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成果及论文

† Represents co-first author; Represents the corresponding author

加入安徽师范大学后

2024 

[86] Hui Wang, Qi Cai, Shengyu Dai*

Direct Synthesis of Poly(α-olefin) Thermoplastic Elastomers Via Controlled Chain Straightening Using Bulky α-Diimine Palladium Complexes 

Polym. Chem.2024DOI:10.1039/D4PY00353E.  https://doi.org/10.1039/D4PY00353E

[85] Mengya Ma Shengyu Dai*

Flexible Monoarylmethyl Substituents in Efficient Polyethylene Elastomer Synthesis: Facilitating Chain Walking and Enhancing Chain Growth

Polymer2024, 308, 127292. https://doi.org/10.1016/j.polymer.2024.127292


[84] 韩婷婷,吴新月,代胜瑜

邻芳基卤素效应促进大位阻铁配合物催化不同分子量高度线性聚乙烯的合成

Chin. J. Synth. Chem. 2024, DOI: 10.15952/i.cnki.cisc.1005-1511.24103。

[83] Jianhai ChenZhou Lu,  Shengyu Dai*

Synthesis of Chain-end Functionalized Highly Branched Polyethylene Waxes Using Sterically Open α-Diimine Ni(II) Catalysts.

 J. Polym. Sci. 2024, DOI:10.1002/pol.20240243. https://doi.org/10.1002/pol.20240243

[82] Zhou Lu, Beihang Ding Shengyu Dai*

Suppression of Chain Walking and Chain Transfer in Ethylene (Co)Polymerization with Iminodibenzyl Substituents Containing Second Coordination Spheres

Macromolecules 2024 575262-5270. https://doi.org/10.1021/acs.macromol.4c00493

[81]  Qi Cai,  Shengyu Dai*

Promotion of Chain Growth and Suppression of Chain Transfer by 2-Methoxy Group in Diarylmethyl Moiety in Pyridine-Imine Nickel- and Palladium-Catalyzed Ethylene (Co)Polymerization.

Eur. Polym. J. 2024214, 113132. https://doi.org/10.1016/j.eurpolymj.2024.113132

[80]  Weiqing Lu, Beihang Ding Shengyu Dai*

Control of Chain Transfer and Chain Walking by Tailored Metal−π Interactions in Polymerization Catalysis

J. Catal. 2024, 435, 115550.  https://doi.org/10.1016/j.jcat.2024.115550

[79]  Jianjian Dai, Shengyu Dai*

Impact of o-Aryl Halogen Effects on Ethylene Polymerization: Steric vs Electronic Effects

Dalton Transactions, 2024, 53, 9268-9293. https://doi.org/10.1039/D4DT00850B (Invited Contributions, Inside Front Cover)

[78] Huayin Sun, Xinyue Wu, Wenping Zou, Shengyu Dai*

A Hybrid Steric Ligand Modification Strategy Promotes Propylene (Co)Polymerization

Polymer2024,  302127050. https://doi.org/10.1016/j.polymer.2024.127050

在安徽大学期间

2023 

[77] Weiqing Lu, Beihang Ding, Wenping Zou, Shengyu Dai*

Direct Synthesis of Polyethylene Thermoplastic Elastomers with High Molecular Weight and Excellent Elastic Recovery Via A Hybrid Steric Bulky Strategy

Eur. Polym. J. 2023201, 112577. https://doi.org/10.1016/j.eurpolymj.2023.112577

[76] Beihang Ding,  Shengyu Dai*

Palladium-Catalyzed Synthesis of Hyperbranched Polar Functionalized Polyethylene with High Density Hydrophilic Groups 

ACS Applied Polymer Materials  2023, 59536-9542. https://doi.org/10.1021/acsapm.3c01989

[75] Xinyue Wu, Wenping Zou, Shengyu Dai*

Functionalized Semicrystalline Polyethylene with Polar Groups at Branch End Enabled by Bulky Cationic Palladium Catalysts

J. Polym. Sci. 2023, 61, 3288–3294. https://doi.org/10.1002/pol.20230546 


[74] Wenbin Yuan, Weimin Li*Shengyu Dai*

Preparation of Polyethylene Thermoplastic Elastomers Using CS-Symmetric Nickel Catalysts in Ethylene Polymerization

Polymer 2023,  285126322. https://doi.org/10.1016/j.polymer.2023.126322

[73] Chuangao Zhu, Beihang Ding, Shengyu Dai*

Synthesis of Branched Polyethylene Waxes Using Benzocycloalkyl Pyridine-Imine Ni(II) Catalysts with Dibenzosuberyl Group

 J. Organomet. Chem.20231000, 122852. https://doi.org/10.1016/j.jorganchem.2023.122852

[72] Zhou Lu, You Ge,  Shengyu Dai*

A Flexible Axial Shielding Strategy for Improving Ethylene (Co)polymerization with 8-Cycloalkylnaphthyl α-Diimine Catalysts

Inorg. Chem. 2023, 62, 14888-14895. https://doi.org/10.1021/acs.inorgchem.3c01568

[71] Hua Wang, Zhou Lu*,  Shengyu Dai*  

Synthesis of Hyperbranched Polyethylene and Carboxylate Functionalized Polyethylene Using Bis(benzocyclopentyl) α-Diimine Pd(II) Catalysts with Axial Substituent-Constrained Strategy

Eur. Polym. J. 2023196, 112247. https://doi.org/10.1016/j.eurpolymj.2023.112247

[70] Qi Cai, Fei Fang, Jiangang Gao*, Hui Wang*, Shengyu Dai*  

Preparation of Branched Oligoethylene and Polar Functionalized Oligoethylene Using Unsymmetrical Arylamine Based Cationic Ni(II) and Pd(II) Iminopyridyl Catalysts. 

Eur. Polym. J. 2023, 193, 112094. https://doi.org/10.1016/j.eurpolymj.2023.112094

[69] Zhengpeng Yan, Wenping Zou, Shengyu Dai*  

Unexpected o-Aryl tBu Group Effect on Suppression of Chain Transfer in Pyridine-Imine Ni(II) and Pd(II) Catalyzed Ethylene (Co)Polymerization

Polym. Chem.202314, 2107–2116. https://doi.org/10.1039/D3PY00146F

[68]  Hui Wang, Weiqing Lu, Huiqin BiShengyu Dai*  

Dibenzosuberyl Substituents Suppressing Chain Transfer in Bis(imino)pyridyl Iron(II) Catalyzed Ethylene Polymerization

Polymer 2023,  273125868. https://doi.org/10.1016/j.polymer.2023.125868

[67] Hui Wang, Weiqing Lu, Mingmin Zou, Shengyu Dai*  

Direct Synthesis of Polyethylene Thermoplastic Elastomers Using Hybrid Bulky Acenaphthene-Based α‑Diimine Ni(II) Catalysts.

Molecules 2023, 28, 2196161. (Invited Contributions) https://doi.org/10.3390/molecules28052266

[66] Beihang Ding, Lihang Jiang, Xiaohui Kang, Shengyu Dai* 

Enhancing Suppression of Chain Transfer via Catalyst Structural Evolution in Ethylene (Co)Polymerization.

Chinese J. Chem., 2023, 41, 1509—1516. (Back cover) (Highlighted by CBG News). https://doi.org/10.1002/cjoc.202200842

[65] Huayin Sun, Huijun Fan, Chuangao Zhu, Wenping Zou*, Shengyu Dai*  

Direct Synthesis of Partially Chain-straightened Propylene Oligomers and P-MA Co-oligomers Using Axially Flexible Shielded Iminopyridyl Palladium Complexes

Polymers 2023, 15, 111. https://doi.org/10.3390/polym15010111. (Invited Contributions)

[64] Huijun Fan, Guanru Chang, Hui Wang*, Shengyu Dai* 

Second Coordination Sphere Effect of Benzothiophene Groups Enhances Chain Transfer in Ethylene (Co)Oligomerization

New J. Chem., 202347, 2488 - 2494. https://doi.org/10.1039/D2NJ05617H

[63] Zhou Lu, Xiaowei Xu, Yi Luo* , Shengbao He, Weigang Fan*, Shengyu Dai*

The Unexpected Effect of Catalyst’s Structural Symmetry on Branching Microstructure of Polyethylene in Late Transition Metal Polymerization Catalysis

ACS Catal. 2023, 13, 725–734. (Highlighted by CBG News).  https://doi.org/10.1021/acscatal.2c04525 

[62] Zhengpeng Yan, Guanru Chang, Wenping Zou, Gen Luo*, Shengyu Dai*

Synthesis of Lightly Branched Ultrahigh-Molecular-Weight Polyethylene Using Cationic Benzocyclohexyl Nickel Catalysts 

Polym. Chem.202314, 183-90. https://doi.org/10.1039/D2PY01087A

[61] Weiqing Lu,  Weigang Fan*, Shengyu Dai*

A Rigid–Flexible Double-Layer Steric Strategy Promoting Ethylene Polymerization and Copolymerization in Alkane Solvents

Inorg. Chem. Front. 202310, 108-117. (Highlighted by the Journal  in Wechat and Twitter

https://doi.org/10.1039/D2QI01895K

2022 

[60] Xinyue Wu,  Guoyong Xu, Weiqing Lu, Zhong-Yuan Li*,   Shengyu Dai*

Ethylene (Co)oligomerization in Alkane Solvents Facilitated by Rigid-Flexible Double-Layer Steric Strategy

Eur. Polym. J. 2022169, 111459. (Accept directly without modifications) https://doi.org/10.1016/j.eurpolymj.2022.111459

[59] Jianhai Chen, Zhengpeng Yan, Zhong-Yuan Li,   Shengyu Dai*

Direct Synthesis of Chain-End Toluene Functionalized Hyperbranched Ethylene Oligomers

Polymers 2022, 14, 3049. https://www.mdpi.com/1747856. (Invited feature article with free APC) 


[58] Yudan Liao, Qi Cai,  Shengyu Dai*

Synthesis of High Molecular Weight Polyethylene and E-MA Copolymers Using Iminopyridine Ni(II) and Pd(II) Complexes Containing a Flexible Backbone and Rigid Axial Substituents

Chin. J. Polym. Sci. 2023, 41, 233-239. https://doi.org/10.1007/s10118-022-2847-5.

[57] Beihang Ding, Guanru Chang, Zhengpeng Yan,  Shengyu Dai*

Ethylene (Co)oligomerization Using Iminopyridyl Ni(II) and Pd(II) Complexes Bearing Benzocycloalkyl Moieties to Access Hyperbranched Ethylene Oligomers and Ethylene-MA Co-oligomers     

Front. Chem. 2022, 10, 961426.  (Invited Contributions)   https://doi.org/10.3389/fchem.2022.961426


[56] You Ge, Zhou Lu,  Shengyu Dai*

A Flexible Axial Shielding Strategy for the Synthesis of High-Molecular-Weight Polyethylene and Polar Functionalized Polyethylene with Pyridine-imine Ni(II) and Pd(II) Complexes

Organometallics 2022, 41, 2042-2049. (Highlighted by ACS  in Wechat)

https://pubs.acs.org/doi/10.1021/acs.organomet.2c00207.

[55] Huijun Fan, Yudan Liao,  Shengyu Dai*

Propylene Polymerization and Copolymerization with Polar Monomers Facilitated by Flexible Cycloalkyl Substituents in α-Diimine Systems

Polymer2022254125076https://doi.org/10.1016/j.polymer.2022.125076

[54] Zhou Lu, Yudan Liao, Weigang Fan*, Shengyu Dai*

Efficient Suppression of Chain Transfer Reaction in Ethylene Coordination Polymerization with Dibenzosuberyl Substituents

Polym. Chem.202213, 4090–4099. https://doi.org/10.1039/D2PY00282E. (Selected as Front Cover)

[53]  Weiqing Lu, Yudan Liao, Shengyu Dai*

Facile Access to Ultra-Highly Branched Polyethylenes Using Hybrid “Sandwich” Ni(II) and Pd(II) Catalysts

J. Catal. 2022411, 54-61. https://doi.org/10.1016/j.jcat.2022.05.003

[52] You Ge, Qi Cai, Yuyin Wang, Jiangang Gao*, Yue Chi*, Shengyu Dai*

Synthesis of High-Molecular-Weight Branched Polyethylene Using a Hybrid “Sandwich” Pyridine-Imine Ni(II) Catalyst

Front. Chem. 2022, 10, 886888. https://doi.org/10.3389/fchem.2022.886888. (Invited Contributions)       


[51] Huijun Fan, Guoyong Xu, Hui Wang, Shengyu Dai*

Direct Synthesis of Hyperbranched Ethylene Oligomers and Ethylene-MA Co-oligomers Using Iminopyridyl Systems with Weak Neighboring Group Interactions

J. Polym. Sci. 2022, 60, 1944–1953. (Selected as Front Cover; Highlighted by the Journal  in Tweet; Highlighted by Wiley Advanced Science News) (ESI Highly Cited Paper) https://doi.org/10.1002/pol.20220047

[50] Weiqing Lu, Hui Wang, Weigang Fan*, Shengyu Dai*

Exploring the Relationship Between Polyethylene Microstructure and Spatial Structure of α-Diimine Pd(II) Catalysts via A Hybrid Steric Strategy

Inorg. Chem. 2022, 61, 6799–6806. https://doi.org/10.1021/acs.inorgchem.1c03969 (Highlighted by the Journal  in Tweet

[49] Zhengpeng Yan, Huiqin Bi, Beihang Ding, Hui Wang*, Guoyong Xu*, Shengyu Dai*  

A Rigid-Flexible Double-Layer Steric Strategy for Ethylene (Co)oligomerization with Pyridine-imine Ni(II) and Pd(II) Complexes

New J. Chem. 2022, 46, 8669 - 8678. https://doi.org/10.1039/D2NJ00183G. (ESI Highly Cited Paper)

[48] Zhengpeng Yan, Guoyong Xu, Hui Wang, Shengyu Dai* 

Synthesis of Thermoplastic Polyethylene Elastomers and Ethylene-Methyl Acrylate Copolymers Using Methylene-Bridged Binuclear Bulky Dibenzhydryl α-Diimine Ni(II) and Pd(II) Catalysts 

Eur. Polym. J. 2022168, 111105. https://doi.org/10.1016/j.eurpolymj.2022.111105


[47] Hui Wang, Gaokun Duan, Huijun Fan, Shengyu Dai* 

Second Coordination Sphere Effect of Benzothiophene Substituents on Chain Transfer and Chain Walking in Ethylene Insertion Polymerization 

Polymer 2022, 245, 24707. (Highlighted by 化学与材料科学) https://doi.org/10.1016/j.polymer.2022.124707

[46] Zhou Lu†, Guanru Chang†, Hui Wang, Kun Jing, Shengyu Dai* 

A Dual Steric Enhancement Strategy in α-Diimine Nickel and Palladium Catalysts for Ethylene Polymerization and Copolymerization

Organometallics 202241, 124–132. https://pubs.acs.org/doi/10.1021/acs.organomet.1c00568

[45] Huijun Fan†, Guanru Chang†, Huiqin Bi, Xu Gui, Hui Wang*, Guoyong Xu*, Shengyu Dai* 

Facile Synthesis of Hyperbranched Ethylene Oligomers and Ethylene-Methyl Acrylate Co-oligomers with Different Microscopic Chain Architectures

ACS Polymers Au20222, 88–96. (Invited Contributions, Highlighted by the Journal  in Tweet) https://doi.org/10.1021/acspolymersau.1c00039

2021 

[44] Weiqing Lu, Guoyong Xu, Guanru Chang*, Hui Wang*, Shengyu Dai*

Synthesis of Highly Branched Polyethylene and Ethylene-MA Copolymers Using Hybrid Bulky α-Diimine Pd(II) Catalysts

J. Organomet. Chem.2021, 953, 122118. https://doi.org/10.1016/j.jorganchem.2021.122118. (Communication)


[43] Zhou Lu, Hui Wang, Shuaikang Li , Shengyu Dai* 

Direct Synthesis of Various Polar Functionalized Polypropylene Materials with Tunable Molecular Weights and High Incorporation Ratios

Polym. Chem., 2021, 12, 5495–5504. https://doi.org/10.1039/D1PY01064F

[42] Lihua Guo*, Xueyan Hu, Weiqing Lu, Guoyong Xu, Qin Liu, Shengyu Dai*

Investigations of Ligand Backbone Effects on Bulky Diarylmethyl-based Nickel(II) and Palladium(II) Catalyzed Ethylene Polymerization and Copolymerization

J. Organomet. Chem.2021, 952, 122046. https://doi.org/10.1016/j.jorganchem.2021.122046

 [41] You Ge, Shuaikang Li, Hui Wang*, Shengyu Dai* 

Synthesis of Branched Polyethylene and Ethylene-MA Copolymers Using Unsymmetrical Iminopyridyl Nickel and Palladium Complexes

Organometallics 2021, 40, 3033-3041. https://pubs.acs.org/doi/10.1021/acs.organomet.1c00388.


[40] Zijuan Hai, Zhou Lu, Shuaikang Li, Zhong-Yan Cao*, Shengyu Dai*

Synergistic Effect of Rigid and Flexible Substituents in Insertion Polymerization with α-Diimine Nickel and Palladium Catalysts 

Polym. Chem. 2021, 12, 4643 - 4653. https://doi.org/10.1039/D1PY00812A

Synopsis:

The introduction of flexible cycloalkyl groups greatly enhanced the chain growth of the Ni(II) catalytic system and facilitated the insertion of polar monomers of Pd(II) catalytic system.

[39] 陆卫青,代胜瑜*  

亮点评述:中性不对称环番配位的烯烃聚合催化剂

Chin. J. Synth. Chem. 2021, 29, 902-903. (Invited Contributions)

[38] Zhengpeng Yan, Shuaikang Li,  Shengyu Dai*  

Synthesis and Characterization of Hyperbranched Polar Functionalized Olefin Oligomers

Chin. J. Synth. Chem. 2021, 29, 1033-1044. (Invited Contributions)

[37] Shengyu Dai*, Gen Li, Weiqing Lu, Yudan Liao*, Weigang Fan*

Suppression of Chain Transfer via Restricted Rotation Effect of Dibenzosuberyl Substituents in Polymerization Catalysis 

Polym. Chem., 2021, 12, 3240–3249(Front Cover) https://doi.org/10.1039/D1PY00333J



[36] You Ge, Shuaikang Li, Weigang Fan*, Shengyu Dai*

Flexible “Sandwich” (8-Alkylnaphthyl α-Diimine) Catalysts in Insertion Polymerization 

Inorg. Chem. 2021, 60, 5673−5681. https://doi.org/10.1021/acs.inorgchem.0c03715 

[35] Shuaikang Li, Yihua Zhao, Shengyu Dai*

Synthesis of PolyethyleneThermoplastic Elastomer by Using Robust α-Diimine Ni(II) Catalysts with Abundant tBu Substituents

J. Polym. Sci.202159, 638–645.   https://doi.org/10.1002/pol.20210017

[34] Shuaikang Li, Zhou Lu, Weigang Fan*, Shengyu Dai*

Efficient Incorporation of Polar Comonomer for Direct Synthesis of Hyperbranched Polar Functional Ethylene Oligomers.

New J. Chem., 2021, 45, 4024 - 4031.  (Top 10% of Highly Cited Articles in 2021https://doi.org/10.1039/D0NJ05857B.

[33] Hongwei Peng, Shuaikang Li, Gen Li, Shengyu Dai*, Mingjun Ji, Zhe Liu, Lihua Guo*

Rotation-Restricted Strategy to Synthesize High Molecular Weight Polyethylene Using Iminopyridyl Nickel and Palladium Catalyst.

Appl. Organomet. Chem., 2021, e6140. DOI: 10.1002/aoc.6140

[32] Yihua Zhao, Shuaikang Li,  Weigang Fan*, Shengyu Dai* 

Reversion of the Chain Walking Ability of α-Diimine Nickel and Palladium Catalysts with Bulky Diarylmethyl Substituents

J. Organomet. Chem.2021, 932, 121649. https://doi.org/10.1016/j.jorganchem.2020.121649.

[31] Chaoqun Wang, Xiaohui Kang, Shengyu Dai,† Fengchao Cui, Yunqi Li, Hongliang Mu, Stefan Mecking,* and Zhongbao Jian*

Efficient Suppression of Chain Transfer and Branching via Cs-Type Shielding in a Neutral Ni(II) Catalyst.

Angew. Chem. Int. Ed. 202160, 4018 –4022 https://doi.org/10.1002/anie.202013069

[30] Shuaikang Li, Shengyu Dai* 

Highly Efficient Incorporation of Polar Comonomers in Copolymerizations with Ethylene Using Iminopyridyl Palladium System.

J. Catal. 2021393,51–59. DOI: 10.1016/j.jcat.2020.11.015 (Highlighted by CBG)


2020 

[29] Shuaikang Li, Shengyu Dai* 

8-Arylnaphthyl Substituent Retarding Chain Transfer in Insertion Polymerization with Unsymmetrical α-Diimine Systems.

Poly. Chem. 202011, 7199 - 7206. DOI: 10.1039/D0PY01231A

[28] Gen Li, Guoyong XuYou Ge,  Shengyu Dai*

Synthesis of fluorinated polyethylene of different topologies via insertion polymerization with semifluorinated acrylates.

Poly. Chem. 2020, 11, 6335–6342. DOI: 10.1039/D0PY00993H.

[27] Gen Li, You Ge, Guoyong Xu*, Shengyu Dai*

The electronic effects on unsymmetrical Bis(imino)pyridyl iron(ii) catalyzed ethylene polymerization.

J. Organomet. Chem., 2020, 923, 121457. DOI: 10.1016/j.jorganchem.2020.121457

[26] Shengyu Dai, Changle Chen*.

A Self-Supporting Strategy for Gas-Phase and Slurry-Phase Ethylene Polymerization using Late-Transition-Metal Catalysts.

Angew. Chem. Int. Ed., 2020, 59, 14884–14890. DOI: 10.1002/anie.202004024

[25] Shengyu Dai*, Shuaikang Li.

Effect of aryl orientation on olefin polymerization in iminopyridyl catalytic system.

Polymer 2020, 200, 122607. DOI: 10.1016/j.polymer.2020.122607

[24] Shengyu Dai*, Shuaikang Li, Guoyong Xu, Changle Chen*

Direct Synthesis of Polar Functionalized Polyethylene Thermoplastic Elastomer.

Macromolecules 2020, 53, 2539−2546. DOI: 10.1021/acs.macromol.0c00083

ESI Highly Cited Paper.

[23] Shuaikang Li, Guoyong Xu, Shengyu Dai*

A remote nonconjugated electron effect in insertion polymerization with α-diimine nickel and palladium species.

Polym. Chem., 2020, 11, 2692–2699. DOI: 10.1039/D0PY00218F

 Polymer Chemistry Most Popular 2020 (31/762)

[22] Shengyu Dai*, Shuaikang Li, Guoyong Xu, Cheng Wu, Yudan Liao*, Lihua Guo*

Flexible Cycloalkyl Substituents in Insertion Polymerization with α-Diimine Nickel and Palladium Species.

Polym. Chem. 2020, 11, 1393 – 1400. DOI: 10.1039/C9PY01901D

 Polymer Chemistry Most Popular 2020 (31/762)


2019 

[21] Yanfeng Gong, Shuaikang Li, Chen Tan, Wenyu Kong, Shaojie Zhang*, Binyuan Liu*, Shengyu Dai*

π–π Interaction Effect in Insertion Polymerization with α-Diimine Palladium Systems.

J. Catal. 2019, 378, 184-191. DOI: 10.1016/j.jcat.2019.08.034

[20] Lihua Guo, Wenting Sun, Shuaikang Li, Guoyong Xu, Shengyu Dai*

Bulky yet flexible substituents in insertion polymerization with α-diimine nickel and palladium systems.

Polym. Chem. 2019, 10, 4866–4871. DOI: 10.1039/C9PY00857H.

[19] Lihua Guo, Shuaikang Li, Mingjun Ji, Wenting Sun, Wenjing Liu, Gen Li, Jingwen Zhang, Zhe Liu, Shengyu Dai*

Monoligated vs Bisligated Effect in Iminopyridyl Nickel Catalyzed Ethylene Polymerization. 

Organometallics 2019, 38, 2800−2806. DOI: 10.1021/acs.organomet.9b00325.

[18] Yanfeng Gong, Shuaikang Li, Qi Gong, Shaojie Zhang*, Binyuan Liu*, Shengyu Dai* 

Systematic Investigations of Ligand Steric Effects on α‑Diimine Nickel Catalyzed Olefin Polymerization and Copolymerization.

Organometallics 2019, 38, 2919−2926. DOI: 10.1021/acs.organomet.9b00267.

[17] Lihua Guo*, Wenjing Liu, Kun Li, Mengmeng Sun, Wenting Sun, Liping Zhao, Guorun Jiang, Hongwei Peng, Zhe Liu*, Shengyu Dai*

Synthesis of functional and hyperbranched ethylene oligomers using unsymmetrical α-diimine palladium catalysts. 

Eur. Polym. J. 2019115, 185-192. DOI: 10.1016/j.eurpolymj.2019.03.030.


2018 

[16] Lihua Guo*, Yanlan Liu, Kunbo Lian, Wenting Sun, Huaxia Zhu, Zhe Liu*, Xiaoyu Chen, Shengyu Dai*.

The Backbone Electronic Effects on Bis(imino)pyridyl Iron(II) Catalyzed Ethylene Polymerization.

Eur. J. Inorg. Chem. 2018, 4887-4892. DOI: 10.1002/ejic.201800908.

[15] Shengyu Dai, Changle Chen*.

Palladium-Catalyzed Direct Synthesis of Various Branched, Carboxylic-Acid-Functionalized Polyolefins: Characterization, Derivatization and Properties., 

Macromolecules 2018, 51, 6818–6824. DOI: 10.1021/acs.macromol.8b01261.

Monthly most read article in 2018/09. ESI Highly Cited Paper.

[14] Lihua Guo, Kunbo Lian, Wenyu Kong, Shuai Xu, Guorun Jiang, Shengyu Dai*.

Synthesis of Various Branched Ultra-High-Molecular-Weight Polyethylenes Using Sterically Hindered Acenaphthene-Based α-Diimine Ni(II) Catalysts.

Organometallics 2018, 37, 2442-2449. DOI: 10.1021/acs.organomet.8b00275.

[13] Yinna Na,# Shengyu Dai (co-first),# Changle Chen*.

Direct Synthesis of Polar-Functionalized Linear Low-Density Polyethylene (LLDPE) and Low-Density Polyethylene (LDPE). 

Macromolecules 201851, 4040-4048. DOI: 10.1021/acs.macromol.8b00467.

Monthly most read article in 2018/06. ESI Highly Cited Paper.

[12] Lihua Guo*, Wenyu Kong, Yanjian Xu, Yuliang Yang, Rui Ma, Li Cong, Shengyu Dai*, Zhe Liu*. 

Large-scale synthesis of novel sterically hindered acenaphthene-based α-diimine ligands and their application in coordination chemistry.

J. Organomet. Chem., 2018, 859, 58-67. DOI: 10.1016/j.jorganchem.2018.01.055.


在安徽大学之前

[11] Kunbo Lian, Yun Zhu, Weimin Li, Shengyu Dai *, Changle Chen*.

Direct Synthesis of Thermoplastic Polyolefin Elastomers from Nickel-Catalyzed Ethylene Polymerization.

Macromolecules 201750, 6074-6080. DOI: 10.1021/acs.macromol.7b01087

Monthly most read article in 2017/08 and 2017/09.

[10] Lihua Guo, Chen Zou, Shengyu Dai*, Changle Chen* 

Direct Synthesis of Branched Carboxylic Acid Functionalized Poly(1-octene) by α-Diimine Palladium Catalysts. 

Polymers, 20179, 122. DOI: 10.3390/polym9040122

Special Issue: Metal Complexes-Mediated Catalysis in Polymerization.

[9] Chen Zou, Shengyu Dai, Changle Chen*.

Ethylene Polymerization and Copolymerization using Nickel 2-Iminopyridine-N-oxide Catalysts: Modulation of Polymer Molecular Weights and Molecular-weight Distributions.

Macromolecules 2018, 51, 49–56. DOI: 10.1021/acs.macromol.7b02156

ESI Highly Cited Paper.

[8] Shengyu Dai, Shixin Zhou, Wen Zhang, Changle Chen*.

Systematic Investigations of Ligand Steric Effects on α-Diimine Palladium Catalyzed Olefin Polymerization and Copolymerization with Methyl Acrylate.

Macromolecules 2016, 49, 8855-8862. DOI: 10.1021/acs.macromol.6b02104

Monthly most read article in 2016/12 and 2017/01. ESI Highly Cited Paper.

[7] Shengyu Dai, Changle Chen*.

Direct Synthesis of Functionalized High-Molecular-Weight Polyethylene from the Copolymerization of Ethylene with Polar Monomers.

Angew. Chem. Int. Ed. 2016, 55, 13281-13285. DOI: 10.1002/anie.201607152

(Highlighted in Synfacts 2016, 12, 1252; Chin. J. Org. Chem. 2016, 36, 3005), ESI Highly Cited Paper.

[6] Lihua Guo, Shengyu Dai, Changle Chen*.

Investigations of the Ligand Electronic Effects on α-diimine Nickel(II) Catalyzed Ethylene Polymerization.

Polymers 2016, 8, 37. DOI: 10.3390/polym8020037

[5] Xiaohui Hu, Shengyu Dai, Changle Chen*.

Ethylene Polymerization by Salicylaldimine Nickel(II) Complexes Containing Dibenzhydryl Moiety.

Dalton Trans. 2016, 45, 1496-1503. DOI: 10.1039/c5dt04408a

[4] Shengyu Dai, Xuelin Sui, Changle Chen*.

Synthesis of High Molecular Weight Polyethylene Using Iminopyridyl Nickel Catalysts.

Chem. Commun. 2016, 52, 9113-9116. DOI: 10.1039/c6cc00457a

Special Issue: 2016 Emerging Investigators. 

[3] Lihua Guo, Shengyu Dai, Xuelin Sui, Changle Chen*.

Palladium and Nickel Catalyzed Chain Walking Olefin Polymerization and Copolymerization.

ACS Catal. 2016, 6, 428-441. DOI: 10.1021/acscatal.5b02426

Monthly most read article in 2016/01 and 02. ESI Highly Cited Paper and ESI Hot Paper.

[2] Xuelin Sui, Shengyu Dai, Changle Chen*.

Ethylene Polymerization and Copolymerization with Polar Monomers by Cationic Phosphine Phosphonic Amide Palladium Complexes.

ACS Catal. 2015, 5, 5932-5937. DOI: 10.1021/acscatal.5b01490

[1] Shengyu Dai, Xuelin Sui, Changle Chen*.

Highly Robust Palladium(II) α-Diimine Catalysts for Slow-Chain-Walking Polymerization of Ethylene and Copolymerization with Methyl Acrylate.

Angew. Chem. Int. Ed. 2015, 54, 9948-9953. DOI: 10.1002/anie.201503708

(Highlighted in New Chemical Materials 2015, 11, 245.) ESI Highly Cited Paper.