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成果及论文

Chen. C.; Kehr, G.; Erker, G.* The B=C bond: some recent developments. Org. Chem. Front. 2023, 10, 4161. (Invited review)

Chen. C.; Daniliuc, C. G.; Kehr, G.; Erker, G.* Bora-alkenes: Metal Coordination and Reactions with B-H boranes. Chem. Eur. J. 2023, 29, e202301044.


Jie, X.; Chen. C.; Daniliuc, C. G.; Kehr, G.; Erker, G.* Boraalkenes Made by a Hydroboration Route: Cycloaddition and B=C Bond Cleavage Reactions. Angew. Chem. Int. Ed., 2023, 62, e202214700. (Contributed equally)


Chen. C.; Daniliuc, C. G.; Kehr, G.; Erker, G.* Generation of Boryl-nitroxide Radicals from a Boraalkene via the Nitroso Ene Reaction. Chem. Sci., 202213, 10891.


K. Škoch, Chen. C.; Daniliuc, C. G.; Kehr, G.; Erker, G.* A deprotonation pathway to reactive [B]CH2 boraalkenes. Dalton Trans., 202251, 7695.


Chen. C.; Daniliuc, C. G.; Kehr, G.; Erker, G.* N-Heterocyclic Carbene Stabilized 1-Bora-1,3-butadienes. J. Am. Chem. Soc. 2021, 143, 21312.


Chen. C.; Daniliuc, C. G.; Kehr, G.; Erker, G.* Formation and Cycloaddition Reactions of a Reactive Boraalkene Stabilized Internally by N-Heterocyclic Carbene. Angew. Chem. Int. Ed. 2021, 60, 19905.



Chen. C.; Daniliuc, C. G.; Mück-Lichtenfeld, C.; Kehr, G.; Erker, G.* A BH Borenium-Derived Thioxoborane, Its Persulfide, and Their Li+-Induced Reactions with Alkynes and with Carbon Dioxide. J. Am. Chem. Soc. 2020, 142, 19763.


Chen. C.; Li, J.; Daniliuc, C. G.; Mück-Lichtenfeld, C.; Kehr, G.; Erker, G.* The [(NHC)B(H)C6F5]+ Cations and their [B](H)-CO Borane Carbonyls. Angew. Chem. Int. Ed. 202059, 21460.


Chen. C.; Daniliuc, C. G.; Mück-Lichtenfeld, C.; Kehr, G.; Erker, G.* A rare olefin 1,1-carboboration reaction opens a synthetic pathway to an unusually structured frustrated Lewis pair. Chem. Commun. 2020. 56, 8806.


Chen, C.; Liu, G. (2020) Direct Trifluoromenthoxylation of Aliphatic Compounds. In Emerging Fluorinated Motifs (eds Cahard, D. and Ma, J.-A.). p251-266. (Book chapter)


Chen. C.; Hou, C.; Chen, P.; Liu, G.* Palladium(II)-Catalyzed Aminotrifluoromethoxylation of Alkenes: Mechanistic Insight into the Effect of N-Protecting Groups. Chin. J. Chem. 2020, 38, 346. (Breaking report)


Chen, C.; Chen, P.; Liu, G. (2019) N,N′-Difluoro-1,4-Diazoniabicyclo[2.2.2]octane Salt Electrophilic Fluorination In Fluorination. Synthetic Organofluorine Chemistry. (eds Hu, J.; Umemoto, T.) Springer, Singapore. (invited)


Chen, C.; Pflüger, P. M.; Chen, P.; Liu, G.* Pd(II)-Catalyzed Enantioselective Aminotrifluoromethoxylation of Unactivated Alkenes using CsOCF3 as a Trifluoromethoxide Source. Angew. Chem. Int. Ed. 2019, 58, 2392.


Chen, C.; Luo, Y.; Fu, L.; Chen, P.; Lan, Y.;* Liu, G.* Palladium-Catalyzed Intermolecular Ditrifluoromethoxylation of Unactivated Alkenes: F3CO-palladation Initiated by Pd(IV). J. Am. Chem. Soc. 2018, 140, 1207.


Qi, X.; Chen, C.; Hou, C.; Fu, L.; Chen, P.; Liu, G.* Enantioselective Pd(II)-Catalyzed Intramolecular Oxidative 6-endo Aminoacetoxylation of Unactivated Alkenes. J. Am. Chem. Soc. 2018, 140, 7415. (Contributed equally)


Zhang, H.; Wang, H.-Y.;* Luo, Y.; Chen, C.; Cao, Y.; Chen, P.; Guo, Y.-L.; Lan, Y.;* Liu, G.* Regioselective Palladium-Catalyzed C-H Bond Trifluoroethylation of Indoles: Exploration and Mechanistic Insight.  ACS Catal. 2018, 8, 2173.


Chen, C.; Fu, L.; Chen, P.; Liu, G.* Recent Advances and Perspectives of Transition Metal-Catalyzed Asymmetric Fluorination Reactions. Chin. J. Chem. 2017, 35, 1781. (Review)


Chen, C.; Chen, P.; Liu, G.* Palladium-Catalyzed Intramolecular Amino-Trifluoromethoxylation of Alkenes. J. Am. Chem. Soc. 2015, 137, 15648.


Chen, C.; Ouyang, L.; Lin, Q.; Liu, Y.; Hou, C.; Yuan, Y.; Weng, Z.* Synthesis of Cu(I) Trifluoromethylselenates for Trifluoromethylselenolation of Aryl and Alkyl Halides. Chem. Eur. J. 2014, 20, 657.


Chen, C.; Hou, C.; Wang, Y.; Andy Hor, T. S.;* Weng, Z.* Copper-Catalyzed Trifluoromethylselenolation of Aryl and Alkyl Halides: the Silver Effect in Transmetalation. Org. Lett.201416, 524. (Contribute equally)


Weng, Z.;* He, W.; Chen, C.; Lee, R.; Tan, D.; Lai, Z.; Kong, D.; Yuan, Y.; and Huang, K-W.* An Air-Stable Copper Reagent for Nucleophilic Trifluoromethylthiolation of Aryl Halides. Angew. Chem. Int. Ed. 2013, 52, 1548.


Liu, Y.; Chen, C.; Li, H.; Huang, K-W.;* Tan, J.; Weng, Z.* SN2 Fluorination of Primary and Secondary Alkyl Bromides by Cu(I) Fluoride Complexes. Organometallics, 2013, 32, 6587.


Chen, C.; Weng, Z.*; Hartwig, J. F.* Synthesis of Copper(I) Thiolate Complexes in the Thioetherification of Aryl Halides. Organometallics. 2012, 31, 8031.