Publications

2023

S-o-(p-Methoxyphenylethynyl)benzyl (SMPEB) Glycosides for Catalytic Glycosylation and Their Application in the Synthesis of Polyporus Umbellatus Polysaccharides

 

• Jincai Wang
• , 
• Xinguang Lan
• , 
• Shuangshuang Zhang
• , 
• Chenglin Cai
• , 
• Qi Zhang
• , 
• Yingle Feng*
• , and 
• Yonghai Chai*. Org. Lett. 2023, 25, 33, 6116–6121.

Photosensitive Fluorous Tag-Assisted Convergent Synthesis of β-1,4-Mannuronates

• Yingle Feng*
, 
• Jie Yang
, 
• Xueqing Fan
, 
• Qi Zhang
, and 
• Yonghai Chai*. 
Org. Lett. 2023, 25, 19, 3548–3552.

Tf₂O/TfOH catalytic glycosylation using o-(p-methoxyphenylethynyl) benzyl glycosides as donors and its application in synthesis of oligosaccharides 

Xinguang Lan, Chenglin Cai, Jincai Wang, Qi Zhang, Yingle Feng*, Yonghai Chai*. Tetrahedron Lett. 10.1016/j.tetlet.2023.154342

2022

Ni(II)-Catalyzed Regio- and Stereoselective O-Alkylation for the Construction of 1,2-cis-Glycosidic Linkages

• Yingle Feng*
, 
• Tiantian Guo
, 
• Han Yang
, 
• Guoqiang Liu
, 
• Qi Zhang
, 
• Shengyong Zhang
, and 
• Yonghai Chai*. 
Org. Lett. 2022, https://doi.org/10.1021/acs.orglett.2c02419

Insights into the Activation of Alkyne-Installed Glycosyl Donors with Dual Acidic Metal Catalysts: Reaction Pathway, Influencing Factors, and Enlightenment for Glycosylation

• Chenglin Cai
, 
• Xingchun Sun
, 
• Yingle Feng
, 
• Qi Zhang*
, and 
• Yonghai Chai*. 
Org. Lett. 2022, https://doi.org/10.1021/acs.orglett.2c02338 

Catalytic and highly stereoselective β-mannopyranosylation using a 2,6-lactone-bridged mannopyranosyl ortho-hexynylbenzoate as donor

Yingle Feng*, Jie Yang , Chenglin Cai, Taotao Sun, Qi Zhang, Yonghai Chai*. Chin. Chem. Lett. 2022, 33, 4878-4881.

Photolabile 2-(2-Nitrophenyl)-propyloxycarbonyl (NPPOC) for Stereoselective Glycosylation and Its Application in Consecutive Assembly of Oligosaccharides

Jincai Wang, Yingle Feng*, Taotao Sun, Qi Zhang, and Yonghai Chai*. J. Org. Chem. 2022, 87, 3402–3421.

2021

Structurally Diverse Synthesis of Five-, Six-, and Seven-Membered Benzosultams through Electrochemical Cyclization.

• Aiyun Liu
, 
• Tiantian Guo
, 
• Shuangshuang Zhang
, 
• Han Yang
, 
• Qi Zhang*
, 
• Yonghai Chai*
, and 
• Shengyong Zhang*.Org. Lett. 2021, 23, 16, 6326–6331.

2020

Environmentally Benign Access to Isoindolinones: Synthesis, Separation and Resource Recycling. 

Weiwei Guo, Qi Zhang, Yang Cao, Kaihua Cai, Shengyong Zhang*, and Yonghai Chai*. Green Chem. 2020, 22, 2873-2878.

Fast and Low-Cost Purification Strategy for Oligosaccharide Synthesis Based on a Hop-On/Off Carrier.

Yingle Feng, Jingjing Wu, Guosong Chen*, and Yonghai Chai*. Org. Lett. 2020, 22, 2564−2568.

2019

n-Pentenyl-Type Glycosides for Catalytic Glycosylation and Their Application in Single-Catalyst One-Pot Oligosaccharide Assemblies.

Yujia Zu^†, Chenglin Cai^†, Jingyuan Sheng, Lili Cheng, Yingle Feng, Shengyong Zhang, Qi Zhang*, and Yonghai Chai*. Org. Lett. 2019, 21, 8270−8274.

Stereoselective β‐Mannosylation with 2,6‐Lactone‐bridged Thiomannosyl Donor by Remote Acyl Group Participation.

Huanfang Xu^†,  Long Chen^†, Qi Zhang, Yingle Feng, Yujia Zu, and Yonghai Chai*. Chem. - Asian J. 2019, 14, 1424-1428.

Tuning the Chemoselectivity of Silyl Protected Rhamnals by Temperature and Brønsted Acidity: Kinetically Controlled 1,2-Addition vs Thermodynamically Controlled Ferrier Rearrangement.

Jincai Wang, Chuqiao Deng, Qi Zhang*, and Yonghai Chai*. Org. Lett. 2019, 21, 1103−1107.

Diverse synthesis of pyrimido[1,2-a]benzimidazoles and imidazo[2,1-b]benzothiazoles via CuI-catalyzed decarboxylic multicomponent reactions of heterocyclic azoles, aldehydes and alkynecarboxylic acids.

Jiarong Wu^† , Huan Luo^†, Tao Wang , Huaming Sun , Qi Zhang*, and Yonghai Chai*. Tetrahedron 2019, 75, 1052-1063.

2018

Organo-Catalyzed Regio- and Geometry-Specific Construction of β-Hydroxyl-α-vinyl Carboxylic Esters: Substrate Scope, Mechanistic Insights, and Applications.

Yonghai Chai*, JinJin Zhou, Yanbin Wu, Yingle Feng, Panru Wang, Yange Chen, Xinying Wang, Beibei Zhao, and Qi Zhang*. J. Org. Chem. 2018, 83, 10476−10486.

2017

Recyclable benzyl-type fluorous tags: Preparation and application in oligosaccharide synthesis

YongHai Chai*, Ying Le Feng, Jing Jing Wu, Chu Qiao Deng, Ai-Yun Liua, Qi Zhang,* Chin. Chem. Lett. 2017, 28, 1693-1700.

Metal‐Free Synthesis of Pyrazoles from 1,3‐Diarylpropenes and Hydrazines via Multiple Inter‐/Intramolecular C–H Aminations.

Li Tang, Minyan Ma, Qi Zhang*, Huan Luo, Tao Wang, and Yonghai Chai*. Adv. Synth. Catal. 2017, 359, 2610 –2620.

Synthesis of the ABC Tricyclic System of Daphnicyclidin A.

Jianlong Li,† Hongwei Shi,† Qi Wang, Yonghai Chai, and Jun Yang*. Org. Lett. 2017, 19, 1497−1499.

2016

Cascade reaction of propargylic alcohols with hydroxylamine hydrochloride: facile synthesis of α,β-unsaturated oximes and nitriles.

Qi Zhang*, Linjing Zhang, Chaojun Tang, Huan Luo, Xuediao Cai, and Yonghai Chai*. Tetrahedron 2016, 72, 6935-6942.

Transition‐Metal‐Free Synthesis of 1,3‐Butadiene‐Containing π‐Conjugated Polymers.

Xuediao Cai,* Yating Liu, Tian Lu, Rui Yang, Chuxin Luo, Qi Zhang, and Yonghai Chai*. Macromol. Rapid Commun. 2016, 37, 2005−2010.

Biodegradation of patulin by a Byssochlamys nivea strain.

Xiaorui Zhang, Yurong Guo*, Yu Ma, Yonghai Chai, and Yangyang Li. Food Control, 2016, 64, 142-150.

2015

Efficient Large Scale Syntheses of 3-Deoxy-d-manno-2-octulosonic acid (Kdo) and Its Derivatives.

Yingle Feng, Jie Dong, Fangyuan Xu, Aiyun Liu, Li Wang, Qi Zhang, and Yonghai Chai*. Org. Lett. 2015, 17, 2388−2391.

Mild and Selective Deprotection of tert-Butyl(dimethyl)silyl Ethers with Catalytic­ Amounts of Sodium Tetrachloroaurate(III) Dihydrate.

Qi Zhang*, Xiuqin Kang, Lei Long, Lijuan Zhu, and Yonghai Chai*.  Synthesis 2015, 47, 55–64.

Diphenylprolinol silyl ether-derived thioureas as highly efficient catalysts for the asymmetric Michael addition of aldehydes to nitroalkenes.

Chunyan He, Xiaochen Ren, Yingle Feng, Yonghai Chai*, Shengyong Zhang, and Weiping Chen*. Tetrahedron Lett. 2015, 56, 4036–4038.

Novel ferrocene-based bifunctional amine–thioureas for asymmetric Michael addition of acetylacetone to nitroolefins.

Xiaochen Ren, Chunyan He, Yingle Feng, Yonghai Chai*, Wei Yao, Weiping Chen, and Shengyong Zhang*. Org. Biomol. Chem. 2015, 13, 5054-5060.

专利：

（1）双侧链苄基型氟载体及其应用。 柴永海；吴晶晶；冯颖乐；刘爱云；张琦。 专利号： ZL 2014105380632.2

（2）一种合成萘环衍生物和苯并杂环类化合物的方法。 柴永海；康磊；张敏；冯颖乐；吴晏兵；张琦。专利号：ZL 2014 10763995.7

（3）3-脱氧-D-甘露-2-辛酮糖酸铵盐的合成方法。柴永海；张琦；徐芳园；董洁；冯颖乐。 ZL 201210558246.1

（4）一种1，5-烯炔醇类化合物的合成方法及其应用。柴永海；祖瑜佳；盛靖园；程丽丽； 张琦。ZL 201410810658.9

（5）一种合成a-烯基-b-羟基酯类化合物的方法。柴永海；吴晏兵；周瑾瑾；康磊；冯颖乐； 陈艳鸽；王盼茹；徐阳；张琦。ZL 201410819813.3

（6）一种中药水蛭提取物及其用途。柴永海 ; 杨培民 ; 刘国飞 ; 邱学伟 ; 代龙 。ZL 201310097031.9

（7）棒曲霉素的制备方法。张晓瑞 ; 郭玉蓉 ; 柴永海 ; 马瑜。 ZL 201410408772.9

（8）扩展青霉FP2菌株及其应用。张晓瑞 ; 郭玉蓉 ; 马瑜 ; 柴永海。ZL 201410408759.3

（9）由7-羟基香豆素合成甘光草定的方法。柴永海；刘爱云；谢玉柔；张琦。中国，CN 109232603 A 20190118.

（10）一种在温和条件下制备卤代糖的方法，柴永海，郭建云，周华凤，王金财，杨静。中国，CN 111269279 A 2020-06-12.