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成果及论文

(22) Asymmetric Formal Abnormal Claisen Rearrangement Enabled by Rh-Catalyzed Regio- and Enantioselective Allylic Alkylation

Bing Li, Yanshu Luo, Min Liu, Yuanzhi Xia, Changkun Li

ACS Catal. 202313,  5482-5490. 



(21) Regio- and Enantioselective Allylic Cyanomethylation by Synergistic Rhodium and Silane Catalysis

Minghe Sun, Linsheng Wei, Changkun Li

J. Am. Chem. Soc. 2023145, 3897-3902. 


(20) Rhodium-Catalyzed N-Reverse Prenylation of Nonactivated Indoles.

Minghe Sun,# Linsheng Wei,# Changkun Li

Synlett 202334DOI: 10.1055/a-1995-5791.


(19)  Cobalt-catalyzed regiodivergent hydrofunctionalization of allenes.

Jia-Feng Chen, Sajid Ur Rehman, Changkun Li

Org. Chem. Front., 2022,9, 6869-6874.

Graphical abstract: Cobalt-catalyzed regiodivergent hydrofunctionalization of allenes


(18)  Rhodium-Catalyzed Regio- and Enantioselective Direct Allylation of Methyl Ketones

Bing Li, Changkun Li

Synlett 2022, 33, 1863-1867.


(17) Rh-Catalyzed Regio- and Enantioselective Allylic Phosphinylation

Bing Li, Min Liu, Sajid Ur Rehman, and Changkun Li*

J. Am. Chem. Soc. 2022144,  2893-2898.

 

(16)  Eantioselective Synthesis of Pyridiens with All-Carbon Quaternary Carbon Centers via Cobalt-Catalyzed Desymmetric [2+2+2] Cycloaddition

Ke Li, Linsheng Wei, Minghe Sun, Bing Li, Min Liu, Changkun Li* 

Angew. Chem. Int. Ed. 202160, 20204-20209.

 

(15)  Rhodium-Catalyzed Regio- and Enantioselective Allylic Amination of racemic 1,2-Disubstituted Allylic Phosphates.

Wen-Bin Xu,† Minghe Sun,† Mouhai Shu, Changkun Li* (†, equal contribution)

J. Am. Chem. Soc. 2021143, 8255-8260.


(14)  Rh-Catalyzed Chemodivergent Regio- and Enantioselective Allylic Alkylation of Indoles
Minghe Sun, Min Liu, Changkun Li*

Chem. Eur. J. 202127, 3457-3462.


(13)  Pd-Catalyzed Enantioselective Synthesis of 2-Methyl-3-methyleneindoline

Chun-Hua Lu, Sima, Darvishi, Vahid, Khakyzadeh, Changkun Li.*

Chin. Chem. Lett. 202132, 405-407

 

(12) Rh(I)-Catalyzed Regio- and Enantioselective Allylic Alkylation of Meldrum's Acid 

Min Liu, Haiying Zhao,* Changkun Li.*

Chin. Chem. Lett. 202132, 385-388.


(11) Enantioselective Synthesis of 3-Allylindolizines via Sequential Rh-Catalyzed Asymmetric Allylation and Tschitschibabin Reaction
Ke Li, Changkun Li*

Org. Lett. 202022, 9456-9461.


(10) Regio- and Enantioselective Allylic Alkylation of Terminal Alkynes by Synergistic Rh/Cu Catalysis

Wen-Yu Huang, Chun-Hua Lu, Samir Ghorai, Bing Li, Changkun Li*

J. Am. Chem. Soc. 2020142, 15276-15281. 

 

(9) Desymmetrization construction of chiral lactones by synergistic Cu(II) complex and organic base

Murad Ali, Changkun Li*

Tetrahedron Lett. 2020, 61, 152106.


(8) Cobalt/Bisoxazolinephosphine-Catalyzed Asymmetric Alkynylation of Isatins

Jia-Feng Chen, Changkun Li*

Org. Lett. 202022, 4686-4691.

 

(7) Cobalt-Catalyzed Regio- and Enantioselective Allylic Alkylation of Malononitriles

Samir Ghorai, Sajid Ur Rehman, Wen-Bin Xu, Wen-Yu Huang, Changkun Li.*

Org. Lett. 202022, 3519-3523.


(6) Rh(I)/Bisoxazolinephosphine-Catalyzed Regio- and Enantioselective Allylic Substitutions

Wen-Bin Xu, Samir Ghorai, Wenyu Huang, Changkun Li.*

ACS. Catal202010, 4491-4496. 

 

(5) Cobalt-Catalyzed gem-Cross-Dimerization of Terminal Alkynes.

Jia-Feng Chen, Changkun Li.*

ACS. Catal. 202010, 3881-3889. 


(4) Cobalt-Catalyzed Regio- and Enantioselective Allylic Amination.

Samir Ghorai, Sahadev Shrihari Chirke, Wen-Bin Xu, Jia-Feng Chen, Changkun Li.*

J. Am. Chem. Soc. 2019141, 11430−11434.


(3) Construction of Vicinal Quaternary Carbon Centers via Cobalt-Catalyzed  Asymmetric Reverse Prenylation.

Minghe Sun#, Jia-Feng Chen#, Shufeng Chen, Changkun Li.*

Org. Lett. 201921, 1278-1281. (#, equal contribution)

 

(2) Enol Ester Synthesis via Cobalt-Catalyzed Regio- and Stereoselective Addition of Carboxylic Acids to Alkynes.

Jia-Feng Chen, Changkun Li.*

Org. Lett. 201820, 6719-6724.


(1)  Rh(I)-Catalyzed Carbonylative [3+1] Constrcution of Cyclobutenones via C-C s-Bond Activation of Cyclopropenes.

Wen-Bin Xu, Changkun Li,* and Jianbo Wang

Chem. Eur. J. 201824, 15786-15790.