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成果及论文

34.  Yingtao Wu, Xin Guan, Kehan Jiao, Huaqiu Zhao, Mingrui Li, Jiaqiong Sun, Guangfan Zheng * and Qian Zhang 

Synthesis of axially chiral thiourea by NHC-catalyzed desymmetrizative amidation

Green Chem., 2024DOI: 10.1039/D4GC03113J.


33.  Mingrui Li, Yingtao Wu, Xiao Song, Jiaqiong Sun,* Zuxiao Zhang, Guangfan Zheng* and Qian Zhang

Visible Light-Mediated Organocatalyzed 1,3-Aminoacylation of Cyclopropane Employing N-benzoyl Saccharin as Bifunctional Reagent

Nat. Commun., 2024, DOI : 10.1038/s41467-024-53202-8


 

32.  Jiuli Xia, # Ruiyang Ma, # Lihong Wang, # Jiaqiong Sun, * Guangfan Zheng * and Qian Zhang

NHCs and Photoredox Catalysis Dual-Catalyzed 1,4-Mono-/di-fluoromenthylative Acylation of 1,3-Enynes

Org. Chem. Front., 2024DOI: 10.1039/D4QO00372A.

31. Shengbo Xu,  Rui-Jie Mi,  Guangfan Zheng*  and  Xingwei Li*  

Cobalt- or Rhodium-Catalyzed Synthesis of 1,2-Dihydrophosphete Oxides via C–H Activation and Formal Phosphoryl Migration

Chem. Sci., 2024; https://doi.org/10.1039/D4SC00649F


30.  Yingtao Wu, Xin Guan, Huaqiu Zhao, Mingrui Li, Tianlong Liang, Jiaqiong Sun, Guangfan Zheng*  and Qian Zhang*  

Synthesis of Axially Chiral Diaryl Ethers via NHCs-Catalyzed Atroposelective Esterification

Chem. Sci.,  2024; https://doi.org/10.1039/D3SC06444A


29.  Jiuli Xia, Yunliang Guo, Zhiguang Lv, Jiaqiong Sun*, Guangfan Zheng*, Qian Zhang

Visible Light-Mediated Monofluoromethylation/Acylation of Olefins by Dual Organo-Catalysis

Molecules 202429(4), 790; https://doi.org/10.3390/molecules29040790 (Invited Paper)



28.  Jiaqiong Sun#,*, Yunliang Guo#, Jiuli Xia, Guangfan Zheng* and Qian Zhang

Catalyst-Free Trans-Selective Oxyiodination and Oxychlorination of Alkynes Employing N–X (Halogen) Reagents

Molecules 202328(21), 7420; https://doi.org/10.3390/molecules28217420 (Invited Paper)



27. Jiaqiong Sun, Lihong Wang,  Guangfan Zheng, *  and Qian Zhang * 

Recent advances in three-component radical acylative difunctionalization of unsaturated carbon-carbon bonds.
Org. Chem. Front.2023, 10, 4488-4515. DOI: 10.1039/D3QO01010D (Invited Paper)


26. Tianlong Liang#, Yingtao Wu#, Jiaqiong Sun#, Mingrui Li,  Huaqiu Zhao,  Jingjing Zhang,  Guangfan Zheng, *  and Qian Zhang * 

Visible Light-Mediated Cobalt and Photoredox Dual-Catalyzed Asymmetric Reductive Coupling for Axially Chiral Secondary Alcohols

Chin. J. Chem. 2023,  41, 3253-3260. DOI: 10.1002/cjoc.202300398.




25.  Lihong Wang#, Jiaqiong Sun#, Jiuli Xia, Ruiyang Ma, Guangfan Zheng * and Qian Zhang

Visible light-mediated NHC and photoredox co-catalyzed 1,2-sulfonylacylation of allenes via acyl and allyl radical cross-coupling

Org. Chem. Front., 2023, 10, 1047–1055.  DOI: 10.1039/d2qo01993k(Invited Paper)


24. Lihong Wang#, Ruiyang Ma#, Jiuli Xia, Ximin Liu, Jiaqiong Sun*, Guangfan Zheng* and Qian Zhang

DBU-Mediated Isomerization/6-π Electro-Cyclization/Oxidation Cascade of Sulfonyl-Substituted Allenyl Ketones for the Construction of Hetero-1,3,5-Trisubstituted Benzene

Chem.Eur. J. 2023, 29, e202203309. DOI: 10.1002/chem.202203309(Invited Paper)


23. Yingtao Wu, Mingrui Li, Jiaqiong Sun, Guangfan Zheng*, Qian Zhang*

Synthesis of Axially Chiral Aldehydes by N-Heterocyclic-Carbene-Catalyzed Desymmetrization Followed by Kinetic Resolution

Angew. Chem., Int. Ed. 2022, 61, e202117340. DOI: 10.1002/anie.202117340.


22. Lihong Wang, Jiaqiong Sun, Jiuli Xia, Mingrui Li, Lianjin Zhang, Ruiyang Ma, Guangfan Zheng*, Qian Zhang*

Visible light-mediated NHCs and photoredox co-catalyzed radical 1,2-dicarbonylation of alkenes for 1,4-diketones

Sci. China Chem. 2022, 65, 1938–1944. DOI: 10.1007/s11426-022-1328-5.


21. Lihong Wang, Ruiyang Ma, Jiaqiong Sun, Guangfan Zheng*, Qian Zhang*

NHC and visible light-mediated photoredox co-catalyzed 1,4-sulfonylacylation of 1,3-enynes for tetrasubstituted allenyl ketones

Chem. Sci., 2022, 13, 3169-3175. DOI: 10.1039/d1sc06100c.


20. Jiaqiong Sun, Weiliang Yuan, Rong Tian, Peiyuan Wang, Xue-Peng Zhang,* and Xingwei Li* 

Rhodium(III)-Catalyzed Asymmetric [4+1] and [5+1] Annulation of Arenes and 1,3-Enynes: Distinct Mechanism of Allyl Formation and Allyl Functionalization. 

Angew. Chem. Int. Ed. 2020, 59, 22706-22713. DOI: 10.1002/anie.202010832.


19. Guangfan Zheng , Jiaqiong Sun , Youwei Xu , Xukai Zhou , Hui Gao* , Xingwei Li*

Rhodium(III)-catalyzed chelation-assisted C-H imidation of arenes via umpolung of the imidating reagent

Chin. J. Catal., 2020, 41, 1723–1733. DOI:10.1016/S1872-2067(20)63587-2.


18. Guangfan Zheng,# Zhi Zhou,# Guoxun Zhu,# Shuailei Zhai, Huiying Xu, Xujing Duan, Wei Yi,* Xingwei Li* 

Rhodium(III)-Catalyzed Enantio- and Diastereoselective C−H Cyclopropylation of N-Phenoxylsulfonamides: Combined Experimental and Computational Studies

Angew. Chem., Int. Ed. 2020, 59, 2890-2896. DOI: 10.1002/anie.201913794.


17. Jie Jiang, Dongmei Zhang, Hong Zhang, Kai Yu, Na Li,* Guangfan Zheng* 

Degradation Mechanism Study of Fluoroquinolones in UV/Fe2+/Peroxydisulfate by On-Line Mass Spectrometry 

Chemosphere, 2020, 239, 124737. DOI: 10.1016/j.chemosphere.2019.124737.


16. Guangfan Zheng,* Xujing Duan, Lu Chen, Jiaqiong Sun, Shuailei Zhai, Xiaojiao Li, Jierui Jing, Xingwei Li

Access to [4,3,1]-Bridged Carbocycles via Rhodium(III)-Catalyzed C−H Activation of 2-Arylindols and Annulation with Quinone Monoacetals 

J. Org. Chem. 2020, 85, 4543−4552. DOI: 10.1021/acs.joc.0c00018.


15. Dachang Bai, Jintao Xia, Fangfang Song, Xueyan Li, Bingxian Liu, Lihong Liu, Guangfan Zheng, Xifa Yang, Jiaqiong Sun*, Xingwei Li*

Rhodium(III)-Catalyzed Diverse [4+1] Annulation of Arenes with 1,3-Enynes via sp3/sp2 C-H Activation and 1,4-Rhodium Migration

Chem. Sci., 2019, 10, 3987–3993. DOI: 10.1039/C9SC00545E.


14. Jiaqiong Sun, Dachang Bai, Peiyuan Wang, Kuan Wang, Guangfan Zheng, Xingwei Li* 

Chemodivergent Oxidative Annulation of Benzamides and Enynes via 1,4-Rhodium Migration

Org. Lett. 2019, 21, 1789−1793.  DOI: 10.1021/acs.orglett.9b00363.


13.  Jiaqiong Sun, Kuan Wang, Peiyuan Wang, Guangfan Zheng,* and Xingwei Li* 

Rhodium(III)-Catalyzed Oxidative Allylic C−H Indolylation via Nucleophilic Cyclization 

Org. Lett. 2019, 21, 4662−4666. DOI: 10.1021/acs.orglett.9b01553.



12.  Peiyuan Wang, Youwei Xu, Jiaqiong Sun*, and Xingwei Li*

Rhodium(III)-Catalyzed Chemo-divergent Couplings of Sulfoxonium Ylides with Oxa/azabicyclic Olefins

Org. Lett. 2019, 21, 8459–8463. DOI: 10.1021/acs.orglett.9b03226.


11.  Xifa Yang, Guangfan Zheng,* Xingwei Li*

Rhodium(III)-Catalyzed Enantioselective Coupling of Indoles and 7-Azabenzonorbornadienes by C-H Activation/Desymmetrization

Angew. Chem., Int. Ed.  2019, 58, 322-326.  DOI: 10.1002/anie.201811998.


10. Guangfan Zheng, Jiaqiong Sun, Youwei Xu, Shuailei Zhai, Xingwei Li* 

Mn-Catalyzed Dehydrocyanative Transannulation of Heteroarenes and Propargyl Carbonates through C-H Activation: Beyond the Permanent Directing Effects of Pyridines/Pyrimidines.

Angew. Chem., Int. Ed. 2019, 58, 5090-5094. DOI: 10.1002/anie.201900166.


9. Guangfan Zheng, Miaomiao Tian, Youwei Xu, Xiaohong Chen, Xingwei Li*

Rhodium(III)-Catalyzed Annulative Coupling Between Arenes and Sulfoxonium Ylides via C–H Activation

Org. Chem. Front. 2018, 5, 998-1002.  DOI: 10.1039/c7qo01033h.


8. Jiaqiong Sun, Guangfan Zheng, Yongmei Fu, Lihong Wang, Yan Li* and Qian Zhang 

Copper-Catalyzed Cascade Aminoalkynylation-Oxidation of Pro-pargylic Alcohols: Stereospecific Synthesis of (Z)-2-Amino Conjugated Enynals/Enynones

Org. Lett. 2018, 20, 5597−5600. DOI: 10.1021/acs.orglett.8b02272.


7. Jiaqiong Sun, Guangfan Zheng, Yongmei Fu, Qiao Zhang, Yimin Wang, Qian Zhang, Yan Li* and Qian Zhang*

Copper-catalyzed tandem radical amination/1,2‐carbon migration of allylic alcohols: Direct access to α‐quaternary‐β‐amino ketones

Chin. J. Catal. 2018, 39, 138–145. DOI: 10.1016/S1872-2067(18)63028-1.


6. Guangfan Zheng, Jiaqiong Sun, Yang Liu, Shengbiao Yang, Yan Li,* Haizhu Sun,* Qian Zhang 

Copper-Catalyzed Azidative Multifunctionalization of Alkynes

J. Org. Chem. 2017, 82, 12813-12820. DOI: 10.1021/acs.joc.7b02148.


5. Jiaqiong Sun, Guangfan Zheng, Qiao Zhang, Yimin Wang, Shengbiao Yang, Qian Zhang, Yan Li*, and Qian Zhang*

Copper-Catalyzed Imidovinylation of Alkynes via 1,3-Vinyl Migration

Org. Lett. 2017, 19, 3767–3770. DOI: 10.1021/acs.orglett.7b01599.


4. Guangfan Zheng,# Jinbo Zhao,# Zhanyu Li, Qiao Zhang, Jiaqiong Sun, Haizhu Sun, Qian Zhang* 

Highly Regio- and Stereoselective Intermolecular Seleno- and Thioamination of Alkynes

Chem. Eur. J. 2016, 22, 3513-3518. DOI: 10.1002/chem.201504534.


3. Jiaqiong Sun, Guangfan Zheng, Tao Xiong, Qiao Zhang, Jinbo Zhao, Yan Li,* and Qian Zhang

Copper-Catalyzed Hydroxyl-Directed Aminoarylation of Alkynes

ACS Catal. 2016, 6, 3674−3678.  DOI: 10.1021/acscatal.6b00759.


2. Guangfan Zheng, Yan Li, Jingjie Han, Tao Xiong & Qian Zhang*

Radical cascade reaction of alkynes with N-fluoroarylsulfonimides and alcohols

Nat. Commun. 2015, 6, 7011. DOI: 10.1038/ncomms8011.


1. Jiaqiong Sun and Guangfan Zheng*

Chiral Cyclopentadienyl Ligand for Asymmetric C-H Activation

Handbook of CH-Functionalization, Edited by Debabrata Maiti, WILEY-VCH , 2023 DOI: 10.1002/9783527834242.chf0136.