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成果及论文

2024 


      Peng Wang+, Lu Lin+, Yao Huang, Honghai Zhang, Saihu Liao*, Radical Fluorosulfonamidation: A Facile Access to Sulfamoyl Fluorides. Angew. Chem. Int. Ed. 2024, e202405944. PDF


     Rongbiao Wei, Guanhua Pei, Yao Huang, Saihu Liao*, Accessing SuFExable Cyclobutane-Fused Indolines via Photocatalytic Intermolecular [2+2] Cycloaddition of Indoles. Adv. Synth. Catal. 2024, 366, accepted. PDF  https://onlinelibrary.wiley.com/doi/10.1002/adsc.202400274

        

         Xun Zhang+, Pan Sun+, Qiang Ma, Yu Jiang, and Saihu Liao*, Unlocking the Photoredox and Photoacid Dual Catalytic Activity of BINOLs for the Development of Organocatalytic Orthogonal Polymerization of ATRP and ROP with Light Regulation. ACS Catal2024, asap. PDF https://doi.org/10.1021/acscatal.4c01330


           Lu Lin, Guanhua Pei, Zhong-Yan Cao,* and Saihu Liao*,Recent Advances in Developing Radical Methods for the Synthesis of Aliphatic Sulfonyl Fluorides, Eur. J. Org. Chem2024, e202400279  (InvitedContribution). PDF  https://doi.org/10.1002/ejoc.202400279


           Yingyin Zhang, Qingyuan Feng, Yu Zheng, Yanju Lu, Saihu Liao, and Shenlin Huang*,  Radical Hydro-Fluorosulfonylation of Propargylic Alcohols via Electron Donor–Acceptor Photoactivation. Org. Lett. 202426, 1410−1415 PDF https://doi.org/10.1021/acs.orglett.4c00010


           Pan Sun, Zixuan Li, Xun Zhang, Yun Liao, Saihu Liao*, Visible Light-Regulated Ring-Opening Polymerization of Lactones by Employing Indigo as a Photoacid Catalyst. Macromol. Rapid Commun. 2024, 2400054. PDF


       Haonan Liu+, Jianxu Chen+, Zan Yang, Liuyin Jiang, Wenya Liu, Jun-An Ma*, and Saihu Liao*,   Light-Controlled Cationic RAFT Polymerization of Vinyl Ethers Using N-Arylacridinium Photocatalysts, Macromolecules 2024, 57, 3751–3756. PDF


           Zan Yang, Yun Liao, Zhengyi Zhang, Jianxu Chen, Xun Zhang, and Saihu Liao*, Asymmetric Ion-Pairing Photoredox Catalysis for Stereoselective Cationic Polymerization under Light Control. J. Am. Chem. Soc2024, doi.org/10.1021/jacs.3c12694. PDF


2023 

 Zhengyi Zhang, Zan Yang, Yun Liao and Saihu Liao*, Organic Brønsted Acid-Catalyzed Stereoselective Cationic RAFT Polymerization: the Effect of RAFT Agents. Chin. J. Polym. Sci. 2023, accepted. PDF


         Zan Yang, Yun Liao, Zhengyi Zhang, Jianxu Chen, Xun Zhang and Saihu Liao*, Photocontrolled Stereoselective Cationic Polymerization. ChemRxiv 2023, 10.26434/chemrxiv-2023-b5x16PDF


         Xin Fang, Xuebing Geng, Peng Wang, Honghai Zhang and Saihu Liao*, FSO2 Radical-Initiated Photoredox Cyclization of 4-Enoic Acids to Functionalized γ-Lactones. Synthesis 2023, doi: 10.1055/s-0042-1751535 (Invited Contribution to Special Issue “New Trends in Organic Synthesis from Chinese Chemists”) PDF


        Qingyuan Feng, Tianyu He, Shencheng Qian, Peng Xu, Saihu Liao, and Shenlin Huang*, Electroreductive hydroxy fluorosulfonylation of alkenes. Nat. Commun. 2023, 14, 8278. PDF


         Zhaogang Liu, Xun Zhang, Pan Sun, Junwei Han and Saihu Liao*,  Harnessing the photo-acidity of organic dyes for the development of ring-opening polymerization of lactones under visible light. Polym. Chem. 2023.14, 4414–4418. PDF


       Shuai Shi, Xueyan Zhao, Dengfeng Chen, Jinyue Luo, Saihu Liao, and Shenlin Huang*, C(sp3)–H fluorosulfonylvinylation/aza-Michael addition approach to FSO2-functionalized tetrahydropyridines. Org. Chem. Front. 2023, 10, 3805-3810. PDF


        Ziyang Gan, Jie Zhou, Lingyun Zhu, Xinyu Chen, Qiang Ma, Jianfeng Yan, Wei Jiang, Saihu Liao* and Yuanming Li*, Synthesis, properties, and application of phenanthrenone: an undeveloped building block and a photocatalyst. Org. Chem. Front. 2023, 10, 3830-3836. PDF


         Na Yang, Chenxi Mao, Honghai Zhang, Peng Wang, Shaojie Li, Lili Xie,* and Saihu Liao*,FSO2 Radical-Initiated Tandem Addition Reaction of Two Different Olefins: A Facile Access to Multifunctional Aliphatic Sulfonyl Fluorides.  Org. Lett. 2023, 25, 4478–4482. PDF


         Hui Zhu+,Yu Jiang+ , Zan Yang , Xun Zhang* , Saihu Liao*Organocatalytic stereoselective cationic polymerization of alkenyl vinyl ethers and post-functionalization via click chemistry. Giant, 2023, 14,100151. PDF


        Evgeniya Podyacheva, Alexandra I. Balalaeva, Oleg I. Afanasyev, Sofiya A. Runikhina, Olga Chusova, Andrey S. Kozlov, Saihu Liao, and  Denis Chusov*, Syngas as a synergistic reducing agent for selective reductive amination—a mild route to bioactive amines. New J. Chem. 2023, 47, 10514-10518. PDF


       Xueyan Zhao, Dengfeng Chen, Shengzhen Zhu, Jinyue Luo, Saihu Liao, Binnan Zheng, and Shenlin Huang*, Fluorosulfonylvinylation of Unactivated C(sp3)–H via Electron Donor–Acceptor Photoactivation. Org. Lett. 2023, 25, 3109-3113. PDF


       Lu Lin, Peng Wang, Tao Dong, Gavin Chit Tsui*, and Saihu Liao*,Radical Fluorosulfonyl Heteroarylation of Unactivated Alkenes with Quinoxalin-2(1H)-ones and Related N-Heterocycles. Org. Lett. 2023. 25, 1088−1093. PDF


2022

         Jianxu Chen, Junqiang Lin, Zan Yang, Yi Wu and Saihu Liao *,The development of highly efficient monophosphonium photocatalysts for the visible light-regulated metal-free cationic polymerization of vinyl ethers. Polym. Chem., 2023, 14, 486–491. PDF


         Meng Li, Jun-An Ma, Saihu Liao*,Atom-Transfer Radical Polymerization of a SuFExable Vinyl Monomer and Polymer Library Construction via SuFEx Click Reaction. Macromolecules. 202356, 806−814. PDF


         Guangrong Wang, Hui Shao, Jun-An Ma, and Saihu Liao*,Chalcogenide-Doped Anthracenes as Organophotocatalysts for Metal-Free Atom Transfer Radical Polymerization. Macromol. Chem. Phys. 2022. 224, 2200382 PDF

 

            Xun Zhang+, Pan Sun+, Yu Jiang, and Saihu Liao*,Organocatalytic Ring-Opening Polymerization of ɛ-Caprolactonewith Phosphoramidimidates(PADIs) as a Bifunctional Brønsted Acid Catalyst.  Chem AsianJ.2023,18, e202201127. PDF

        

            Yu Jiang, Hui Zhu,Jianxu Chen and Saihu Liao* ,Organocatalytic [2 + 2] Photopolymerization under Visible Light: Accessing Sustainable Polymers from Cinnamic AcidsMacromol. Rapid Commun. 2023. 44, 2200702. PDF


         Yu Jiang, Hui Zhu, Jianxu Chen, Qiang Ma, and Saihu Liao*Linear Cyclobutane-Containing Polymer Synthesis via [2 + 2] Photopolymerization in an Unconfined Environment under Visible Light. ACS Macro Lett. 2022, 11, 1336−1342. PDF


         Honghai Zhang,§ Na Yang,§ Jing Li, Peng Wang, Shaojie Li, Lili Xie, and SaihuLiao*, Radical Fluorosulfonyl Arylation of Alkenes: Accessing FSO2‑Functionalized Chromanes via Formal, Endo and Exo Cyclization. Org. Lett. 2022. 24, 81708175. PDF

         Peng Wang‡ , Shaojie Li‡ , Honghai Zhang , Na Yang , Saihu Liao∗, Photo-organocatalytic Synthesis of β-Keto Sulfonyl Fluorides via Radical Fluorosulfonylation of Vinyl Acetates. Synlett. 2023, 34, 471–476 PDF  


         Zan Yang, Jianxu Chen, and Saihu Liao*,Monophosphoniums as Effective Photoredox Organocatalysts for Visible Light-Regulated Cationic RAFT PolymerizationACS Macro Lett. 2022, 11, 1073−1078. PDF


         Peng Wang,# Honghai Zhang,# Mingqi Zhao,# Shuang shuang Ji, Lu Lin, Na Yang, Xingliang Nie, Jinshuai Song,* and Saihu Liao*, Radical Hydro-Fluorosulfonylation of Unactivated Alkenes and Alkynes. Angew. Chem.Int. Ed. 2022,e202207684. PDF *OPRD Highlight.


         Honghai Zhang, Shaojie Li, Han-Liang Zheng, Gangguo Zhu, Saihu Liao, Xingliang Nie*.  Photocatalytic Fluorosulfonylation of Aliphatic Carboxylic Acid NHPI Esters. Org. Chem. Front2022, 9, 4854–4860.  PDF


        Qiang Ma,  Yu Jiang, Junqiang Lin, Xun Zhang, Hui Shao and Saihu Liao*, Organocatalytic orthogonal ATRP and ringopening polymerization using a single dual-function photocatalyst. Polym. Chem2022, 13, 4284-4289. PDF


        Jingtao Hu, Junjie Zhang, Zhangxiang Lin, Lili Xie*, Saihu Liao, and Xiong Chen*, Construction of a Hollow Spherical Covalent Organic Framework with Olefin and Imine Dual Linkages Based on Orthogonal Reactions. Chem. Mater2022, 34,  5249–5257. PDF

         

        Peng Wang, Honghai Zhang, Xingliang Nie, Tianxiao Xu, Saihu Liao*, Photoredox catalytic radical    fluorosulfonylation of olefins enabled by a bench-stable redox-active fluorosulfonyl radical  precursorNat. Commun2022, 13, 3370. PDF


        Qingyuan Feng, Yuanyuan Fu, Yu Zheng, Saihu Liao, and Shenlin Huang*, Electrochemical Synthesisof β‑Keto Sulfonyl Fluorides via Radical Fluorosulfonylation of Vinyl Triflates. org. Lett. 2022, 24, 3702–3706. PDF


         Haonan Liu, Yueyong Chen, Deng An, Xun Zhang*, Saihu Liao*, Acetalization of Enol thers with Alcohols under Visible Light Irradiation Using BINOLs as Photoacid Catalysts. Synlett2022, 33, 800-804. PDF


        Siping Hu, Jianxu Chen, Xun Zhang, Yuying Zhang, and Saihu Liao*, Visible Light-Regulated Organocatalytic Ring-Opening Polymerization of Lactones Using Hydroxybenzophenones as PhotocatalystACS Appl. Polym. Mater. 2022, 4, 3361–3368. PDF


        Zan Yang, Wenpei Xiao, Xun Zhang and Saihu Liao *Organocatalytic cationic degenerate chain transfer polymerization of vinyl ethers with excellent temporal control. Polym. Chem2022,13, 2776-2781. PDF


         Yu Jiang, Qiang Ma, Xun Zhang, Junfang Lin and Saihu Liao *,  Solution [2 + 2]photopolymerization of biomassderived nonrigid biscinnamate monomers enabled by energy transfer catalysis. Polym. Chem2022,13, 2538-2544. PDF


         Fulin Zhang, Ruihua Zhao, Lei Zhu, Yinghua Yu, Saihu Liao, Zhi-Xiang Wang*and Xueliang Huang*, Divergent isoindolinone synthesis through palladium-catalyzed isocyanide bridging C–H activation. Cell Reports Physical Science. 2022, 3, 100776. PDF


         Xun Zhang#, Zan Yang#, Yu Jiang, and Saihu Liao*, Organocatalytic, Stereoselective, Cationic Reversible Addition− Fragmentation Chain-Transfer Polymerization of Vinyl Ethers. J. Am. Chem. Soc2022, 144, 679–684. PDF

       

2021

        Qiang Ma, Xun Zhang, Yu Jiang, Junqiang Lin, Bernadette Graff, Siping Hu, Jacques Lalevée,* Saihu Liao,* Organocatalytic PET-RAFT Polymerization with ppm of Organic Photocatalyst under Visible Light  Polym. Chem. 2022,13, 209-219. PDF


        Xingliang Nie, Saihu Liao,*  Radical Fluorosulfonylation: Accessing Alkenylsulfonyl Fluorides from Alkenes and Alkynes. Synlett. 2022. 33, 401-408. (SYNPACTS) PDF


        Dengfeng Chen, Xingliang Nie, Qingyuan Feng, Yingyin Zhang, Yiheng Wang, Qiuyue Wang, Lin Huang, Shenlin Huang,* Saihu Liao,* Electrochemical Oxo-Fluorosulfonylation of Alkynes under Air: A Facile Access to β-Keto Sulfonyl Fluorides. Angew. Chem. Int. Ed.  2021, 60, 27271-27276. PDF


        Zan Yang, Xun Zhang, Yu Jiang, Qiang Ma, Saihu Liao,* Organocatalytic Stereoselective Cationic Polymerization of Vinyl Ethers by Employing a Confined Brønsted Acid as the Catalyst. Science China Chemistry2022, 65, 304–308. PDF

   See the earlier preprint posted on ChemRxiv on 2021-10-04, see ChemRxiv doi: 10.33774/chemrxiv-2021-qlpb. PDF


       Xingliang Nie, Tianxiao Xu, Yuhao Hong, Honghai Zhang, Chenxi Mao, Saihu Liao,* Introducing A New Class of Sulfonyl Fluoride Hubs via Radical Chloro-Fluorosulfonylation of Alkynes. Angew. Chem. Int. Ed.  2021, 60, 22035-22042. PDF  

    *Selected as "Hot Paper"; highlighted in WileyChem.


       Xianli Shu, Ruting Xu, Saihu Liao.* Photocatalytic Divergent Decarboxylative Amination: A Metal-Free Access to Aliphatic Amines and Hydrazines. Sci. China Chem. 2021, 64, 1756-1762. PDF


       Xun Zhang, Yu Jiang, Qiang Ma, Siping Hu, and Saihu Liao,* Metal-Free Cationic Polymerization of Vinyl Ethers with Strict Temporal Control by Employing an Organophotocatalyst. J. Am. Chem. Soc. 2021, 143, 6357-6362. PDF

    * Highlighted in Synfacts. link


       Xun Zhang, Qiang Ma, Yu Jiang, Siping Hu, Junfang Li, Saihu Liao.* Visible light-regulated organocatalytic ring-opening polymerization of lactones by harnessing excited state acidity. Polym. Chem. 2021, 12, 885-892. PDF

    * Selected as Polymer Chemistry Author of the Month. link


      Qiang Ma, Jinshuai Song, Xun Zhang, Yu Jiang, Li Ji, Saihu Liao,* Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight. Nat. Commun. 2021, 12, 429. PDF

    *Highlighted by Nature Review Chemistry. Link


      Fulin Zhang+, Luoting Xin+, Yinghua Yu, Saihu Liao,* Xueliang Huang,* Recent Advances in Palladium-Catalyzed Bridging C–H Activation by Using Alkenes, Alkynes or Diazo Compounds as Bridging Reagents. Synthesis 2021, 53, 238–254. PDF


      Xingliang Nie, Tianxiao Xu, Jinshuai Song, Anandkumar Devaraj, Bolun Zhang, Yong Chen,  Saihu Liao,* Radical Fluorosulfonylation: Accessing Alkenyl Sulfonyl Fluorides from Alkenes. Angew. Chem. Int. Ed. 2021, 60, 3956–3960. PDF 

    *Highlighted by WileyChem, X-Mol.


2020

        Tianpeng Cao, Tianxiao Xu, Ruting Xu, Xianli Shu, Saihu Liao,* Decarboxylative thiolation of redox-active esters to free thiols and further diversification. Nat. Commun. 2020, 11:5340. PDF

        Featured in Org. Chem. Highlights.


        Xianli Shu, Ruting Xu, Qiang Ma and Saihu Liao,*. Accessing alkyl boronic esters via visible light-mediated decarboxylative addition reactions of redox-active esters. Org. Chem. Front. 2020, 7, 2003–2007. PDF


        Xun Zhang, Siping Hu, Qiang Ma, and Saihu Liao,* Visible light-mediated ring-opening polymerization of lactones based on the excited state acidity of ESPT molecules. Polym. Chem. 2020, 11, 3709–3715. PDF


       Tianxiao Xu, Tianpeng Cao, Mingcheng Yang, Ruting Xu, Xingliang Nie, and Saihu Liao,* Decarboxylative Thiolation of Redox-Active Esters to Thioesters by Merging Photoredox and Copper CatalysisOrg. Lett. 2020, 22, 3692–3695. PDF Selected by Org. Chem. Portal. Link.


      Tianxiao Xu+, Tianpeng Cao+, Qingyuan Feng, Shenlin Huang,* and Saihu Liao,* Metal-free dehydrosulfurization of thioamides to nitriles under visible light. Chem. Commun. 2020, 56, 5151–5153. PDF


      Xun Zhang, Yu Jiang, Qiang Ma, Siping Hu, Qinggang Wang, and Saihu Liao,* Imidodiphosphorimidate (IDPi) as an Efficient Organocatalyst for Controlled/Living Ring-Opening Polymerization of Lactones. Eur. Polym. J. 2020, 123: 109449. PDF


2019

       Qiang Ma, Xun Zhang, Li Ji, Saihu Liao,* BINOLs as Visible Light Photocatalyst for Metal-Free Atom Transfer Radical Polymerization. Qiang Ma, Xun Zhang, Li Ji, Saihu Liao,* Polym. Chem. 2019, 10, 6662-6668. PDF


       Mingcheng Yang, Tianpeng Cao, Tianxiao Xu, Saihu Liao,* Visible-Light-Induced Deaminative Thioesterification of Amino Acid Derived Katritzky Salts via Electron Donor–Acceptor Complex Formation. Org. Lett. 2019, 21, 8673–8678. PDF Selected by Org. Chem. Portal. Link.


       Rongbiao Wei, Liang Ge, Hongli Bao, Saihu Liao,* Yajun Li,* Copper-Catalyzed Nitrogenation of Aromatic and Aliphatic Aldehydes: A Direct Route to Carbamoyl Azides. Synthesis 2019, 51, 4645–4649. PDF


      Ruting Xu, Tianxiao Xu, Mingcheng Yang, Tianpeng Cao, Saihu Liao,*  A Rapid Access to Aliphatic Sulfonyl Fluorides. Nat. Commun. 2019, 10, 3752. PDF


      Li Ji+, Jia-Shuai Liu+, Xiao-Yan Wang, Jun-Fang Li, Zhou Chen, Saihu Liao,* Xiu-Li Sun,* Yong Tang, An Efficient and Mild Route to Highly Fluorinated Polyolefins via Copolymerization of Ethylene and 5-Perfluoroalkylnorbornenes. Polym. Chem. 2019, 10, 3604–3609. PDF


      Zhu Cao+, Jian-Bo Zhu+, Lijia Wang,* Saihu Liao,* Yong Tang, A Synthesis of Multifunctionalized Indoles from [3 + 2] Annulation of 2‑Bromocyclopropenes with Anilines. Org. Lett. 2019, 21, 4097–4100. PDF


2018

     Hai-Xian Gong, Zhu Cao, Saihu Liao, Mei-Jin Lin*, Photoexcited Perylene Diimide Radical Anions for the Reduction of Aryl Halides: A Bay-substituent Effects. Hai-Xian Gong, Zhu Cao, Saihu Liao, Mei-Jin Lin*, Org. Chem. Front. 2018, 5, 2296–2302. PDF


Before FZU

Mattia Riccardo Monaco, D Fazzi, Nobuya Tsuji, Markus Leutzsch, Saihu Liao, W Thiel, Benjamin List*, The Activation of Carboxylic Acids via Self-Assembly Asymmetric Organocatalysis: A Combined Experimental and Computational Investigation, J. Am. Chem. Soc., 2016, 138, 14740-14749. PDF

 

Saihu Liao, Markus Leutzsch, Mattia Riccardo Monaco, Benjamin List*, Catalytic Enantioselective Conversion of Epoxides to Thiiranes, J. Am. Chem. Soc., 2016, 138, 5230-5233. PDF (Highlighted by SynFacts, Nature Chemistry)


Christian Merten*, Corina H. Pollok, Saihu Liao, Benjamin List*, Stereochemical Communication within a        Chiral Ion Pair Catalyst, Angew. Chem. Int. Ed., 2015, 54, 8841-8845. PDF  


Pan Wang, Liang-Wen Feng, Lijia Wang, Jun-Fang Li, Saihu Liao, and Yong Tang*, Asymmetric 1,2-Perfluoroalkyl Migration: Easy Access to Enantioenriched α-Hydroxy-α-perfluoroalkyl Esters, J. Am. Chem. Soc., 2015, 137, 4626–4629. PDF


Hao Xu, Jiang-Lin Hu, Lijia Wang, Saihu Liao, and Yong Tang*, Asymmetric Annulation of Donor–Acceptor Cyclopropanes with Dienes, J. Am. Chem. Soc., 2015, 137, 8006-8009. PDF


Saihu Liao, Xiu-Li Sun, Yong Tang*, Sidearm Strategy for Catalyst Design Based on Bisoxazolines in the Remote Control of Enantioselection and Related, Acc. Chem. Res., 2014, 47, 2260-2272. PDF  

Jian-Bo Zhu, Hao Chen, Saihu Liao, Yu-Xue Li* and Yong Tang*, A Sidearm-assisted Phosphine for Catalytic Ylide Intramolecular Cyclopropanation, Org. Chem. Front., 2014, 1, 1035-1039. PDF  

Peng Wang, Saihu Liao, Jian-Bo Zhu and Yong Tang*, Double γ-alkylation of allylic phosphorus ylides: a unique access to oxa-bicyclic[3.3.0] diene skeletons, Chem. Commun., 2014, 50, 808-810. PDF  

Pan Wang, Wen-Jie Tao, Xiu-Li Sun, Saihu Liao* and Yong Tang*, A Highly Efficient and Enantioselective Intramolecular Cannizzaro Reaction under TOX/Cu(II) Catalysis, J. Am. Chem. Soc., 2013, 135, 16849-16852. PDF (Highlighted by SynFacts)

Peng Wang, Saihu Liao, Jian-Bo Zhu, and Yong Tang*, Iron-Catalyzed Three-Component Reaction: Multiple C-C Bond Cleavages and Reorganizations, Org. Lett., 2013, 15, 3606-3609. PDF

Peng Wang, Saihu Liao, Sunewang R. Wang, Run-Duo Gao and Yong Tang*, Reaction of trisubstituted alkenes with iron porphyrin carbenes: facile synthesis of tetrasubstituted dienes and cyclopentadienes, Chem. Commun., 2013, 49, 7436-7438. PDF

Jian-Bo Zhu, Peng Wang, Saihu Liao*, and Yong Tang*, Ylide Hydrolysis in Tandem Reactions: A Highly Z/E-Selective Access to 3-Alkylidene Dihydrobenzofurans and Related Analogues, Org. Lett., 2013, 15, 3054-3057. PDF

Hu Xiong, Hao Xu, Saihu Liao, Zuowei Xie*, and Yong Tang*, Copper-Catalyzed Highly Enantioselective Cyclopentannulation of Indoles with Donor–Acceptor Cyclopropanes, J. Am. Chem. Soc., 2013, 135, 7851-7854. PDF (Highlighted by SynStory)

Jian-Bo Zhu, Peng Wang, Saihu Liao* and Yong Tang*, PPh3-mediated Intramolecular Conjugation of AlkylHalides with Electron-deficient Olefins: Facile Synthesis of Chromans and Relevant Analogues, Chem. Commun., 2013, 49, 4570-4572. PDF

Peng Wang, Lin Ling, Sai-Hu Liao, Jian-Bo Zhu, Sunewang R. Wang, Yu-Xue Li,* and Yong Tang*, Reactions of Iron Carbenes with a,b-Unsaturated Esters by Using anUmpolung Approach: Mechanism and Applications, Chem. Eur. J., 2013, 19, 6766-6773. PDF

Hao Xu, Jian-Ping Qu, Saihu Liao, Hu Xiong, and Yong Tang*, Highly Enantioselective [3+2] Annulation of Cyclic Enol Silyl Ethers with D-A Cyclopropanes: Accessing 3a-Hydroxy [n,3,0] Carbobicycles, Angew. Chem. Int. Ed., 2013, 52, 4004-4007.


Sai-Hu Liao, Peng Wang, Yong Tang, “Covalent Activations: Ylides” in Comprehensive Enantioselective Organocatalysis: Catalysts, Reactions, and Applications, P. Dalko, Ed., Wiley-VCH & Sons: Weinheim, Germany, 2013. (Book Chapter)

You-Yun Zhou, Jun Li, Lin Ling, Saihu Liao, Xiu-Li Sun*, Yu-Xue Li*, Li-Jia Wang, and Yong Tang*, Highly Enantioselective [3+3] Cycloaddition of Aromatic AzomethineImines with Cyclopropanes Directed by pi–piStacking Interactions, Angew. Chem. Int. Ed., 2013, 52, 1452-1456.

Zhen-Cao Shu, Jian-Bo Zhu, Saihu Liao, Xiu-Li Sun, and Yong Tang*, Facile and Controllable Synthesis of Multiply Substituted Benzenesvia a Formal [3+3] Cycloaddition Approach, Tetrahedron 2013, 69, 284-292.

Saihu Liao and Benjamin List*, Asymmetric Counteranion-Directed Iron Catalysis: A Highly Enantioselective Sulfoxidation, Adv. Syn. Catal., 2012, 354, 2363-2367.

 

Benjamin List and Sai-Hu Liao,“The Proline-Catalyzed Mannich Reaction and the Advent of Enamine Catalysis”, in Organic Chemistry–Breakthroughs and Perspectives,K. Ding, L.-X. Dai, Eds., Wiley-VCH: Weinheim, Germany, 2012. (Book Chapter)


Saihu Liao, Ilija Čorić, Qinggang Wang, and Benjamin List*, Activation of H2O2 by Chiral Confined Brønsted Acids: A Highly Enantioselective Catalytic Sulfoxidation, J. Am. Chem. Soc., 2012, 134, 10765-10768. (Highlighted by SynFacts)

 Jun Li, Sai-Hu Liao, Hu Xiong, You-Yun Zhou, Xiu-Li Sun*, Yue Zhang, Xiao-Guang Zhou, and Yong Tang* Highly Diastereo-and Enantioselective Cyclopropanation of 1,2-Disubstituted Alkenes. Angew. Chem. Int. Ed., 2012, 51, 8838-8841.

Jiang-Hua Chen, Sai-Hu Liao, Xiu-Li Sun, Qi Shen*, and Yong Tang*, Tris(oxazoline)/Copper-Catalyzed Coupling of Alkynes with Nitrones: AHighly Enantioselective Access to β-Lactams, Tetrahedron 2012, 68, 5042-5045.

Saihu Liao and Benjamin List*, Asymmetric Counteranion-Directed Transition-Metal Catalysis: Enantioselective Epoxidationof Alkenes with Manganese(III)-Salen Phosphate Complexes, Angew. Chem. Int. Ed., 2010, 49, 628-631. (Selected as “Hot Paper”,highlightedby SynFacts)

Fanglin Zhang, Yiyuan Peng, Saihu Liao, and Yuefa Gong*, Pyrrolidine as an Efficient Organocatalyst for Direct Aldol Reactionof Trifluoroacetaldehyde Ethyl Hemiacetal with Ketones, Tetrahedron 2007, 63, 4636-4641.