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成果及论文


18. Synthesis of Z-gem-Cl,CF3 -Substituted Alkenes by Stereoselective Cross-Metathesis and the Role of Disubstituted Mo Alkylidenes.

Liu, Q.; Qin, C.; Wan, J.; Bin, K.; Sui, X.; Kobayashi, H.; Zahedian, H.; Liu, P.; Hoveyda, A. H.

J. Am. Chem. Soc. 2024, 146, 22485.


17. Taking Olefin Metathesis to the Limit: Stereocontrolled Synthesis of Trisubstituted Alkenes. 

Hoveyda, A. H.*; Qin, C.; Sui, X. Z.; Liu, Q.; Li, X.; Nikbakht, A. 

Acc. Chem. Res. 2023, 56, 2426.


Prior to CPU:


16.  Catalytic Cross-Metathesis Reactions that Afford E- and Z-Trisubstituted Alkenyl Bromides. Scope, Applications, Mechanistic Insights. 

Koengeter, T.; Qin, C.; Mai, B. K.; Liu, Q.; Mu, Y.; Liu, P.; Hoveyda, A. H.*

J. Am. Chem. Soc. 2023, 145, 3774-3785. (IF: 16.3)


15. Stereodefined alkenes with a fluoro-chloro terminus as a uniquely enabling compound class. 

Liu, Q.; Mu, Y.; Koengeter, T.; Schrock, R.; Hoveyda, A. H.* 

Nat. Chem 2022, 14, 463. (IF: 24.3)


14. Difluoromethyl 2-pyridyl sulfoximine: a stereoselective nucleophilic reagent for difluoro(aminosulfinyl)methylation and difluoro(aminosulfonyl)methylation. 

Liu, Q.; Ni, C.; Wang, Q.; Meng, D.; Hu, J.* 

CCS Chem 2022, 4, 3648.


13.  Commercially available organofluorine compounds as convenient launching points for stereocontrolled synthesis of more complex derivatives. 

Paioti, P. H. S.; Fager, D.; Xu, S.; Liu, Q.; Hoveyda, A. H.*

Angew. Chem. Int. Ed. 2022, accepted. (IF: 16.8) (doi.org/10.1002/anie.202208742)


12.  From C1 to C3: copper-catalyzed gem-bis(trifluoromethyl)olefination of α-diazo esters with TMSCF3

Wang, Q.; Ni, C.; Hu, M.; Xie, Q.; Liu, Q.; Pan, S.; Hu, J.*

Angew. Chem. Int. Ed. 2020, 59, 8507. (IF: 16.8)


11.  Catalytic enantioselective synthesis of allylic boronates bearing a trisubstituted alkenyl fluoride and related derivatives. 

Akiyama, S.; Kubota, K.; Mikus, M. S.; Paioti, P. H. S.; Romiti, F.; Liu, Q.; Zhou, Y.; Hoveyda, A. H.*; Ito, H.*

Angew. Chem. Int. Ed. 2019, 58, 11998. (IF: 16.8)


10.  Stereoselective carbonyl olefination with fluorosulfoximines: facile access to Z or E terminal monofluoroalkenes. 

Liu, Q.; Shen, X.; Ni, C.; Hu, J.*

Angew. Chem. Int. Ed. 2017, 56, 619. (IF: 16.8)


9.  China's flourishing synthetic organofluorine chemistry: innovations in the new millennium.

Liu, Q. ; Ni, C. ; Hu, J.*

Natl. Sci. Rev. 2017, 4, 303. (IF: 23.2)


8.  Reagent-Controlled Highly Stereoselective Difluoromethylation: Efficient Access to Chiral a-Difluoromethylamines from Ketimines. 

Liu, Q.; Kong, T.; Ni, C.; Hu, J.*

Molecules 2022, 27, 7076. (IF: 4.9)


7.  Dynamic kinetic resolution enabled highly stereoselective nucleophilic fluoroalkylation to access chiral b-fluoro amines. 

Liu, Q.; Kong, T.; Ni, C.; Hu, J.*

Org. Lett. 2022, 24, 5982. (IF: 6.0)


6.  Deoxyfluorination of alcohols with aryl fluorosulfonates.

Wang, X. #;Zhou, M. #; Liu, Q. #;Ni, C.; Fei, Z.; Li, W.; Hu, J.*

Chem. Commun. 2021, 4, 303. (IF: 6.1)


5.  Stereoselective synthesis of (sulfonimidoyl)cyclopropanes with (R)-PhSO(NTs)CH2Cl and a,b-unsaturated Weinreb amides: tuning the of selectivity between C-Cl and C-S bond cleavage. 

Shen, X.; Liu, Q.; Zhang, W.; Hu, J.*

Eur. J. Org. Chem. 2016, 906. (IF: 3.3)


4.  Nucleophilic difluoromethylation of epoxides with PhSO(NTBS)CF2H by a preorganization strategy. 

Shen, X.; Liu, Q.; Luo, T.; Hu, J.*

Chem. Eur. J. 2014, 20, 6795. (IF: 5.0)


3.  Nucleophilic difluoro(phenylsulfonimidoyl)methylation of unactivated alkyl bromides with PhSO(NTBS)CF2H: facile entry into gem-difluoroalkenes. 

Shen, X.; Liu, Q.; Ni, C.; Hu, J.*

Chin. J. Chem. 2014, 32, 703. (IF: 5.6)


2.  A novel manganese(II) coordination polymer built by thiourea-based carboxylate ligand.

Liu, Q.; Gao, Y.; Guo, M.; Li, G.*

Synth. React. Inorg. Met-Org. Chem. 2011, 41, 958. (Currently known as Inorganic and Nano-Metal Chemistry)


1.  Three main group metal coordination polymers bearing imidazole-based dicarboxylates: hydro(solvo)thermal syntheses, crystal structures and properties.

Gao, Y.; Liu, Q.; Zhang, F.; Li, G.*; Wang, W.; Lu, H.  

Polyhedron 2011, 30, 1. (IF: 3.3)