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120. W. F. Zhou and S.-P. Guo*. Rational Design of Novel Promising Infrared Nonlinear Optical Materials: Structural Chemistry and Balanced Performances, Acc. Chem. Res. 2024, 57, 648‒660.

119. J.-L. Qi#, Y. Guo#, J. J. Wu*, Q.-F. Huang, J.-J. Xu, S.-F. Yan, W. L. Liu and S.-P. Guo*. Ultraviolet a-excitable cyan-emissive hybrid copper(I) halides nonlinear optical crystals with near-unity photoluminescence quantum yield and high-efficiency X-ray scintillation, Angew. Chem. Int. Ed. 2024, e202407074. DOI: 10.1002/anie.202407074

118. J. J. Wu*, Y. Guo, J.-L. Qi, W.-D. Yao, S.-X. Yu, W. L. Liu and S.-P. Guo*. Multi-stimuli responsive luminescence and domino phase transition of hybrid copper halides with nonlinear optical switching behaviors, Angew. Chem. Int. Ed. 2023, 62, e202301937. 

117. X. Huang#, S.-H. Yang#, X.-H. Li, W. L. Liu and S.-P. Guo*. Eu2P2S6: The first ternary rare-earth chalcophosphate exhibiting large second-harmonic generation response and high laser-induced damage threshold, Angew. Chem. Int. Ed. 2022, 61, e202206791.

116. X.-H. Li#, Z.-H. Shi#, M. Yang, W. L. Liu and S.-P. Guo*. Sn7Br10S2: The first ternary halogen-rich chalcohalide exhibiting a chiral structure and pronounced nonlinear optical properties, Angew. Chem. Int. Ed. 2022, 61, e202115871.

115. S.-P. Guo#*, X. Y. Chen#, Z.-D. Sun, Y. Chi, B.-W. Liu, X.-M. Jiang, S.-F. Li, H.-G. Xue, S. Q. Deng,* V. Duppel, J. Kӧhler and G.-C. Guo*. Large second harmonic generation (SHG) effect and high laser-induced damage threshold (LIDT) observed coexisting in gallium selenide, Angew. Chem. Int. Ed. 2019, 58, 8087–8091.

114. Y. Chi#, J. Xu#, H.-G. Xue, Y. P. Zhang, X. L. Chen, M.-H. Whangbo, S.-P. Guo* and S. Q. Deng*, Triple-layer Kagomé lattices of mixed-valence rare-earth ions exhibiting quantum spin liquid behaviors: synthesis and characterization of Eu9MgS2B20O41, J. Am. Chem. Soc. 2019, 141, 9533–9536.

113. S.-P. Guo*, Y. Chi and H.-G. Xue. SnI4∙(S8)2, a novel adduct-type infrared second-order nonlinear optical crystal, Angew. Chem. Int. Ed. 2018, 57, 11540–11543.

112. M. Yan#, C.-L. Hu#, R.-L. Tang*, W.-D. Yao, W. L. Liu and S.-P. Guo*. KBa3M2F14Cl (M = Zr, Hf): novel short-wavelength metal mixed halides with largest second-harmonic generation responses contributed by mixed functional moieties, Chem. Sci. 2024, 15, 8500–8505.

111. M. Yan, R.-L. Tang,* W.-D. Yao, W. L. Liu and S.-P. Guo*. Exploring new short-wavelength nonlinear optical fluoride material by unprecedented polar cis-[Zr6F34]10‒ clusters, Chem. Sci. 2024, 15, 2883–2888.

110. R.-L. Tang*, W. Xu, X. Lian, Y.-Q. Wei, Y.-L. Lv, W. L. Liu and S.-P. Guo*. Na2CeF6: a highly laser damage-tolerant double perovskite type Ce(IV) fluoride exhibiting strong second-harmonic generation effect, Small 2024, 20, 2308348.

109. N. Zhang, M. Yang, W.-D. Yao, W. Xu, W. F. Zhou, W. L. Liu and S.-P. Guo*. Cation and anion co-partial substitution induced centrosymmetric to noncentrosymmetric structural transformation to construct nonlinear-optical rare-earth oxythiogermanates, Inorg. Chem. Front. 2024, accept

108. J. J. Wu*, J.-L. Qi, Y. Guo, S.-F. Yan, W. L. Liu and S.-P. Guo*. Reversible tristate structural transition within hybrid copper (I) bromides toward tunable multiple emissions, Inorg. Chem. Front. 2024, 11, 156‒163.

107. L. Ma, W. Xu, L. Y. Y. Xu, Y.-L. Lv, W. L. Liu, S.-P. Guo* and R.-L. Tang*. CsSn2(HPO3)2I: the first inorganic metal phosphite iodide as a promising birefringent material exhibits a large birefringence with ideally layered framework, Scripta Mater. 2024, 242, 115913.

106. J. J. Wu, R.-L. Tang and S.-P. Guo*. Three types of promising functional building units for designing metal halide nonlinear optical crystals, Chin. J. Struct. Chem. 2024, 43, 100291.

105. R.-L. Tang*, L. Ma, Y.-L. Lv, W. L. Liu and S.-P. Guo*. From Pb6(HPO3)(H2PO3)Cl9 to Pb6(HPO3)2Br8(H2O)·H2O: halogen regulation to achieve the first inorganic metal phosphite halide nonlinear optical material with unprecedented Pb-centered polyhedral units, Inorg. Chem. 2024, 63, DOI: 10.1021/acs.inorgchem.4c02401

104. J. J. Wu*, Z.-P. Xu, Y. Guo, J.-L. Qi, S.-F. Yan, W. L. Liu and S.-P. Guo*. Highly selective protic-solvent-mediated organic-inorganic hybrid cuprous bromides achieving structural transformation, Inorg. Chem. 2024, 63, DOI: 10.1021/acs.inorgchem.4c00318

103. M. Yan, R.-L. Tang*, W.-D. Yao, W. L. Liu and S.-P. Guo*. From BaCaZr2F12 to K2BaZr2F12: heterovalent cation substitution generating the first phase-matchable deep-ultraviolet nonlinear optical halide, Inorg. Chem. 2024, 63, 10949–10953.

102. M.-Y. Li, J. Li, W.-D. Yao, N. Zhang, H.-P. Xu, W. F. Zhou and S.-P. Guo*. Design of MQ4-containing chalcogenides Ag2In2SiSxSe6-x (x = 4, 5) based on the bucket effect: local structural evolution and high-performance nonlinear optical responses induced by partial congener substitution of sulfur and selenium, Inorg. Chem. 2024, 63, 63, 7555–7559.

101. X.-X. Fan, M. Yang, W.-D. Yao, W. F. Zhou*, W. L. Liu and S.-P. Guo*. Novel pentanary oxythiogermanates Ba3MGe3O2S8 (M = Ca, Zn) featuring [Ge3O2S8]8− trimer and {[MGe3O2S8]6−}∞ chain: structural chemistry and physical properties, Inorg. Chem. 2024, 63, 7549–7554.

100. L. Ma, W. Xu, X.-F. Ao, Y.-L. Lv, W. L. Liu, S.-P. Guo* and R.-L. Tang*. Centric Sc(HPO3)(H2PO3)(H2O) and acentric Sc(H2PO3)3: Two UV scandium phosphites optical crystals, Inorg. Chem. 2024, 63, 7118–7122.

99. Y.-L. Lv, W. Xu, W.-D. Yao, M.-B. Xu, W. L. Liu, S.-P. Guo* and R.-L. Tang*. Hg16O12(NO3)6F2(H2O): A novel mercury-rich nitrate oxyfluoride with diverse triple coordinated mercury-based units exhibiting unparalleled [(Hg16O12F2(H2O))6+]∞ cationic framework and large birefringence, Inorg. Chem. 2024, 63, 6127–6131.

98. J. Li, J.-N. Li, L.-Y. Hu, J.-J. Ni, W.-D. Yao, W. F. Zhou, W. L. Liu and S.-P. Guo*. Polysubstitution induced centrosymmetric to noncentrosymmetric structural transformation and nonlinear optical behavior: the case of Na0.45Ag0.55Ga3Se5, Inorg. Chem. 2024, 63, 6116–6121.

97. M. Yan, R.-L. Tang*, W. Xu, W. L. Liu and S.-P. Guo*. Centrosymmetric CaBaMF8 and noncentrosymmetric Li2CaMF8 (M = Zr, Hf): dimension variation and nonlinear optical activity resulting from isovalent cation substitution-oriented design, Inorg. Chem. 2024, 63, 5260–5268.

96. C.-Y. Zhao, W.-D. Yao, M.-Y. Li, W. F. Zhou, W. L. Liu and S.-P. Guo*. KREP2S6 (RE = Sm, Gd, Tb, Dy): a series of polar rare-earth thiophosphates with high laser-induced damage thresholds and moderate nonlinear-optical responses synergistically contributed by isolated P2S6 units and {[RE2S15]24–}∞ layers, Inorg. Chem. 2024, 63, 4017–4021.

95. Y.-Q. Wei, W. Xu, L. Huai, Y.-L. Lv, W. L. Liu, S.-P. Guo* and R.-L. Tang*. From ZnF2 to ZnF2(H2O)4: Partial substitution achieves structural transformation and nonlinear optical activity with keeping short ultraviolet cut-off edge, Inorg. Chem. 2024, 63, 1714–1719.

94. S.-F. Yan, Y. Guo, W. L. Liu, S.-P. Guo* and J. J. Wu*. Tellurium (IV) halide achieving effective nonlinear optical activity: the role of chiral ligands and lattice distortion, Inorg. Chem. 2024, 63, 73–77.

93. W. Xu, L. Ma, Y.-L. Lv, S.-Y. Ma, W. L. Liu, S.-P. Guo*, R.-L. Tang*. C(NH2)3Cd(C2O4)Cl(H2O)·H2O and BaCd(C2O4)1.5Cl(H2O)2: two oxalate chlorides obtained by chemical scissors strategy exhibiting low-dimensional structural networks and balanced overall optical properties, Inorg. Chem. 2024, 63, 67–72.

92. W. F. Zhou, J. J. Wu*, W. L. Liu and S.-P. Guo*. Ag-based chalcogenides and derivatives as promising infrared nonlinear optical materials, Coord. Chem. Rev. 2023, 477, 214950.

91. Z.-X. Chen, W. L. Liu and S.-P. Guo*. A review of structures and physical properties of rare earth chalcophosphates, Coord. Chem. Rev. 2023, 474, 214870.

90. J. Li#, X.-H. Li#, W.-D. Yao, W. L. Liu and S.-P. Guo*. Three-in-one strategy constructing the first high-performance nonlinear optical sulfide crystallizing with the P43 space group, Small 2023, 19, 2303090. 

89. Z.-X. Chen, C.-Y. Zhao, X.-H. Li, W.-D. Yao, W. L. Liu and S.-P. Guo*. KREP2Se6 (RE = Sm, Gd, Tb): the first rare earth selenophosphates with remarkable nonlinear optical activities realized by synergistic effect of RE- and P-based motifs, Small 2023, 19, 2206910.

88. J. Li, W.-D. Yao, J.-N. Li, W. L. Liu and S.-P. Guo*. Partial substitution induced structural transformation and enhanced nonlinear optical properties of Na2GaxIn6-xSe10 (x = 3, 3.76), Mater. Today Phys. 2023, 32, 101007.

87. M. Yang, W.-D. Yao, W. L. Liu* and S.-P. Guo*. The first quaternary rare-earth oxythiogermanate with second-harmonic generation and ferromagnetic behaviors, Chem. Commun. 2023, 59, 3894–3897.

86. J.-L. Qi, J. J. Wu*, Y. Guo, Z.-P. Xu, W. L. Liu and S.-P. Guo*. The first quasi-linear CuX2 (X = Cl, Br) motif-built hybrid copper halides with encouraging nonlinear optical activities, Inorg. Chem. Front. 2023, 10, 3319–3325.

85. C.-Y. Zhao, Z.-X. Chen, W.-D. Yao, W. F. Zhou*, W. L. Liu and S.-P. Guo*. NaREP2Se6 (RE = Y, Sm, Gd–Dy): quaternary rare-earth selenophosphates with unique 3D {[REP2Se6]–}∞ framework built by RESe8 and P2Se6 motifs and multiple properties, Inorg. Chem. 2023, 62, 19843-19847.

84. J.-L. Qi, J. J. Wu*, S.-F. Yan, J.-J. Xu, W. L. Liu and S.-P. Guo*. Cluster-centered excited states induced bright low-energy emissive hybrid copper iodide constructing stable white LEDs, Inorg. Chem. 2023, 62, 18825–18829.

83. N. Zhang, X. Huang, W.-D. Yao, Y. Chen, Z.-R. Pan, B. X. Li, W. L. Liu* and S.-P. Guo*. Eu2MGe2OS6 (M = Mn, Fe, Co): three melilite-type rare-earth oxythiogermanates exhibiting balanced nonlinear-optical behaviors, Inorg. Chem. 2023, 62, 16299–16303.

82. J. Li, W. F. Zhou*, W.-D. Yao, W. L. Liu and S.-P. Guo*. Three-in-one tetrahedral functional units constructing diamondlike Ag2In2SiS3.06Se2.94 with high-performance nonlinear optical activity, Inorg. Chem. 2023, 62, 13179–13183.

81. Y. Guo, S.-F. Yan, W.-D. Yao, H.-Y. Chen, W. L. Liu, J. J. Wu* and S.-P. Guo*. Dual monomeric inorganic units constructed bright emissive zero-dimensional antimony chlorides with solvent-induced reversible structural transition, Inorg. Chem. 2023, 62, 13692–13697.

80. W.-D. Yao#, X. Huang#, M. Yan, W. L. Liu* and S.-P. Guo*. KHg4Ga3S9: A Hg-based sulfide with NLO activity in the A–MⅡ–MⅢ–Q (A = alkali metal; MⅡ = d10 metal; MⅢ = Ga, In; Q = S, Se) system, Inorg. Chem. 2023, 62, 12639-12643.

79. W. Xu, R.-L. Tang*, Y.-L. Wei, J.-M. Wang, Y.-Q. Zhang, W. L. Liu and S.-P. Guo*. SrCl2·6H2O: an alkaline-earth metal chloride hexahydrate as deep ultraviolet nonlinear optical crystal with the {[Sr(H2O)6]2+}∞ cationic framework, Inorg. Chem. 2023, 62, 10523–10527.

78. X. Huang, Y.-C. Wang, Q.-H. Ren, Y. Xue, Y.-X. Chen, W. L. Liu, J. J. Wu* and and S.-P. Guo*. {[In2S7]8−}∞ chain and isolated HgS4 planar unit constructed one-dimensional pentanary sulfide K2Ba7HgIn4S16 exhibiting nonlinear optical activity, Inorg. Chem. 2023, 62, 7160–7164.

77. N. Zhang, S.-S. Han, Y. Xie, D.-L. Chen, W.-D. Yao, X. Huang, W. L. Liu* and S.-P. Guo*. Mixed rare-earth chalcogenide borates Eu9-xRExMgS2B20O41 (RE = Sm, Gd), featuring 3D {[B20O41]22–}∞ framework connected by [B6O9(O0.5)6]6– and [B7O13(O0.5)3]8– clusters, Inorg. Chem. 2023, 62, 7681–7688.

76. G.-X. Liu, R.-L. Tang*, L. Ma, Y.-L. Lv, W. L. Liu and S.-P. Guo*. From Pb2(HPO3)2 to Pb2Cl2(HPO3)(H2O) and Pb3Br2(HPO3)2: enlarged birefringence induced by halogen regulation, Inorg. Chem. 2023, 62, 1069–1074.

75. R.-L. Tang*, G.-X. Liu, W.-D. Yao, L.-N. Zhang, W. L. Liu and S.-P. Guo*. BaSc2(HPO3)4(H2O)2: a new nonlinear optical phosphite exhibiting 3D {[Sc2(HPO3)4]2–}∞ anionic framework and phase matchable SHG effect, Inorg. Chem. Front. 2022, 9, 5377–5385.

74. W. F. Zhou, W. L. Liu and S.-P. Guo*. AAg2PS4 (A = K, Na/K): the first-type of noncentrosymmetric alkali metal Ag-based thiophosphates exhibiting excellent second-order nonlinear optical performances, Inorg. Chem. Front. 2022, 9, 4990–4998.

73. W. F. Zhou, M. Geng, M. Yan, N.-T. Suen, W. L. Liu and S.-P. Guo*. Alkali metal partial substitution induced improved second-harmonic generation and enhanced laser-induced damage threshold for Ag-based sulfides, Inorg. Chem. Front. 2022, 9, 3779–3787.

72. S.-S. Han, S.-X. Yu, W. L. Liu and S.-P. Guo*. KNa0.78Eu0.27In3.80B12S12: a hexanary thioborate featuring B12S12 cluster and diverse InSx (x = 4, 5, 6) units, Inorg. Chem. Front. 2022, 9, 2462–2469.

71. W. F. Zhou, W. L. Liu and S.-P. Guo*. (Na0.74Ag1.26)BaSnS4: A new AgGaS2-type nonlinear optical sulfide with a wide band gap and high laser induced damage threshold, Chem. Eur. J. 2022, 28, e202202063.

70. R.-L. Tang*, X. Lian, X.-H. Li, L. Huai, W. L. Liu and S.-P. Guo*. From CsKTaF7 to CsNaTaF7, alkali metal cations regulation to generate SHG activity, Chem. Eur. J. 2022, 28, e202201588.

69. J.-N. Li, X.-H. Li, Y.-X. Xu, W. L. Liu and S.-P. Guo*. First investigation of nonlinear optical oxychalcogenide with three-dimensional anionic framework and special windwill-like functional motifs, Chin. J. Chem. 2022, 40, 2407–2414.

68. M. Yan, R.-L. Tang*, W. L. Liu and S.-P. Guo*. From Ba3Nb2O2F12(H2O)2 to Ba0.5NbO2F2(H2O): achieving balanced nonlinear optical performance by O/F ratio regulation, Inorg. Chem. 2022, 61, 20709–20715.

67. N. Zhang#, Qian-Ting Xu#, Z.-H. Shi, M. Yang and S.-P. Guo*. Characterizations and nonlinear-optical properties of pentanary transition-metal oxysulfide Sr2CoGe2OS6, Inorg. Chem. 2022, 61, 17002–17006.

66. M. Yang, W. L. Liu* and S.-P. Guo*. Sb5O7I: The first ternary Sb-based oxyhalide being second-harmonic generation-active, Inorg. Chem. 2022, 61, 14517–14522.

65. M. Yan, R.-L. Tang*, G.-X. Liu, L. Huai, W. L. Liu and S.-P. Guo*. Pb5(GeO4)(Ge2O7) and Pb3.32Ca1.68(GeO4)(Ge2O7): two nonlinear optical germanates induced by diverse Pb‒O polyhedra, Inorg. Chem. 2022, 61, 13637–13643.

64. X. Huang, S.-H. Yang, W. L. Liu and S.-P. Guo*. Ba3HgGa2S7: a zero-dimensional quaternary sulfide featuring unique [Hg2Ga4S14]12– unit and exhibiting photocurrent response, Inorg. Chem. 2022, 61, 12954–12958.

63. Y. Guo, J. J. Wu*, W. L. Liu and S.-P. Guo*. Organic cation modulation triggered second harmonic response in manganese halides with bright fluorescence, Inorg. Chem. 2022, 61, 11514–11518.

62. R.-L. Tang, Y.-L. Wei, Y. Chi*, Z.-H. Shi, W. L. Liu, and S.-P. Guo*. Cations regulation to investigate chalcogenide borates RE6Nb2MgSB8O26 (RE = La–Nd) family, Inorg. Chem. 2022, 8653–8661.

61. Q.-T. Xu, S.-S. Han, J.-N. Li and S.-P. Guo*. NaGa3Se5: an infrared nonlinear optical material with balanced performance contributed by complex {[Ga3Se5]–}∞ anionic network, Inorg. Chem. 2022, 61, 5479–5483.
60. R.-L. Tang*, M. Yan, W.-D. Yao, W. L. Liu and S.-P. Guo*. HgTeO2F(OH): a nonlinear optical oxyfluoride constructed by active [TeO2F(OH)]2– pyramids and V-shaped [HgO2]2– groups, Inorg. Chem. 2022, 61, 2333–2339.

59. Q.-T. Xu, Y. Chi*, X.-H. Li, W. L. Liu and S.-P. Guo*. Structural chemistry and excellent nonlinear optical properties of a series of ternary selenides GaxIn2-xSe3, Inorg. Chem. 2022, 61, 431–438.

58. M. Yang, Z.-H. Shi, W.-D. Yao and S.-P. Guo*. Second-order nonlinear optical-active oxyhalides CuSb2O3X (X = Cl, Br): experimental and theoretical analysis, Inorg. Chem. 2022, 61, 42–46.

57. M. Yan, W. F. Zhou, W. L. Liu, R.-L. Tang* and S.-P. Guo*. Pb3SBrI3: The first Pb-based chalcohalide contains multiple halogens featuring unique two-dimensional structure composed by diverse Pb-centered polyhedra, Dalton Trans. 2022, 51, 12921–12927.

56. J. J. Wu*, Y. Guo, W.-D. Yao, W. L. Liu and S.-P. Guo*. Symmetry breaking of A3M2X9-type perovskites-derivative induced by polar quaternary ammonium cation: achieving efficient nonlinear optical properties, Dalton Trans. 2022, 51, 4878–4883.

55. S.-S. Han, Q.-T. Xu, W. L. Liu and S.-P. Guo*. KEu2In3B12S13: a novel type of thioborate featuring B12S12 cluster and unique In6S6 12-membered ring, Dalton Trans. 2022, 51, 4619–4622.

54. S.-H. Yang, H.-G. Xue and S.-P. Guo*. Borates as promising electrode materials for rechargeable batteries, Coord. Chem. Rev. 2021, 427, 213551.

53. J.-N. Li, X.-H. Li, W.-D. Yao, W. L. Liu and S.-P. Guo*. New nonlinear optical-active AAgGa6S10 (A = K, Rb, Cs) featuring {[AgGa6S10]–}∞ framework and high laser damage threshold, Chem. Commun. 2021, 57, 5175–5178.

52. J.-N. Li, W.-D. Yao, X.-H. Li, W. L. Liu, H.-G. Xue and S.-P. Guo*. A novel promising infrared nonlinear optical selenide KAg3Ga8Se14 designed from benchmark AgGaQ2 (Q = S, Se), Chem. Commun. 2021, 57, 1109–1112.

51. Z.-T. Lu, S.-H. Yang, W. L. Liu* and S.-P. Guo*. A series of oxysulfides RE2M2S3O4 (RE = Y, Tm; M = Zr, Hf) featuring unique MS3O4 motif and {[M2S3O4]8–}∞ wrinkle layer, Chem. Commun. 2021, 57, 3500–3503.

50. Y.-N. Li, Z.-X. Chen, W.-D. Yao, R.-L. Tang* and S.-P. Guo*. Heterovalent cations substitution to design asymmetric chalcogenides with promising nonlinear optical performances, J. Mater. Chem. C 2021, 9, 8659–8665.

49. X. Huang, S.-H. Yang, W. L. Liu and S.-P. Guo*. Noncentrosymmetric Ba6In2Q10 (Q = S, Se): structural chemistry and nonlinear optical activity, Inorg. Chem. 2021, 60, 16932–16936.

48. M. Yan, W.-D. Yao, W. L. Liu, R.-L. Tang* and S.-P. Guo*. Helical {[HgS]}∞ chain-induced balanced nonlinear-optical performance for trigonal mercury sulfide, Inorg. Chem. 2021, 60, 16917–16921.

47. Z.-H. Shi, M. Yang, W. L. Liu and S.-P. Guo*. SnPQ3 (Q = S, Se, S/Se): a series of lone-pair cation chalcogenophosphates exhibiting balanced NLO activity originated from SnQ8 units, Inorg. Chem. 2021, 60, 14390–14398.

46. W. F. Zhou, Q. Zhang, W.-D. Yao, H. G. Xue and S.-P. Guo*. Stepwise Li substitution induced structure evolution and improved nonlinear optical performance for diamond-like sulfides, Inorg. Chem. 2021, 60, 12536–12544.

45. X. Lian, Z.-T. Lu, W.-D. Yao, S.-H. Yang, W. L. Liu, R.-L. Tang* and S.-P. Guo*. Structural transformation and second-harmonic-generation activity in rare-earth and d0 transition-metal oxysulfides RE3NbS3O4 (RE = Ce, Sm, Gd, Dy), Inorg. Chem. 2021, 60, 10885–10889.

44. X.-H. Li, W.-D. Yao, Y.-L. Wei and S.-P. Guo*. Three-in-one strategy constructing a series of hybrid tetrahedral motif-based selenides with balanced second-order nonlinear optical performance, Inorg. Chem. 2021, 60, 6641–6648.

43. W. F. Zhou, W.-D. Yao, H. G. Xue and S.-P. Guo*. Introduction of Li into Ag-based noncentrosymmetric sulfides for high-performance infrared nonlinear optical materials, Inorg. Chem. 2021, 60, 5198–5205.

42. S.-S. Han, W.-D. Yao, S.-X. Yu, Y. L. Sun, A. H. Gong and S.-P. Guo*. A series of pentanary salt-inclusion chalcogenoborates containing a B12Q12 (Q = S, Se) cluster exhibiting a Kleinman-forbidden frequency-doubling effect, Inorg. Chem. 2021, 60, 3375–3383.

41. X. Lian, W.-D. Yao, W. L. Liu, R.-L. Tang* and S.-P. Guo*. KNa2ZrF7: A mixed metal fluoride exhibits phase-matchable SHG effect and high laser-induced damage threshold, Inorg. Chem. 2021, 60, 19–23.

40. M. Yan, H. G. Xue and S.-P. Guo*. Recent achievements on lone-pair cation-based infrared second-order nonlinear optical materials, Cryst. Growth & Des. 2021, 21, 698–720.

39. R.-L. Tang*, X. Lian, W.-D. Yao, W.-L. Liu and S.-P. Guo*. K3Na(TaF7)(SiF6): a mixed-anion pentanary fluoride with zero dimensional anions exhibiting large band gap, Dalton Trans. 2021, 50, 16562–16567.

38. Y. Chi,# Z.-D. Sun,# Q.-T. Xu, H. G. Xue and S.-P. Guo*. Hexagonal In2Se3: a defect wurtzite-type infrared nonlinear optical material with moderate birefringence contributed by unique InSe5 unit, ACS Appl. Mater. Interfaces 2020, 12, 17699–17705.

37. M. Yan, Z.-D. Sun, W.-D. Yao, W. F. Zhou, W. L. Liu* and S.-P. Guo*. A Highly distorted HgS4 tetrahedra induced moderate second-harmonic generation response of EuHgGeS4, Inorg. Chem. Front. 2020, 7, 2451–2458.

36. X.-H. Li, Y.-T. Chen, H. G. Xue and S.-P. Guo*. KInSi1.32Sn0.68Se6: an infrared nonlinear optical material containing three types of tetrahedral units, Inorg. Chem. 2020, 59, 5823–5827.

35. Z.-T. Lu, W.-J. Fan, Z.-Q. Wang, N. Gu, Z.-H. Yue, H.-G. Xue and S.-P. Guo*. Second-order nonlinear optical-active selenide borate YSeBO2: featuring [YSeBO2]n planar belt, Inorg. Chem. 2020, 59, 7905–7909.

34. Y.-N. Li, H. G. Xue and S.-P. Guo*. (Na0.60Ba0.70)Ga2Se4: an infrared nonlinear optical crystal designed using AgGaSe2 as the template, Inorg. Chem. 2020, 59, 3546–3550.

33. Z.-H. Shi, Y. Chi, M. Yang, W. L. Liu and S.-P. Guo*. A series of chalcogenide borates RE6Ta2MgQB8O26 (RE = Sm, Eu, Gd; Q = S, Se) featuring a B4O10 cluster, Inorg. Chem. 2020, 59, 3532–3536.

32. Y. Chi, H.-G. Xue and S.-P. Guo*. Designing sulfide borate as a novel type of second-order nonlinear-optical crystal, Inorg. Chem. 2020, 59, 1547–1555.

31. Y.-N. Li, Y. Chi, Z.-D. Sun, H. G. Xue, N.-T. Suen and S.-P. Guo*. Partial substitution induced centrosymmetric to noncentrosymmetric structure transformation and promising second-order nonlinear optical properties of K0.38Ba0.81Ga2Se4, Chem. Commun. 2019, 55, 13701–13704.

30. Q.-T. Xu, H.-G. Xue and S.-P. Guo*. Status and prospects of SexSy cathodes for lithium/sodium storage, Inorg. Chem. Front. 2019, 6, 1326–1340.

29. Q.-T. Xu,# Z.-D. Sun,# Y. Chi and S.-P. Guo*. Monoclinic gallium selenide: an AgGaS2-type structure variant with balanced infrared nonlinear optical performance, J. Mater. Chem. C 2019, 7, 11752–11756.

28. X.-H. Li, N.-T. Suen, Y. Chi, Y. L. Sun, A. H. Gong, H. G. Xue and S.-P. Guo.* Partial congener substitution induced centrosymmetric to noncentrosymmetric transformation witnessed by K3Ga3(Ge7-xMx)Se20 (M = Si, Sn) and their nonlinear optical properties, Inorg. Chem. 2019, 58, 13250–13257.

27. Z.-H. Shi, Y. Chi, Z.-D. Sun, W. L. Liu* and S.-P. Guo*, Sn2Ga2S5: a type of infrared nonlinear optical material, Inorg. Chem. 2019, 58, 12002–12006.

26. Z.-T. Lu, Z.-D. Sun, Y. Chi, H.-G. Xue and S.-P. Guo*. Balanced second-order nonlinear optical properties of adducts CHI3·(S8)3 and AsI3·(S8)3: a systematic survey, Inorg. Chem. 2019, 58, 4619–4625.

25. Y. Chi, T.-F. Jiang, H.-G. Xue and S.-P. Guo*. Transition metal free monoclinic Eu8In17.33S34 and its anisotropic photoelectronic responses, Inorg. Chem. 2019, 58, 3574–3577.

24. Z.-H. Yue,# Z.-T. Lu,# H.-G. Xue and S.-P. Guo*, KBiCl2SO4: the first bismuth chloride sulphate being second-order nonlinear optical active, Cryst. Growth & Des. 2019, 19, 3843–3850.

23. M.-M. Chen, H.-G. Xue and S.-P. Guo*. Multinary metal chalcogenides with tetrahedral structures for second-order nonlinear optical, photocatalytic, and photovoltaic applications, Coord. Chem. Rev. 2018, 368, 115–133.

22. Y. Pan, H.-G. Xue, S.-P. Guo*, B.-W. Liu and G.-C. Guo*. Second-order nonlinear optical crystals with mixed-anions, Coord. Chem. Rev. 2018, 374, 464–496.

21. S.-P. Guo*, Z.-D. Sun, Y. Chi, Z.-T. Lu and H.-G. Xue, Adduct-type IR nonlinear-optical crystal SbI3∙(S8)3 with a large second-harmonic generation and a high laser-induced damage threshold, Inorg. Chem. 2018, 57, 11282–11288.

20. Y. Chi, L.-Z. Rong, N.-T. Suen, H.-G. Xue and S.-P. Guo*. Crystal chemistry and photocatalytic properties of RE4S4Te3 (RE = Gd, Ho, Er, Tm), experimental and theoretical investigations, Inorg. Chem. 2018, 57, 5343–5351.

19. Y. Chi, H.-G. Xue and S.-P. Guo*. The first investigation of europium silicate melilite for second-order nonlinear optical application: experimental and theoretical studies, Dalton Trans. 2018, 47, 13434–13441.

18. Q.-T. Xu, J.-C. Li, H.-G. Xue and S.-P. Guo*. Effective combination of FeS2 microspheres and Fe3S4 microcubes with reduced graphene oxides as anode material for high-capacity and long-cycle lithium-ion batteries, J. Power Sources 2018, 396, 675–682.

17. Q.-T. Xu, J.-C. Li, H.-G. Xue and S.-P. Guo*. Binary iron sulfides as anode materials for rechargeable batteries: Crystal structures, syntheses, and electrochemical performance, J. Power Sources 2018, 379, 41–52.

16. Q.-T. Xu, H.-G. Xue and S.-P. Guo*. FeS2 walnut-like microspheres wrapped with rGO as anode material for advanced lithium-ion batteries, Electrochim. Acta 2018, 292, 1–9.

15. Q.-T. Xu, H.-G. Xue and S.-P. Guo*. Facile preparation of FeS@GO and its outstanding electrochemical performances for lithium storage, Inorg. Chem. Front. 2018, 5, 2540–2545.

14. M.-H. Wang, Z. Ma, H.-G. Xue and S.-P. Guo*. LiFeTiO4/CNTs composite as a cathode material with high cycling stability for lithium-ion batteries, Inorg. Chem. Front. 2018, 5, 2306–2313.

13. J.-R. Xiao, S.-H. Yang, F. Feng, H.-G. Xue and S.-P. Guo*. A review of the structural chemistry and physcial properties of metal chalcogenide halides, Coord. Chem. Rev. 2017, 347, 23–47.

12. S.-P. Guo*, Y. Chi and G.-C. Guo*. Recent achievements on middle and far-infrared second-order nonlinear optical materials, Coord. Chem. Rev. 2017, 335, 44–57.

11. S.-P. Guo*, J.-C. Li, J.-R. Xiao and H.-G. Xue*. Fe3S4 nanoparticles wrapped in an rGO matrix for promising energy storage: outstanding cyclic and rate performance, ACS Appl. Mater. Interfaces 2017, 9, 37694–37701.

10. Z.-D. Sun, Y. Chi, H.-G. Xue and S.-P. Guo*, A series of pentanary inorganic supramolecular sulfides (A3X)[MB12(MS4)3] (A = K, Cs; X = Cl, Br, I; M = Ga, In, Gd) featuring B12S12 clusters, Inorg. Chem. Front. 2017, 4, 1841–1847.

9. S.-P. Guo*, J.-C. Li, Q.-T. Xu, Z. Ma and H.-G. Xue*. Recent achievements on polyanion-type compounds for sodium-ion batteries: Syntheses, crystal chemistry and electrochemical performance, J. Power Sources 2017, 361, 285–299.

8. S.-P. Guo, Y. Chi, B.-W. Liu and G.-C. Guo*. Synthesis, crystal structure and second-order nonlinear optical property of a novel pentanary selenide (K3I)[In4(B12Se12)], Dalton Trans. 2016, 45, 10459–10465.

7. S.-P. Guo*, Y. Chi and H.-G. Xue*. Sm3S3BO3: the first sulfide borate without S–O and B–S bonds, Inorg. Chem. 2015, 54, 11052–11054.

6. S.-P. Guo and G.-C. Guo*. Crystal structure and magnetic and photocatalytic properties of a new ternary rare-earth mixed chalcogenide, Dy4S4Te3, J. Mater. Chem. A 2014, 2, 20621–20628.        

5. S.-P. Guo, G.-E Wang, M.-F. Wu, G.-N. Liu, X.-M. Jiang, G.-C. Guo* and J.-S. Huang. Novel single-crystal’s voltage dependent effect and magnetic order of Ln2ZrQ5 (Ln = La, Sm and Gd; Q = S and Se), Dalton Trans. 2013, 42, 2679–2682.

4. S.-P. Guo, T.-S. You and S. Bobev*. Closely related rare-earth metal germanides RE2Li2Ge3 and RE3Li4Ge4 (RE = La–Nd, Sm): synthesis, crystal chemistry and magnetic properties, Inorg. Chem. 2012, 51, 3119–3129.

3. S.-P. Guo, T.-S. You, Y.-H. Jung and S. Bobev*. Synthesis, crystal chemistry, and magnetic properties of RE7Li8Ge10 and RE11Li12Ge16 (RE = La–Nd, Sm): new members of the [REGe2]n[RELi2Ge]m homologous series, Inorg. Chem. 2012, 51, 6821–6829.

2. S.-P. Guo, G.-C. Guo*, M.-S. Wang, J.-P. Zou, H.-Y. Zeng, L.-Z. Cai and J.-S. Huang. A facile approach to hexanary chalcogenoborate featuring 3-D chiral honeycomb-like open-framework constructed from rare-earth consolidating thiogallate-closo-dodecaborate, Chem. Commun. 2009, 4366–4368.

1. S.-P. Guo, G.-C. Guo*, M.-S. Wang, J.-P. Zou, G. Xu, G.-J. Wang, X.-F. Long and J.-S. Huang. A series of new infrared NLO semiconductors, ZnY6Si2S14, Al0.33-xLn3+xSiS7 (Ln = Sm, Dy) and Al0.33Sm3SiS7, Inorg. Chem. 2009, 48, 7059–7065.