2024

268.Guan-Ming Chen, Zi-Hao Ye, Zhi-Ming Li,* and Jun-Liang Zhang*

Universal descriptors of quasi transition states for small-data-driven asymmetric catalysis prediction in machine learning model.

^{Cell Reports Physical Science 2024, 5, 102043. DOI: 10.1016/j.xcrp.2024.102043}

267.Zhou Luo,‡ Tianxiang Fan,‡ Jingyan Luo, Yuanyuan Liu * and Junliang Zhang*

Ir/XuPhos-catalyzed direct asymmetric reductive amination of ketones with secondary amines.

Org. Chem. Front.,2024,11,6735–6741.

Xu-Phos

266. Zhi-Kun Zhang, Yin Yuan, Huiling Peng, Yidan Han, Junliang Zhang*, Junfeng Yang*

Synthesis of Sulfinamidines via Iron-Catalyzed Nitrene Transfer Reaction with Sulfenamides.

J. Org. Chem. 2024, XXXX, XXX-XXX, DOI:.org/10.1021/acs.joc.4c02286.

Xu-Phos

265.Bing Xu, Danting Ji, Zhan-Ming Zhang, * Junliang Zhang*

Remote C─H Bond Activation via Enantioselective Carbopalladation and 1,4-Pd Migration Cascade Process.

Adv. Sci. 2024, 11, 2406443.    

Xu-Phos

• 
  •      
  •      
  •                
  • 264. Kangning Cao, Jie Han, Wenshao Ye, Dejun Hu, Zihao Ye, Junfeng Yang,* Junliang Zhang,* and Fener Chen*

  • Enantioselective Aminosilylation of Alkenes byPalladium/Ming-Phos-Catalyzed TandemNarasaka–Heck/Silylation Reaction.      

    Adv. Sci. 2024, 11, 2403470.

             
  • Ming-Phos 
  • • • • 

•  
•  
•  
•  
•  
•  
•  
• 263. 
• Jinrong Wang, 
• Bing Xu, 
• Yibo Wang, 
• Guangzhen Xia, 
• Zhan-Ming Zhang
• *
• , and 
• Junliang Zhang*

• Pd-Catalyzed Enantioselective Three-Component Carboaminationof 1,3-Cyclohexadiene.    
  • • • J. Am. Chem. Soc. 2024, 146, 21231−21238. 
    • Ming-Phos 
    • •   
  262. Yin Yuan, Yidan Han, Zhi-kun Zhang, Shijin Sun, Ke Wu,Junfeng Yang*, and Junliang Zhang*
• • Enantioselective Arylation of Sulfenamides to Access SulfiliminesEnabled by Palladium Catalysis.
  • Angew. Chem. Int. Ed. 2024, e202409541.      
    Wei-Phos      
    • 
      •      
      •      
      •      
      •         
      •                                                  

• 261. Yixiang Shi
• , 
• Yin Yuan
• , 
• Jianhui Li
• , 
• Junfeng Yang*
• , and 
• Junliang Zhang*

Catalytic Asymmetric Synthesis of Sulfinamides via Cu-Catalyzed Asymmetric Addition of Aryl Boroxines to Sulfinylamines.

J. Am. Chem. Soc. 2024, XXXX, XXX, XXX-XXX, DOI:10.1021/jacs.4c03473.

Xu-Phos

260. Qiaojing Meng, Yinggao Meng, Qinglin Liu, Bing Yu, Zhong-Jun Li, Er-Qing Li*, Junliang Zhang*

Enantioselective Synthesis of Oxazocines via MQ-Phos Enabled Palladium-Catalyzed Asymmetric Formal [4+4]-Cycloadditions.

Adv. Sci. 2024, 11, 2402170.

259. Jin-Lan Zhou, Yuanjiu Xiao, Linke He, Xin-Yu Gao, Xue-Chun Yang, Wen-Biao Wu, Guoqiang Wang, Junliang Zhang*, and Jian-Jun Feng*

Palladium-Catalyzed Ligand-Controlled Switchable Hetero-(5 + 3)/Enantioselective [2σ+2σ] Cycloadditions of Bicyclobutanes with Vinyl Oxiranes.

J. Am. Chem. Soc. 2024, XXXX, XXX-XXX, DOI: 10.1021/jacs.4c01851.

258. Lujia Zhou, Longling Ma, Bing Xu, Zhan-Ming Zhang*, Junliang Zhang*

Palladium/Xu-Phos Catalyzed Enantioselective Intramolecular Heck Reaction of Unactivated Alkenes.

Chin. J. Chem. 2024, 42, 2466—2470, DOI: 10.1002/cjoc.202400391.

Xu-Phos

257. Qi Pan, Kuai Wang, Weipeng Xu, Yuqi Ai, Yuanyuan Ping, Chuhan Liu, Minyan Wang*, Junliang Zhang*, and Wangqing Kong*

Ligand-Controlled, Nickel-Catalyzed Stereodivergent Construction of 1,3-Nonadjacent Stereocenters.

J. Am. Chem. Soc. 2024, 146, 22, 15453–15463.

Ming-Phos     

256. Mengyuan Liu, Kexin Dong, Bing Xu, Zhan-Ming Zhang*, Zhong Wei *, and Junliang Zhang *

Nickel(0)-catalyzed ring-opening reaction of silacyclobutanes with 1,3-dienes to access allylsilane.

Org. Chem. Front., 2024, DOI: 10.1039/D4QO00357H.

255. Yidan Han, Yin Yuan, Shutao Qi, Zhi-Kun Zhang, Xiangfei Kong*, Junfeng Yang*, and Junliang Zhang*

Copper-Catalyzed Sulfur Alkylation of Sulfenamides with N-Sulfonylhydrazones

Org. Lett. 2024, 26, 18, 3906–3910.                       

‍254. Kangning Cao#, Shutao Qi#, Jianhui Li , Wenshao Ye, Junfeng Yang*, Junliang Zhang*, Fener Chen*

Palladium-catalyzed tandem aza-Heck reaction of alkene-tethered oxime esters with cyclopropanols.

Green Synthesis and Catalysis, 2024,DOI: 10.1016/j.gresc.2024.04.002.

253. Shuai Zhu#, Mingjie Chen#,Haichao Shen, Hanming Ding*, Wenbo Li*, Junliang Zhang*‍

Palladium/Xu-Phos-catalyzed enantioselective arylalkoxylation reaction of γ-hydroxyalkenes at room temperature

Chinese Chemical Letters, 2024, 109879. DOI: 10.1016/j.cclet.2024.109879.

Xu-Phos

252. Zhao Yongzhe, Kong Xiangfei*, Zhang Junliang*, Yang Junfeng* 

Research Progress in the Application of Supported Catalysts Containing Phosphine.

Chin. J. Org. Chem. 2024, 44, xxxx～xxxx, DOI: 10.6023/cjoc202403016.

251. Chao Fang, Quan-Pu Wang, Bing Xu, Zhan-Ming Zhang* and Junliang Zhang*

Palladium/Xu-Phos-catalyzed enantioselective cascade Heck/intermolecular C(sp2)–H alkylation reaction

Chem. Sci., 2024,15, 5573-5580

Xu-Phos

• 250. Kangning Cao#
• , 
• Jie Han#
• , 
• Haichao Shen
• , 
• Junfeng Yang*
• , 
• Junliang Zhang*
• , and 
• Fener Chen*

Pd-Catalyzed Asymmetric Aza-Heck Cyclization/Sonogashira Reaction of Alkene-Tethered Oxime Esters and Alkynes.

ACS Catal. 2024, 14, 5305–5313.

Ming-Phos

249. Genwei Zhang, Bin Yang, Junfeng Yang*, and Junliang Zhang*

Pd-Catalyzed Asymmetric Larock Indole Synthesis to Access Axially Chiral N-Arylindoles.

J. Am. Chem. Soc. 2024, 146, 5493–5501. DOI:10.1021/jacs.3c13356.

Ming-Phos      

248. Lei Wang*, Yinqiang Wang, Shuaijie Wu, Chao-Guo Yan, Chaoshen Zhang*, Junliang Zhang*, and Ying Han*

Enantioselective Synthesis of Isoindolinone by Palladium-Catalyzed Aminoalkynylation of O-Phenyl Hydroxamic Ethers with Alkynes.

J. Am. Chem. Soc. 2024, 146, 4320–4326

247. Shutao Qi, Yunkai Hua, Liangkai Pan, Junfeng Yang*, Junliang Zhang*

Nickel-Catalyzed Regio- and Stereoselective Defluorinative Arylation of gem-Difluorinated Cyclopropanes.

Chin. J. Chem. 2024, 42, 823-828

246. Wenbo Li and Junliang Zhang*

Sadphos as Adaptive Ligands in Asymmetric Palladium Catalysis.

Acc. Chem. Res. 2024, 57, 489–513.

2023年 

245. Shuai Zhu#, Zihao Ye#, Ming-Jie Chen#, Lei Wang , Yu-Zhuo Wang , Ke-Nan Zhang , Wen-Bo Li , Han-Ming Ding , Zhiming Li *, Junliang Zhang*

Mechanistic study on the side arm effect in a palladium/Xu-Phos-catalyzed enantioselective alkoxyalkenylation of γ-hydroxyalkenes.

Nature Communications | (2023) 14:7611, DOI: 10.1038/s41467-023-43202-5

Xu-Phos

244. Shutao Qi, Wenshao Ye, Yunkai Hua, Liangkai Pan, Junfeng Yang*, and Junliang Zhang*

Ligand-enabled palladium-catalysed enantioselective synthesis of α-quaternary amino and glycolic acids derivatives.

Nat. Synth. 2023, DOI: 10.1038/s44160-023-00448-7.

Xiang-Phos

243. Yue Sun, Kaida Zhou, Chun Ma, Zhiming Li*, and Junliang Zhang*

Rhodium/Ming-Phos-catalyzed asymmetric annulation reaction of silacyclobutanes with terminal alkynes.

Green Synth. Catal. 2023, DOI: 10.1016/j.gresc.2023.09.001.

Ming-Phos

242. Hui Zhang, Bing Xu, Liejin Zhou , Zhan-Ming Zhang*, and Junliang Zhang*

Polymer-supported chiral palladium-based complexes as efficient heterogeneous catalysts for asymmetric reductive Heck reaction.

Green Synth. Catal. 2023, DOI: 10.1016/j.gresc.2023.04.002.

Xu-Phos

241. Li-Ming Zhang, Wenjun Luo, Jiangzhen Fu, Yu Liu*, and Junliang Zhang*

W-Phos Ligand Enables Copper-Catalyzed Enantioselective Alkylation of N-Sulfonyl Ketimines with Grignard Reagents

ACS Catal. 2023, 13, XXX, 8830–8837. DOI: 10.1021/acscatal.3c01775

W-Phos

240. Jie Han†, Siyuan Liu†, Huanan Wang, Jie Wang, Hui Qian, Zhiming Li*, Shengming Ma*,Junliang Zhang*

Pd/Xu-Phos-catalyzed asymmetric elimination of fully substituted enol triflates into axially chiral trisubstituted allenes

Sci. Adv. 2023, 9, eadg1002.   DOI: 10.1126/sciadv.adg1002

(†These authors contributed equally to this work)

Xu-Phos

239. Shuting Zhang, Shuaijie Wu, Qiang Wang, Shiji Xu, Ying Han, Chao-Guo Yan, Junliang Zhang*, Lei Wang*

Enantioselective Synthesis of Dihydropyrazoles by Palladium/Xu-Phos-Catalyzed Alleneamination of β,γ-Unsaturated Hydrazones with Propargylic Acetates

Angew. Chem.Int. Ed. 2023, 62, e202300309

Xu-Phos

238. Shiquan Gao, Chen Wang, Junfeng Yang* & Junliang Zhang* 

Cobalt-catalyzed enantioselective intramolecular reductive cyclization via electrochemistry. 

Nat. Commun. 2023, 14, 1301.

237. Youshao Tu, Bing Xu, Qian Wang, Honglin Dong, Zhan-Ming Zhang*, Junliang Zhang* 

Palladium/TY-Phos-Catalyzed Asymmetric Heck/Tsuji–Trost Reaction of o-Bromophenols with 1,3-Dienes

J. Am. Chem. Soc. 2023, DOI: 10.1021/jacs.2c12752

TY-Phos

236. Ronghua Zhang, Shan Xu, Zhou Luo, Yuanyuan Liu,* and Junliang Zhang*

Enantiodivergent Hydrogenation of Exocyclic α,β-Unsaturated Lactams Enabled by Switching the N-Chirality of Iridium Catalyst

Angew. Chem. Int. Ed. 2023, e202213600

Rong-Phos

235. Chun Ma, Yue Sun, Junfeng Yang*, Hao Guo*, and Junliang Zhang*

Catalytic Asymmetric Synthesis of Tröger’s Base Analogues with Nitrogen Stereocenter

ACS Cent. Sci. 2023, DOI: 10.1021/acscentsci.2c01121

GF-Phos

234. Yin Yuan, Junfeng Yang* and Junliang Zhang* 

Cu-catalyzed enantioselective decarboxylative cyanation via the synergistic merger of photocatalysis and electrochemistry.

Chem. Sci., 2023, DOI: 10.1039/D2SC05428K

2022年 

233. Juan Feng,‡ Jiayi Shi,‡ Lan Wei,‡ Mingqing Liu, Zhiming Li, * Yuanjing Xiao* and Junliang Zhang*

Palladium/PC-Phos-Catalyzed Asymmetric Heck/Tsuji-Trost Reactions of Amino-Tethered 1,3-Cyclohexadiene with Aryl and Alkenyl Halides.

Angew. Chem. Int. Ed. 2022, e202215407

(‡ These authors contributed equally to this work)

PC-Phos

232. Wenge Zhang‡, Pei-Chao Zhang‡, Yin-Lin Li, Hai-Hong Wu, and Junliang Zhang*

PC-Phos Enabled Catalytic Palladium-heteroallyl Asymmetric Cycloaddition

J. Am. Chem. Soc. 2022, 144, 19627–19634.

(‡ These authors contributed equally to this work)

231. Chun Ma, Yue Sun, Siyuan Liu, Zhi-Ming Li, Junfeng Yang*, Hao Guo*, Junliang Zhang.*

Enantioselective construction of axially chiral cyclohexylidene scaffolds via Pd-catalyzed asymmetric coupling reaction.

Chem Catalysis, 2022, 2, 3196-3206.

Xu-Phos

230. Wenya Feng, Yuanjing Xiao, Chuanfang Zhao, Zhanming Zhang, Wei Liu, Juan Ma, Tomas Ganz, Junliang Zhang*, Sijin Liu*.

New Deferric Amine Compounds Efficiently Chelate Excess Iron to Treat Iron Overload Disorders and to Prevent Ferroptosis.

Adv. Sci., 2022, 9, 2202679.

229. Yaochen Zhang, Zhangjin Pan, Hao Guo,* Junfeng Yang,* Junliang Zhang*

10 Gram-scale synthesis of TY-Phos ligand and its application in carbene insertion of Si-H bonds

Tetrahedron Lett., 2022, 107, 154120

TY-Phos

228. Honghao Bao,  Yixiang Shi,  Junliang Zhang,* Junfeng Yang* and  Junliang Wu*.

Stereoselective synthesis of trisubstituted epoxides via cobalt catalysis. 

Org. Chem. Front., 2022, 9, 4932-4936.

227. Yue Sun, Chun Ma, Zhiming Li,* Junliang Zhang*  

Palladium/GF-Phos-Catalyzed Asymmetric Carbenylative Amination to Access Chiral Pyrrolidines and Piperidines. 

Chem. Sci., 2022, 13, 11150-11155.

GF-Phos

226. Huanan Wang, Hui Qian*, Junliang Zhang*, and Shengming Ma*

Catalytic Asymmetric Axially Chiral Allenyl C–P Bond Formation. 

J. Am. Chem. Soc. 2022, 144, 12619–12626.

225. Bin Yang, Kangning Cao, Guofeng Zhao, Junfeng Yang*, and Junliang Zhang*

Pd/Ming-Phos-Catalyzed Asymmetric Three-Component Arylsilylation of N-Sulfonylhydrazones: Enantioselective Synthesis of gem-Diarylmethine Silanes.

J. Am. Chem. Soc. 2022, 144, 15468–15474.

Ming-Phos

224. Wenjun Luo, Li-Ming Zhang, Zhan-Ming Zhang, Junliang Zhang*.

Synthesis of W-Phos Ligand and Its Application in the Copper-Catalyzed Enantioselective Addition of Linear Grignard Reagents to Ketones. 

Angew. Chem. Int. Ed. 2022, DOI: 10.1002/anie.202204443

W-Phos

223. Sanliang Li‡, Qiaoyu Chen‡, Junfeng Yang*, Junliang Zhang*.

Palladium-Catalyzed Enantioselective γ-Arylation of β,γ-Unsaturated Butenolides. 

Angew. Chem. Int. Ed. 2022, DOI: 10.1002/anie.202202046.

(‡ These authors contributed equally to this work)

222. Bing Xu, Danting Ji, Lizuo Wu, Lujia Zhou, Yu Liu, Zhan-Ming Zhang*, Junliang Zhang*. 

Palladium/Xu-Phos-catalyzed enantioselective cascade Heck/remote C(sp2) –H alkylation reaction. 

Chem. 2022, 8, 836-849.

Xu-Phos

221. Xiao-Qing Han‡, Lei Wang‡, Ping Yang‡, Jing-Yuan Liu, Wei-Yan Xu, Chao Zheng, Ren-Xiao Liang, Shu-Li You*, Junliang Zhang*, and Yi-Xia Jia*. 

Enantioselective Dearomative Mizoroki–Heck Reaction of Naphthalenes. 

ACS Catal. 2022, 12, 655–661. (‡ These authors contributed equally to this work)

Xu-Phos

220. Bing Xu, Zhan-Ming Zhang, Jie Han, Guangxin Gu*, Junliang Zhang*.

Enantioselectivity Tunable Gold-Catalyzed Intermolecular [3 + 2] Cycloaddition of N-Allenamides with Nitrones. 

Chin. J. Chem. 2022, 40, 1407-412. （封面文章）&（荣获“新和成《中国化学》创新奖", NHU-CJC Innovation Award）

Ming-Phos

219. Xiaoxiao Xie, Sanliang Li, Qiaoyu Chen, Hao Guo, * Junfeng Yang，* Junliang Zhang*. 

Synthesis and application of novel P-chiral monophosphorus ligands. 

Org. Chem. Front., 2022, 9, 1589-1592.

Xiao-Phos

2021年 

218.   Kangning Cao, Zhan-Ming Zhang, Junliang Zhang*, and Fener Chen*.

 Palladium-Catalyzed Asymmetric Cross-Coupling Reactions of Cyclobutanols and Unactivated Olefins.  

Org. Lett. 2021, 23, 9520–9525.

Xu-Phos

                                        

217. Sanliang Li‡，Qiaoyu Chen‡，Zhan-Ming Zhang，JunliangZhang*.

Pd-catalyzed enantioselective intramolecular Heck reaction to access disubstituted dihydroisoquinolinone with a terminal olefin. 

Green Synth. Catal. 2021, 2, 374. (‡ These authors contributed equally to this work)

Ming-Phos

216. Sanliang Li‡, Qiaoyu Chen‡, Xiaoxiao Xie, Junfeng Yang*, and Junliang Zhang*

Pd-Catalyzed Enantioselective Dearomative Allylic Annulation to Access PPAPs Analogues. 

Org. Lett. 2021, 23, 7824. (‡ These authors contributed equally to this work)

215. Qiang Dai, Lu Liu,* Junliang Zhang*. 

Palladium/Xiao-Phos-Catalyzed Kinetic Resolution of sec-Phosphine Oxides by P-Benzylation.  

Angew. Chem. Int. Ed. 2021, 60, 27247.

(Dedicated to 70th anniversary of East China Normal University)

Xiao-Phos

214. Guofeng Zhao, Yi Wu, Hai-Hong Wu, Junfeng Yang*, and Junliang Zhang*. 

Pd/GF-Phos-Catalyzed Asymmetric Three-Component Coupling Reaction to Access Chiral Diarylmethyl Alkynes. 

J. Am. Chem. Soc. 2021, 143, 17983–17988.

GF-Phos

 

213. Yin-Lin Li,‡ Pei-Chao Zhang,‡ Hai-Hong Wu and Junliang Zhang.* 

Palladium-Catalyzed Asymmetric Tandem Denitrogenative Heck/Tsuji–Trost of Benzotriazoles with 1,3-Dienes. 

J. Am. Chem. Soc. 2021, 143, 13010–13015. (‡ These authors contributed equally to this work)

（清华大学唐叶峰教授在<<有机化学>>全文亮点评述：链接）

Xu-Phos & PC-Phos

212. Pei-Chao Zhang, Yin-Lin Li, Jiafeng He, Hai-Hong Wu,* Zhiming Li* & Junliang Zhang*. 

Simultaneous construction of axial and planar chirality by gold/TY-Phos-catalyzed asymmetric hydroarylation. 

Nat. Commun.volume 2021, 12, 4609.

TY-Phos

211.  Zhangjin Pan, Wenbo Li, Shuai Zhu, Feng Liu, Hai-Hong Wu, Junliang Zhang*. 

Palladium/TY-Phos-Catalyzed Asymmetric Intermolecular α-Arylation of Aldehydes with Aryl Bromides. 

Angew. Chem. Int. Ed. 2021, 60, 18542–18546. (Hot Paper)

TY-Phos

210. Y. Wu, B. Xu, G. Zhao, Z. Pan, Z.-M. Zhang*, J. Zhang*. 

Palladium/Xu-Phos Catalyzed Enantioselective Tandem Heck/Cacchi Reaction of Unactivated Alkenes. 

Chin. J. Chem. 2021, 39, 3255–3260.

Xu-Phos

209. B. Yang, J. Yang*, J. Zhang*. 

Synthesis of Axially Chiral Anilides Enabled by a Palladium/ Ming-Phos-Catalyzed Desymmetric Sonogashira Reaction.

Chin. J. Chem. 2022, 40, 317-322.

Ming-Phos

208. Zhenli Liu, Guanghui Li, Tengfei Yao, Junliang Zhang*, Lu Liu*. 

Triflic Acid-Catalyzed Chemo- and Site-Selective C−H Bond Functionalization of Phenols With 1,3-Dienes. 

Adv. Synth. Catal. 2021, 363, 2740-2745.

207. Qiaoyu Chen, Sanliang Li, Xiaoxiao Xie, Hao Guo*, Junfeng Yang*, and Junliang Zhang* 

Pd-Catalyzed Enantioselective Dicarbofunctionalization of Alkene to Access Disubstituted Dihydroisoquinolinone. 

Org. Lett. 2021, 23, 4099–4103.

Xu-Phos

206. Wangqin Ji, Hai-Hong Wu, Wenbo Li* and Junliang Zhang*. 

Copper-catalyzed cyclization reaction: synthesis of trifluoromethylated indolinyl ketones. 

Chem. Commun., 2021, 57, 4448-4451.

205. Zhunzhun Yu, Guanghui Li,  Junliang Zhang* and  Lu Liu*. 

Iron-catalysed chemo- and ortho-selective C–H bond functionalization of phenols with α-aryl-α-diazoacetates. 

Org. Chem. Front., 2021, 8, 3770-3775.

204. Yuzhuo Wang, Lei Wang,Mingjie Chen,Youshao Tu, Yu Liu* and Junliang Zhang* 

Palladium/Xu-Phos-catalyzed asymmetric carboamination towards isoxazolidines and pyrrolidines. 

Chem. Sci., 2021,12, 8241.

Xu-Phos

2020年 

203. Deyun Qian and Junliang Zhang*，

Yne–Enones Enable Diversity-Oriented Catalytic Cascade Reactions: A Rapid Assembly of Complexity. 

Acc. Chem. Res. 2020, 53, 2358–2371.

202. Lin, Tao.-Yan.; Pan, Zhangjin.; Tu, Youshao; Zhu, Shuai; Wu, Hai-Hong; Liu, Yu; Li, Zhiming*; Zhang, Junliang*. 

Design and Synthesis of TY-Phos and Application in Palladium-Catalyzed Enantioselective Fluoroarylation of gem-Difluoroalkenes. 

Angew. Chem., Int. Ed. 2020, 59, 22957−22962.

TY-Phos

201. Chu, Haoke; Cheng, Jie; Yang, Junfeng; Guo, Yin-Long. Zhang Junliang*. 

Asymmetric Dearomatization of Indole via Palladium/PC-Phos-Catalyzed Dynamic Kinetic Transformation. 

Angew. Chem. Int. Ed. 2020, 59, 21991–21996. (Hot Paper)

PC-Phos

200. Lujia Zhou,‡ Sanliang Li,‡ Bing Xu, Danting Ji, Lizuo Wu, Yu Liu, Zhan-Ming Zhang,* and Junliang Zhang*. Enantioselective Difunctionalization of Alkenes by a Palladium-Catalyzed Heck/Sonogashira Sequence. 

Angew. Chem. Int. Ed. 2020, 59, 2769–2775. (‡ These authors contributed equally to this work)

Xu-Phos

199. Dai, Qiang; Liu, Lu; Qian, Yanyan; Li, Wenbo; Zhang, Junliang*. 

Construction of P-Chiral Alkenylphosphine Oxides through Highly Chemo-, Regio-, and Enantioselective Hydrophosphinylation of Alkynes. 

Angew.Chem. Int.Ed. 2020, 59, 20645–20650.

Xiao-Phos

198. Lei Wang, Kenan Zhang, Yuzhuo Wang, Wenbo Li, Mingjie Chen, and Junliang Zhang*.  

Enantioselective Synthesis of Isoxazolines Enabled by Palladium-Catalyzed Carboetherification of Alkenyl Oximes. 

Angew. Chem. Int. Ed. 2020, 59, 4421 – 4427.

Xiang-Phos

197. Huanan Wang, Hongwen Luo, Zhan-Ming Zhang, Wei-Feng Zheng, Yu Yin, Hui Qian,*Junliang Zhang,* and Shengming Ma*. 

Pd-Catalyzed Enantioselective Syntheses of Trisubstituted Allenes via Coupling of Propargylic Benzoates with Organoboronic Acids. 

J. Am. Chem. Soc. 2020, 142, 9763-9771.

Ming-Phos

196. Wangqin Ji, Hai-Hong Wu,* and Junliang Zhang*, 

Axially Chiral Biaryl Monophosphine Oxides Enabled by Palladium/WJ-Phos-Catalyzed Asymmetric Suzuki−Miyaura Cross-coupling. 

ACS Catal. 2020, 10, 1548−1554.

WJ-Phos

195. Tao, Mengna; Tu, Youshao; Liu, Yu; Wu, Haihong; Liu, Lu*; Zhang, Junliang*. 

Pd/Xiang-Phos-catalyzed enantioselective intermolecular carboheterofunctionalization under mild conditions.  

Chem. Sci., 2020, 11, 6283-6288.

Xiang-Phos

194. Qiu, Haile; Dai, Qiang; He, Jiafeng; Li, Wenbo; Zhang, Junliang*. 

Access to P-chiral sec- and tert-phosphine oxides enabled by Le-Phos-catalyzed asymmetric kinetic resolution.  

Chem. Sci., 2020, 11, 9983-9988.

Le-Phos

193. Lujia Zhou, Bing Xu,  Danting Ji,  Zhan-Ming Zhang,*and Junliang Zhang*, 

Ming-Phos/Gold(I)-Catalyzed Stereodivergent Synthesis of HighlySubstituted Furo[3,4-d][1,2]oxazines. 

Chin. J. Chem. 2020, 38, 577-582.

Ming-Phos

192. Yongfeng Li, Zhiqiong Tang, Junliang Zhang,* and Lu Liu*, 

Gold-Catalyzed Intermolecular [4+1] Spiroannulation via Site Selective Aromatic C(sp2)-H Functionalization and Dearomatization of Phenol Derivatives. 

Chem. Commun., 2020, 56, 8202-8205.

191. Liu, Bing; Qiu, Haile; Chen, Xiaofeng; Li, Wenbo; Zhang, Junliang*. 

Copper-catalyzed asymmetric tandem borylative addition and aldol cyclization. 

Org. Chem. Front., 2020, 7, 2492-2498.

190. Li, Wenbo; Zhang, Junliang*. 

Synthesis of Heterocycles through Denitrogenative Cyclization of Triazoles and Benzotriazoles.  

Chem. Eur. J. 2020, 26, 11931-11945.

189. Ma, Ben; Tang, Zhiqiong; Zhang, Junliang*; Liu, Lu.* 

Copper-catalysed ortho-selective C-H bond functionalization of phenols and naphthols with α-aryl-α-diazoesters.  

Chem. Commun., 2020, 56, 9485-9488.

188. Wang, Huamin; Li, Xiuzheng; Tu, Youshao; Zhang, Junliang*. 

Catalytic Enantiodivergent Michael Addition by Subtle Adjustment of Achiral Amino Moiety of Dipeptide Phosphines.  iScience 2020, 23, 101138. 

187. Li, Sanliang; Chen, Qiaoyu; Li, Wenbo; Gu, Guanxin; Zhang, Junliang*. 

Visible Light Driven Copper(I) Catalyzed Oxyamination of Electron Deficient Alkenes.  

Chin. J. Chem. 2020, 38, 1116-1122.

186. Qi, Shutao; Gao, Shiquan; Xie, Xiaoxiao; Yang, Junfeng; Zhang, Junliang. 

Palladium-Catalyzed Fluoroarylation of gem-Difluoroenynes to Access Trisubstituted Trifluoromethyl Allenes.  

Org. Lett. 2020, 22, 5229-5234. 

185. Yao, Tengfei; Zhang, Fang; Zhang, Junliang*; Liu, Lu*. 

Palladium-Catalyzed Intermolecular Heck-Type Dearomative [4 + 2] Annulation of 2H-Isoindole Derivatives with Internal Alkynes. 

Org. Lett. 2020, 22, 5063-5067.

184. Qian, Yanyan; Dai, Qiang; Li, Zhiming; Liu, Yu; Zhang, Junliang. 

O-Phosphination of Aldehydes/Ketones toward Phosphoric Esters: Experimental and Mechanistic Studies. 

Org. Lett. 2020, 22, 4742-4748.

183. Tengfei Yao, Tong Xia, Wei Yan, Haofeng Xu, Fang Zhang, Yuanjing Xiao, Junliang Zhang*and Lu Liu* 

Copper-Catalyzed Chemodivergent Cyclization of N‑(orthoalkynyl)aryl-Pyrrole and Indoles. 

Org. Lett. 2020, 22, 4511-4516.

2019年 

182. Dai, Qiang; Li, Wenbo; Li, Zhiming; Zhang, Junliang*. 

P-Chiral Phosphines Enabled by Palladium/Xiao-Phos-Catalyzed Asymmetric P–C Cross-Coupling of Secondary Phosphine Oxides and Aryl Bromides. 

J. Am. Chem. Soc. 2019, 141, 20556-20564.

Xiao-Phos

181. Zhu, Chenghao; Chu, Haoke; Li, Gen; Ma, Shengming;* Zhang, Junliang.* 

Pd-Catalyzed Enantioselective Heck Reaction of Aryl Triflates and Alkynes. 

J. Am. Chem. Soc. 2019, 141, 19246-19251.

Xu-Phos

（首次将亚磺酰胺膦配体统称Sadphos家族配体）

180. Zhang, Zhan-Ming; Xu, Bing; Wu, Lizuo; Wu, Yuanqi; Qian, Yanyan; Zhou, Lujia; Liu, Yu; Zhang, Junliang *

Enantioselective Dicarbofunctionalization of Unactivated Alkenes by Palladium-Catalyzed Tandem Heck/Suzuki Coupling Reaction

Angew. Chem. Int. Ed. 2019, 58, 14653–14659.

Xu-Phos

179.  Pei-Chao Zhang, Jie Han and Junliang Zhang* 

Pd/PC-Phos-Catalyzed Enantioselective Intermolecular Denitrogenative Cyclization of Benzotriazoles with Allenes and N-Allenamides. 

Angew. Chem. Int. Ed. 2019, 58, 11444-11448 (VIP).

PC-Phos

178.  Zhan-Ming Zhang,‡ Bing Xu,‡ Lizuo Wu, Lujia Zhou, Danting Ji, Yu Liu, Zhiming Li* and Junliang Zhang* 

Palladium/XuPhos-Catalyzed Enantioselective Carboiodination of Olefin-Tethered Aryl Iodides

J. Am. Chem. Soc. 2019, 141, 8110-8115. (‡ These authors contributed equally to this work)

Xu-Phos

177.  Huamin Wang‡, Junyou Zhang‡, Youshao Tu and Junliang Zhang* 

Phosphine-Catalyzed Enantioselective Dearomative [3+2]-Cycloaddition of 3-Nitroindoles and 2-Nitrobenzofurans

Angew. Chem. Int. Ed. 2019, 58, 5422-5426.

(‡ These authors contributed equally to this work)

Xiao-Phos

176. Qiu, Haile;‡  Chen, Xiaofeng;‡  Zhang, Junliang.  

Design, synthesis and application of a new type of bifunctional Le-Phos in highly enantioselective γ-addition reactions of N-centered nucleophiles to allenoates

Chem. Sci., 2019,10, 10510-10515.

(‡ These authors contributed equally to this work)

Le-Phos

175. Yu, Zhunzhun; Li, Yongfeng; Zhang, Pei-Chao; Liu, Lu; Zhang, Junliang. 

Ligand and counteranion enabled regiodivergent C–H bond functionalization of naphthols with α-aryl-α-diazoesters

Chem. Sci., 2019,10, 6553-6559.

174.  Xiaoyu Di, Yidong Wang, Lizuo Wu, Zhan-Ming Zhang, Qiang Dai, Wenbo Li,* Junliang Zhang*. 

Enantioselective Gold(I)-Catalyzed Heterocyclization–Intermolecular Exo [4 + 3]-Cycloaddition Reactions for the Synthesis of Chiral Oxa-Bridged Benzocycloheptanes.

Org. Lett. 2019, 21, 3018−3022.

Ming-Phos

173. Han, Jie; Zhou, Wei; Zhang, Pei-Chao; Wang, Huamin; Zhang, Ronghua; Wu, Hai-Hong; Zhang, Junliang. 

Design and Synthesis of WJ-Phos, and Application in Cu-Catalyzed Enantioselective Boroacylation of 1,1-Disubstituted Allenes.

ACS Catal. 2019, 9, 6890-6895.

WJ-Phos

172. Zhaowei Chu, Zhiqiong Tang, Kenan Zhang, Lei Wang, Wenbo Li,* Hai-Hong Wu,* and Junliang Zhang*  

Gold(I)-Catalyzed Enantioselective Cyclopropanation of α-Aryl Diazoacetates with Enamides.

Organometallics, 2019, 38, 4036−4042.

171. Liu, Zhenli; Xu, Haofeng; Yao, Tengfei; Zhang, Junliang;* Liu, Lu.* 

Catalyst-Enabled Chemodivergent Construction of Alkynyl- and Vinyl-Substituted Diarylmethanes from p-Quinone Methides and Alkynes.

Org. Lett. 2019, 21, 7539-7543.

170. Cong, Tiantian; Wang, Huamin; Li, Xiuzheng; Wu, Hai-Hong; Zhang, Junliang* 

Chiral bifunctional bisphosphine enabled enantioselective tandem Michael addition of tryptamine-derived oxindoles to ynones.

Chem. Commun., 2019, 55, 9176-9179.

Peng-Phos

169. Chenghao Zhu, Junliang Zhang* 

Nickel-catalyzed alkyl–alkyl cross-coupling reactions of non-activated secondary alkyl bromides with aldehydes as alkyl carbanion equivalents.

Chem. Commun., 2019, 55, 2793-2796.

168.  Bing Liu, Wenbo Li, Hai-Hong Wu *, Junliang Zhang*. 

Enantiodivergent synthesis of 1,2-bis(diphenylphosphino)ethanes via asymmetric [3 + 2]-cycloaddition.

Org. Chem. Front., 2019, 6, 694–698.

167. Wu, Yi-Peng; Yan, Meng; Gao, Zhong-Zheng; Hou, Jun-Li; Wang, Hui; Zhang, Dan-Wei; Zhang, Junliang; Li, Zhan-Ting. 

Ruthenium(II)-cored supramolecular organic framework-mediated recyclable visible light photoreduction of azides to amines and cascade formation of lactams.

Chin. Chem. Lett., 2019, 30, 1383-1386.

166.  Lei Wang, Mingjie Chen, Junliang Zhang*. 

Transition metal-free base-promoted arylation of sulfenate anions with diaryliodonium salts.

Org. Chem. Front., 2019, 6, 32–35.

2018年 

165. Huamin Wang, Li Zhang, Youshao Tu, Ruiqi Xiang, Yin-Long Guo* and Junliang Zhang* 

Phosphine-Catalyzed Difunctionalization of β-Fluoroalkyl α,β-Enones: A Direct Approach to β-Amino α-Diazo Carbonyl Compounds.

Angew. Chem. Int. Ed. 2018, 57, 15787-15791.

Peng-Phos

164. Zhan-Ming Zhang+, Bing Xu+, Yanyan Qian, Lizuo Wu, Yuanqi Wu, Lujia Zhou, Yu Liu and Junliang Zhang* 

Palladium-Catalyzed Enantioselective Reductive Heck Reactions: Convenient Access to 3,3-Disubstituted 2,3-Dihydrobenzofuran.

Angew. Chem. Int. Ed. 2018, 57, 10373-10377. (‡ These authors contributed equally to this work)

Xu-Phos

163. Lei Wang, Mingjie Chen, Pei-Chao Zhang, Wenbo Li and Junliang Zhang* 

Palladium/PC-Phos-Catalyzed Enantioselective Arylation of General Sulfenate Anions: Scope and Synthetic Applications.

J. Am. Chem. Soc. 2018, 140, 3467-3473.

PC-Phos

162. Shan Xu, Zhan-Ming Zhang, Bing Xu, Bing Liu, Yuanyuan Liu,* and Junliang Zhang* 

Enantioselective Regiodivergent Synthesis of Chiral Pyrrolidines with Two Quaternary Stereocenters via Ligand-Controlled Copper(I)-Catalyzed Asymmetric 1,3-Dipolar Cycloadditions.

J. Am. Chem. Soc. 2018, 140, 2272-2283.

161. Tao-Yan Lin, Hai-Hong Wu, Jian-Jun Feng, Junliang Zhang*  

Chirality Transfer in Rhodium(I)-Catalyzed [3 + 2]-Cycloaddition of Vinyl Aziridines and Oxime Ethers: Atom-Economical Synthesis of Chiral Imidazolidines.

Org. Lett., 2018, 20 , 3587-3590.

160.  Bing Xu, Zhan-Ming Zhang, Lujia Zhou, Junliang Zhang* 

Direct Asymmetric Formal [3 + 2] Cycloaddition Reaction of Isocyanoesters with β-Trifluoromethyl β,β-Disubstituted Enones Leading to Optically Active Dihydropyrroles.

Org. Lett., 2018, 20, 2716-2719.

159. Bing Liu, Zhan-Ming Zhang, Bing Xu, Shan Xu, Hai-Hong Wu, Junliang Zhang*  

Cu(I)-Ming-phos Catalyzed Enantioselective [3+2] Cycloadditions of Glycine ketimines to β-Trifluoromethyl Enones.

Adv. Synth. Catal., 2018, 360, 2144-2150.

Ming-Phos

158. Mei Zhang, Xiaoyu Di, Mingrui Zhang, Junliang Zhang* 

Gold(I)-Catalyzed Diastereo- and Enantioselective Synthesis of Polysubstituted Pyrrolo[3,4-d][1,2]oxazines.

Chin. J. Chem, 2018, 36, 519-525. 

157. Shan Xu, Bing Liu, Zhan-Ming Zhang, Bing Xu, Junliang Zhang* 

Copper(I)-Catalyzed Asymmetric [3+2]-Cycloaddition of α-Substituted Iminoesters with α-Trifluoromethyl α,β-Unsaturated Esters.

Chin. J. Chem. 2018, 36, 421-429.

156. Chao-Ze Zhu, Jian-Jun Feng, Junliang Zhang* 

Divergent synthesis of functionalized pyrrolidines and γ-amino ketones via rhodium-catalyzed switchable reactions of vinyl aziridines and silyl enol ethers.

Chem. Commun., 2018, 54, 2401-2404.

155. Qin Zeng, Li Zhang, Yuanjing Xiao,* Junliang Zhang* 

Divergent access to N-hydroxypyrroles and isoxazoles via the gold(i)- or Brønsted acid-catalysed regioselective cyclization of N-(2-trifluoromethyl-3-alkynyl) oximes.

Org. Biomol. Chem, 2018, 16, 1375-1380.

154. Qiang Dai, Junliang Zhang* 

Direct Synthesis of Sulfinamides by the Copper-Catalyzed Electrophilic Amidation of Sulfenate Anions.

Adv. Synth. Catal., 2018, 360,  1123-1127.

153. Peng Chen, Junyou Zhang, Junliang Zhang*  

Highly Substituted Cyclohexenes via Phosphine-Catalyzed [4+2] Annulation of Electron-deficient Dienes and Vinyl Ketones.

Adv. Synth. Catal., 2018, 360, 682-685.

152. Pei-Chao Zhang, Yidong Wang, Zhan-Ming Zhang, Junliang Zhang* 

Gold(I)/Xiang-Phos-Catalyzed Asymmetric Intramolecular Cyclopropanation of Indenes and Trisubstituted Alkenes.

Org. Lett, 2018, 20, 7049-7052.

Xiang-Phos

151. Tao Zhou, Tong Xia, Zhenli Liu, Lu Liu,* Junliang Zhang* 

Asymmetric Phosphine-Catalyzed [4+1] Annulations of o-Quinone Methides with MBH Carbonates.

Adv. Synth. Catal.,2018, 360, 4475-4479.

150. Huayu Cheng, Xiaofan Zhou, Anjing Hu, Shiteng Ding, Yimo Wang, Yuanjing Xiao,* Junliang Zhang*  

Thioether-functionalized trifluoromethyl-alkynes, 1,3-dienes and allenes: divergent synthesis from reaction of 2-trifluoromethyl-1,3-conjugated enynes with sulfur nucleophiles.

RSC .Adv. 2018, 8, 34088-34093.

149. Yongfeng Li, Huamin Wang, Yuwei Su, Runchen Li, Cao Li, Lu Liu,* Junliang Zhang* 

Phosphine-Catalyzed [3 + 2] Cycloaddition Reaction of α-Diazoacetates and β-Trifluoromethyl Enones: A Facile Access to Multisubstituted 4-(Trifluoromethyl)pyrazolines.

Org. Lett. 2018, 20, 6444-6448.

148. Yidong Wang, Zhan-Ming Zhang, Feng Liu, Yinyan He, Junliang Zhang* 

Ming-Phos/Gold(I)-Catalyzed Diastereo- and Enantioselective Synthesis of Indolyl-Substituted Cyclopenta[c]furans.

Org. Lett. 2018, 20, 6403-6406.

Ming-Phos

147.  Ben Ma, Lu Liu,* Junliang Zhang* 

Gold-Catalyzed Site-Selective C−H Bond Functionalization with Diazo Compounds.

Asian J. Org. Chem., 2018, 7, 2015-2025.

146.  Bing Liu, Hai-Hong Wu, Junliang Zhang* 

Cu(II)-Catalyzed Enantioselective β-Boration of β-Trifluoromethyl, β,β-Disubstituted Enones and Esters: Construction of a CF3- and Boron-Containing Quaternary Stereocenter.

ACS .Catal., 2018, 8, 8318-8323.

2017年

145.  Yidong Wang,‡ Pei-Chao Zhang,‡ Xiaoyu Di, Qiang Dai, Zhan-Ming Zhang and Junliang Zhang* 

Gold-Catalyzed Asymmetric Intramolecular Cyclization of N-Allenamides for the Synthesis of Chiral Tetrahydrocarbolines

Angew. Chem. Int. Ed. 2017, 56, 15905-15909. (‡ These authors contributed equally to this work)

PC-Phos

144.  Ben Ma, Zhaowei Chu, Ben Huang, Zhenli Liu, Lu Liu* and Junliang Zhang* 

Highly para-Selective C−H Alkylation of Benzene Derivatives with 2,2,2-Trifluoroethyl α-Aryl-α-Diazoesters

Angew. Chem. Int. Ed., 2017, 56,  2749-2753.

143.  Chao-Ze Zhu, Jian-Jun Feng,* and Junliang Zhang* 

Rhodium(I)-Catalyzed Intermolecular Aza-[4+3] Cycloaddition of Vinyl Aziridines and Dienes: Atom-Economical Synthesis of Enantiomerically Enriched Functionalized Azepines. 

Angew. Chem. Int. Ed. 2017, 56, 1351-1355.

 

142.  Yangyan Li, WenboLi and Junliang Zhang* 

Gold-Catalyzed Enantioselective Annulations. 

Chem. Eur. J., 2017, 23, 467–512.

141. Bing Xu,^‡ Zhan-Ming Zhang,^‡ Shan Xu, Bing Liu, Yuanjing Xiao and Junliang Zhang*. 

Copper(I)/Ming-Phos-Catalyzed Asymmetric Intermolecular [3+2] Cycloaddition of Azomethine Ylides with α-Trifluoromethyl α,β-Unsaturated Esters. 

ACS Catal. 2017, 7, 210−214. (‡ These authors contributed equally to this work)

Ming-Phos

140.  Xiaofan Zhou,Chaoqian Huang, Yu Zeng, Jiarui Xiong, Yuanjing Xiao*, Junliang Zhang* 

Silver-catalysed tandem hydroamination and cyclization of 2-trifluoromethyl-1,3-enynes with primary amines: modular entry to 4-trifluoromethyl-3-pyrrolines. 

Chem. Commun. 2017,53, 1084-1087.

139. Jieru Yang, Xiaofan Zhou,Yu Zeng, Chaoqian Huang, Yuanjing Xiao*, Junliang Zhang* 

Divergent synthesis from reactions of 2-trifluoromethyl-1,3-conjugated enynes with N-acetylated 2-aminomalonates. 

Org. Biomol. Chem., 2017, 15, 2253–2258.

138. Huamin Wang, Wei Zhou, Mengna Tao, Anjing Hu, Junliang Zhang* 

Functionalized Tetrahydropyridines by Enantioselective Phosphine-Catalyzed Aza-[4 + 2] Cycloaddition of N-Sulfonyl-1-aza-1,3-dienes with Vinyl Ketones. 

Org. Lett. 2017, 19, 1710 – 1713.

Peng-Phos

137.  Shenhuan Li, Yuanyuan Liu, Ben Huang, Tao Zhou, Hongmei Tao, Yuanjing  Xiao, Lu Liu*, Junliang Zhang*  Phosphine-Catalyzed Asymmetric Intermolecular Cross-Vinylogous Rauhut–Currier Reactions of Vinyl Ketones with para-Quinone Methides. 

ACS. Catal. 2017,7, 2805 – 2809.

Peng-Phos

136. Taoyan Lin,Haihong Wu, Jianjun Feng, Junliang Zhang* 

Transfer of Chirality in the Rhodium-Catalyzed Chemoselective and Regioselective Allylic Alkylation of Hydroxyarenes with Vinyl Aziridines. 

Org. Lett. 2017, 19, 2897-2900.

135. Taoyan Lin, Haihong Wu, Jianjun Feng*, Junliang Zhang*  

Design and Enantioselective Synthesis of β-Vinyl Tryptamine Building Blocks for Construction of Privileged Chiral Indole Scaffolds. 

ACS. Catal. 2017, 7, 4047 – 4052.

134. Pei-Chao Zhang, Yidong Wang, Deyun Qian, Wenbo Li*, Junliang Zhang*  

Synthesis of Substituted Naphtho-Ferrocenes via a Gold(I)-Catalyzed Intramolecular 6-endo-Dig Cyclization. 

Chin. J. Chem. 2017,35, 849 – 852.

133. Xingxing Wu, Wei Zhou, Haihong Wu, Junliang Zhang*  

Enantioselective [3+2] cycloaddition of azomethine ylides and aldehydes via Ni/bis(oxazoline)-catalyzed ring opening of N-tosylaziridines through a chirality transfer approach. 

Chem. Commun. 2017, 53, 5661 – 5664.

132. Chaoze Zhu, Jianjun Feng*, Junliang Zhang*  

Rhodium-catalyzed intermolecular [3+3] cycloaddition of vinyl aziridines with C,N-cyclic azomethine imines: stereospecific synthesis of chiral fused tricyclic 1,2,4-hexahydrotriazines. 

Chem. Commun. 2017 , 53, 4688 – 4691.

131. Wei Zhou, HuaminWang, Mengna Tao, Chaoze Zhu, Taoyan Lin, Junliang Zhang*  

Phosphine-catalyzed enantioselective [3 + 2] cycloadditions of γ-substituted allenoates with β-perfluoroalkyl enones. 

Chem. Sci. 2017, 8, 4660 – 4665.

130. Bing Xu, Zhanmin Zhang, Bing Liu, Shan Xu, Liejin Zhou, Junliang Zhang* 

Copper(i)-catalyzed asymmetric exo-selective [3+2] cycloaddition of azomethine ylides with β-trifluoromethyl β,β-disubstituted enones. 

Chem. Commun. 2017, 53,  8152 – 8155.

129. Lu Liu, Junliang Zhang*  

过渡金属催化重氮化合物参与的芳烃碳（sp2）-氢键官能团化研究进展. 

Chin. J. Org. Chem. 2017, 37, 1117 – 1126.

128. Jianjun Feng*, Junliang Zhang* 

Rhodium-Catalyzed Stereoselective Intramolecular Tandem Reaction of Vinyloxiranes with Alkynes: Atom- and Step-Economical Synthesis of Multifunctional Mono-, Bi-, and Tricyclic Compounds. 

ACS. Catal. 2017, 7, 1533 – 1542.

127. Yuanyuan Liu, Wenbo Li, Junliang Zhang* 

Chiral ligands designed in China. 

Natl. Sci. Rev. 2017, 4, 326 – 358.

126. Bing Liu, Zhanmin Zhang, Bing Xu, Shan Xu, Haihong Wu, Yuanyuan Liu*, Junliang Zhang*  

Cu(I)-catalyzed Michael addition of ketiminoesters to β-trifluoromethyl β,β-disubstituted enones: rapid access to 1-pyrrolines bearing a quaternary all-carbon stereocenter. 

Org. Chem. Front. 2017, 4, 1772 – 1776.

125. Yu Zeng, Chaoqian Huang, PeiyunNi, Lu Liu, Yuanjing Xiao*, Junliang Zhang* 

Silver-Catalyzed Double Hydrocarbonation of 2-Trifluoromethyl-1,3-Conjugated Enynes with 1,3-Dicarbonyl Compounds: Synthesis of Ring-Trifluoromethylated Cyclopentene. 

Adv. Synth. Catal. 2017, 359, 3555 – 3559.

124. Ben Ma, Jiaojiao Wu, Lu Liu*, Junliang Zhang*  

Gold-catalyzed para-selective C–H bond alkylation of benzene derivatives with donor/acceptor-substituted diazo compounds. 

Chem. Commun. 2017 ,53, 10164 – 10167.

123. Chaoqian Huang, Yu Zeng, Huayu Cheng, Anjing Hu, Lu Liu, Yuanjing Xiao*, Junliang Zhang*  

A One-Pot Construction of Halogenated Trifluoromethylated Pyrroles through NXS (X = Br, I) Triggered Cascade. 

Org. Lett. 2017,19, 4968 – 4971.

122. MengnaTao, Wei Zhou, Junliang Zhang*  

Phosphine-Catalyzed Asymmetric Intermolecular Cross Rauhut–Currier Reaction of β-Perfluoroalkyl-Substituted Enones and Vinyl Ketones. 

Adv. Synth. Catal. 2017, 359, 3347 – 3353.

Peng-Phos

121. Huamin Wang, Weike Lu, Junliang Zhang* 

Ferrocene Derived Bifunctional Phosphine-Catalyzed Asymmetric Oxa-[4+2] Cycloaddition of α-Substituted Allenones with Enones. 

Chem. Eur. J. 2017, 23, 13587 – 13590.

120. Tao Zhou, Shenhuan Li, Ben Huang, Chao Li, Yang Zhao, Jieqiong Chen, Aoling Chen, Yuanjing Xiao, Lu Liu*, Junliang Zhang*  

Phosphine-catalyzed Friedel–Crafts reaction of naphthols with para-quinone methides: expedient access to triarylmethanes. 

Org. Biomol. Chem., 2017, 15, 4941–4945.

119. Ben Huang, Chao Li, Huamin Wang, Caihui Wang, Lu Liu*, Junliang Zhang*  

Phosphine-Catalyzed Diastereo- and Enantioselective Michael Addition of β-Carbonyl Esters to β-Trifluoromethyl and β-Ester Enones: Enhanced Reactivity by Inorganic Base. 

Org. Lett. 2017, 19, 5102−5105.

118. Taoyan Lin, Haihong Wu, Jianjun Feng*, Junliang Zhang*  

Divergent Access to Functionalized Pyrrolidines and Pyrrolines via Iridium-Catalyzed Domino-Ring-Opening Cyclization of Vinyl Aziridines with β-Ketocarbonyls. 

Org. Lett.  2017, 19,  6526–6529.

117.  Junyou Zhang, Haihong Wu*, Junliang Zhang*  

Enantioselective Phosphine-Catalyzed Allylic Alkylations of mix-Indene with MBH Carbonates. 

Org. Lett. 2017, 19, 6080−6083.

Xiao-Phos

116. Chaoze Zhu, Jianjun Feng,* junliang Zhang* 

铑催化烯基氮杂环丙烷与炔胺的立体专一性[3+2]环加成反应(封面文章) 

Chin. J. Org. Chem. 2017, 37, 1165-1172.

2016年

115. Haoxiang Hu, Yidong Wang, Deyun Qian,  Zhan-Ming Zhang, Lu Liu* and Junliang Zhang*

Enantioselective gold-catalyzed intermolecular [2 + 2]-cycloadditions of 3-styrylindoles with N-allenyl oxazolidinone. 

Org. Chem. Front., 2016,3, 759-763.

Xiang-Phos

114. W. Zhou, L. Gao, M. Tao, X. Su, Q. Zhao, J. Zhang* 

多功能手性膦催化活泼烯烃的不对称分子间Rauhut-Currier反应. 

Acta Chim. Sinica 2016, 74, 800-804.

                                                                        Xiao-Phos

113. W. Zhou, Z. Yue, J. Zhang*

A highly efficient one-pot trifluoromethylation/cyclization reaction of electron-deficient 1,3-conjugated enynes: modular access to trifluoromethylated furans and 2,3-dihydrofurans. 

Org. Chem. Front. 2016, 3, 1416.

112. Zhunzhun Yu,Yongfeng Li, Jiameng Shi, Ben Ma, Lu Liu and Junliang Zhang*

(C₆F₅)₃B -Catalyzed Highly Chemoselective and Ortho-selective C-H Bond Functionalization of Phenols Oriented by Hydrogen Bonds. 

Angew. Chem. Int. Ed., 2016, 55, 14807-14811.

111. Feng, Jian-Jun;* Zhang, Junliang* 

Synthesis of Unsaturated N-Heterocycles by Cycloadditions of Aziridines and Alkynes. 

ACS Catal. 2016, 6, 6651-6661. (Invited Review)

110. Peng Chen, Zhenting Yue, Junyou Zhang, Xi Lv, Lei Wang and Junliang Zhang*

Phosphine-Catalyzed Asymmetric Umpolung Addition of Trifluoromethyl Ketimines to Morita–Baylis–Hillman Carbonates. 

Angew. Chem. Int. Ed. 2016, 55, 13316-13320.

                                                                        Peng-Phos

109. Zhenting Yue, Wenbo Li, Lu Liu, Cuihong Wang* and Junliang Zhang*

Enantioselective Synthesis of 4H-Pyrans Through Organocatalytic Asymmetric Formal [3+3] Cycloadditions of 2-(1-Alkynyl)-2-alken-1-ones with β-Keto Esters. 

Adv. Synth. Catal. 2016, 358, 3015-3020 (VIP).

108. Lin, Tao-Yan; Zhu, Chao-Ze; Zhang, Pei-Chao; Wang, Yidong; Wu, Hai-Hong; Feng, Jian-Jun;* Zhang, Junliang*

Regiodivergent Intermolecular [3+2] Cycloadditions of Vinyl Aziridines and Allenes: Stereospecific Synthesis of Chiral Pyrrolidines. 

Angew. Chem. Int. Ed. 2016, 55, 10844-10848.

107. WenboLi, Xiuzhao Yu, Zhenting Yue, and Junliang Zhang*

Asymmetric Construction of 2,3-Dihydroisoxazoles via an Organocatalytic Formal [3 + 2] Cycloaddition of Enynes withN-Hydroxylamines. 

Org. Lett. 2016, 18, 3972–3975

106. Ben Ma, Ziang Wu, Ben Huang, Lu Liu* and Junliang Zhang*

Gold-catalysed facile access to indene scaffold via sequential C-H functionalization and 5-endo-dig carbocyclization. 

Chem. Commun, 2016, 52, 9351-9354.

105. Wei Zhou, Peng Chen, Mengna Tao, Xiao Su, Qingjie Zhao* and Junliang Zhang*

Enantioselective intermolecular cross Rauhut–Currier reactions of activated alkenes with acrolein. 

Chem. Commun, 2016, 52, 7612-7615.
                                                                         Xiao-Phos

104. ZhunZhun Yu, Lu Liu* and Junliang Zhang*

Triflic Acid-Catalyzed Enynes Cyclization: A New Strategy beyond Electrophilic π-Activation. 

Chem. Eur. J., 2016, 22, 8488-8492.

  

103. Zhan-Ming Zhang,‡ Bing Xu,‡ Shan Xu, Hai-Hong Wu and Junliang Zhang* 

Diastereo- and Enantioselective Copper(I)-Catalyzed Intermolecular [3+2] Cycloaddition of Azomethine Ylides with β-Trifluoromethyl β,β-Disubstituted Enones. 

Angew. Chem. Int. Ed. 2016, 55, 6324–6328. (‡ These authors contributed equally to this work)

                                                                             Ming-Phos

102. Jieru Yang, Xiaofan Zhou, Yu Zeng, Chaoqian Huang, Yuanjing Xiao* and Junliang Zhang*

Synthesis of 2-fluoro-2-pyrrolines via tandem reaction of α-trifluoromethyl-α,β-unsaturated carbonyl compounds with N-tosylated 2-aminomalonates. 

Chem. Commun., 2016, 52, 4922.

101. Jian-Jun Feng,‡ Tao-Yan Lin,‡ Chao-Ze Zhu, Huamin Wang, Hai-Hong Wu and Junliang Zhang*. 

The Divergent Synthesis of Nitrogen Heterocycles by Rhodium(I)-Catalyzed Intermolecular Cycloadditions of Vinyl Aziridines and Alkynes. 

J. Am. Chem. Soc. 2016, 138, 2178-2181. (‡ These authors contributed equally to this work)

100. Wenbo Li and Junliang Zhang*

Recent developments in the synthesis and utilization of chiral β-aminophosphine derivatives as catalysts or ligands. 

Chem. Soc. Rev. 2016, 45, 1657-1677.

第100篇文章

99. Peng Chen, Xiao Su, Wei Zhou, Yuanjing Xiao* and Junliang Zhang*

Novel Chiral Sulfinamide Phosphines : Valuable Precursors to Chiral β-Aminophosphines. 

Tetrahedron 2016, 72, 2700-2706.

                                                                              Xiao-Phos

98.Yanqing Zhang, Yuanjing Xiao* and Junliang Zhang*

Gold(I)-Catalyzed Stereospecific [4+3]-Cycloaddition Reaction of 1-(Alk-1-ynyl)cyclopropyl Ketones with Nitrones: A Modular Entry to Enantioenriched 5,7-Fused Bicyclic Furo[3,4-d][1,2]oxazepines. 

Synthesis 2016, 48, 512-519. (Invited feature article)

97. Lu Liu* and Junliang Zhang*

Gold-catalyzed transformations of α-diazocarbonyl compounds: selectivity and diversity. 

Chem. Soc. Rev. 2016, 45, 506-516.

96. Zhunzhun Yu, Haile Qiu, Lu Liu* and Junliang Zhang*

Gold-Catalyzed Construction of Two Adjacent Quaternary Stereocenters via Sequential C-H Functionalization and Aldol Annulation. 

Chem. Commun. 2016, 52, 2257-2260.

95 Wenbo Li, Liejing Zhou and Junliang Zhang*

Recent Progress in Dehydro(genative) Diels–Alder Reaction. 

Chem. Eur. J. 2016, 22, 1558-1571. (Invited Reviews)

94. Yuan Liu,‡ Zhunzhun Yu,‡ John Zenghui Zhang, Lu Liu,* Fei Xia* and Junliang Zhang*

Origins of Unique Gold-Catalyzed Chemo- and Site-Selective C-H Functionalization of Phenols with Diazo Compounds. 

Chem. Sci. 2016,7, 1988-1995. (‡These authors contributed equally to this work)

2015年

 

93 Jian-Jun Feng, Tao-Yan Lin, Hai-Hong Wu, and Junliang Zhang*

Modular Access to the Stereoisomers of Fused Bicyclic Azepines: Rhodium-Catalyzed Intramolecular Stereospecific Hetero-[5+2] Cycloaddition of Vinyl Aziridines and Alkenes. 

Angew. Chem. Int. Ed. 2015, 54, 15854-15858.

92. Mingjin Chen, Zhan-Ming Zhang, Zhunzhun Yu, Haile Qiu, Ben Ma, Hai-Hong Wu* and Junliang Zhang*

Polymer-Bound Chiral Gold-Based Complexes as Efficient Heterogeneous Catalysts for Enantioselectivity Tunable Cycloaddition. 

ACS Catal. 2015, 5, 7488−7492.

                                                                         Ming-Phos

91. Wenbo Li, Lihua Gao, Zhenting Yue and Junliang Zhang*

Phosphine-Catalyzed Regioselective and Stereoselective Hydrohalogenation Reaction of 2-(1-Alkynyl)-2-alken-1-ones: Synthesis of 2-Halo-1,3-dienes. 

Adv. Synth. Catal. 2015, 357, 2651-2655.

90. Wei Zhou, Xiao Su, Mengna Tao,Chaoze Zhu, Qingjie Zhao* and Junliang Zhang*

A Novel Chiral Sulfinamide Bisphosphine Catalysts: Design, Synthesis, and Application in Highly Enantioselective Inter-molecular Cross Rauhut–Currier Reactions. 

Angew. Chem. Int. Ed. 2015, 54, 14853-14857.

                                                                         Wei-Phos

 

 

89. Yidong Wang, Pei-Chao Zhang, Deyun Qian and Junliang Zhang*

Highly Regio-, Diastereo-, and Enantioselective Gold(I)-Catalyzed Intermolecular Annulations with N-Allenamides at the Proximal C=C Bond. 

Angew. Chem. Int. Ed. 2015, 54, 14849-14852 (Cover paper). 

（Highlighted by Synfacts 2015, 11, 1302）

 

 

88. Yidong Wang, Peichao Zhang, Yuan Liu, Fei Xia* and Junliang Zhang*

Enantioselective Gold-Catalyzed Intermolecular [2+2] versus [4+2]-Cycloadditions of 3-Styrylindoles with N-Allenamides: Oberservation of Interesting Substituent Effect. 

Chem. Sci. 2015, 6, 5564-5570.

（Highlighted by Synfacts 2016, 12, 55）

 

87. Yangyan Li, Xiao Su, Wei Zhou, Wenbo Li and Junliang Zhang*

Amino Acid Derived Phosphine-Catalyzed Enantioselective 1,4-Dipolar Spiroannulation of Cyclobutenones and Isatylidenemalononitrile. 

Chem. Eur. J. 2015, 21, 4224-4228. 

86. Liejin Zhou, Bing Xu and Junliang Zhang*

Metal-free Dehydrogenative Diels-Alder Reactions of 2-Methyl, 3-Aryl-methyl-indoles and Dienophiles：A Rapid Access to Tetrahydrocarbazoles, Carbazoles and Heteroacenes. 

Angew. Chem. Int. Ed.2015, 54, 9092-9096. 

 

85. Feng Liu, Yidong Wang, Weiming Ye, and Junliang Zhang*

Gold(I)-catalyzed asymmetric [3 + 2]-cycloadditions of γ-1-ethoxyethoxy-propiolates and aldehydes. 

Org. Chem. Front.2015, 2, 221-225. 

 

84. Xiao Su, Wei Zhou, Yangyan Li, and Junliang Zhang*

Design, Synthesis, and Application of a Chiral Sulfinamide Phosphine Catalyst for the Enantioselective Intramolecular Rauhut–Currier Reaction. 

Angew. Chem. Int. Ed. 2015, 54, 6874-6877. 

                                                                               Xiao-Phos

83. Jieru Yang, Ao Mao, Zhenting Yue, Wenxuan Zhu, Xuewei Luo, Chuwei Zhu, Yuanjing Xiao* and Junliang Zhang*

A simple base-mediated synthesis of diverse functionalized ring-fluorinated 4H-pyrans via double direct C–F substitutions. 

Chem. Commun.2015, 51, 8326-8329. (Highlighted by http://x-mol.com/news/508) 

 

82. Jian-Jun Feng, Tao-Yan Lin, Hai-Hong Wu and Junliang Zhang*

Transfer of Chirality in the Rhodium-Catalyzed Intramolecular Formal Hetero-[5 + 2] Cycloaddition of Vinyl Aziridines and Alkynes: Stereoselective Synthesis of Fused Azepine Derivatives. 

J. Am.Chem. Soc. 2015, 137, 3787-3790.

 

81. Deyun Qian and Junliang Zhang*

Gold-Catalyzed Cyclopropanation Reactions by Carbenoid Precursor Toolbox. 

Chem. Soc. Rev. 2015, 44, 677-698. (Cover paper)

2014年 

80. Li Zhang,Qin Zeng, Ao Mao, Ziang Wu, Tian Luo, Yuanjing Xiao* and Junliang Zhang*

NIS-mediated oxidative cyclization of N-(2-trifluoromethyl-3-alkynyl) hydroxylamines: a facile access to 4-trifluoromethyl-5-acylisoxazoles. 

Org. Biomol. Chem.2014,12, 8942-8946.

 

79. Deyun Qian, Haoxiang Hu, Feng Liu, Bin Tang, Weimin Ye, Yidong Wang and Junliang Zhang* 

Gold(I)-Catalyzed Highly Diastereo- and Enantioselective Alkyne Oxidation/Cyclopropanation of 1,6-Enynes. 

Angew. Chem. Int. Ed. 2014, 53, 13751-13755.

78. Lu Liu and Junliang Zhang*

Product Selectivity Control in the Domino Cyclization of 2-(2-Alkynylarylidene)-1,3-dicarbonyl Compounds Catalyzed by Metal Lewis Acids. 

Synthesis, 2014, 46, 2133-2142. (Invited feature article)

 77. Lai Wei, Lu Liu* and Junliang Zhang* 

Scandium-Catalyzed Tandem Selective Oxirane Ring-opening / Friedel-Crafts Alkylation: A Facile Access to [1,4]Oxazino[4,3-a]indoles and 3,4-Dihydro-1H-pyrrolo[2,1-c][1,4]oxazines. 

Org. Biomol. Chem.2014,12, 6869-6877. 

 

76.   Weimin Ye, Wenbo Li and Junliang Zhang* 

A metal-free dyotropic-like rearrangement of 2-oxa allylic alcohols in the presence of organoboronic acids. 

Chem. Commun., 2014,50, 9879-9882.

75. Liejin Zhou, Mingrui Zhang, Wenbo Li and Junliang Zhang* 

Furan-Based o-Quinodimethanes by Gold-Catalyzed Dehydrogenative Heterocyclization of 2-(1-Alkynyl)-2-alken-1-ones: A Modular Entry to 2,3-Furan-Fused Carbocycles. 

Angew. Chem. Int. Ed. 2014, 53, 6542-6545.

 

74. Zhunzhun Yu, Ben Ma, Mingjin Chen, Hai-Hong Wu, Lu Liu* and Junliang Zhang*

J. Am. Chem. Soc. 2014, 136, 6904-6907. 

(Featured in JACS Spotlights：J. Am. Chem. Soc. 2014, 136, 7187−7188 当月JACS Most Read Articles top 3，同时被SCIENCE CHINA Chemistry 2014, 57, 1057重点评述)

73. Deyun Qian and Junliang Zhang*

 Gold-Catalyzed Cascade Reactions for Synthesis of Carbo- and Heterocycles: Selectivity and Diversity. 

Chem. Rec. 2014, 14, 280-302. (Invited Account)

72. Zhan-Ming Zhang, Peng Chen, Wenbo Li, Yanfei Niu, Xiao-Li Zhao and Junliang Zhang* 

A New Type of Chiral Sulfinamide Monophosphine Ligands: Stereodivergent Synthesis and Application in Enantioselective Gold(I)-Catalyzed Cycloaddition Reactions. 

Angew. Chem. Int. Ed. 2014, 53, 4350-4354. 

                                        First report of Sadphos: Ming-Phos

 

71. Ziqi Tian, Yuanjing Xiao, Xiangai Yuan, Zuliang Chen, Junliang Zhang*, and Jing Ma*

 Control of Chemoselectivity by Coordinated Water and Relative Size of Ligands to Metal Cations of Lewis Acid Catalysts for Cycloaddition of an Oxirane Derivative to an Aldehyde: Theoretical and Experimental Study. 

Organometallics 2014, 33, 1715-1725.

 

70. Qin Zeng, Li Zhang, Jieru Yang, Bing Xu, Yuanjing Xiao*and Junliang Zhang*

 Pyrroles versus cyclic nitrones: catalyst-controlled divergent cyclization of N-(2-perfluoroalkyl-3-alkynyl) hydroxylamines. 

Chem. Commun. 2014, 50, 4203-4206.

 

69. Wenbo Li and Junliang Zhang*

 Phosphine-Mediated Regio- and Stereoselective Hydrocarboxylation of Enynes. 

Org. Lett. 2014, 16, 162-165.

 

68. Mingrui Zhang and Junliang Zhang*

 Base-Catalyzed Tandem Michael/Dehydro-Diels-Alder Reaction of α,α-Dicyanoolefins with Electron-Deficient 1,3-Conjugated Enynes: A Facile Entry to Angularly Fused Polycycles. 

Chem. Eur. J. 2014, 20, 399-404.

2013年

67. Hui Qian, Xiuzhao Yu, Junliang Zhang* and Jianwei Sun* 

Organocatalytic Enantioselective Synthesis of 2,3-Allenoates by Intermolecular Addition of Nitroalkanes to Activated Enynes. 

J. Am. Chem. Soc. 2013,135, 18020–18023.

  

66. Mei Zhangand Junliang Zhang*

 Gold(I)-Catalyzed Diastereoselective Domino Reactions of 2-(1-Alkynyl)alk-2-en-1-one Oxime Ethers with α,β-Unsaturated Imines Consisting of 1,2-Alkyl Migration. 

Isr. J. Chem. 2013, 53, 911–914.

 

65. Junqing Zhang, Yuanjing Xiao and Junliang Zhang*

Nickel-Catalyzed Annulation of Donor–Acceptor Oxiranes with Imines: Diastereoselective Access to Highly Substituted 2,4-trans-Oxazolidines. 

Adv. Synth. Catal. 2013, 355, 2793-2797.

 

64. Jieming Zhang, Hai-Hong Wu and Junliang Zhang*

Cesium Carbonate Mediated Borylation of Aryl Iodides with Diboron in Methanol. 

Eur. J. Org. Chem.2013, 6263-6266.

 

63. Zuliang Chen, Yuanjing Xiao and Junliang Zhang*

Reaction of Two Differently Functionalized Oxiranes with Nickel Perchlorate: A Modular Entry to Highly Substituted 1,3-Dioxolanes. 

Eur. J. Org. Chem.2013, 4748-4751. 

62. Renrong Liu and Junliang Zhang*

Organocatalytic Michael Addition of Indoles to Isatylidene-3-acetaldehydes: Application to the Formal Total Synthesis of (-)-Chimonanthine. 

Org. Lett. 2013, 15, 2266-2269..

 

61. Renrong Liu and Junliang Zhang*

 Organocatalytic Michael Addition of Malonates to Isatylidene-3-acetaldehydes: Application to the Total Synthesis of (-)-Debromoflustramine E. 

Chem. Eur. J. 2013, 19, 7319-7323. 

 

60. Deyun Qian and Junliang Zhang*

 Gold/Bronsted Acid Relay Catalysis for Enantioselective Construction of Spirocyclic Diketones. 

Chem. Eur. J. 2013, 19, 6984-6988. 

2012年

59. Xingxing Wu, Lei Liand Junliang Zhang*

 Direct aza-Darzens Aziridination of N-Tosyl Imines with 2-Bromomalonates for Efficient Synthesis of Highly Functionalized Donor-acceptor Aziridines. 

Adv. Synth. Catal. 2012, 354, 3485-3489.

58. Xingxing Wu and Junliang Zhang*

 Y(OTf)₃-Catalyzed Diastereoselective [3+2]Cycloaddition of N-Tosylaziridines and Imines; Efficient Synthesis of Multisubstituted Imidazolidines. 

Synthesis 2012, 44, 2147-2154.

57. Yanqing Zhang and Junliang Zhang*

 Highly Substituted Pyrroles by Gold(I)-Catalyzed Tandem Reaction of 1-(1-Alkynyl)cyclopropyl Oxime Ethers with Nucleophiles. 

Synlett,2012, 23, 1389-1393.

56. Renrong Liu and Junliang Zhang*

 Palladium(II)-Catalyzed Stereospecific Three-Component Domino Reactions of Diyne-enones, Nucleophiles, and Vinyl Ketones. 

Chem. Asian. J. 2012. 7, 294-297.

55. Wenbo Li, Yuying Li, Guanghua Zhou, Xiangshu Wu, and Junliang Zhang*

 Gold(I)-Catalyzed Regiodivergent Rearrangements: 1,2- and 1,2’-Alkyl Migration in Skipped Alkynyl Ketones. 

Chem. Eur. J. 2012, 18, 15113-15121.

54. Xiuzhao Yu, and Junliang Zhang*

A Base-Promoted Tandem Cycloaddition/Air Oxidation Reaction of Electron-Deficient Conjugated Enynes and Hydrazines: Synthesis of Highly Substituted Pyrazoles. 

Chem. Eur. J. 2012, 18, 12945-12949.

 

53. Yanqing Zhang, Junliang Zhang*

 Gold(I)-Catalyzed Regio- and Stereoselective 1,3-Dipolar Cycloaddition Reactions of 1-(1-Alkynyl)cyclopropyl Oximes with Nitrones: A Modular Entry to Highly Substituted Pyrrolo[3,4-d][1,2]oxazepines. 

Adv. Synth. Catal.2012‚ 354‚ 2556-2560.

 

52. Zuliang Chen, Ziqi Tian, Jieming Zhang, Jing Ma*, Junliang Zhang*

 C-O Versus C-C Bond Cleavage: Selectivity Control in Lewis Acid Catalyzed Chemodivergent Cycloadditions of Aryl Oxiranyldicarboxylates with Aldehydes, and Theoretical Rationalizations of Reaction Pathways. 

Chem. Eur. J. 2012,18, 8591-8595.  

 

51. Hongyin Gao, Junliang Zhang*

Cationic Rhodium(I)-Catalyzed Regioselective Tandem Heterocyclization/[3+2] Cycloaddition of 2-(1-Alkynyl)-2-alken-1-ones with Alkynes.  

Chem. Eur. J. 2012,18, 2777-2782. 

50. Deyun Qian, Junliang Zhang*

Catalytic oxidation/C–H functionalization of N-arylpropiolamides by means of gold carbenoids: concise route to 3-acyloxindoles. 

Chem. Commun. 2012,48, 7082-7084. 

 

49. Mei Zhang, Junliang Zhang*

Gold(I)-catalyzed cyclization of 2-(1-alkynyl)-alk-2-en-1-one oximes: a facile access to highly substituted N-alkoxypyrroles. 

Chem. Commun. 2012,48, 6399-6401. 

  

 

48. Xiuzhao Yu, Guanghua Zhou, Junliang Zhang*

DBU-catalyzed tandem additions of electron-deficient 1,3-conjugated enynes with 2-aminomalonates: a facile access to highly substituted 2-pyrrolines. 

Chem. Commun. 2012,48, 4002-4004. 

 

47. Yanqing Zhang, Junliang Zhang*

Kinetic resolution of 1-(1-alkynyl)cyclopropyl ketones by gold(I)-catalyzed asymmetric [4+3]cycloaddition with nitrones: scope, mechanism and applications. 

Chem. Commun. 2012,48, 4710-4712. 

 

46. Lai Wei, Junliang Zhang*

Efficient synthesis of isochromanones and isoquinolines viaYb(OTf)₃-catalyzed tandem oxirane/aziridine ring opening/Friedel–Crafts cyclization. 

Chem. Commun. 2012,48, 2636-2638. 

  

45. Jieming Zhang, Junliang Zhang*

Ni(ClO₄)₂-catalysed regio- and diastereoselective [3+2] cycloaddition of indoles and aryl oxiranyl-dicarboxylates/diketones: a facile access to furo[3,4-b]indoles. 

Chem. Commun. 2012,48, 1817-1819. 

 

2011年

44. Jian-Jun Feng‚Junliang Zhang* 

An Atom-Economic Synthesis of Bicyclo[3.1.0]hexanes by Rhodium N-Heterocyclic Carbene-Catalyzed Diastereoselective Tandem Hetero-[5 + 2] Cycloaddition/Claisen Rearrangement Reaction of Vinylic Oxiranes with Alkynes. 

J. Am. Chem. Soc. 2011,133‚7304–7307.

43. Deyun Qian, Junliang Zhang*

A gold(I)-catalyzed intramolecular oxidation–cyclopropanation sequence of 1,6-enynes: a convenient access to [n.1.0]bicycloalkanes. 

Chem. Commun. 2011,47, 11152-11154. 

 

 

42. Xingxing Wu, Lei Li, Junliang Zhang*

Nickel(II)-catalyzed diastereoselective [3+2] cycloaddition of N-tosyl-aziridines and aldehydes via selective carbon–carbon bond cleavage. 

Chem. Commun. 2011,47, 7824-7826. 

 

        

                 

41. Lei Li,Xingxing Wu, Junliang Zhang*

Lewis acid-catalyzed formal [3+2] cycloadditions of N-tosyl aziridines with electron-rich alkenes via selective carbon–carbon bond cleavage. 

Chem. Commun. 2011,47, 5049-5051. 

 

  

              

40. Lei Li‚ Junliang Zhang*

Lewis Acid-catalyzed [3 + 2]Cyclo-addition of Alkynes with N-Tosyl-aziridines via Carbon–Carbon Bond Cleavage: Synthesis of Highly Substituted 3-Pyrrolines. 

Org. Lett.2011‚13‚ 5940-5943.

39. Zuliang Chen‚ Lai Wei‚ Zhang Junliang*

Lewis Acid Catalyzed Carbon-Carbon Bond Cleavage of Aryl Oxiranyl Diketones: Synthesis of cis-2‚5-Disubstituted 1‚3-Dioxolanes. 

Org. Lett.2011‚13‚ 1170-1173.

38. Renrong Liu, Mei Zhang‚ Junliang Zhang*

Highly regioselective Lewis acid-catalyzed [3+2] cycloaddition of alkynes with donor–acceptor oxiranes by selective carbon–carbon bond cleavage of epoxides. 

Chem. Commun. 2011,47, 12870-12872.

  

37. Xiuzhao Yu‚ Junliang Zhang* 

Regioselective Addition of Organometallic Reagents to 2-(1-Alkynyl)-2-alken-1-ones for an Efficient Synthesis of Substituted 1‚2-Allenyl Ketones. 

Adv. Synth. Catal.2011‚ 353‚ 1265-1268.

36. Deyun Qian‚ Junliang Zhang* 
Au(I)/Au(III)-catalyzed Sonogashira-type reactions of functionalized terminal alkynes with arylboronic acids under mild conditions. 

Beilstein J. Org. Chem. 2011‚ 7‚ 808–812. (Invited contribution in honor of F. Dean Toste )

                 

35. Hongyin Gao‚ Xingxing Wu‚ Junliang Zhang*

Gold(I)-Catalyzed‚ Highly Diastereoselective‚ Tandem Heterocyclizations/[3+2] Cycloadditions: Synthesis of Highly Substituted Cyclopenta[c]furans. 

Chem. Eur. J. 2011‚ 17‚ 2838-28414.

34. Guanghua Zhou‚ Feng Liu‚ Junliang Zhang*

Enantioselective Gold-Catalyzed Functionalization of Unreactive sp³ C-H Bonds through a Redox–Neutral Domino Reaction. 

Chem. Eur. J. 2011‚ 17‚3101-3104.

33. Tao Wang‚ Junliang Zhang*

Chemoselective C-C Bond Cleavage of Epoxide Motifs: Gold(I)-Catalyzed Diastereoselective [4+3] Cycloadditions of 1-(1-Alkynyl)oxiranyl Ketones and Nitrones. 

Chem. Eur. J. 2011‚ 17‚ 86-90.

 

32. Tao Wang‚ Cui-Hong Wang ‚ Junliang Zhang* Unexpected C–C bond cleavage of epoxide motif: Rhodium(i)-catalyzed tandem heterocyclization/[4+1] cycloaddition of 1-(1-alkynyl)oxiranyl ketones. 

Chem. Commun. 2011‚ 47‚ 5578-5580.

 

31. Wanxiang Zhao‚Junliang Zhang* 

Rhodium-Catalyzed Tandem Heterocyclization and Carbonylative [(3+2)+1] Cyclization of Diyne-enones. 

Org. Lett. 2011‚13‚688–691.

 

30. Renrong Liu‚ Junliang Zhang*

Polyheterocycles by Palladium(II)-Catalyzed Oxidative Domino Reactions Involving Direct C-H Functionalization. 

Adv. Synth. Catal. 2011‚ 353‚ 36-40. 

2010年

29. Liu Lu‚ Wei Lai‚ Zhang Junliang* 

A Facile Route to Polysubstituted Naphthalenes and Benzofluorenols via Scandium Triflate- and Triflic Acid- Catalyzed Benzannulation of 2-(2-Alkynylarylidene)- 1,3-Dicarbonyl Compounds. 

Adv. Synth. Catal. 2010‚352‚1920-1924.

28. Xiuzhao Yu‚ Bo Du‚ Kai Wang and Junliang Zhang*

Highly Substituted 2,3-Dihydroisoxazoles by Et3N-Catalyzed Tandem Reaction of Electron-Deficient 1,3-Conjugated Enynes with Hydroxylamines. 

Org. Lett. 2010‚12‚1876–1879.

                      

27. Xiuzhao Yu‚Zhongyan Cao‚Junliang Zhang*

Organocatalytic hetero [4+2] cycloaddition reactions of 2-(1-alkynyl)-2-alkene-1-ones: metal-free access to highly substituted 4H-pyrans. 

Org. Biomol. Chem. 2010‚8‚5059-5061.  

   

 26. Wanxiang Zhao‚ Junliang Zhang*

Rhodium-catalyzed domino heterocyclization and [(3+2)+2] carbocyclization: construction of fused tricycloheptadienes. 

Chem. Commun. 2010‚ 46‚ 7816-7818. 

 

25. Hongyin Gao‚ Xingxing Wu‚ Junliang Zhang* 

Exo/endo selectivity-control in Lewis-acid catalyzed tandem heterocyclization/formal [4+3] cycloaddition: synthesis of polyheterocycles from 2-(1-alkynyl)-2-alken-1-ones and 1,3-diphenylisobenzofuran. 

Chem. Commun. 2010‚ 46‚ 8764-8766. 

  

24. Wenbo Li‚ Junliang Zhang*

Tetrasubstituted furans by PdII/CuI-cocatalyzed three-component domino reactions of 2-(1-alkynyl)-2-alken-1-ones, nucleophiles and diaryliodonium salts. 

Chem. Commun.2010‚ 46‚ 8839-8841. 

   

   

23. Lu Liu‚ Lai Wei‚ Yong Lu‚ Junliang Zhang* 

One-Pot Tandem Catalysis: A Concise Route to Fused Bicyclic Scaffolds from Acyclic β-Ketoesters and Alkynyl Aldehydes

Chem. Eur. J. 2010‚ 16‚ 11813-11817.

22. Guanghua Zhou‚Junliang Zhang* 

Product-selectivity control by the nature of the catalyst: Lewis acid-catalyzed selective formation of ring-fused tetrahydroquinolines and tetrahydroazepines via intramolecular redox reaction. 

Chem. Commun. 2010‚46‚6593–6595.

21. Feng Liu‚Deyun Qian‚Lei Li‚ Xiaoli Zhao‚Junliang Zhang* 

Diastereo- and Enantioselective Gold(I)-Catalyzed Intermolecular Tandem Cyclization/[3+3]Cycloadditions of 2-(1-Alkynyl)-2-alken-1-ones with Nitrones. 

Angew. Chem. Int. Ed. 2010‚49‚ 6669-6672.

20. Zuliang Chen‚ Junliang Zhang*

An Unexpected Phosphine-Catalyzed Regio- and Diastereoselective [4+1] Annulation Reaction of Modified Allylic Compounds with Activated Enones. 

Chem. Ansia J. 2010‚ 5, 1542-1545.

 

19. Wenbo Li‚ Yuying Li‚ Junliang Zhang*

Gold-Catalyzed Domino Reactions Consisting of Regio- and Stereoselective 1‚2-Alkyl Migration. 

Chem. Eur. J. 2010‚ 16‚ 6447-6450.

 

18. Yanqing Zhang‚ Feng Liu‚ Junliang Zhang*

Catalytic Regioselective Control in the Diastereoselective 1‚3-Dipolar Cycloaddition Reactions of 1-(1-Alkynyl)cyclopropyl Ketones with Nitrones. 

Chem. Eur. J. 2010‚16‚ 6146-6150.

 

17. Wanxiang Zhao‚ Junliang Zhang*

Rhodium-catalyzed tandem nucleophilic addition/bicyclization of diyne-enones with alcohols: a modular entry to 2‚3-fused bicyclic furans. 

Chem. Commun. 2010‚ 46‚ 4384-4386.

 

16. Tao Wang‚ Junliang Zhang*

Synthesis of 2-acylfurans from 3-(1-alkynyl)-2-alken-1-ones via the oxidation of gold-carbene intermediates by H₂O₂. 

Dalton Trans. 2010‚ 39‚ 4270-4273.

 

15. Xiuzhao Yu‚ Bo Du‚ Kai Wang‚ Junliang Zhang*

Highly Substituted 2‚3-Dihydroisoxazoles by Et3N-Catalyzed Tandem Reaction of Electron-Deficient 1‚3-Conjugated Enynes with Hydroxylamines. 

Org. Lett. 2010‚ 12‚ 1876-1879.

 

14. Hongyin Gao‚ Xiaoli Zhao‚ Yihua Yu‚ Junliang Zhang*

Highly Substituted Furo[3‚4-c]azepines by Gold(I)-Catalyzed Diastereoselective Tandem Double Heterocyclizations and 1‚2-Alkyl Migration. 

Chem. Eur. J. 2010‚ 16‚ 456-459.

13. Yuanjing Xiao‚ Junliang Zhang*

Tetrasubstituted allenes by Pd(0)-catalyzed three-component tandem Michael addition/cross-coupling reaction. 

Chem. Commun. 2010‚ 46‚ 752-754.

 

2009年

12. Lu Liu‚Junliang Zhang* 

Selectivity Control in Lewis Acid Catalyzed Regiodivergent Tandem Cationic Cyclization/Ring Expansion Terminated by Pinacol Rearrangement. 

Angew. Chem. Int. Ed. 2009‚48‚6093-6096.

 

11. Feng Liu‚ Yihua Yu‚ and Junliang Zhang* 

Highly Substituted Furo[3,4-d][1,2]oxazines: Gold-Catalyzed Regiospecific and Diastereoselective 1,3-Dipolar Cycloaddition of 2-(1-Alkynyl)-2-alken-1-ones with Nitrones. 

Angew. Chem. Int. Ed. 2009‚48‚5505–5508.

10. Wenbo Li‚ Yuanjing Xiao‚ Junliang Zhang* Alkynyl Group as Activating Group: Base-Catalyzed Diastereoselective Domino Reactions of Electron-Deficient Enynes. 

Adv. Synth. Catal. 2009‚ 351‚ 3083-3088.

 

9. Zuliang Chen‚ Junliang Zhang*Highly Functionalized 4-Alkylidenebicyclo[3.1.0]hex-2-enes by Tandem Michael Addition and Annulation of Electron-Deficient Enynes. 

Chem. Asian J. 2009‚ 4‚ 1527-1529.

 

8. Renrong Liu‚ Junliang Zhang*Tetrasubstituted Furans by Pd-II-Catalyzed Three-Component Domino Reactions of 2-(1-Alkynyl)-2-alken-1-ones with Nucleophiles and Vinyl Ketones or Acrolein. 

Chem. Eur. J. 2009‚ 15‚ 9303-9306. 

 

7. Yuanjing Xiao‚ Junliang Zhang*

Furans versus 4H-pyrans: catalyst-controlled regiodivergent tandem Michael addition–cyclization reaction of 2-(1-alkynyl)-2-alken-1-ones with 1‚3-dicarbonyl compounds. 

Chem. Commun. 2009‚ 3594-3596.

 

6. Yanqing Zhang‚ Zuliang Chen‚ Yuanjing Xiao‚ Junliang Zhang*

RhI-Catalyzed Regio- and Stereospecific Carbonylation of 1-(1-Alkynyl)cyclopropyl Ketones: A Modular Entry to Highly Substituted 5‚6-Dihydrocyclopenta[c]furan-4-ones. 

Chem. Eur. J. 2009‚ 15‚ 5208-5211.

 

5. Yuanjing Xiao‚ Junliang Zhang*

Palladium(II)-Catalyzed Domino Reaction of 2-(1-Alkynyl)-2-alken-1-ones with Nucleophiles: Scope‚ Mechanism and Synthetic Application in the Synthesis of 3‚4-Fused Bicyclic Tetrasubstituted Furans. 

Adv. Synth. Catal. 2009‚ 351‚ 617.

 

4. Hongyin Gao‚ Junliang Zhang*

A Dramatic Substituent Effect in Silver(I)-Catalyzed Regioselective Cyclization of ortho-Alkynylaryl Aldehyde Oxime Derivatives. 

Adv. Synth. Catal. 2009‚ 351‚ 85.

 2008年

                                                          

3. Liyan Fan‚ Wanxiang Zhao‚ Weihua Jiang‚ Junliang Zhang*

One-Pot Synthesis of Fused Tricyclic Heterocycles with Quaternary Carbon Stereocenter by Sequential Pauson–Khand Reaction and Formal [3+3] Cycloaddition. 

Chem. Eur. J. 2008‚14‚ 9139-9142.

 

2. Xiuzhao Yu‚ Hongjun Ren‚ Yuanjing Xiao‚ Junliang Zhang*. Efficient Assembly of Allenes, 1,3-Dienes, and 4H-Pyrans by Catalytic Regioselective Nucleophilic Addition to Electron-Deficient 1,3-Conjugated Enynes. 

Chem. Eur. J. 2008‚ 14‚ 8481-8485.

 

1. Yuanjing Xiao and Junliang Zhang* 

Tetrasubstituted Furans by a PdII-Catalyzed Three-Component Michael Addition/Cyclization/Cross-Coupling Reaction. 

Angew. Chem. Int. Ed. 2008‚47‚1903-1906.