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成果及论文

Research Articles

28) Fang, T.; Zhang, P.*; Liu, C.* "Boron Ylide" Enables Stereoselective Construction of gem-Diborylcyclopropanes, Angew. Chem. Int. Ed. 2024, 63, e202415301.(Hot Paper) <link>


27) Yang, T.; Chen, D.; Zhang, P.*; Liu, C.* Application of Triborylmethane Reagent in the Stereoselective Synthesis of Dissymmetric gem-Diborylalkenes, Chin. J. Org. Chem. 2024, online. <link>


26) Xu, L.; Chen, D.; Zhang, P.*; Xia, C.*; Liu, C.* Atom Swap in Triple Bonds via Nitrogen Deletion Coupling with gem-Diborylalkanes, Chem 2024, 10, 3474. <link>


25) Ren, B.; Xu, J.; Liu, C.* Rapid and Practical Synthesis of gem-Dibromoalkanes from Aldehydes by Tribromide Reagent, Chem. Asian J. 2024, 19, e202301087. <link>

-Invited for special issue: “Special Collection: 30th Years of Suzhou Industrial Park”


24)  Fang, T.; Wang, L.; Wu, M.; Qi, X.*; Liu, C.* Diborodichloromethane as Versatile Reagent for Chemodivergent Synthesis of gem-Diborylalkanes, Angew. Chem. Int. Ed. 2024, 63, e202315227.<link>


23) Chen, D.; Xu, L.; Wang, Z.; Liu, C.*, Enriched 10B-Diboron Reagents Synthesis from10BF3Chem 2023, 9, 3212-3223. <link>

 -See Preview by Prof. Z. Xie and Prof. T. B. Marder: Chem  2023, 9, 3015-3017.<link>

-Highlighted by Chemstation <link>



22) Chen, D.; Xu, L.; Ren, B.; Wang, Z.; Liu, C.* Triflylpyridinium as Coupling Reagent for Rapid Amide and Ester Synthesis, Org. Lett. 2023, 25, 4571-4575. <link>

- Highlighted by "多肽加" <link>



21) Xu, J.; Qin, Y.; Liu, C.* Direct Amination of Benzylic Pinacol Boronates by an Aminoazanium, Synlett 2023, 34, 2244-2248. <link>

- Invited for Special Issue on Modern Boron Chemistry: 60 years of the Matteson Reaction



20) Sun, W.+; Xu, L.+; Qin, Y.; Liu, C.*  Alkyne synthesis through coupling of gem-diborylalkanes with carboxylic acid esters Nat. Synth. 2023, 2, 413-425.<link>

- See News & Views by Prof. A. Masarwa in Nat. Synth. : "Triple coupling to make alkynes"  <link>

- Highlighted by Organic Chemistry Portal <link>



19) Chen, D.; Xu, L.; Yu, Y.; Mo, Q.; Qi, X.*; Liu, C.* Triflylpyridinium Enables Rapid and Scalable Controlled Reduction of Carboxylic Acids to Aldehydes using Pinacolborane, Angew. Chem. Int. Ed. 2023, 62, e202215168 <link>. 

- Highlighted by OPR&D:Org. Process Res. Dev. 2023, 27, 1–9 <link>

- Highlighted by CJOC: Chin. J. Org. Chem. 2023, 43, 783-785 <link>

- Highlighted by "Organic Route" <link>

- Highlighted by "Organicsyntheses" <link>




18)  Qin, Y.; Xu, L.; Xu, J.; Liu, C.* 1,2-Migration Enabled Borylation of Benzylic Quaternary Ammonium, Chin. J. Org. Chem. 2023, 43, 1868-1874 <link>. 

-Invited for Special Issue: Organoboron Chemistry



17)Fang, T.; Xu, L.; Qin, Y.; Jiang, N.; Liu, C.* A Novel Synthesis of Halogenated gem-Diboron Reagents, Chin. J. Org. Chem. 2023, 43, 777-780 <link>.



16) Xu, L.; Hu, Y.; Zhu, X.; He, L.; Wu, Q.; Li, C.; Xia, C.; Liu, C.* Momentary Clicking Nitrile Synthesis Enabled by an Aminoazanium Reagent, Org. Chem. Front. 2022, 9, 3420-3427 <link>.  

- Hot Paper

A new application of H2N-DABCO reagent




15) Xu N.; Xu J.; Zhu Q.; Liu C.* Synthesis of Allylboronates via Zweifel‐type Deprotonative Olefination, Adv. Synth. Catal. 2021363, 2403-2407 <link>

VIP paper 

Invited for themed issue: Boron in Catalysis and Organic Synthesis



14Zhu Q.; Xia C.; Liu C.*Iron-Catalyzed Borylation of Ketones to α-Hydroxyboronates, Chin. J. Org. Chem. 2021, 41, 661-668<link>



13) Shi, D.; Xia, C.; Liu, C.* Photoinduced Transition-Metal-Free Alkynylation of Alkyl Pinacol Boronates, CCS Chem. 20213, 1718-1728. <link>



12) Sun, W.; Wang, L.; Hu, Y.; Wu, X.; Xia, C.; Liu, C.* Chemodivergent Transformations of Amides using gem-Diborylalkanes as Pro-nucleophiles, Nat. Commun. 2020, 11, 3113. <link>



11) Liu, X.; Zhu, Q.;  Chen, D.; Wang, L.; Jin, L.*; Liu, C.* Aminoazanium of DABCO: An Amination Reagent for Alkyl and Aryl Pinacol Boronates, Angew. Chem. Int. Ed. 2020, 59, 2745-2749. <link>

- Highlighted by CJOC: Chin. J. Org. Chem. 2020, 40, 547-548

- China Patent:  Chao Liu, Xingxing Liu, CN110845506A



10) Zou, L.*; Fan, M.; Wang, L.*; Liu, C.* Hetero Diacylation of 1,1-Diborylalkanes: Practical Synthesis of 1,3-Diketones, Chin. Chem. Lett., 2020, 31, 1911-1913.  <link>



9) Hu, Y.; Sun, W.; Zhang, T.; Xu, N.; Xu, J.; Lan, Y.; Liu, C.* Stereoselective Synthesis of Trisubstituted Vinylboronates from Ketone Enolates Triggered by 1,3-Metalate Rearrangement, Angew. Chem. Int. Ed. 201958, 15813-15818. <link> 

- Hot paper

 



8) Zhu, Q.; He, Z.; Wang, L.; Hu, Y.; Xia, C.; Liu, C.* α-C-H Borylation of Secondary Alcohols via Ru/Fe Relay Catalysis: Building a Platform for Alcoholic C-H/C-O Functionalizations, Chem. Commun. 2019, 55, 11884-11887. <link>



7) He, Z.; Zhu, Q.; Hu, X.; Wang, L.; Xia, C.; Liu, C.* Cooperation between an alcoholic proton and boryl species in the catalytic gem-hydrodiborylation of carboxylic esters to access 1,1-diborylalkanes, Org. Chem. Front. 20199, 900-907. <link><pdf>

- Hot paper


6)  He, Z.; Fan, M.; Xu, J.; Hu, Y.; Wang, L.; Wu, X.; Xia, C.; Liu, C.* Iron-catalyzed deoxygenative diborylation of ketones to internal gem-diboronates, Chin. J. Org. Chem. 201939, 3438-3445. <link>

Cover Article 

     


5) Wang, L.; Sun, W.; Liu, C.* Cu-Catalyzed Deoxygenative gem-Hydroborylation of Aromatic Aldehydes and Ketones to Access Benzylboronic Esters, Chin. J. Catal. 2018, 39, 1725 -1729. <link>

Award Invitation

- Cover Article


4) Shi, D.; Wang, L.; Xia, C.; Liu, C.* Access to Secondary and Tertiary Alkyl Boronic Esters via gem-Carboborylation using Carbonyl as Bis(electrophile) Equivalent, Angew. Chem. Int. Ed. 201857, 10318-10322. <link>

- highlighted by CJOC: Chin. J. Org. Chem. 2018, 38, 2805



3) Sun, W.; Wang, L.; Xia, C.*; Liu, C.* Dual Functionalization of α-Monoboryl Carbanion via A Deoxygenative Enolization with Carboxylic Acids, Angew. Chem. Int. Ed. 201857, 5501-5505. <link>

- Highlighted by CJOC: Chin. J. Org. Chem. 2018, 38, 2184


2)Kuan, S. H. C.; Sun, W.; Wang, L.; Xia, C.; Tay, M. G.; Liu, C.* Double Carbonylation Using Glyoxal (HCOCOH): A Practical Copper-Promoted Synthesis of Isatins from Primary and Secondary Anilines, Adv. Synth. Catal. 2017, 359, 3484-3489.



1) Wang, L.; Zhang, T.; Sun, W.; He, Z.; Xia, C.; Lan, Y.*; Liu, C.* C-O Functionalization of α-Oxyboronates: A Deoxygenative gem-Diborylation and gem-Silylborylation of Aldehydes and Ketones, J. Am. Chem. Soc. 2017139, 5257-5264. <link> 



Review Articles

14) Fang, T.; Liu, C.* Formal Buchner-Curtius-Schlotterbeck Reaction enabled by Acyl Radical Addition, Chem Catal. 2023 Accepted. (Invited Preview)<link>

13) Jiang, N.; Chen, D.; Liu, C.* Recent Advances in the Chemistry of α-Oxylboronate Reagents, Org. Chem. Front. 2023, 10, 3684-3700. (Invited review) <link>

12) Xu, J.; Chen, D.; Liu, C.* Recent advances of aminoazanium salts as amination reagents in organic synthesis, Org. Biomol. Chem. 202220, 8353-8365 <link>. (Review article)

11) Yi, W.; Sun, W.; Hu, X.; Liu, C.*; Jin, L.* Recent Advance of Ketones Synthesis from Carboxylic Esters, Chin. J. Org. Chem. 202242, 1626-1639. <link> (Reivew article).

10) Zhu, Q.; Liu, C.* The future directions of synthetic chemistry, Pure Appl. Chem. 2021, 93, 1463-1472. (Invited paper as part of "IUPAC organizational structure review" for the "future direction of chemistry survey") <link>

9) Shi, D; Wang, L.; Xia, C.; Liu, C.* Recent Advances in Photoinduced Transformation of Alkyl Boron Compounds, Chin. J. Org. Chem. 202040, 3605-3619. (Invited Review )  <link>

8)Zhu, Q.; Liu, C.* New Chiral Brønsted Acid for Asymmetric Reduction of Indoles,  Chin. J. Org. Chem. 2020, 40, 2164-2166.(Invited Highlight). <link>

7) Xu,N.; Hu, Y.*; Liu, C.*  烯基偕二硼的催化合成及应用研究进展, 分子催化2020, 34, 88-96. (Invited Review<link>

6) Sun, W.; Hu, Y.; Xia, C.; Liu, C.* Recent advances in the synthesis and transformation of gem-borylsilylalkanes, New J. Chem. 202145, 14847-14854. <link><pdf> (Invited Perspective for the Themed issue "Celebrating Todd B. Marder's Contributions to Chemistry")

5) Hu, Y.; Liu, C.* Introduction of 1, 2-Migration for Organoboron Compounds, Univ. Chem. 201934, 39-44. <link>

4) He, Z.; Hu, Y.*; Xia, C.; Liu, C.* Recent Advances in the Borylative Transformation of Carbonyl and Carboxyl Compounds, Org. Biomol. Chem. 2019,17, 6099-6113  (Invited Review for the themed collections: "Trends in Organoboron Chemistry"). <link>

3) Hu, Y.; Sun, W.; Liu, C.* Deoxygenative Transformation of Carbonyl and Carboxyl Compounds Using gem-Diborylalkanes, Synlett  201930, 1105-1110 (Invited Synpacts). <link>

2) Wang, L.; Sun, W.; Liu, C.* Recent Advances in Homogeneous Carbonylation Using CO2 as CO Surrogate, Chin. J. Chem. 2018, 36, 353-362. <link> (Invited Review)

1) Zhu Q.; Wang, L.; Xia, C.; Liu, C.* Recent Advance of Transition Metal-Catalyzed Direct C-H Bond Carboxylation with CO2Chin. J. Org. Chem. 2016, 36, 2813-2821. <link> (Invited Review)