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成果及论文


  • 2024年度:

    • 23. Rhodium-Catalyzed Synthesis of Trifluoromethyl-Containing Allylic Alcohols Via Z‑Alkenyl Transfer with High Stereochemistry Retention. Cheng Liang, Zheng-Qiang Liu, Min Lin, Xue-Mei Huang, Si-Qi Xiong, Xue Zhang, Qing-Hua Li,* and Tang-Lin Liu*, Organic Letters 2024, 10.1021/acs.orglett.4c03160.


    • 22. Rhodium-Catalyzed 1,4-Hydroxyl Migration of Alkenyl AlcoholsXue Zhang, Jiang-Min Yan, Jia-Ning Zhang, Si-Qi Xiong, Cheng Liang, Qing-Hua Li* and Tang-Lin Liu*Organic Chemistry Frontiers 2024, 10.1039/D4QO01103A. 11, 5368 - 5373


    • 21. Synthesis of 1,2,4,5-Tetra-Substituted Benzenes via Copper-Catalyzed Dimerization of γ,δ-Unsaturated ketones. Kai-Xian Ma,   Chuan-Ming Hong,   Jiang-Min Yan,   Qing-Hua Li  and  Tang-Lin Liu.  Chem. Commun2024DOI: 10.1039/D4CC02458C 60, 7753 - 7756


    • 20. Alkenylation and arylation of secondary alcohols enabled by productive merger of β-carbon and β-hydrogen elimination via an isodesmic reaction. Xiong, S.-Q.; Liu, Z.-Q.; Liang, C.; Huang, X.-M.; Zhang, X.; Li, Q.-H.; Liu, T.-L., Organic Chemistry Frontiers 2024, 10.1039/D4QO00482E11, 3868-3873



    • 19.  Regioselective Thiolation of Indoles with Sulfinyl Amides.  Yan Liu, Xue Zhang, Zhen Luo, Prof. Tanglin Liu, Prof. Qinghua Li,  ChemistrySelect20249, e20230389 



2023年度:



2022年度:



  • 12. Chuan-Ming Hong, Xin Zhuang, Zhen Luo, Si-Qi Xiong, Zheng-Qiang Liu, Qing-Lin Li, Fei-Fei Zou, Qing-Hua Li,* and Tang-Lin Liu*. Copper-Catalyzed Transfer Methylenation via C(sp3)-C(sp3) Bond Cleavage of Alcohols. Org. Chem. Front.2022, 9, DOI: 10.1039/D2QO01373H6547-6555


  • 11. Liu, Z.-Q.; Liang, C.; Luo, Z.; Wu, Y.-F.; Hong, C.-M.; Li, Q.-H.; Liu, T.-L., Transfer Vinylation and Dienylation via Rhodium(I)-Catalyzed Deketonation of Allylic Alcohols. ACS Catalysis 2022, 10.1021/acscatal.2c02325, 7030-7036.


  • 10. Xin Zhuang, Min Zhu, Chuan-Ming Hong, Zhen Luo, Wan-Fang Li, Qing-Hua Li, Qun-Li Luo* and Tang-Lin Liu*,  Alkynyl Borrowing: Silver Catalyzed Amination of Secondary Propargylic Alcohols via C(sp3)-C(sp) Bond Cleavage, The Journal of Organic Chemistry, 2022,  87, 5395-5403.


  • 9. Zhen Luo, Zheng-Qiang Liu, Ting-Ting Yang, Xin Zhuang, Chuan-Ming Hong, Fei-Fei Zou, Zhi-Yong Xue,* Qing-Hua Li*, and Tang-Lin Liu*, HFIP-Assisted Catalyst-Free Sulfonation of Allylic Alcohols with Sulfinyl Amides Org. Lett.202224, 741–745.


  • 8. Chuan-Ming Hong, Fei-Fei Zou, Xin Zhuang, Zhen Luo, Zheng-Qiang Liu, Li-Qing Ren, Qing-Hua Li* and Tang-Lin Liu*, 2-Pyridinylmethyl Borrowing: Base-promoted C-Alkylation of (Pyridin-2-yl)methyl Alcohols with Ketones via Cleavage of Unstrained C(sp3)–C(sp3) Bonds, Org. Chem. Front.2022, 9, 299-304. 


                                                                        


2021年度:


  • 7. Li-Qing Ren, Yu-Shuai He, Yu-Ting Yang, Zhao-Feng Li, Zhiyong Xue*, Qing-Hua Li* and Tang-Lin Liu*, Chlorocyclization/Cycloreversion of Allylic Alcohols to Vinyl Chlorides, Org. Chem. Front., 2021, 8, 6628-6635.


 


  • 6. Liu, Z.-Q.; Tao, J.; Zhuang, X.; Hong, C.-M.; Luo, Z.; Wu, Y.-F.; Li, Q.-H.*; Liu, T.-L.*, Rhodium(III)-Catalyzed Aryl Borrowing Amination of Diaryl Methanols Containing Pyridine-Directing Groups. Adv. Synth. Catal. 2021, 363(23), 5279-5283.    




                                                                                         


  • 5. Zhuang, X.; Tao, J.; Luo, Z.; Hong, C.-M.; Liu, Z.-Q.; Li, Q.-H.; Ren, L.-Q.; Luo, Q.-L.*; Liu, T.-L.*, Silver catalyzed pyridine-directed acceptorless dehydrogenation of secondary alcohols. J. Chin. Chem. Soc. 2021, 68 (2), 245-249.


 


2020年度:

  • 3. Cyano-Borrowing: Titanium-Catalyzed Direct Amination of Cyanohydrins with Amines and Enantioselective Examples. Liu, T.-L.*; Li, Z.-F.; Tao, J.; Li, Q.-H.; Li, W.-F.; Li, Q.; Ren, L.-Q.; Peng, Y.-G.*, Chem. Commun. 2020, 56, 651-654.

2019年度:

  • 2. Li, Z.-F.; Li, Q.; Ren, L.-Q.; Li, Q.-H.; Peng, Y.-G.*; Liu, T.-L.*Cyano-borrowing reaction: nickel-catalyzed direct conversion of cyanohydrins and aldehydes/ketones to β-cyano ketone. Chem. Sci. 2019, 10(22), 5787-5792.


  • 1. Li, Q.-H.*; Li, Z.-F.; Tao, J.; Li, W.-F.; Ren, L.-Q.; Li, Q.; Peng, Y.-G.; Liu, T.-L.*, Titanium-Catalyzed Cyano-Borrowing Reaction for the Direct Amination of Cyanohydrins with Ammonia.  Org. Lett. 2019, 21 (20), 8429-8433.

             


独立工作前的论文列表:

  • 16. Huang, R.-Z.; Lau, K. K.; Li, Z.; Liu, T.-L.*; Zhao, Y.*, Rhodium-Catalyzed Enantioconvergent Isomerization of Homoallylic and Bishomoallylic Secondary Alcohols.  J. Am. Chem. Soc. 2018, 140 (44), 14647-14654.


  • 15. Wang, Y.-N.; Yang, L.-C.; Rong, Z.-Q.; Liu, T.-L.; Liu, R.; Zhao, Y.*, Pd-Catalyzed Enantioselective [6+4] Cycloaddition of Vinyl Oxetanes with Azadienes to Access Ten-Membered Heterocycles.  Angew. Chem., Int. Ed. 2018, 57 (6), 1596-1600.


  • 14. Tang-Lin Liu, Teng Wei Ng, Yu Zhao*, Rhodium-Catalyzed Enantioselective Isomerization of Secondary Allylic Alcohols to Access Ketones with a-Tertiary Stereocenter.  J. Am. Chem. Soc. 2017, 139, 3643-3646.


  • 13. Tang-Lin Liu, Ji’En. Wu, Yu. Zhao*, Divergent Reactivities in Fluoronation of Allylic Alcohols: Synthesis of Z-Fluoroalkenes via Carbon-Carbon Bond Cleavage.  Chem. Sci. 2017, 8, 3885-3890.


  • 12. Tang-Lin Liu#, Qing-Hua Li#, Liang Wei, Yong Xiong, Chun-Jiang Wang*.  Copper(I)-Catalyzed One-Pot Sequential [3+2]/[8+2] Annulations for Highly (Z)-Selective Construction of Heterocyclic Diazabicyclo[5.3.0]decatrienes. Adv. Synth. Catal. 2017, 359, 1854-1859. (IF: 5.646) #共同一作)


  • 11,Tang-Lin Liu, Qing-Hua Li, Zhao-Lin He, Jia-Wei Zhang, Chun-Jiang Wang*. Catalytic Asymmetric Construction of Spiro Pyrrolidines With Contiguous Quaternary Centers via 1,3-Dipolar Cycloaddition of Azomethine Ylides.  Chinese. J. Catal. 2015, 36, 68-77.,


  • 10. Zhou, M.; Liu, T.-L.; Cao, M.; Xue, Z.; Lv, H.*; Zhang, X.*,  Highly Enantioselective Synthesis of Chiral Cyclic Allylic Amines via Rh-Catalyzed Asymmetric Hydrogenation. Org. Lett. 2014, 16, 3484-3487.


  • 9. Tang-Lin Liu, Chun-Jiang. Wang,* Xumu. Zhang*. Synthesis of Chiral Aliphatic Amines through Asymmetric Hydrogenation. Angew. Chem., Int. Ed. 2013, 52, 8416-8419.


  • 8. Tang-Lin Liu, Wei. Li, Huilin. Geng, Chun-Jiang. Wang,* Xumu. Zhang*, Catalytic Enantioselective Desymmetrization of Meso Cyclic Anhydrides via Iridium-Catalyzed HydrogenationOrg. Lett. 2013, 15, 1740-1743.


  • 7. Li, Q.-H.; Liu, T.-L.; Wei, L.; Zhou, X.; Tao, H.-Y.; Wang, C.-J.*,  exo-Selective construction of spiro-[butyrolactone-pyrrolidine] via 1,3-dipolar cycloaddition of azomethine ylides with α-methylene-γ-butyrolactone catalyzed by Cu(I)/DTBM-BIPHEP. Chem. Commun. 2013, 49, 9642-9644.


  • 6. Liu, T.-L.; He, Z.-L.; Tao, H.-Y.; Wang, C.-J.*,  Stereoselective Construction of Spiro(butyrolactonepyrrolidines) by Highly Efficient Copper(I)/TF-BiphamPhos-Catalyzed Asymmetric 1,3-Dipolar Cycloaddition. Chem. - Eur. J. 2012, 18, 8042-8046, S8042/1-S8042/86.


  • 5. Liu, T.-L.; Xue, Z.-Y.; Tao, H.-Y.; Wang, C.-J.*,  Catalytic asymmetric 1,3-dipolar cycloaddition of N-unprotected 2-oxoindolin-3-ylidene derivatives and azomethine ylides for the construction of spirooxindole-pyrrolidines. Org. Biomol. Chem. 2011, 9, 1980-1986.


  • 4. Liu, T.-L.; He, Z.-L.; Wang, C.-J.*,  Highly efficient construction of spirocyclic chromanone-pyrrolidines via Cu(I)/TF-BiphamPhos-catalyzed asymmetric 1,3-dipolar cycloaddition. Chem. Commun. 2011, 47, 9600-9602.


  • 3. Liu, T.-L.; He, Z.-L.; Tao, H.-Y.; Cai, Y.-P.; Wang, C.-J.*,  Stereoselective construction of a 5-aza-spiro[2,4]heptane motif via catalytic asymmetric 1,3-dipolar cycloaddition of azomethine ylides and ethyl cyclopropylidene acetate. Chem. Commun. 2011, 47, 2616-2618.


  • 2. Liu, T.-L.; He, Z.-L.; Li, Q.-H.; Tao, H.-Y.; Wang, C.-J.*,  Catalytic Asymmetric Construction of Spirocycles Containing Pyrrolidine Motifs and Spiro Quaternary Stereogenic Centers via 1,3-Dipolar Cycloaddition of Azomethine Ylides with 2-Alkylidene-Cycloketones. Adv. Synth. Catal. 2011, 353, 1713-1719.


  • 1. Xue, Z.-Y.; Liu, T.-L.; Lu, Z.; Huang, H.; Tao, H.-Y.; Wang, C.-J.*,  exo-Selective asymmetric 1,3-dipolar cycloaddition of azomethine ylides with alkylidene malonates catalyzed by AgOAc/TF-BiphamPhos. Chem. Commun. 2010, 46, 1727-1729.