张兵课题组主要面向水中氢高效催化利用,从分析反应过程入手,设计与合成催化材料,调控关键步骤与优化反应途径,结合多种原位谱学技术与计算模拟研究催化材料在反应过程中的动态结构演化与构效关系,实现耦合可再生能源的绿氢制备与高效电催化氢化,并探索其工业化应用。主要学术贡献如下:
(1) 发现了合成高效电解水析氢新材料和新方法,提出了无机材料结构调控以水为氢源的电催化氢化反应新策略,建立了有机电氧化耦合电还原析氢/氢化的新体系(部分成果获2012年度中国化学会青年化学奖和2023年度天津市自然科学一等奖)。
(2) 提出了水为氢源和氧源“空气电氧化合成硝酸”和“硝酸根电还原合成氨”的人工固氮的绿色新途径,发明了耦合电解水低温低压合成绿氨新方法与新技术。
(3) 创新了水为氢源的双组分电催化氢化-偶联新方法,以氮氧化物为氮源,实现了酰胺、肟和氨基酸等C–N键的构建。
近年来,张兵教授以通讯作者在Acc. Chem. Res.(2篇)、Nat. Rev. Chem.、Nat. Catal.(4篇)、Nat. Sustain.、Nat. Synth.等期刊发表论文,包括2篇J. Am. Chem. Soc.外封面等。相关论文得到诺贝尔化学奖得主等学者在Science、Nat. Chem.、Nat. Rev. Chem.、Nat. Rev. Mater.等期刊上的正面引用和评价,近五年他引20000余次,单篇最高他引2900余次。
收到Acc. Chem. Res.、Nat. Rev. Chem.、Nat. Catal.、Nat. Synth.等期刊的约稿。此外,培养了国家四青人才、全国博新计划入选者等一批优秀青年人才,多名毕业研究生和博士后在重点院校任教授/研究员、副教授及企事业单位工作(详见往届成员:https://www.x-mol.com/groups/bzhangtju/people/8565)。
主要科研进展时间表如下:
2024
Cuibo Liu, Fanpeng Chen, Bohang Zhao, Yongmeng Wu, Bin Zhang*, Electrochemical Hydrogenation and Oxidation of Organic Species involving Water, Nature Reviews Chemistry 2024, 8(4), 277–293. https://doi.org/10.1038/s41570-024-00589-z
Yuting Wang, Bin Zhang*, Solid Electrolyte Reactor for Nitrate-to-Ammonia, Nature Catalysis 2024, 7(9), 959–960. https://doi.org/10.1038/s41929-024-01223-3
Bohang Zhao, Bin Zhang*, Electrochemistry-Inspired Design of Thermocatalysts, Nature Catalysis 2024, 7(3), 229–230. https://doi.org/10.1038/s41929-024-01128-1
Cuibo Liu, Ying Gao, Bin Zhang*, Organonitrogen Electrosynthesis from CO2 and Nitrogenous Sources in Water, Nature Synthesis 2024, 3(7), 794–796. https://doi.org/10.1038/s44160-024-00550-4
Meng He, Rui Li, Chuanqi Cheng, Cuibo Liu*, Bin Zhang*, Microenvironment Regulation Breaks the Faradaic Efficiency-Current Density Trade-Off for Electrocatalytic Deuteration using D2O, Nature Communications 2024, 15, 5231. https://doi.org/10.1038/s41467-024-49544-y
Fanpeng Chen, Li Li, Chuanqi Cheng, Yifu Yu, Bo-Hang Zhao*, Bin Zhang*, Ethylene Electrosynthesis from Low-Concentrated Acetylene via Concave-Surface Enriched Reactant and Improved Mass Transfer, Nature Communications 2024, 15, 5914. https://doi.org/10.1038/s41467-024-50335-8
Nannan Meng, Zhitan Wu,Yanmei Huang, Jie Zhang, Maoxin Chen, Haibin Ma, Shuhe Han, Hongjiao Li*, Shibo Xi, Ming Lin, Wenya Wu, Yifu Yu, Quan-Hong Yang, Bin Zhang*, Kian Ping Loh*, High Yield Oxygenates Electrosynthesis from CO using a Relay Cu-Ag Co-Catalyst System, Nature Communications 2024, 15, 3892. https://doi.org/10.1038/s41467-024-48083-w
Junwei Yao, Rong Yang, Cuibo Liu, Bohang Zhao, Bin Zhang*, Yongmeng Wu*, Alkynes Electrooxidation to α,α-Dichloroketones in Seawater with Natural Chlorine Participation via Competitive Reaction Inhibition and Tip-Enhanced Reagent Concentration, ACS Central Science 2024, 10(1), 155–162. https://doi.org/10.1021/acscentsci.3c01277
Ying Gao, Mingming Yan, Chuanqi Cheng, Hao Zhong, Bohang Zhao, Cuibo Liu, Yongmeng Wu, Bin Zhang*, Membrane-Free Electrosynthesis of Epichlorohydrin Mediated by Bromine Radicals over Nanotips, Journal of the American Chemical Society 2024, 146(1), 714–722. https://doi.org/10.1021/jacs.3c10585
Jinying Meng, Chuanqi Cheng, Yuting Wang*, Yifu Yu*, Bin Zhang*, Carbon-Support Enhanced Mass Transfer and Metal-Support Interaction Promoted Activation for Low-Concentrated Nitric Oxide Electroreduction to Ammonia, Journal of the American Chemical Society 2024, 146(14), 10044–10051. https://doi.org/10.1021/jacs.4c00898
Kaiwen Yang, Shuhe Han, Chuanqi Cheng, Chengying Guo, Tieliang Li, Yifu Yu*, Unveiling the Reaction Mechanism for Nitrate Reduction to Ammonia over Cobalt-based Electrocatalysts, Journal of the American Chemical Society 2024, 146( 19), 12976–12983. https://doi.org/10.1021/jacs.3c13517
Rong Yang, Yuting Wang, Hongjiao Li, Jin Zhou, Zeyuan Gao, Cuibo Liu, Bin Zhang*, Descriptor-Based Volcano Relations Predict Single Atoms for Hydroxylamine Electrosynthesis, Angewandte Chemie International Edition 2024, 63(14), e202317167. (VIP) https://doi.org/10.1002/anie.202317167
Yue Xu, Chuanqi Cheng, Jiewei Zhu, Bin Zhang, Yuting Wang*, Yifu Yu*, Sulphur-Boosted Active Hydrogen on Copper for Enhanced Electrocatalytic Nitrate-to-Ammonia Selectivity, Angewandte Chemie International Edition 2024, 63(16), e202400289. https://doi.org/10.1002/anie.202400289
Biwen Wang, Jiahao Ma, Rong Yang, Bocheng Meng, Xiubo Yang, Qiuyu Zhang*, Bin Zhang*, Sifei Zhuo*, Bridging Ni-MOF and Cu Single Atoms/Clusters with H-Substituted Graphdiyne for the Tandem Catalysis of Nitrate to Ammonia, Angewandte Chemie International Edition 2024, 63(30), e202404819. (Hot Paper) https://doi.org/10.1002/anie.202404819
Yuting Wang, Yue Xu, Chuanqi Cheng, Baoshun Zhang, Bin Zhang, Yifu Yu*, Phase-Regulated Active Hydrogen Behavior on Molybdenum Disulfide for Electrochemical Nitrate-to-Ammonia Conversion, Angewandte Chemie International Edition 2024, 63(4), e202315109. https://doi.org/10.1002/anie.202315109
Qingqing Ruan, Shanshan Lu, Jiaqi Wu, Yanmei Shi*, Bin Zhang, Structural Degradation of M–N–C (M=Co, Ni and Fe) Single-Atom Electrocatalysts at Industrial-Grade Current Density for Long-Term Reduction, Angewandte Chemie International Edition 2024, 63(35), e202409000. https://doi.org/10.1002/anie.202409000
Shanshan Lu, Zhipu Zhang, Chuanqi Cheng, Bin Zhang, Yanmei Shi*, Unveiling the Aggregation of M−N−C Single-Atoms into Highly Efficient MOOH Nanoclusters during Alkaline Water Electroxidation, Angewandte Chemie International Edition 2024, 63(x), e202413308. https://doi.org/10.1002/anie.202413308
Ziyang Song, Rong Yang, Xinyu Liu, Bin Zhang*, Yongmeng Wu*, An Organic Molecular Mimetic Metal-Free Heterogeneous Catalyst for Electrocatalytic Alkyne Semihydrogenation, Angewandte Chemie International Edition 2024, 63(42), e202410200. (Hot Paper) https://doi.org/10.1002/anie.202410200
Chuanqi Cheng, Fanpeng Chen, Bin Zhang*, Bo-Hang Zhao*, Xiwen Du*, Promoting Water Dissociation and Weakening Active Hydrogen Adsorption to Boost the Hydrogen Transfer Reaction over a Cu-Ag Superlattice Electrocatalyst, Angewandte Chemie International Edition 2024, 63(x), e202413897. (Hot Paper) https://doi.org/10.1002/anie.202413897
Linke Cai, Yao Liu, Ying Gao, Bo-Hang Zhao, Jiacheng Guan, Xiao Liu, Bin Zhang*, Yi Huang*, Atomically Asymmetrical Ir–O–Co Sites Enable Efficient Chloride-Mediated Ethylene Electrooxidation in Neutral Seawater, Angewandte Chemie International Edition 2024, 63(x), e202417092. (VIP) https://doi.org/10.1002/anie.202417092
Rong Yang, Yuting Wang*, Bin Zhang*, Regulating Spin Magnetization for Enhanced Ammonia Production, Joule 2024, 8(6), 1562–1566. https://doi.org/10.1016/j.joule.2024.05.017
Ying Gao, Bin Zhang*, Direct Electrochemical Propylene Epoxidation Driven by Water-Activation Intermediates, Chem 2024, 10(3), 761–763. https://doi.org/10.1016/j.chempr.2024.01.029
Ying Gao, Bin Zhang*, Bromine-Mediated Membrane-Free Electrooxidation Reactions in Water, Science Bulletin 2024, 69(11), 1595–1597. https://doi.org/10.1016/j.scib.2024.03.058
Bo-Hang Zhao*, Bin Zhang*, Heterocatalytic Ethylene Methoxycarbonylation via a Pseudo-Hydride Pathway over Pt1/MoS2, Science China Chemistry 2024, 67(8), 2427–2428. https://doi.org/10.1007/s11426-024-1939-6
Baoshun Zhang, Wangyang Ji, Jiewei Zhu, Baian Shen, Menghao Lv, Bin Zhang, Tihu Wang, Yifu Yu*, A Perspective to Ammonia-Hydrogen Energy Industry in China, Science China Chemistry 2024, 67(6), 1765–1775. https://doi.org/10.1007/s11426-024-2046-0
Zhaole Lu, Rong Yang, Yingchao Yu, Yuting Wang, Bin Zhang*, Lingjun Kong*, Boosting Active Hydrogen Generation by Anchored Ru Sites in Co3O4 for Nitrate-to-Ammonia Electrosynthesis, Chem Catalysis 2024, accept. https://doi.org/10.1016/j.checat.2024.101152
2023
Cuibo Liu, Yongmeng Wu, Bohang Zhao, Bin Zhang*, Designed Nanomaterials for Electrocatalytic Organic Hydrogenation using Water as the Hydrogen Source, Accounts of Chemical Research 2023, 56(13), 1872–1883. https://doi.org/10.1021/acs.accounts.3c00192
Bohang Zhao, Fanpeng Chen, Mengke Wang, Chuanqi Cheng, Yongmeng Wu, Cuibo Liu, Yifu Yu, Bin Zhang*, Economically Viable Electrocatalytic Ethylene Production with High Yield and Selectivity, Nature Sustainability 2023, 6(7), 827–837. https://doi.org/10.1038/s41893-023-01084-x
Mengyang Li, Yongmeng Wu, Bohang Zhao, Chuanqi Cheng, Jinghui Zhao, Cuibo Liu, Bin Zhang*, Electrosynthesis of Amino Acids from NO and α-Keto Acids using Two Decoupled Flow Reactors, Nature Catalysis 2023, 6(10), 906–915. https://doi.org/10.1038/s41929-023-01012-4
Shuhe Han, Hongjiao Li, Tieliang Li, Fanpeng Chen, Rong Yang, Yifu Yu*, Bin Zhang*, Ultralow Overpotential Nitrate Reduction to Ammonia via a Three-Step Relay Mechanism, Nature Catalysis 2023, 6(5), 402–414. https://doi.org/10.1038/s41929-023-00951-2
Shanshan Lu, Chuanqi Cheng, Yanmei Shi*, Yongmeng Wu, Zhipu Zhang, Bin Zhang*, Unveiling the Structural Transformation and Activity Origin of Heteroatom-Doped Carbons for Hydrogen Evolution, Proceedings of the National Academy of Sciences (PNAS) 2023, 120(20), e2300549120. https://doi.org/10.1073/pnas.2300549120
Meng He, Yongmeng Wu*, Rui Li, Yuting Wang, Cuibo Liu, Bin Zhang*, Aqueous Pulsed Electrochemistry Promotes C–N Bond Formation via a One-Pot Cascade Approach, Nature Communications 2023, 14, 5088. https://doi.org/10.1038/S41467-023-40892-9
Yongmeng Wu*, Jinghui Zhao, Changhong Wang, Tieliang Li, Bohang Zhao, Ziyang Song, Cuibo Liu, Bin Zhang*, Electrosynthesis of a Nylon-6 Precursor from Cyclohexanone and Nitrite under Ambient Conditions, Nature Communications 2023, 14, 3057. https://doi.org/10.1038/s41467-023-38888-6
Yanmei Huang, Caihong He, Chuanqi Cheng, Shuhe Han, Meng He, Yuting Wang, Nannan Meng, Bin Zhang, Qipeng Lu*, Yifu Yu*, Pulsed Electroreduction of Low-Concentration Nitrate to Ammonia, Nature Communications 2023, 14, 7368. https://doi.org/10.1038/s41467-023-43179-1
Shuyan Han, Chuanqi Cheng, Meng He, Rui Li, Ying Gao, Yifu Yu, Bin Zhang*, Cuibo Liu*, Preferential Adsorption of Ethylene Oxide on Fe and Chlorine on Ni Enabled Scalable Electrosynthesis of Ethylene Chlorohydrin, Angewandte Chemie International Edition 2023, 62(13), e202216581. (VIP) (Editors' Choice: Spotlights) https://doi.org/10.1002/anie.202216581
Jin Zhou, Shuhe Han, Rong Yang, Tieliang Li, Wenbin Li, Yuting Wang, Yifu Yu*, Bin Zhang*, Linear Adsorption Enables NO Selective Electroreduction to Hydroxylamine on Single Co Sites, Angewandte Chemie International Edition 2023, 62(27), e202305184. (VIP) https://doi.org/10.1002/anie.202305184
Tieliang Li, Shuhe Han, Yuting Wang, Jin Zhou, Bin Zhang, Yifu Yu*, A Spectroscopic Study on Nitrogen Electrooxidation to Nitrate, Angewandte Chemie International Edition 2023, 62(19), e202217411. (Hot Paper) https://doi.org/10.1002/anie.202217411
Huaifang Zhang, Yanbo Li, Chuanqi Cheng, Jin Zhou, Pengfei Yin, Haoming Wu, Zhiqin Liang, Jiangwei Zhang, Qinbai Yun, An-Liang Wang, Lijie Zhu, Bin Zhang, Wenbin Cao, Xiangmin Meng, Jing Xia*, Yifu Yu*, Qipeng Lu*, Isolated Electron-Rich Ruthenium Atoms in Intermetallic Compounds for Boosting Electrochemical Nitric Oxide Reduction to Ammonia, Angewandte Chemie International Edition 2023, 62(4), e202213351. https://doi.org/10.1002/anie.202213351
Jiewei Zhu, Jiang Shao, Bai-An Shen, Jixiang Chen, Yifu Yu, Shuyan Song, Xin-Bo Zhang, Bin Zhang*, Bohang Zhao*, Formamide Electrosynthesis from Methanol and Ammonia in Water over Pr-Doped MnO2, JACS Au 2023, 3(11), 2987–2992. https://doi.org/10.1021/jacsau.3c00537
Ziyang Song, Chuanqi Cheng, Changhong Wang, Junwei Yao, Cuibo Liu, Bin Zhang*, Yongmeng Wu*, Interstitial Modification of Palladium Nanocubes with Nitrogen Atoms Promotes Aqueous Electrocatalytic Alkyne Semihydrogenation, ACS Materials Letters 2023, 5(11), 3068–3073. https://doi.org/10.1021/acsmaterialslett.3c00944
Bohang Zhao*, Fanpeng Chen, Chuanqi Cheng, Li Li, Cuibo Liu, Bin Zhang*, C60-Stabilized Cu+ Sites Boost Electrocatalytic Reduction of CO2 to C2+ Products, Advanced Energy Materials 2023, 13(19), 2204346. (Hot Topic: C–C Coupling). https://doi.org/10.1002/aenm.202204346
Bao Shun Zhang, Yuting Wang, Na Zhang, Jiewei Zhu, Wangyang Ji, Fanpeng Chen, Xing Chen, Yifu Yu*, Bin Zhang*, Electromagnetic Field-Assisted Low-Temperature Ammonia Synthesis, Science Bulletin, 2023, 68(17), 1871–1874. https://doi.org/10.1016/j.scib.2023.07.037(Highlighted by Prof. Hideo Hosono "Field-assisted green ammonia synthesis" in Sci. Bull., https://doi.org/10.1016/j.scib.2023.10.001)
Yongmeng Wu, Jinghui Zhao, Bin Zhang*, Electrochemical C–S Bond Construction from CO2 and an Inorganic Sulfur Source, Science Bulletin 2023, 68(14), 1466–1468. (Highlight) https://doi.org/10.1016/j.scib.2023.06.035
Xianen Lan, Chuanqi Cheng, Chengying Guo, Minghao Guo, Tieliang Li, Yongmeng Wu*, Yifu Yu*, Bin Zhang*, Electrosynthesis of Hydroxylamine from Nitrate Reduction in Water, Science China Chemistry 2023, 66(6), 1758–1762. https://doi.org/10.1007/s11426-023-1580-2
Yongmeng Wu, Mengyang Li, Tieliang Li, Jinghui Zhao, Ziyang Song, Bin Zhang*, Electrosynthesis of 15N-Labeled Amino Acids from 15N-Nitrite and Ketonic Acids, Science China Chemistry 2023, 66(6), 1854–1859. https://doi.org/10.1007/s11426-023-1613-x
Shanshan Lu, Zhipu Zhang, Bin Zhang, Yanmei Shi,* Insight into the Change in Local pH near the Electrode Surface Using Phosphate Species as the Probe, Journal of Physical Chemistry Letters 2023, 14, 10457–10462. https://doi.org/10.1021/acs.jpclett.3c02919
Kaiwen Yang, Shuhe Han, Yuting Wang*, Bin Zhang, Yifu Yu*, Sustainable Production and In-Place Utilization of a Liquid Nitrogenous Fertilizer, Joule 2023, 7(9), 1948–1955. https://doi.org/10.1016/j.joule.2023.07.020
2022
2021
2012–2019 selected papers