu, Tingting Gao, Fagen Zhang, Chao Lu, Wenrui Cao, Ziwei Fu, Chun Hu, Lai Lyu*. Surface sulfur vacancies enhanced electron transfer over Co-ZnS quantum dots for efficient degradation of plasticizer micropollutants by peroxymonosulfate activation. Chinese Chemical Letters, 2022, 33, 3829-3834. (JCR-Q1, IF=8.455)

[34] Peng Zhang, Haobin Tan, Zhongkai Wang, Lai Lyu*, Chun Hu. Efficient H2O2 dissociation and formation on zinc chalcogenides: A density functional theory study. Applied Surface Science, 2023, 616, 156495. (JCR-Q1, IF=7.392)

[35] Yuhao Shi, Zhiju Xie, Chun Hu, Lai Lyu*. Resourcelized conversion of livestock manure to porous cage microsphere for eliminating emerging contaminants under peroxymonosulfate trigger. iScience, 2023, 26(3), 106139. (Cell子刊, JCR-Q1, IF= 6.107)

[36] Yumeng Wang#, Lai Lyu#, Di Wang, Han-Qing Yu, Tong Li, Yaowen Gao, Fan Li, John C. Crittenden, Lili Zhang, Chun Hu*. Cation–π induced surface cleavage of organic pollutants with -OH formation from H2O for water treatment. iScience, 2021, 24(8), 102874. (Cell子刊, JCR-Q1, IF= 6.107)

[37] Chao Lu, Kanglan Deng, Chun Hu, Lai Lyu*. Dual-reaction-center catalytic process continues Fenton’s story. Frontiers of Environmental Science & Engineering, 2020, 14(5), 82. (JCR-Q2, IF=6.048, 中国卓越期刊-重点《环境科学与工程前沿》特邀Account)

[38] Guangfei Yu, Lai Lyu*, Fagen Zhang, Dengbiao Yan, Wenrui Cao, Chun Hu. Theoretical and experimental evidence for rGO-4-PP Nc as a metal-free Fenton-like catalyst by tuning the electron distribution. RSC Advances, 2018, 8, 3312-3320. (JCR-Q2, IF=4.036)

[39] Lai Lyu, Chun Hu*. Heterogeneous Fenton catalytic water treatment technology and mechanism. Progress in Chemistry, 2017, 29, 981-999 (《化学进展》特邀综述, in Chinese).

[40] Fan Zhang, Yang Song, Chun Hu, Lai Lyu*. Fe-Ti co-doped alumina inducing surface dual reaction center for catalytic ozonation to remove pollutants from water (铁钛共掺杂氧化铝诱发表面双反应中心催化臭氧化去除水中污染物). Environmental Science (环境科学), 2021, 42(5), 2360-2369. (中国卓越期刊/北大核心, in Chinese)

[41] Lai Lyu, Kanglan Deng, Junrong Liang, Chao Lu, Tingting Gao, Wenrui Cao, Chun Hu*. Interaction of surface electron distribution-polarized Fe/polyimide hybrid nanosheets with organic pollutants driving sustainable Fenton-like process. Materials Advances, 2020, 1, 1083-1091 (入选 Materials Advances HOT Article Collection).

[42] Chao Lu, Qian Fang, Chun Hu, Lai Lyu*. Sustainable micro-activation of dissolved oxygen driving pollutant conversion on Mo-enhanced zinc sulfide surface in natural conditions. Fundamental Research, 2023, 3(3), 422-429.

[43] Wenrui Cao, Chun Hu, Lai Lyu*. Efficient decomposition of organic pollutants over nZVI/FeOx/FeNy anchored NC layers via a novel dual-reaction-centers-based wet air oxidation process under natural conditions. ACS ES&T Engineering, 2021, 1(9), 1333-1341.

[44] Kanglan Deng#, Yuting Gu#, Tingting Gao, Zhengyan Liao, Yuxiang Feng, Su Zhou, Qian Fang, Chun Hu, Lai Lyu*. Carbonized MOF-coated zero-valent Cu driving an efficient dual-reaction-center Fenton-like water treatment process through utilizing pollutants and natural dissolved oxygen. ACS ES&T Water, 2022, 2(1), 174-183.

[45] Tingting Gao, Hongqiang Wang, Jun Xu, Chun Hu, Lai Lyu*. Enhanced water purification efficiency induced by trace H2O2 on electron distribution-polarized unequilibrium surface of CuS/ZnO nanosheets. ACS ES&T Water, 2023, 3(1), 79-85.

[46] Yingtao Sun, Yehong Lin, Xuanying Cai, Zhitai Zhang, Fagen Zhang, Chun Hu,  Lai Lyu*. Surface cleavage and electron donation mechanism of emerging contaminants excited by H2O2 assisted Cu-based catalyst (H2O2协助铜基催化剂激发新污染物表面裂解性能与供电子机制). Energy Environmental Protection (能源环境保护), 2023, 37(2), 187-195.  (特邀论文, in Chinese)

[47] Lai Lyu, Yumeng Wang, Chao Lu, Fan Li, Wenrui Cao, Yingtao Sun, Chun Hu*. Potential and prospects in molecular orbital level micro-electric field for low energy consumption water purification. National Science Open (国家科学进展), 2023, doi:10.1360/nso/20230017. 

[48]   Tingting Gao, Chun Hu, Congfeng Xu, Xianhua Liang, Zhiqing Chen,  Lai Lyu*. Resourcelized conversion of poultry feces to ordered carbon with electron poor/rich microregions for water purification induced by peroxymonosulfate. Environmental Pollution, 2023, 337, 122536. (JCR-Q1, IF= 8.9)

[49] Qin Dai#, Guangfei Yu#, Juanjuan Qi, Yanan Wang, Lei Xing, Yihao Wang, Zhijie Zhang, Xiaolin Zhong, Zhimo Fang, Penghui Du, Lai Lyu*, Lidong Wang*. Ternary Co…Ov…Cu sites trigger Co-utilization of endogenous electron donor-acceptor for sustainable removal of refractory low-carbon fatty amines in Fenton-like system. Applied Catalysis B: Environmental, 2024, 340, 123184. (JCR-Q1, IF= 22.1)

[50] Yuhao Shi#, Dongxuan Yang#, Chun Hu, Lai Lyu*. Water self-purification via electron donation effect of emerging contaminants arousing oxygen activation over ordered carbon-enhanced CoFe quantum dots. Environmental Science and Ecotechnology, 2024, 20, 100356. (JCR-Q1, IF= 12.6)

[51] Yuhang Liu, Wenxuan Deng, Xiaojun Wu, Chun Hu, Lai Lyu*. Enhanced Fenton-like process over Cu/L(+)-ascorbic acid co-doping mesoporous silica for toxicity reduction of emerging contaminants. Frontiers of Environmental Science & Engineering, 2024, 18(4), 44. (JCR-Q1, IF=6.7)

[52] Yingtao Sun#, Yuting Gu#, Meiyi Li, Hongqiang Wang, Chun Hu, Lai Lyu*. Fast Elimination of Emerging Contaminates in Complicated Water Environment Medium over the Resource Conversion Product of Chicken Manure Biochar Triggered by Peroxymonosulfate. Carbon Research, 2024, 3(1), 8. (JCR-Q1)

[53] Yingtao Sun#, Xuanying Ca#, Chun Hu, Lai Lyu*. Simultaneous emerging contaminant removal and H2O2 generation through electron transfer carrier effect of Bi-O-Ce bond bridge without external energy consumption. Advanced Science, 2024, just accepted. (JCR-Q1, IF=15.1)

[54] Congfeng Xu, Fangxing Guo, Chun Hu, Lai Lyu*. Pulp and Paper Wastewater Treatment Technology Research Progress and Thinking (制浆造纸废水处理技术研究进展及思考). China Pulp & Paper (中国造纸), 2024, just accepted. (中文核心期刊, in Chinese)

代表性专利：

[1] 一种无金属非均相类芬顿型催化剂及其制备方法与应用。专利号：ZL 2017 1 0861138.4 授权公告日：2020年4月14日

[2] 一种纳米纤维球状硅基多相芬顿催化剂及合成方法与应用。专利号：ZL 2017 1 1083340.5 授权公告日：2020年2月7日

[3] 一种固体芬顿催化剂及其制备方法与应用。专利号：ZL 2016 1 0121173.8 授权公告日：2018年3月13日

[4] 一种固载化芬顿催化剂及其制备方法与应用。专利号：ZL 2017 1 0859772.4 授权公告日：2020年6月5日

[5] 一种表面固相配体增强型芬顿催化剂及其制备方法和应用。专利号：ZL 2017 1 1083202.7 授权公告日：2020年07月31日

[6] 一种铜掺杂碳氮聚合体多相芬顿催化剂及其合成与应用。专利号：ZL 2018 1 0678731.X 授权公告日：2020年10月23日

[7] 一种有序纳米片层团簇无金属催化剂及其合成与用途。专利号：ZL 2018 1 0564578.8 授权公告日：2021年03月12日

[8] 钴硫共掺杂石墨烯的多相芬顿催化剂及其合成方法和用途。专利号：ZL 2018 1 0979783.0 授权公告日：2021年6月8日

[9] 一种表面有机络合硫化铜芬顿催化剂及其合成方法与应用。专利号：ZL 2018 1 0823312.0 授权公告日：2021年6月25

[10] 一种金属有机复合多相芬顿催化剂及其制备方法和应用。专利号：ZL 2019 1 0046405.1 授权公告日：2021年09月03日