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成果及论文

2024年


[33] Yuqin Wang, Yiling Zeng, Ya-Nan Tian, Zheng Liu, Jinhua Wang,* Shuyou Chen,* Shiqing Li*. Mechanistic insights into rhodium-catalyzed C−H activation and annulation using vinyl acetate to access cinnolines and cinnolin-4(1H)-ones. Organic Chemistry Frontiers, 2024, DOI: 10.1039/D4QO01734J  (Link)


[32]Liangfeng Wang, Linfeng Zhang, Chao Zhou, Tiantian Gou, Nan-Ying Chen, Ke Feng, Shiqing Li, Jun-Cheng Su, Jingxian Yu, Guixia Wang, Xiangfei Kong. Synthesis of Rutaecarpine Analogues by Borrowing Hydrogen Strategy. Advanced Synthesis & Catalysis, 2024, DOI: 10.1002/adsc.202400698 (Link)


[31] Yuqin Wang, Yiling Zeng, Yi Xiao, Jinhua Wang,*  Shiqing Li*. Rh(III)- or Ru(II)-Catalyzed C−H Annulation with Vinylene Carbonate and an Unexpected Aerobic Oxidation/Deprotection Cascade to Yield Cinnolin-4(1H)‑ones. The Journal Organic Chemistry, 2024, 89, 14233−14241.  (Link)


[30] Shuang Zhao, Yingman Sun, Shiqing Li*, Dongbing Zhao*trans-Selective Element−Element′ Addition to AlkynesChemCatChem2024, e202400913. DOI: 10.1002/cctc.202400913 (Invited Review, Link)


[29] Peiyan Zhu, Yanyan Yang, Hui Li, Jinhua Wang, Shiqing Li*Rh(III)-Catalyzed sequential ring-retentive/-opening [4 + 2] annulations of 2H-imidazoles towards full-color emissive imidazo[5,1-a]isoquinolinium salts and AIE-active non-symmetric 1,1′-biisoquinolinesChinese Chemical Letters2024, 35, 109533.  (Link)

[28] Yi Xiao, Xiya Zhang, Yuqin Wang, Kaida Li (本科生), Guixia Wang, Xiangfei Kong, Jinhua Wang*, Shiqing Li*Sequential annulation of bidentate diamines for the modular access to N-fused/helical/spiro-carbazole scaffoldsOrganic Chemistry Frontiers2024, 11, 401406.  (Link)


2023年

[27] Shiqing Li,‡*, Shihai Lv,‡  Yanyan Yang,, Peiyan Zhu,a Dongbing Zhao,*  Ming-Hua Zeng*Mechanistic insights into an NH4OAc-promoted imine dance in Rhcatalysed multicomponent double C-H annulations through an N-retention/exchange dual channelChemical Science2023, 14, 1344613452. (‡Equal contribution) (Link)


[26] Yanyan Yang, Rongrong Xie, Yiwen Wang, Peiyan Zhu, Jinhua Wang, Shiqing Li*. Efficient synthesis of benzo[c]cinnolines and azoarenes via dual C−N coupling of phthalhydrazide and trivalent halogen reagentsOrganic Chemistry Frontiers, 202310, 27012707. (Link)

[25] Chaoying Wen, Yuqin Wang, Yanyan Yang, Ya-Nan Tian, Jinhua Wang, Shiqing Li*. Hydrazone-oxime Selectively Directed Redox-Neutral [4 + 2] Annulations Cascade with Alkynes and Iodonium Ylides to Build 1,1′-Biisoquinoline Mono‑N‑oxides. Organic Letters, 2023, 25, 2616–2621 (Link)

[24] Rongrong Xie, Yi Xiao, Yiwen Wang, Zhi-Wei Xu, Ning Tian, Shiqing Li*, Ming-Hua Zeng*. Hydrazine−Halogen Exchange Strategy Toward N=N-Containing Compounds and Process Tracking for Mechanistic Insight. Organic Letters, 2023, 14, 2415–2419. (Equal contribution) (封面文章,Link(Highlighted by Organic Chemistry Portal)

                      

[23] Yiwen Wang, Ya-Nan Tian, Shiyan Ren (本科生), Ruijie Zhu (本科生), Bin Huang(本科生), Yanqiong Wen(本科生), Shiqing Li*. Metal-free homo-/cross-anion–cation coupling of cyclic diaryl λ3-bromanes. Organic Chemistry Frontiers, 2023, 10, 793–798. (Link)

[22] Linfeng Zhang, Dong Chen, Chao Zhou, Yutong Yin, Guixia Wang, Qiping Zhu, Shiqing Li*, Xiangfei Kong*. Synthesis of evodiamine and its derivatives through a visiblelight-driven intramolecular C-N-cross-coupling reaction. Tetrahedron Lett., 2023, 1115, 154305.  

[21] Ya-Nan Tian, Shihai Lv, Lingyu Huang, Chaoying Wen, Yanyan Yang, Xiangfei Kong, Qiping Zhu*, Shiqing Li*, Experimental and computational studies on rhodium-catalyzed C4(5)aryl−H activation/annulations of imidazoles with alkynes: facile synthesis of six types of N-heterocycles. Organic Chemistry Frontiers, 2023, 10, 83−91. (Link)

2022年

[20] Shihai Lv, Ya-Nan. Tian, Yanyan Yang, Chaoying Wen, Shiqing Li*. Rh(III)-Catalyzed One-Pot Three-Component Diannulation of Benzils, Ammonium Acetate, and Alkynes to Build 1,1-Biisoquinolines. Journal of Organic Chemistry, 2022, 87, 16019−16025. (Link)

[19] Lingyu Huang, Ya-Nan Tian, Shiyan Ren(本科生), Jingwei Wang, Yi Xiao, Qiping Zhu* and Shiqing Li*, Palladium-catalysed dual ring-opening [3 + 4] annulation of isatoic anhydrides with cyclic iodoniums to build tribenzo[b,d,f]azepines and a mechanistic DFT study. Organic Chemistry Frontiers, 2022, 9, 6259-6264.  (Link)

[18] Lingyu Huang,‡ Rongrong Xie,‡ Chaoying Wen, Yanyan Yang, Yiwen Wang, Shiyan Ren(本科生), Bin Huang(本科生) and Shiqing Li*. Decarbonylative/decarboxylative [4 + 2] annulation of phthalic anhydrides and cyclic iodoniums towards triphenylenes. Organic & Biomolecular Chemistry, 2022, 20, 3913–3916. (‡Equal contributionLink(Highlighted by Synfacts)

             

[17] Yuzhou Wang,‡ Yu Yu,‡ Rongrong Xie, Ya-Nan Tian, Lingyu Huang, Shihai Lv, Xiaona Meng(本科生), Xiangfei Kong and Shiqing Li*. Cu/Fe-mediated N(sp 2 )-arylation/alkenylation of pyridines with aryl-/alkenylboronic acids to yield versatile cationic materials. New Journal of Chemistry, 2022, 46, 2320–2325. (‡Equal contribution) (Link)

2021年

[16] Yuzhou Wang, Rongrong Xie, Lingyu Huang, Ya-Nan Tian, Shihai Lv, Xiangfei Kong and Shiqing Li*. Divergent synthesis of unsymmetrical azobenzenes via Cu-catalyzed C–N coupling. Organic Chemistry Frontiers, 2021, 8, 5962–5967. (Link)

[15] Xiangfei Kong, Ronggen Luo, Hongkang Gong, Dong Chen, Shijun Yang, Shiqing Li*, Guixia Wang*, and Zhiqun He*. Discotic liquid crystals with aggregation-induced emission properties based on tetraphenylethylene and triphenylene derivatives. Mol. Cryst. Liq. Cryst., 2021, 724, 2637.

[14] Dong Chen, Shiqing Li, Jinhua Wang, Tiantian Gou, Linfeng Zhang, Guixia Wang*, and Xiangfei Kong*. Visible-light-mediated synthesis of rutaecarpine alkaloids through C–N cross-coupling reaction. Synlett, 2021, 32, 987992.

2020年

[13] Shiqing Li*, Hongxu Lv, Rongrong Xie, Xiuqing Ye(本科生) and Xiangfei Kong*. The C−H Activation/Bidirecting Group Strategy for Selective Direct Synthesis of Diverse 1,1′-Biisoquinolines. Organic Letters, 2020, 22, 42074212. (Link)

[12] Rongrong Xie,# Hongxu Lv,# Xiuqing Ye(本科生), Xiangfei Kong* and Shiqing Li*. Cu-Catalyzed tandem N-arylation of phthalhydrazides with cyclic iodoniums to yield dihydrobenzo[c]cinnolines. Organic & Biomolecular Chemistry, 2020, 18, 4824−4830. (#Equal contribution) (Link)

[11] Yu Yu(本科生), Hongxu Lv and Shiqing Li*. The C–H functionalization of organic cations: an interesting and fresh journey. Organic & Biomolecular Chemistry, 2020, 18, 8810–8826. (Review, Link)

2019年

[10] Shiqing Li*, Hongxu Lv, Yu Yu(本科生), Xiuqing Ye(本科生), Baisong Li(本科生), Songming Yang(本科生), Yanru Mo(本科生) and Xiangfei Kong*. Domino N-/C- or N-/N-/C-arylation of imidazoles to yield polyaryl imidazolium salts via atom-economical use of diaryliodonium salts. Chemical. Communications, 2019, 55, 11267−11270. (Link)


2014-2018年

[9]   Shiqing Li, Fan Yang, Taiyong Lv, Jingbo Lan, Ge Gao* and Jingsong You*, “Synthesis of unsymmetrical imidazolium salts by direct quaternization of N-substituted imidazoles using arylboronic acids”, Chem. Commun. 2014, 50, 39413943.

[8]   Shiqing Li, Junbin Tang, Yinsong Zhao, Ruyong Jiang, Tianbao Wang, Ge Gao* and Jingsong You*, “Cu-Catalyzed Controllable C−H Mono-/Di-/Triarylations of Imidazolium Salts for Ionic Functional Materials”, Chem. Commun. 2017, 53, 3489−3492.

[7]   Yinsong Zhao, Shiqing Li, Xuesong Zheng, Junbin Tang, Zhijie She, Ge Gao*, and Jingsong You*, “Rh/Cu-Catalyzed Cascade [4+2] Vinylic C−H O-Annulation and Ring Contraction of a-Aryl Enones with Alkynes in Air”, Angew. Chem. Int. Ed. 2017, 56, 4286−4289.

[6]   Junbin Tang, Shiqing Li, Zheng Liu, Yinsong Zhao, Zhijie She, Vilas D. Kadam, Ge Gao,* Jingbo Lan, and Jingsong You*“Cascade C−H Annulation of Aldoximes with Alkynes Using O2 as the Sole Oxidant: One-Pot Access to Multisubstituted Protoberberine Skeletons”, Org. Lett. 2017, 19, 604-607.

[5]   Xiaoyu Li, Shiqing Li, Ge Gao, Di Wu, Jingbo Lan*, Ruiling Wang* and Jingsong You*“High Performance Ruthenium Sensitizers Containing Imidazoliums as Counterions for the Efficient Dye-Sensitization in Water”, ChemSusChem. 2017, 10, 2914−29121.

[4]   Hongjun Zhou, Yinsong, Zhao, Ge Gao*, Shiqing Li, Jingbo Lan, and Jingsong You*, “Highly Selective Fluorescent Recognition of Sulfate in Water by Two Rigid Tetrakisimidazolium Macrocycles with Peripheral Chains”, J. Am. Chem. Soc. 2013, 135, 14908−14911.

[3]   Zhen He, Xiaotian Qi, Shiqing Li, Yinsong Zhao, Ge Gao*, Yu Lan*, Yiwei Wu, Jingbo Lan, and Jingsong You*, “Transition-Metal-Free Formal Decarboxylative Coupling of α-Oxocarboxylates with α-Bromoketones under Neutral Conditions: A Simple Access to 1,3-Diketones”, Angew. Chem. Int. Ed. 2015, 54, 855859.

[2]   Yinsong Zhao, Zhen He, Shiqing Li, Junbin Tang, Ge Gao*, Jingbo Lan and Jingsong You*, “An Air-stable Half-sandwich RuII complex as an Rfficient Catalyst for [3+2] Annulation of 2-Arylcyclo-2-enones with Alkynes”, Chem. Commun. 2016, 52, 4613−4616.

[1]   Zhen He, Xiaotian Qi, Zhijie She, Yinsong Zhao, Shiqing Li, Junbin Tang, Ge Gao,* Yu Lan,* and Jingsong You*, “Room-Temperature Coupling/Decarboxylation Reaction of αOxocarboxylates with αBromoketones: Solvent-Controlled Regioselectivity for 1,2- and 1,3-Diketones”, J. Org. Chem. 2017, 82, 1403−1411.