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简荣坤 教授、团队带头人    

简荣坤,教授/博士生导师。2009和2014年于四川大学分别获得学士学位和高分子化学与物理博士学位,随后就职于福建师范大学化学与材料学院。在2018年6月至2019年6月期间,西班牙马德里高等材料研究院(IMDEA Materials Institute)从事博士后研究。2020年入选欧盟玛丽•居里学者人才计划。工作至今,已主持国家自然科学基金面上项目和青年项目各1项,福建省自然科学基金面上项目和青年创新项目各1项;以第一作者或通讯作者在Chemical Engineering Journal, Journal of Hazardous Materials,Journal of Cleaner Production,Journal of Colloid and Interface Science,Composites part B: Engineering等SCI期刊发表SCI学术论文24篇,其中1篇入选ESI 1%高被引论文,授权中国发明专利11件。

学院个人主页:https://chem.fjnu.edu.cn/30/42/c7566a143426/page.htm

Researchgate:https://www.researchgate.net/profile/Rong-Kun-Jian

研究方向

1)多功能型阻燃剂的设计及高分子材料阻燃改性;

2)膨胀型防火涂料的设计和开发;

3)多功能化高分子及其纳米复合材料;

4)天然高分子基防腐防污涂料。

科研项目

1.国家自然科学基金面上项目, 22075045, 含磷唑类金属配合物的设计合成及其在环氧树脂中的阻燃抑烟与机械增强研究, 63 , 2021/1-2024/12, 在研, 主持;

2.福建省自然科学基金面上项目,2019J01061338, 含磷多元醇/异氰酸酯动态硫化增韧阻燃聚乳酸材料的制备及其性能研究, 10, 2019/7-2022/6, 已结题, 主持;

3.国家自然科学基金青年科学基金项目, 21504015, 大分子次膦酸铵阻燃固化环氧树脂的性能及阻燃机理研究, 20, 2016/1-2018/12, 已结题, 主持;

4.福建省自然科学基金青年创新项目, 2015J05094, 含磷大分子阻燃剂的合成及其阻燃聚乳酸研究, 3, 2015/4-2018/4, 已结题, 主持.

论文著作

1.       Zheng X.T., Dong Y.Q., Liu X.D., Xu Y.L., Jian R.K.* Fully bio-based flame-retardant cotton fabrics via layer-by-layer self assembly of laccase and phytic acid, Journal of Cleaner Production, 2022, 350, 131525.

2.       Liu X.D., Zheng X.T., Dong Y.Q., He L.X., Chen F., Bai W.B., Lin Y.C., Jian R.K.* A novel nitrogen-rich phosphinic amide towards flame-retardant, smoke suppression and mechanically strengthened epoxy resins, Polymer Degradation and Stability, 2022, 196, 109840.

3.       Shao Z.B., Cui J., Lin X.B., Li X.L., Jian R.K.*, Wang D.Y.* In-situ coprecipitation formed Fe/Zn-layered double hydroxide/ammonium polyphosphate hybrid material for flame retardant epoxy resin via synergistic catalytic charring,  Composites Part A-Applied Science and Manufacturing, 2022, 155, 106841.

4.       Jian R.K.*, Pang F.Q., Lin Y.C., Bai W.B. Facile construction of lamellar-like phosphorus-based triazole-zinc complex for high-performance epoxy resins, Journal of Colloid and Interface Science, 2022, 609, 513-522.

5.       Ai Y.F., Liu X.D., Bai W.B., Lin Y.C., Xie R.R.*, Jian R.K.* From herbicide to flame retardant: The lamellar-like phosphorus-bridged amitrole toward high fire safety epoxy resin with light smoke and low toxicity, Chemosphere, 2022, 291, 132704

6.       Xia L., Pang F.Q., Wei F.F.*, Jian R.K. * The effect of Tris-phosphaphenanthrene based phosphonate on the flame retardance, thermal decomposition, and crystallization of bio-based poly(lactic acid). Journal of Applied Polymer Science, 2021, e51592.

7.       Pang F.Q., Liu X.D., Zheng X.T., Lin Y.C.*, Jian R.K*. An intrinsic flame retardant epoxy resin with high transparency and strengthened mechanical property. Journal of Applied Polymer Science, 2021, 138, e51230.

8.       Shao Z. B., Zhang J., Jian R.K.*, et al. A strategy to construct multifunctional ammonium polyphosphate for epoxy resin with simultaneously high fire safety and mechanical properties. Composites Part A-Applied Science and Manufacturing, 2021, 149, 106529.

9.       Jian R.K., Lin X.B., Liu Z.Q., Zhang W., Zhang J., Zhang L., Li Z., Wang D.Y.* Rationally designed zinc borate@ZIF-8 core-shell nanorods for curing epoxy resins along with low flammability and high mechanical property. Composites part B: Engineering, 2020, 200, 108349.

10.    Ai Y.F., Pang F.Q., Xu Y.L., Jian R.K.* Multifunctional phosphorus-containing triazolyl amine toward self-intumescent flame-retardant and mechanically strong epoxy resin with high transparency. Industrial & Engineering Chemistry Research, 2020, 59, 11918-11929.

11.    Ai Y.F., Xia L., Pang F.Q., Xu Y.L., Zhao H.B.*, Jian R.K*. Mechanically strong and flame-retardant epoxy resins with anti-corrosion performance. Composites part B: Engineering, 2020, 193, 108019.

12.    Li X.L.#, Zhang F.H.#, Jian R.K.*, Ai Y.F., Ma J.L., Hui G.J., Wang D.Y.* Influence of eco-friendly calcium gluconate on the intumescent flame-retardant epoxy resin: Flame retardancy, smoke suppression and mechanical properties. Composites part B: Engineering, 2019, 176, 107200.

13.    Jian R.K., Ai Y.F., Xia L., Zhang Z.P., Wang D.Y.* Organophosphorus heteroaromatic compound towards mechanically reinforced and low-flammability epoxy resin. Composites part B: Engineering, 2019, 168, 458-466.

14.    Jian RK#*, Ai YF#, Xia L, Zhao LJ, Zhao HB*. Single component phosphamide-based intumescent flame retardant with potential reactivity towards low flammability and smoke epoxy resins. Journal of Hazardous Materials 2019, 371, 529-539.

15.    Xia L., Jian R.K.*, Ai Y.F., Zheng X.L., Zhao B*. An effective multi-hydroxy-containing ammonium phosphate towards flame-retarding poly(lactic acid): Flame retardance, thermal and pyrolysis behaviors. Journal of Analytical and Applied Pyrolysis, 2018, 134, 265-273.

16.    Jian R.K.#, Xia L.#, Ai Y.F., Wang D.Y.* Novel Dihydroxy-Containing Ammonium Phosphate Based Poly (Lactic Acid): Synthesis, Characterization and Flame Retardancy. Polymers, 2018, 10, 871.

17.    Wang P., Xia L., Jian R.K.*, et al. Flame-retarding epoxy resin with an efficient P/N/S-containing flame retardant: Preparation, thermal stability, and flame retardance. Polymer Degradation and Stability, 2018, 149, 69-77.

18.    Jian R.K.*, Wang P, Duan W.S., et al. A facile method to flame-retard epoxy resin with maintained mechanical properties through a novel P/N/S-containing flame retardant of tautomerization. Materials Letters, 2017, 204, 77-80.

19.    Jian R.K.*, Wang P, Xia L, et al. Low-flammability epoxy resins with improved mechanical properties using a Lewis base based on phosphaphenanthrene and 2-aminothiazole. Journal of Materials Science, 2017, 52, 9907-9921.

20.    Jian R.K.*, Wang P., Xia L., Zheng X.L*. Effect of a novel P/N/S-containing reactive flame retardant on curing behavior, thermal and flame-retardant properties of epoxy resin. Journal of Analytical and Applied Pyrolysis, 2017, 127, 350-368.

21.    Shao Z.B.*, Zhang M.X., Han Y., Yang X.D., Jin J. Jian R.K.* A highly efficient gas-dominated and water-resistant flame retardant for non-charring polypropylene. RSC Advances, 2017, 7, 51919-51927.

22.    Jian R.K.*, Wang P., Duan W.S., et al. Synthesis of a novel P/N/S-containing flame retardant and its application in epoxy resin: Thermal property, flame retardance and pyrolysis behavior. Industrial & Engineering Chemistry Research, 2016, 55, 11520-11527.

授权发明专利:

1.       简荣坤, 艾远芳, 夏龙, 庞付渠. 一种含磷多羟基阻燃剂的制备及其在阻燃聚乳酸的应用. 中国发明专利, 2022.06.17, ZL202011085844.2.

2.       简荣坤, 艾远芳, 夏龙, 张智鹏, 杨俊威, 程洪阳. 一种磷氮硫型阻燃剂及其在环氧树脂中的应用, 2020.05.19, ZL201810589710.0.

3.       简荣坤, 艾远芳, 夏龙, 庞付渠. 一种含磷三氮唑化合物的制备方法及其在阻燃聚乳酸上应用. 20200908, ZL201811259800.X.

4.       简荣坤, 艾远芳, 夏龙, 庞付渠. 一种单组分磷酰胺膨胀型阻燃剂制备及其在阻燃环氧树脂中的应用, 2020.10.30, ZL201811259803.3.

5.       简荣坤, 艾远芳, 夏龙, 王盼, 杨俊威, 程洪阳. 一种用于环氧树脂的叔胺型阻燃固化剂及其制备方法. 中国发明专利, 2019.08.29, ZL201711489080.1.

6.       简荣坤, 夏龙, 张辅辉, 艾远芳, 李小龙, 马金露, 惠国静, 王盼, 杨俊威. 一种膨胀型阻燃环氧树脂及其制备方法. 中国发明专利, 2019.09.02, ZL201711439481.6.

7.       简荣坤, 王盼, 段伟森, 夏龙, 郑雪琳. 一种用于环氧树脂的可异构化膦酰胺阻燃剂及其制备方法. 中国发明专利, 2019.04.05, ZL201710398748.5.

8.       简荣坤, 夏龙, 王盼, 杨俊威, 熊溪. 一种草甘膦三聚氰胺盐阻燃剂的制备及其在聚乳酸中应用. 中国发明专利, 2018.11.23, ZL201710418966.0.

9.       简荣坤, 王盼, 段伟森, 翁家宝. 一种用于环氧树脂的含磷氮硫阻燃剂及其制备方法. 中国发明专利, 2018.06.08, ZL201610470492.X.

10.    简荣坤, 王盼, 夏龙, 余小琴, 郑雪琳. 应用在环氧树脂中含磷氮硫的反应型阻燃剂的制备方法. 中国发明专利, 2018.06.12, ZL201611045125.1.

代表性工作介绍:

1)高性能化阻燃高分子材料

针对环氧树脂无卤阻燃改性研究中存在的阻燃与机械性能难以平衡的矛盾,基于构筑氢键作用和π-π相互作用可增强环氧树脂内聚力,以及通过多元素(磷,氮,硫等)协同作用可实现环氧树脂高效阻燃的研究思想,提出采用含磷芳杂环衍生物改性环氧树脂的方法,成功实现了环氧树脂的阻燃及高性能化。例如,本团队设计了N-噻唑基DOPO膦酰胺并将其用于改性环氧树脂,结果表明仅添加5 wt%该阻燃剂即可使环氧树脂通过UL-94 V-0级,且当添加量提高至10 wt%时,相较于未改性环氧树脂,改性后的环氧树脂的拉伸和弯曲强度分别提高了20 %38 %,冲击韧性提升了92 %,具体信息详见Journal of Materials Science, 2017, 52, 9907-9921。其他成果详见Industrial & Engineering Chemistry Research, 2016, 55, 11520-11527, Composites part B: Engineering, 2019, 168, 458-466Polymer Degradation and Stability, 2022, 196, 109840等。

2)低毒低烟膨胀型阻燃高分子材料

降低高分子材料在燃烧过程中烟毒性气体的释放,可有效提高高分子材料的火安全性。本团队设计集酸源、碳源、气源于一体的单组分膨胀型阻燃剂N-苯并噻唑基新戊二醇磷酰胺并将其用于改性环氧树脂。结果发现,添加17.5wt% 该阻燃剂可使环氧树脂通过UL-94 V-0级,氧指数达到27.5 %;同时,相比于纯环氧树脂,改性后的环氧树脂的烟毒性气体释放大幅度降低。此外,环氧树脂的拉伸强度、弯曲强度和冲击强度均获得了明显提升,具体信息详见Journal of Hazardous Materials 2019, 371, 529-539ESI 1%高被引论文。其他相关成果详见Composites part B: Engineering, 2019, 176, 107200, Industrial & Engineering Chemistry Research, 2020, 59, 11918-11929Composites Part A-Applied Science and Manufacturing, 2021, 149, 106529Composites Part A-Applied Science and Manufacturing, 2022, 155, 106841.