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成果及论文


发表文章及专利:

发表文章:

29. Hong, Y.; Deng, H.-P.* "Research Progress on Photocatalyzed Protic C(sp3)Functionalization" Chin. J. Org. Chem. 2024, doi: 10.6023/cjoc202407049.

28. Hong, Y.; Deng, H.-P.* "Alkylcyanation of Unactivated Alkenes with Protic C(sp3)H Feedstocks via Radical-Initiated Intramolecular Cyano Group Migration Enabled by Photoredox/Brønsted Base Dual CatalysisChemPhotoChem 2024, doi: 10.1002/cptc.202400282.

27. Zhang, G.-X.; Li, D.-S.; Chen, A.-F.; Xue, F.; Deng, H.-P.* "Synthesis of Monofluorocyclohexene via Photocatalytic Defluorinative [4+2] Annulation of gem-Difluoroalkenes with Unactivated AlkenesAdv. Synth. Catal. 2023, 365, 4604-4608.

26. Pan, Z.; Wang, X.; Zhao, S.; Deng, H.-P.; Ma, M.; Xue, F.* "Defluorinative Thiolation of gem-Difluoroalkenes by Convergent Paired Electrolysis" Org. Lett202325, 6143–6148.

25. Chen, P.-F.; Li, D.-S.; Ou, W.-T.; Xue, F.; Deng, H.-P.* "2-Isopropylthioxanthone-Catalyzed Divergent Functionalization of Bicyclo[1.1.0]butanes under Visible-Light IrradiationOrg. Lett202325, 6184–6188. (Front Cover) 

             

24. Sun, Y.; Li, Y.; Wang, X.; Cao, X.; Deng, H.-P.; Bu, X.; Ma, M.; Xue, F.* "Preparation of New Chiral Diene Ligands and Their Use in the Rhodium Catalyzed Asymmetric Annulation of 2-Formylarylboronic Acid with Dialkylalkynes" Chem. Commun. 2023, 59, 9102-9105.

23. Zhao, B.; Pan, Z.; Pan, J.; Deng, H.-P.; Bu, X.; Ma, M.; Xue, F.* "Regiodivergent Electroreductive Defluorinative Carboxylation of gem-Difluorocyclopropanes" Green Chem. 2023, 25, 3095-3102.

22. Hong, Y.; Dong, M.-Y.; Li, D.-S.; Deng, H.-P.* "Photoinduced Three-Component Carboarylation of Unactivated Alkenes with Protic C(sp3)H Feedstocks" Org. Lett. 2022, 24, 7677-7684 highlighted in CBG 资讯

21. Dong, M.-Y.; Han, C.-Y.; Li, D.-S.; Hong, Y.; Liu, F.;* Deng, H.-P.* " Hydrogen-Evolution Allylic C(sp3)H Alkylation with Protic C(sp3)H Bonds via Triplet Synergistic Brønsted Base/Cobalt/Photoredox CatalysisACS Catal. 202212, 9533-9539; highlighted in CBG 资讯 and X-MOL.

20. Li, D.-S.; Liu, T.; Hong, Y.; Cao, C.-L.; Wu, J.;* Deng, H.-P.* "Stop-Flow Microtubing Reactor-Assisted Visible Light-Induced Hydrogen-Evolution Cross Coupling of Heteroarenes with C(sp3)H Bonds" ACS Catal. 2022, 12, 4473-4480. (co-first author); highlighted in Rational Science.

19. Cao, C.-L.; Zhang, G.-X.; Xue, F.; Deng, H.-P.* "Photoinduced CH Monofluoroalkenylation with gem-Difluoroalkenes through Hydrogen Atom Transfer in Batch and Flow" Org. Chem. Front. 2022, 9, 959-965; highlighted in Frontiers Journals. 

18. Xia, Q.; Li, Y.; Cheng, L.; Liang, X.; Cao, C.; Dai, P.; Deng, H.-P.; Zhang W.-H.;* Wang, Q.* "Electron Donor–Acceptor Complex-Initiated Photochemical Cyanation for the Preparation of α-Amino Nitriles" Org. Lett. 2020, 22, 9638-9643.

17. Xia, Q.; Li, Y.; Wang, X.; Dai, P.; Deng, H.-P.; Zhang, W.-H. "Visible Light-Driven α-Alkylation of N-Aryl tetrahydroisoquinolines Initiated by Electron Donor–Acceptor Complexes" Org. Lett. 2020, 22, 7290-7294.

16. Jia, P.; Li, Q.; Poh, W. C.; Jiang, H.; Liu, H.; Deng, H.-P.; Wu, J.* "Light-Promoted Bromine Radical-Mediated Selective Alkylation and Amination of Unactivated C(sp3)-H Bonds." Chem, 2020, 6, 1766-1776.

15. Deng, H.-P.; Zhou, Q.; Wu, J. Microtubing‐Reactor‐Assisted Aliphatic C−H Functionalization with HCl as a Hydrogen‐Atom‐Transfer Catalyst Precursor in Conjunction with an Organic Photoredox Catalyst. Angew. Chem. Int. Ed. 2018,57, 12661-12665.

14. Fan, X.-Z., Rong, J.-W., Wu, H.-L., Zhou, Q., Deng, H.-P., Tan, J. D., Xue, C.-W., Wu, L.-Z., Tao, H.-R., Wu, J.* "Eosin Y as a Direct Hydrogen Atom Transfer Photocatalyst for the Functionalization of C-H Bonds" Angew. Chem. Int. Ed. 2018, 57, 8514-8518.

13. Deng, H.-P.; Fan, X.-Z.; Chen, Z.-H.; Xu, Q.-H.; Wu, J. Photoinduced Nickel-Catalyzed Chemo- and Regioselective Hydroalkylation of Internal Alkynes with Ether and Amide α‑Hetero C(sp3)−H Bonds. J. Am. Chem. Soc. 2017, 139, 13579-13584.

12. Xue, F.+; Deng, H.-P.+; Xue, C.-W.; Mohamed, D. K. B.; Tang, K. Y.; Wu, J. Reaction Discovery Using Acetylene Gas as the Chemical Feedstock Accelerated By the “Stop-Flow” Micro-Tubing Reactor System. Chem. Sci. 2017, 8, 3623-3627. (co-first author).

11. Deng, H.-P.; Wang, D.; Szabó, K. J. Direct Allylation of Quinones with Allylboronates. J. Org. Chem. 2015, 80, 3343-3348.

10. Deng, H.-P.; Eriksson, L.; Szabó, K. J. Allylic sp3 C-H Borylation of Alkenes via Allyl-Pd Intermediates. A Efficient rout to Allylboronates. Chem. Commun. 2014, 50, 9207-9210.

9. Wang, D.; Deng, H.-P.; Wei, Y.; Xu, Q.; Shi, M. Highly Efficient Construction of Trifluoromethylated Heterocycles; [3+2] Annulation of N,N-Cyclic or C,N-Cyclic Azomethine Imines with Trifluoromethyl-Containing Electron-Deficient Olefins. Eur. J. Org. Chem. 2013, 401-406.

8. Deng, H.-P.; Wei, Y.; Shi, M. Enatioselective Synthesis of Highly Functionalized Trifluoromethyl-Bearing Cyclopentenes: Asymmetric [3+2] Annulation of Morita-Baylis-Hillman Carbonates with Trifluoroethylidene malonates Catalyzed by Multifunctional Thiourea-Phosphines. Adv. Synth. Catal. 2012, 354, 783-789.

7. Deng, H.-P.; Shi, M. Preparation of Chiral Multifunctional Thiourea-Phosphanes and Synthesis of Chiral Allylic Phosphites and Phosphane Oxides through Asymmetric Allylic Substitution Reactions of Morita-Baylis-Hillman Carbonates. Eur. J. Org. Chem. 2012, 183-187.

6. Deng, H.-P.; Wei, Y.; Shi, M. Diels-Alder Dimerization of Morita-Baylis-Hillman Acetates Catalyzed by Organocatalysts. Res. Chem. Intermed. 2012, 39, 5-18.

5. Deng, H.-P.; Wang, D.; Wei, Y.; Shi, M. Chiral Multifunctional Thiourea-Phosphine- Catalyzed Asymmetric [3+2] Annulation of Morita-Baylis-Hillman Carbonates with Maleimides. Beilstein J. Org. Chem. 2012, 8, 1098-1104.   

4. Zhang, X.-N.; Deng, H.-P.; Huang, L.; Wei, Y.; Shi, M. Phosphine-Catalyzed Asymmetric [4+1] Annulation of Morita–Baylis–Hillman Carbonates with Dicyano-2-methylenebut- 3-enoates. Chem. Commun. 2012, 48, 8664-8666.

3. Deng, H.-P.; Wei, Y.; Shi, M. Highly Regio- and Diastereoselective Construction of Spirocyclopentene-oxindoles through Phosphine-Catalyzed [3 + 2] Annulation of Morita-Baylis-Hillman Carbonates with Isatylidene Malononitriles. Org. Lett. 2011, 13, 3348-3351.

2. Deng, H.-P.; Wei, Y.; Shi, M. Chiral Bifunctional Thiourea-Phosphane Organocatalysts in Asymmetric Allylic Amination of Morita-Baylis-Hillman Acetates. Eur. J. Org. Chem. 2011, 1956-1960.

1. Deng, H.-P.; Wei, Y.; Shi, M. Axially Chiral Phosphine-Oxazoline Ligands in Silver(I)-Catalyzed Asymmetric Mannich Reaction of Aldimines with Trimethylsiloxyfuran. Adv. Synth. Catal. 2009, 351, 2897-2902. 


专利:

1. 邓红平,洪洋;一种非尼拉敏或其衍生物的合成方法,专利号:ZL 202211070992.6