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44. Xuwen Yang, Gang Ye*, Karolina Tran, Yuru Liu, Jiamin Cao, Jingjin Dong, Giuseppe Portale, Jian Liu, Ping Zhang, Maria Antonietta Loi, Ryan C. Chiechi*, and L. Jan Anton Koster*. Impact of Oligo(Ethylene Glycol) Side Chains on the Thermoelectric Properties of Naphthalenediimide–Dialkoxybithiazole Polymers. ACS Materials Lett, 2024, 6, 1207-1215.

43. Jian Liu; Mariavittoria Craighero; Vandna K. Gupta; Dorothea Scheunemann; Sri Harish Kumar Paleti; Emmy Jaersvall; Youngseok Kim; Kai Xu; Juan Sebastian Reparaz; L. Jan Anton Koster; et al. Electrically Programmed Doping Gradients Optimize the Thermoelectric Power Factor of a Conjugated Polymer. Advanced Functional Materials 2024

42. Yazhuo Kuang; Sander Heester; Shuyan Shao; Gang Ye; Tangqing Yao; Zhiyuan Xie; L. Jan Anton Koster; Jian Liu. Adjusting molecular weight optimizes electronic transport of extrinsically N-type doped conjugated polymer incorporating glycolated side chains. Journal of Materials Chemistry A 2024, 12, 4866-4876.

41. Sihui Deng; Yazhuo Kuang; Liyao Liu; Xinyu Liu; Jian Liu; Jingyu Li; Bin Meng; Chong-an Di; Junli Hu; Jun Liu. High-Performance and Ecofriendly Organic Thermoelectrics Enabled by N-Type Polythiophene Derivatives with Doping-Induced Molecular Order. Advanced Materials 2023.

40. S. H. Deng; J. Liu; B. Meng; J. Liu; L. X. Wang. A Highly Conductive n-Type Polythiophene Derivative: Effect of Molecular Weight on n-Doping Behavior and Thermoelectric Performance. Acs Applied Materials & Interfaces 2023, 15, 45190-45200.

39. S. H. Deng; C. S. Dong; J. Liu; B. Meng; J. L. Hu; Y. Min; H. K. Tian; J. Liu; L. X. Wang. An n-Type Polythiophene Derivative with Excellent Thermoelectric Performance. Angew. Chem.-Int. Edit. 2023, 62, 7.

38. Y. H. Wang; B. Meng; J. Liu; F. Zhu; C. J. Qin; J. Liu; L. X. Wang. A cyano-based electron-accepting building block to design n-type conjugated polymers with absorption wavelength of >1000 nm. Chem. Commun. 2023, 59, 1513-1516.

37. Y. Z. Li; J. Wu; X. T. Yi; Z. K. Liu; H. Liu; Y. Y. Fu; J. Liu; Z. Y. Xie. Layer-by-layer blade-coated organic solar cells with non-halogenated solvents and non-halogenated additive via adjusting morphology and crystallization. Journal of Materials Chemistry C 2023, 11, 13263-13273.

36. D. Scheunemann; E. Järsvall; Jian. Liu; D. Beretta; S. Fabiano; M. Caironi; M. Kemerink; C. Müller. Charge transport in doped conjugated polymers for organic thermoelectrics. Chemical Physics Reviews 2022, 3, 19.

35. D. R. Villalva; S. Singh; L. A. Galuska; A. Sharma; J. H. Han; Jian. Liu; M. A. Haque; S. Jang; A. H. Emwas; L. J. A. Koster; et al. Backbone-driven host-dopant miscibility modulates molecular doping in NDI conjugated polymers. Mater. Horizons 2022, 9, 500-508.

34. A. Rahimichatri; Jian. Liu; F. Jahani; L. Qiu; R. C. Chiechi; J. C. Hummelen; L. J. A. Koster. A method for identifying the cause of inefficient salt-doping in organic semiconductors. Journal of Materials Chemistry C 2022, 10, 13093-13098.

33. Y. Z. Li; J. Wu; H. Tang; X. T. Yi; Z. K. Liu; Q. Q. Yang; Y. Y. Fu; Jian Liu; Z. Y. Xie. Non-Halogenated Solvents and Layer-by-Layer Blade-Coated Ternary Organic Solar Cells via Cascade Acceptor Adjusting Morphology and Crystallization to Reduce Energy Loss. Acs Applied Materials & Interfaces 2022, 12.

32. Scheunemann Dorothea; Jaersvall Emmy; Liu Jian; Beretta Davide; Fabiano Simone; Caironi Mario; Kemerink Martijn; Mueller Christian. Charge transport in doped conjugated polymers for organic thermoelectrics. Chemical Physics Reviews 2022, 3, 021309.

31. Alberto D. Scaccabarozzi, Aniruddha Basu, Filip Anies, Jian Liu et al. Doping Approaches for Organic Semiconductors, Chem. Rev. 2021, XXX, XX, XXX-XXX.

30. Shuyan Shao, Jian Liu*, Molecular insights into n-Type Organic Thermoelectrics, CCS Chemistry, 2021, https://doi.org/10.31635/ccschem.021.202101167.

29. Jian Liu, Li Qiu*, Shuyan Shao*,  Emerging electronic applications of fullerene derivatives: an era beyond OPV, J. Mater. Chem. C, 2021,9, 16143-16163.

Graphical abstract: Emerging electronic applications of fullerene derivatives: an era beyond OPV


28. Jian Liu*, Bas Van der Zee, Diego R Villava, Gang Ye, Simon Kahmann, Max Kamperman, Jingjin Dong, Li Qiu, Giuseppe Portale, Maria Antonietta Loi, Jan C Hummelen, Ryan C Chiechi, Derya Baran, L Jan Anton Koster*,  Molecular Doping Directed by a Neutral Radical, ACS Appl. Mater. Interfaces 2021, 13, 25, 29858–29865. 

27. Jingjin Dong, Jian Liu, Xinkai Qiu, Ryan  Chiechi, L. Jan Anton Koster, and Giuseppe Portale, Engineering the Thermoelectrical Properties of PEDOT:PSS by Alkali Metal Ion Effect, Engineering7, 2021, 647-654.

26. Gang Ye, Jian Liu*, Xinkai Qiu, Sebastian Stater, Li Qiu, Yuru Liu, Xuwen Yang, Richard Hildner, L Jan Anton Koster*, Ryan C Chiechi*, Controlling n-Type Molecular Doping via Regiochemistry and Polarity of Pendant Groups on Low Band Gap Donor–Acceptor CopolymersMacromolecules 2021, 54, 8, 3886–3896.

Abstract Image

25. Jian Liu, Gang Ye, Hinderikus G. O. Potgieser, Marten Koopmans, Selim Sami, Mohamad Insan Nugraha, Diego Rosas Villalva, Hengda Sun, Jingjin Dong, Xuwen Yang, Xinkai Qiu, Chen Yao, Giuseppe Portale, Simone Fabiano, Thomas D. Anthopoulos, Derya Baran, Remco W. A. Havenith, Ryan C. Chiechi, L. Jan Anton Koster, Amphipathic Side Chain of a Conjugated Polymer Optimizes Dopant Location toward Efficient N-Type Organic Thermoelectrics, Advanced Materials, 2021, 33, 2006694. 

Selective increase in the Seebeck coefficient and improvement of the power factor by a factor of ≈5 in an n-doped donor–acceptor copolymer are realized by the use of amphipathic side chains. This strategy can properly control the dopant sites away from the backbone, which minimizes the adverse influence of counterions. Therefore, an excellent power factor of 18 µW m–1 K–2 is achieved.

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24. Marten Koopmans, Miina AT Leiviskä, Jian Liu, Jingjin Dong, Li Qiu, Jan C Hummelen, Giuseppe Portale, Michael C Heiber, L Jan Anton Koster*, Electrical Conductivity of Doped Organic Semiconductors Limited by Carrier–Carrier Interactions, ACS Appl. Mater. Interfaces 2020, 12, 50, 56222–56230

 23. Jian Liu*, Bas van der Zee, Riccardo Alessandri, Selim Sami, Jingjin Dong, Mohamad I Nugraha, Alex J Barker, Sylvia Rousseva, Li Qiu, Xinkai Qiu, Nathalie Klasen, Ryan C Chiechi, Derya Baran, Mario Caironi, Thomas D Anthopoulos, Giuseppe Portale, Remco WA Havenith, Siewert J Marrink, Jan C Hummelen, L Jan Anton Koster*, N-type organic thermoelectrics: demonstration of ZT > 0.3, Nature Communications volume 11, Article number: 5694 (2020) 

figure 1 

22. Matteo Massetti, S Bonfadini, D Nava, M Butti, L Criante, G Lanzani, L Qiu, JC Hummelen, J Liu, LJA Koster, M Caironi,  Fully direct written organic micro-thermoelectric generators embedded in a plastic foilNano Energy, 2020, 75, 104983. 

21. Gang Ye, Yuru Liu, Jian Liu, Xinkai Qiu, L Jan Anton Koster, Ryan C Chiechi, Protonic acid doping of low band-gap conjugated polyionsMater. Chem. Front., 2020, 4, 3585-3593.   

20. Jian Liu*, Sudeshna Maity, Nathan Roosloot, Xinkai Qiu, Li Qiu, Ryan C Chiechi, Jan C Hummelen, Elizabeth von Hauff, L Jan Anton Koster*, The effect of electrostatic interaction on Ntype doping efficiency of fullerene derivatives, Advanced Electronic Materials, 2019, 5, 1800959.      

The impact of electrostatic interaction on the doping efficiency in doped fullerene derivatives is explored. It is found that a polarizable triethylene glycol diether side chain can favor the dissociation of charge transfer complexes, enabling an improved doping efficiency close to unity. This work provides an effective strategy toward a better control of the doping process. 

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19. Jian Liu*, Matt P. Garman, Jingjin Dong, Bas van der Zee, Li Qiu, Giuseppe Portale, Jan C. Hummelen, L. Jan Anton Koster* Doping Engineering Enables Highly Conductive and Thermally Stable n‑Type Organic Thermoelectrics with High Power Factor, ACS Applied Energy Materials, ACS Appl. Energy Mater. 2019, 2, 9, 6664–6671.

18. Jian Liu*, Yongqiang Shi, Jingjin Dong, Mohamad I Nugraha, Xinkai Qiu, Mengyao Su, Ryan C Chiechi, Derya Baran, Giuseppe Portale, Xugang Guo*, L Jan Anton Koster*, Overcoming Coulomb Interaction Improves Free-charge Generation and Thermoelectric Properties for N-doped Conjugated PolymersACS Energy Lett. 2019, 4, 7, 1556–1564. 

Abstract Image

17. Jian Liu*, Gang Ye, Bas van der Zee, Jingjin Dong, Xinkai Qiu, Yuru Liu, Giuseppe Portale, Ryan C Chiechi, L Jan Anton Koster*, NType Organic Thermoelectrics of Donor–Acceptor Copolymers: Improved Power Factor by Molecular Tailoring of the Density of StatesAdvanced Materials, 2018, 30, 1804290.

Significantly boosted n-type organic thermoelectric performance of donor–acceptor (D–A) copolymers by a factor of three orders of magnitude is realized by tailoring the density of states through molecular design. This strategy improves the electrical conductivity effectively and reduces the loss of the Seebeck coefficient, leading to a very good power factor of 4.5 µW m−1 K−2 for doped DA copolymers.

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16. Jian Liu*, Li Qiu, Giuseppe Portale, Solmaz Torabi, Marc CA Stuart, Xinkai Qiu, Marten Koopmans, Ryan C Chiechi, Jan C Hummelen, L Jan Anton Koster*, Side-chain effects on N-type organic thermoelectrics: a case study of fullerene derivativesNano Energy, 2018, 52, 183-191. 

15. Jian Liu*, Li Qiu, Riccardo Alessandri, Xinkai Qiu, Giuseppe Portale, JingJin Dong, Wytse Talsma, Gang Ye, Aprizal Akbar Sengrian, Paulo CT Souza, Maria Antonietta Loi, Ryan C Chiechi, Siewert J Marrink, Jan C Hummelen, L Jan Anton Koster*, Enhancing Molecular nType Doping of Donor–Acceptor Copolymers by Tailoring Side Chains, Advanced Materials, 2018, 30, 1704630. 

Significantly enhanced molecularly doping of an n-type donor–acceptor (D–A) copolymer by rationally tailoring its side chains without changing its donor–acceptor character is demonstrated. Polar triethylene-glycol-based side chains on the host greatly increase the solubility of dopant molecules in the host matrix with respect to the traditional alkyl side chains. The former gives a highest conductivity of 0.17 S cm−1 for D–A copolymers, representing a 200-fold enhancement compared to the latter.

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14. Shuyan Shao, Jian Liu, Giuseppe Portale, HongHua Fang, Graeme R Blake, Gert H ten Brink, L Jan Anton Koster, Maria Antonietta Loi, Highly reproducible Snbased hybrid perovskite solar cells with 9% efficiencyAdvanced Energy Materials, 2018, 8, 1702019.

13. Shuyan Shao, Jian Liu, HongHua Fang, Li Qiu, Gert H ten Brink, Jan C Hummelen, L Jan Anton Koster, Maria Antonietta Loi, Efficient perovskite solar cells over a broad temperature window: the role of the charge carrier extractionAdvanced Energy Materials, 2017, 7, 1701305.

12. Jian Liu, Li Qiu, Giuseppe Portale, Marten Koopmans, Gert Ten Brink, Jan C Hummelen, L Jan Anton Koster*, NType Organic Thermoelectrics: Improved Power Factor by Tailoring Host–Dopant MiscibilityAdvanced Materials, 2017, 29, 1701641.

An efficient n-type doping system by tailoring host–dopant miscibility is demonstrated in this organic thermoelectric study. A record conductivity of 2.05 S cm−1 for solution-processed fullerene derivative films is realized by enhancing the doping efficiency. The optimized system shows a power factor of 16.7 µW m−1 K−2 with a Seebeck coefficient of -284 µV K−1, representing one of the best results for solution-processed n-type organic thermoelectrics.

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11. Li Qiu#, Jian Liu#, Riccardo Alessandri, Xinkai Qiu, Marten Koopmans, Remco WA Havenith, Siewert J Marrink, Ryan C Chiechi, L Jan Anton Koster, Jan C Hummelen, Enhancing doping efficiency by improving host-dopant miscibility for fullerene-based n-type thermoelectrics, Journal of Materials Chemistry A, 2017, 5, 21234-21241. (共同一作)

10. Solmaz Torabi, Jian Liu, Pavlo Gordiichuk, Andreas Herrmann, Li Qiu, Fatemeh Jahani, Jan C Hummelen, L Jan Anton Koster Deposition of LiF onto films of fullerene derivatives leads to bulk doping, ACS Applied Materials & Interfaces, 2016, 8, 22623-22628. 

9. Shunmian Lu, Xing Guan, Xinchen Li, Jian Liu, Fei Huang, Wallace CH Choy*, The incorporation of thermionic emission and work function tuning layer into intermediate connecting layer for high performance tandem organic solar cells, Nano Energy, 2016, 21, 123-132.

8. Jian Liu, Shunmian Lu, Lu Zhu, Xinchen Li, Wallace CH Choy*, Perovskite-organic hybrid tandem solar cells using a nanostructured perovskite layer as the light window and a PFN/doped-MoO3/MoO3 multilayer as the interconnecting layerNanoscale, 2016, 8, 3638-3646. 

7. Shuyan Shao, Mustapha Abdu-Aguye, Li Qiu, Lai-Hung Lai, Jian Liu, Sampson Adjokatse, Fatemeh Jahani, Machteld E Kamminga, H Gert, Thomas TM Palstra, Bart J Kooi, Jan C Hummelen, Maria Antonietta Loi, Elimination of the light soaking effect and performance enhancement in perovskite solar cells using a fullerene derivativeEnergy & environmental science, 2016, 9, 2444-2452.

6. Jian Liu, Xinchen Li, Shaoqing Zhang, Xingang Ren, Jiaqi Cheng, Lu Zhu, Di Zhang, Lijun Huo, Jianhui Hou, Wallace CH Choy, Synergic Effects of Randomly Aligned SWCNT Mesh and SelfAssembled Molecule Layer for HighPerformance, LowBandgap, Polymer Solar Cells with Fast Charge ExtractionAdvanced Materials Interfaces, 2015, 2, 1500324.

5. Haifei Lu, Di Zhang, Jiaqi Cheng, Jian Liu, Jian Mao, Wallace CH Choy, Locally welded silver nanonetwork transparent electrodes with high operational stability by a simple alcoholbased chemical approachAdvanced Functional Materials, 2015, 25, 4211-4218.

4. Jian Liu, Jiang Wu, Shuyan Shao, Yunfeng Deng, Bin Meng, Zhiyuan Xie, Yanhou Geng, Lixiang Wang, Fengling Zhang, Printable highly conductive conjugated polymer sensitized ZnO NCs as cathode interfacial layer for efficient polymer solar cellsACS applied materials & interfaces, 2014, 6, 8237-8245. 

3. Jian Liu, Shuyan Shao, Gang Fang, Jiantai Wang, Bin Meng, Zhiyuan Xie, Lixiang Wang, High-efficiency inverted tandem polymer solar cells with step-Al-doped MoO3 interconnection layer, Solar energy materials and solar cells, 2014, 120, 744-750.

2. Jian Liu, Shuyan Shao, Gang Fang, Bin Meng, Zhiyuan Xie, Lixiang Wang, HighEfficiency Inverted Polymer Solar Cells with Transparent and WorkFunction Tunable MoO3Al Composite Film as Cathode Buffer Layer, Advanced Materials, 2012, 24, 2774-2779.

1. Jian Liu, Shuyan Shao, Bin Meng, Gang Fang, Zhiyuan Xie, Lixiang Wang, Xinglin Li, Enhancement of inverted polymer solar cells with solution-processed ZnO-TiOX composite as cathode buffer layer, Applied Physics Letters, 2012, 100, 213906.