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成果及论文

76.Vojtěch Dočekal, Mohand Melaimi, Simona Petrželová, Jan Veselý., Xiaoyu Yan and Guy Bertrand*, Synthesis of enantiopure 1,2,3-triazolylidene-type mesoionic carbene (MIC) conjugate acids featuring a rigid bicyclic scaffold. 

https://pubs.rsc.org/en/content/articlelanding/2024/qo/d4qo00269e


75.Mehdi Abdellaoui, Kai Oppel, Adam Vianna, Michele Soleilhavoup, Xiaoyu Yan, Mohand Melaimi*, and Guy Bertrand*, 1H-1,2,3-Triazol-5-ylidenes as Catalytic Organic Single-Electron Reductants. doi.org/10.1021/jacs.3c14360

https://pubs.acs.org/doi/full/10.1021/jacs.3c14360


74.Yedong Wang, Shiqing Huang, Zengyu Zhang, Xiaoyu Yan*. Synthesis and Photophysical Properties of Silole-Fused Cycloparaphenylenes. doi.org/10.1021/acs.joc.3c01323

https://pubs.acs.org/doi/full/10.1021/acs.joc.3c01323


73.Fan Gao, Zengyu Zhang, Xiaoyu Yan*. N-Heterocyclic Carbenes (NHCs)-Catalyzed Coupling Reactions of Aldehydes and Organic Halides. doi.org/10.1002/cctc.202301331

https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/cctc.202301331


72.Chen-Yuan Li, Zengyu Zhang, Xiaoyu Yan*. Ir-Catalyzed Ortho-Selective C–H Borylation of Difluoromethyl Arenes. doi.org/10.1021/acs.orglett.3c02308

https://pubs.acs.org/doi/abs/10.1021/acs.orglett.3c02308


71.Yiguang Qian, Ziyu Chen, Jiahui Wang, Man Peng, Shenghua Zhang, Xiaoyu Yan, Xiaole Han, Xiaohui Ou, Jie Sun, Siyue Li*, Ke Chen*. H/D Exchange Coupled with 2H-labeled Stable Isotope-Assisted Metabolomics Discover Transformation Products of Contaminants of Emerging Concern. doi.org/10.1021/acs.analchem.3c02833

https://pubs.acs.org/doi/full/10.1021/acs.analchem.3c02833


70.ChangLiu, ZengyuZhang, Liang-LiangZhao, Prof. Guy Bertrand*, Prof. Xiaoyu Yan*. Mesoionic Carbene-Catalyzed Formyl Alkylation of Aldehydes. doi.org/10.1002/anie.202303478

https://onlinelibrary.wiley.com/doi/full/10.1002/anie.202303478


69.Florian F. Mulks, Mohand Melaimi, XiaoyuYan*, Mu-Hyun Baik*, Guy Bertrand*. How To Enhance the Efficiency of Breslow Intermediates for SET Catalysis. doi.org/10.1021/acs.joc.2c02978

https://pubs.acs.org/doi/full/10.1021/acs.joc.2c02978


68.ShiqingHuang, Xiaoyu Yan*. Rational Design to Activate Tetrafluoromethane by Two-Coordinate Borinium. doi.org/10.1021/acs.inorgchem.2c03900

https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.2c03900


67.Supphachok Chanmungkalakul, ShiqingHuang, XiaWu, Esther Cai Xia Ang, Zi-QiYang, YongxinLi, XiaoyuYan, Choon-Hong Tan, Davin Tan*, XiaogangLiu*. Ground-state intramolecular proton transfer inhibits the selective methylation on quinoline and pyridine derivatives. doi.org/10.1039/D3CP00123G

https://pubs.rsc.org/en/content/articlelanding/2023/cp/d3cp00123g


66.ZengyuZhang, ShiqingHuang, Chen-YuanLi, Liang-LiangZhao, WeiLiu, Mohand Melaimi, Guy Bertrand*, XiaoyuYan*. The triplet state of deprotonated mesoionic carbene Breslow intermediates is thermally accessible: Distal difunctionalization of aldehydes. doi.org/10.1016/j.checat.2022.09.047

https://www.sciencedirect.com/science/article/abs/pii/S2667109322005395


65.YedongWang, YixinWu, ChangLiu, JingliZhang, Prof. Xiaoyu Yan*. Mechanofluorochromism of 2-Biarylyl Cinchoninic Acids with High Sensitivity and Large Mechanochromic Shift. doi.org/10.1002/asia.202200592

https://onlinelibrary.wiley.com/doi/full/10.1002/asia.202200592


64.ZhihaoXiang, ShiqingHuang, Liang-LiangZhao, ZengyuZhang, KeChen, WanqiangCao, KeyuZheng*, XiaoyuYan*. Base-catalyzed H/D exchange of polychlorinated biphenyls. doi.org/10.1016/j.tetlet.2022.154200

https://www.sciencedirect.com/science/article/pii/S0040403922006785


63.ZengyuZhang, Chen-Yuan Li, XiaoyuYan *. Mesoionic carbene-catalyzed arylacylation of alkenes. doi.org/10.1016/j.trechm.2022.06.001
https://www.sciencedirect.com/science/article/abs/pii/S2589597422001496


62.ZengyuZhang, ShiqingHuang, WeiLiu, Liang-LiangZhao, ChubinHu, XiaoyuYan *. Protecting-group-free ortho- C–H borylation of anilines enabled by mesoionic carbene-Ir complex. doi.org/10.1016/j.gresc.2022.05.006
https://www.sciencedirect.com/science/article/pii/S266655492200045X


61.Ke Chen*, Yuhui Xiang, Xiaoyu Yan, Zhenghui Li, Rui Qin, and Jie Sun. Global Tracking of Transformation Products of Environmental Contaminants by 2H-Labeled Stable Isotope-Assisted Metabolomics. doi.org/10.1021/acs.analchem.2c0050

https://pubs.acs.org/doi/abs/10.1021/acs.analchem.2c00500


60.Shiqing Huang,Yixin Wu,Linwei Huang,Chubin Hu,Prof. Xiaoyu Yan *. Synthesis, Characterization and Photophysical Properties of Mesoionic N-Heterocyclic Imines. doi.org/10.1002/asia.202200281
https://onlinelibrary.wiley.com/doi/10.1002/asia.202200281


59.Leiyang Lv *, Huijun Qian , Yangyang Ma , Shiqing Huang , Xiaoyu Yan and Zhiping Li *.Ligand-controlled Regioselective and Chemodivergent Defluorinative Functionalization of Gem-difluorocyclopropanes with Simple Ketones. Chem. Sci202112, 15511-15518
https://pubs.rsc.org/en/content/articlehtml/2021/sc/d1sc05451a


58.Liang-Liang Zhao, Yixin Wu, Shiqing Huang, Zengyu Zhang, Wei Liu, and Xiaoyu Yan*.Ortho-Selective Hydrogen Isotope Exchange of Phenols and Benzyl Alcohols by Mesoionic Carbene-Iridium Catalyst. Org. Lett2021, 23, 23, 9297–9302

https://pubs.acs.org/doi/10.1021/acs.orglett.1c03685


57.Chubin Hu,Shiqing Huang,Zengyu Zhang,Haidan Yao,Yixin Wu,Linwei Huang,Prof. Xiaoyu Yan*.Experimental and Computational Study on Photophysical Properties of Mesoionic Chalcogenones. Chem Asian J202116, 4165-4170
https://onlinelibrary.wiley.com/doi/abs/10.1002/asia.202101157


56. Hongyan Zhao, Linwei Huang, Yedong Wang, Kai Feng, Yunhao Chang, Shiqing Huang, Chenxing Ma, and Xiaoyu Yan*. Mechanochromic Luminescence of 2,6-Bis(4-biphenyl)isonicotinic Acid via Interconversion of Classical/Frustrated Brönsted Pair. J. Org. Chem202186, 18, 12591–12596

https://pubs.acs.org/doi/abs/10.1021/acs.joc.1c01035


55. Shiqing Huang, Yedong Wang, Chubin Hu, Prof. Xiaoyu Yan*. Nucleophilic Activation of Sulfur Hexafluoride by N-Heterocyclic Carbenes and N-Heterocyclic Olefins: A Computational Study. Chem Asian J202116, 2687-2693.

https://onlinelibrary.wiley.com/doi/full/10.1002/asia.202100770


54. Linwei Huang, Shiqing Huang, Zengyu Zhang, Lei Cao, Xingyu Xu, and Xiaoyu Yan*, Mesoionic-Carbene-Stabilized Thiophosphoryl Cation (PS+). Organometallics 2021, 40, 9, 1190–1194.

https://pubs.acs.org/doi/10.1021/acs.organomet.1c00071


53. Wei Liu, Adam Vianna, Zengyu Zhang, Shiqing Huang, Linwei Huang, Mohand Melaimi, Guy Bertrand, Xiaoyu Yan , Mesoionic carbene-Breslow intermediates as super electron donors: Application to the metal-free arylacylation of alkenes, Chem Catalysis1, 1–11, June 17, 2021.

https://www.sciencedirect.com/science/article/pii/S2667109321000117?via%3Dihub


52. Linwei Huang, Wei Liu, Liang-Liang Zhao, Zengyu Zhang and Xiaoyu Yan*. Base-Catalyzed H/D Exchange Reaction of Difluoromethylarenes. J. Org. Chem2021, 86, 3981-3988.

https://pubs.acs.org/doi/10.1021/acs.joc.0c02827


51. Huang Shiqing, Wang Yedong and Yan Xiaoyu*. Computational Study of 1,2,3-Triazol-5-ylidenes with p-Block El-ement Substituents. New J. Chem202145, 4802-4809.

https://pubs.rsc.org/en/content/articlelanding/2021/NJ/D1NJ00050K#!divAbstract


50.  Cao, Lei; Huang, Shiqing; Liu, Wei; Zhao, Hongyan; Xiong, Xiao-Gen; Zhang, Jian-Ping; Fu, Li-Min; Yan, Xiaoyu. Thermally Activated Delayed Fluorescence from d10 Metal Carbene Complexes via Intermolecular Charge Transfer and Multicolor Emission with a Monomer-Dimer Equilibrium. Chem. Eur. J202026,17222 –17229.

 

https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202004106


49. Zengyu Zhang, Shiqing Huang, Linwei Huang, Xingyu Xu, Hongyan Zhao, and Xiaoyu Yan*. Synthesis of Mesoionic N‑Heterocyclic Olefins and Catalytic  Application for Hydroboration Reactions. J. Org. Chem2020, 85, 19, 12036–12043

https://dx.doi.org/10.1021/acs.joc.0c00257


48. Hongyan Zhao, Lei Cao, Shiqing Huang, Chenxing Ma, Yunhao Chang, Kai Feng, Liang-Liang Zhao, Peng Zhao,* and Xiaoyu Yan*.Synthesis, Structure, and Photophysical Properties of m‑PhenyleneEmbedded Cycloparaphenylene Nanorings. J. Org. Chem. 202085, 6951−6958.

https://pubs.acs.org/doi/10.1021/acs.joc.0c00232


47. Lei Cao, Xiaoyu Yan*, Chanjuan Xi*, Marriage of simple alkenes or alkynes and organophosphorus compounds through group IV metallocenes.   Coordination Chemistry Reviews. Volume 416, 1 August 2020, 213330

https://www.sciencedirect.com/science/article/pii/S0010854520300588?via%3Dihub


46.Wei Liu, Lei Cao, Zengyu Zhang, Gang Zhang, Shiqing Huang, Linwei Huang, Peng Zhao*, and Xiaoyu Yan*,Mesoionic Carbene–Iridium Complex Catalyzed Ortho-Selective Hydrogen Isotope Exchange of Anilines with High Functional Group Tolerance. Org. Lett2020, 22, 6, 2210–2214

https://pubs.acs.org/doi/abs/10.1021/acs.orglett.0c00402


45. Xingyu Xu, Shiqing Huang, Zengyu Zhang, Lei Cao and Xiaoyu Yan*, Halogen-bonding-induced diverse aggregation of 4,5-diiodo-1,2,3-triazolium salts with different anions. Beilstein J. Org. Chem. 202016, 78–87.

https://www.beilstein-journals.org/bjoc/articles/16/10


44.Liang-Liang Zhao, Wei Liu, Zengyu Zhang, Hongyan Zhao, Qi Wang and Xiaoyu Yan*, Ruthenium-Catalyzed ortho- and meta-H/D Exchange of Arenes. Org. Lett2019, 21, 24, 10023-10027.

https://pubs.acs.org/doi/10.1021/acs.orglett.9b03955


43.Wei Liu, Liang-Liang Zhao, Mohand Melaimi, Lei Cao, Xingyu Xu, Jean Bouffard* , Guy Bertrand* , and Xiaoyu Yan*. Mesoionic Carbene (MIC)-Catalyzed H/D Exchange at Formyl Groups. Chem, 2019, 5, 2484–2494.

https://www.cell.com/chem/fulltext/S2451-9294(19)30380-8?rss=yes


42. Xingyu Xu, Zengyu Zhang, Shiqing Huang, Lei Cao, Wei Liu and Xiaoyu Yan*;4-Halo-1,2,3-triazolylidenes: Stable Carbenes Featuring Halogen Bonding. Dalton Transactions, 2019,48, 6931–6941.

https://pubs.rsc.org/en/content/articlelanding/2019/dt/c9dt01018a#!divAbstract


41. Hongyan Zhao, Yingchao Ma, Lei Cao, Shiqing Huang, Jianping Zhang and Xiaoyu Yan*; Synthesis and Photophysical Properties of Chalcophenes-Embedded Cycloparaphenylenes. J. Org. Chem, 201984, 5230−5235

https://pubs.acs.org/doi/10.1021/acs.joc.9b00207


40. Linfeng Li, Lei Cao, and Xiaoyu Yan*;Synthesis and Characterization of Palladium(II) CNC Pincer Complexes with Novel Bis(1,2,3- triazolylidene)amine Ligands. ChemistrySelect 20183, 10706-10710

https://onlinelibrary.wiley.com/doi/full/10.1002/slct.201802645


39. Xingyu Xu, Linfeng Li, Zengyu Zhang, Xiaoyu Yan*;Nucleophilic substitution of 4-bromomethyltriazolium with different nucleophiles . Tetrahedron 201874, 6846- 6853

https://doi.org/10.1016/j.tet.2018.10.009


38. Lei Cao ,Shiqing Huang,Wei Liu and Xiaoyu Yan*;4-Phosphino-1,2,3-triazol-5-ylidenes: Stable Bridging Ligands for Coinage Metal Complexes.Organometallics.201837, 2010

https://pubs.acs.org/doi/10.1021/acs.organomet.8b00305


37.Wei Liu, XingyuXu, HongyanZhao, and XiaoyuYan*; Palladium-catalyzed site-selective hydrogen isotope exchange (HIE) reaction of arylsulfonamides using amino acid auxiliary.Tetrahedron,201874, 4111

https://doi.org/10.1016/j.tet.2018.06.024


36. Enlu Ma, Yifan Jiang, Yuanjin Chen, Longying Qi, Xiaoyu Yan, and Zhiping Li*; Salicylate-Directed C@O Bond Cleavage: Iron-Catalyzed Allyli Substitution with Grignard Reagents. Asian J. Org. Chem. 20187, 914

https://doi.org/10.1002/ajoc.201800057


35. Yan,X.;Xi,C. Advances in transmetalation reactions originated from organozirconium compounds. Coord. Chem. Rev2017, 350

https://doi.org/10.1016/j.ccr.2017.07.005


34. Lv, L.; Bai, X.; Yan, X.;* Li, Z.* Iron-catalyzed decarbonylation initiated [2+2+m] annulation of benzene-linked 1,n-enynes with aliphatic aldehydes. Org. Chem. Front. 20163, 1509.


http://pubs.rsc.org/is/content/articlelanding/2016/qo/c6qo00429f#!divAbstract


33. Ma, L.; Li, W.; Xi, H.; Bai, X.; Ma, E.; Yan, X.; Li, Z.* FeCl3-Catalyzed Ring-Closing Carbonyl-Olefin Metathesis. Angew. Chem., Int. Ed. 2016, 55, 10410. http://onlinelibrary.wiley.com/doi/10.1002/anie.201604349/full
32. Yan, X.; Xi, C.* Coord. Chem. Rev. 2016, 308, 22.
31. Yan, X.; Xi, C.* Acc. Chem. Res., 2015, 48, 935.
30. Yan, X.; Yang, X.; Xi, C.* Catal. Sci. Technol. 2014, 4, 4169.
29. Yan, X.; Yi, X.; Xi, C.* Org. Chem. Front. 2014, 1, 657.
28. Yan, X.; Chen, C.; Xi, C.* Beilstein J. Org. Chem. 2014, 10, 528.
27. Yan, X.; Zou, S.; Zhao, P.; Xi, C.* Chem. Commun. 2014, 50, 2775.
26. Zhao, P.; Yan, X.; Yin, H.; Xi, C.* Org. Lett. 2014, 16, 1120.
25. Zhou, Y.; Chen, C.; Yan, X.; Xi, C.* Organometallics 2014, 33, 844.
24. Yan, X.; Fang, K.; Liu, H.; Xi, C.* Chem. Commun. 2013, 49, 10650.
23. Yan, X.; Zhou, Y.; Xi, C.* Organometallics 2013, 32, 869.
22. Zhou, Y.; Yan, X.; Chen, C.; Xi, C.* Organometallics 2013, 32, 6182.
21. Liu, H.; Zhou, Y.; Yan, X.; Chen, C.; Liu, Q.;* Xi, C.* Org. Lett. 2013, 15, 5174.
20. Liu, H.; Yan, X.; Chen, C.; Liu, Q.;* Xi, C.* Chem. Commun. 2013, 49, 5513.
19. Xi, C.;* Yu, B.; Yan, X.; Tang, N. Polyhedron 2013, 52, 1323.
18. Yan, X.; Chen, C.;* Zhou, Y.; Xi, C.* Org. Lett. 2012, 14, 4750.
17. Yan, X.; Bouffard, J.; Guisado-Barrios, G.; Donnadieu, B.; Bertrand, G.* Chem. -Eur. J. 2012, 18, 14627.
16. Liu, Y.; Yan, X.; Yang, N.; Xi, C.* Catal. Commun. 2011, 12, 489.
15. You, W.; Yan, X.; Liao, Q.; Xi, C.* Org. Lett. 2010, 12, 3930.
14. Yu, B.; Yan, X.; Wang, S.; Tang, N.; Xi, C.* Organometallics 2010, 29, 3222.
13. Zhou, Y.; Yan, X.; Xi, C.* Tetrahedron Lett. 2010, 51, 6136.
12. Chen, C.; Yan, X.; Xi, C.* Synth. Commun. 2010, 40, 570.
11. Xie, T.; Gong, M.; Niu, Z.; Li, S.; Yan, X.; Li, Y.* Nano. Res. 2010, 3, 174.
10. Yan, X.; Zhou, Y.; Xi, C.* Chem. Commun. 2010, 46, 7801.
9. Xi, C.*; Yan, X.; You, W.; Takahashi, T. Angew. Chem. Int. Ed. 2009, 48, 8120.
8. Yan, X.; Lai, C.; Xi, C.* Chem. Commun. 2009, 6026.
7. Yan, X.; Yu, B.; Wang, L.; Tang, N.; Xi, C.* Organometallics 2009, 28, 6827.
6. Xi, C.*; Wu, Y.; Yan, X. J. Organomet. Chem. 2008, 693, 3842.
5. Xi, C.;* Yan, X.; Lai, C; Kanno, K.; Takahashi, T. Organometallics 2008, 27, 3834.
4. Yan, X.; Liu, Y.; Xi, C.* Appl. Organomet. Chem. 2008, 22, 341.
3. Yan, X.; Xi, C.* Organometallics 2008, 27, 152.
2. Xi, C.*; Liu, Y.; Yan, X.; Chen, C., J. Organomet. Chem. 2007, 692, 4612.
1. Xi, C.;* Yan, X.; Lai, C. Organometallics 2007, 26, 1084.