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Catalytic Enantioselective Nucleophilic α-Chlorination of Ketones with NaCl Li, Z.; Wang, B.; Zhang, C.; Lo, W. Y.; Yang, L.; Sun, J.*J. Am. Chem. Soc. 2024, 146, 2779-2788. Mild Stereoselective Synthesis of Densely Substituted [3]Dendralenes via Ru-Catalyzed Intermolecular Dimerization of 1,1-Disubstituted Allenes Li, S.; Feng, Q.; Song, L.;* Zhang, X.; Wu, Y.-D.;* Sun, J.*J. Am. Chem. Soc. 2024, 146, 1532-1542. Primary activation of para-quinone methides by chiral phosphoric acid for enantioselective construction of tetraarylmethanes Han, Z.; Zhu, B.; Zang, Y.; Zhang, C.; Dong, X.-Q.; Huang, H.;* Sun, J.*Chem. Sci. 2024, 15, 720-725. Heterodifunctionalization of Electron-Rich Alkynes Catalyzed by in Situ Generated Silylium Ions Su, X.; Wang, Y.; Feng, Q.; Sun, J.*Org. Lett. 2024, 26, 421-426. Organocatalytic Enantioselective Nucleophilic Addition of Indole Imine 5-Methides Li, Y.; Huang, J.; Han, Z.; Huang, H.;* Hong, B.;* Sun, J.*Org. Lett. 2024, 26, 396-400. Asymmetric Synthesis of Remotely Chiral Naphthols and Naphthylamines via Naphthoquinone Methides Liu, S.; Chan, K. L.; Lin, Z.;* Sun, J.* J. Am. Chem. Soc. 2023, 145, 12802-12811. Pd-Catalyzed Ligand-Directed Divergent Cycloaddition of Cyclic 1-Azadienes with Oxo-1,4-dipoles Xie, H.; Chen, L.; Han, Z.; Yang, Z.; Sun, J.;* Huang, H.* Org. Lett. 2023, , ASAP. Chiral Phosphoric Acid Catalyzed Redox Deracemization of Triarylmethanes Liu, C.; Li, Z.; Li, P.;* Sun, J.* Chem. Synth. 2023, 3, 22. Near-Infrared Aggregation-Induced Emission Luminogens for In Vivo Theranostics of Alzheimer's Disease Zhang, T.; Chen, X.; Yuan, C.; Pang, X.; Shangguan, P.; Liu, Y.; Han, L.; Sun, J.; Lam, J. W. Y.; Liu, Y.; Wang, J.;* Shi, B.;* Tang, B. Z.* Angew. Chem., Int. Ed. 2023, 62, e202211550. In Situ Synthesis of AIEgen-based Porous Organic Polymer Films by Interfacial Amino-yne Click Polymerization for Efficient Light-Harvesting Song, B.; Zhang, L.; Sun, J.; Lam, J. W. Y.;* Tang, B. Z.* Angew. Chem., Int. Ed. 2023, 62, e202302543. Dual Behavior Regulation: Tether-Free Deep-Brain Stimulation by Photothermal and Upconversion Hybrid Nanoparticles Sun, F.; Shen, H.; Yang, Q.;* Yuan, Z.; Chen, Y.; Guo, W.; Wang, Y.; Yang, L.; Bai, Z.; Liu, Q.; Jiang, M.; Lam, J. W. Y.; Sun, J.; Ye, R.; Kwok, R. T. K.;* Tang, B. Z.* Adv. Mater. 2023, 35, 2210018. An Alkaline Phosphatase-Responsive Aggregation-Induced Emission Photosensitizer for Selective Imaging and Photodynamic Therapy of Cancer Cells Lam, K. W. K.; Chau, J. H. C.; Yu, E. Y.; Sun, F.; Lam, J. W. Y.; Ding, D.; Kwok, R. T. K.;* Sun, J.; He, X.;* Tang, B. Z.* ACS Nano 2023, 17, 7145-7156. Aggregation-Induced Emission Macromolecular Materials for Antibacterial Applications Zuo, Y.; Kwok, R. T. K; Sun, J.; Lam, J. W. Y.;* Tang, B. Z.* Marcromol. Rapid Commun. 2023, 44, 2300104. Chiral Phosphine Catalyzed Allylic Alkylation of Benzylidene Succinimides with Morita-Baylis-Hillman Carbonates Liu, C.; Sun, J.;* Li, P.* Molecules 2023, 28, 12825. Electricity-Driven Asymmetric Bromocyclization Enabled by Chiral Phosphate Anion Phase-Transfer Catalysis Tan, X.;* Wang, Q.; Sun, J.* Nat. Commun. 2023, accepted. Ir-Catalyzed Regioselective Dihydroboration of Thioalkynes toward Gem-Diboryl Thioethers Wang, Y.;1 Li, Y.;1 Wang, L.; Ding, S.; Song, L.;* Zhang, X.;* Wu, Y.-D.;* Sun, J.* (1: equal contribution) J. Am. Chem. Soc. 2023, 145, ASAP. Enantioselective Synthesis of Tetraarylmethanes through meta-Hydroxyl-directed Benzylic Substitution Tan, X.;1 Deng, Z.;1 Wang, Q.; Chen, S.; Zhu, G.;* Sun, J.* (1: equal contribution)Nat. Synth. 2023, , accepted. Near-Infrared Aggregation-Induced Emission Luminogens for In Vivo Theranostics of Alzheimer's Disease Zhang, T.; Chen, X.; Yuan, C.; Pang, X.; Shangguan, P.; Liu, Y.; Han, L.; Sun, J.; Lam, J. W. Y. L.; Liu, Y.; Wang, J.;* Shi, B.;* Tang, B. Z.* Angew. Chem., Int. Ed. 2023, 62, e202211550. Catalytic Enantioselective Synthesis of 2,3'-Bis(indolyl)methanes Bearing All-Carbon Quaternary Stereocenters via 2?Indole Imine Methides Han, Z.; Wang, W.; Zhuang, H.; Wang, J.; Wang, C.; Wang, J.;* Huang, H.;* Sun, J.* Org. Lett. 2023, 25, ASAP. Metal-free Multicomponent Polymerization of Activated Diyne, Electrophilic Styrene and Isocyanide Towards Highly Substituted and Functional Poly(cyclopentadiene) Liu, X.; Yang, X.; Li, X.; Sun, J.;* He, B.;* Lam, J. W. Y.;* Tang, B. Z.* Sci. Chin. Chem. 2023, , In press. Catalytic Asymmetric Synthesis of α-Tertiary Aminoketones from Sulfoxonium Ylides Bearing Two Aryl Groups Zhou, Y.; Yue, X.; Jiang, F.; Sun, J.; Guo, W.* Chem. Commun. 2023, , Advance Article. Visible-light-induced Organocatalytic Enantioselective N-H Insertion of α-Diazoesters Enabled by Indirect Free Carbene Capture Guo, W.;* Zhou, Y.; Xie, H.; Yue, X.; Jiang, F.; Huang, H.; Han, Z.; Sun, J.* Chem. Sci. 2023, , Advance Article. Design of Smart Aggregates: Toward Rapid Clinical Diagnosis of Hyperlipidemia in Human Blood Sun, F.; Zhao, W.; Shen, H.; Fan, N.; Zhang, J.; Liu, Q.; Xu, C.; Luo, J.; Zhao, M.; Chen, Y.; Lam, K. W. K.; Yang, X.; Kowk, R. T. K.; Lam, J. W. Y.; Sun, J.; Zhang, H.;* Tang, B. Z.* Adv. Mater. 2022, 34, 2207671. Construction of diverse polycyclic N-heterocycles via cascade allylic amination/Diels-Alder reaction Yang, Z.; Xie, H.; Tang, L.; Sun, J.; Han, Z.; Huang, H.* Chem. Commun. 2022, 58, 13258-13261. Nickel-Catalyzed Asymmetric Dicarbofunctionalization of Alkynes to Access Axially Chiral Styrenes Tan, X.; Sun, J.* Chem Catal. 2022, 2, 2813-2815. (Invited Preview article) Rapid Biotransformation of Luminescent Bimetallic Nanoparticles in Hepatic Sinusoids Tan, Y.; Cai, W.; Luo, C.; Tang, J.; Kwok, R. T. K.; Lam, J. W. Y.; Sun, J.; Liu, J.;* Tang, B. Z.* J. Am. Chem. Soc. 2022, 144, 20653-20660. Total Synthesis of Yuzurine-type Alkaloid Daphgraciline Li, L.-X.; Min, L.; Yao, T.-B.; Ji, S.-X.; Qiao C.; Tian, P.-L.; Sun, J.;* Li, C.-C.* J. Am. Chem. Soc. 2022, 144, 18823-18828. Palladium-Catalyzed Intramolecular Enantioselective C(sp3)-H Insertion of Donor/donor Carbenes Li, W.; Zhang, H.; Jiang, H.; Sun, J.; Zhu, S.* Chem. Sci. 2022, 13, 12396-12402. Catalyst-Controlled Divergent Reactions of 2,3-Disubstituted Indoles with Propargylic Alcohols: Synthesis of 3H-Benzo[b]azepines and Axially Chiral Tetrasubstituted Allenes Qian, C.; Huang, T.; Sun, J.;* Li, P.* Org. Lett. 2022, 24, 6472-6476. Organocatalytic Asymmetric Azidation of Sulfoxonium Ylides: Mild Synthesis of Enantioenriched α-Azido Ketones Bearing a Labile Tertiary Stereocenter Guo, W.;* Jiang, F.; Li, S.; Sun, J.* Chem. Sci. 2022, 13, 11648-11655. Construction of Nine-membered N,N,O-Heterocycles via Pd-Catalyzed [6+3] Dipolar Cycloaddition Xie, H.; Yang, Z.; Tang, L.; Han, Z.; Sun, J.;* Huang, H.* Chem. Commun. 2022, 58, 10560-10563. Base-Promoted 5-exo-dig Cyclization of o-Alkynylamides or 2-En-4-ynamides with CO2 toward Fully Substituted Acrylates Sha, Y.; Bai, J.; Li, M.; Gao, W.; Yang, Q.; Sun, J.; Sun, S.* Org. Lett. 2022, 24, 5715-5720. Ru-Catalyzed Hydroboration of Ynones Leads to a Nontraditional Mode of Reactivity Feng, Q.;1 Li, S.;1 Li, Z.; Yan, Q.; Lin, X.; Song, L.;* Zhang, X.;* Wu, Y.-D.;* Sun, J.* (1: equal contribution) J. Am. Chem. Soc. 2022, 144, 14846-14855. Rational Design of NIR-II AIEgens with Ultrahigh Quantum Yields for Photo- and Chemiluminescence Imaging Shen, H.; Sun, F.; Zhu, X.; Zhang, J.; Ou, X.; Zhang, J.; Xu, C.; Sung, H. H. Y.; Williams, I. D.; Chen, S.; Kwok, R. T. K.; Lam, J. W. Y.; Sun, J.; Zhang, F.;* Tang, B. Z.* J. Am. Chem. Soc. 2022, 144, 15391-15402. Ammonia to chiral α-amino acid Yang, L.; Sun, J.* Nat. Catal. 2022, 5, 471-472. Quinone methides and indole imine methides as intermediates in enantioselective catalysis Li, X.; Li, Z.; Sun, J.* Nat. Synth. 2022, 1, 426-438. Ruthenium-Catalyzed Geminal Hydroborative Cyclization of Enynes Tan, Y.-X.; Li, S.; Song, L.;* Zhang, X.; Wu, Y.-D.;* Sun, J.* Angew. Chem., Int. Ed. 2022, 61, e202204319. Secondary through-space interactions facilitated single-molecule white-light emission from clusteroluminogens Zhang, J.; Alam, P.; Zhang, S.; Shen, H.; Hu, L.; Sung, H. H. Y.; Williams, I. D.; Sun, J.; Lam, J. W. Y.;* Zhang, H.;* Tang, B. Z.*Nat. Commun. 2022, 13, 3492. Catalytic Asymmetric Allylic Substitution/Isomerization with Central Chirality Transposition Han, Z.; Zhuang, H.; Tang, L.; Zang, Y.; Guo, W.; Huang, H.;* Sun, J.* Org. Lett. 2022, 24, 4246-4251. Fluorescent Imaging and Sorting of High-Lipid-Content Strains of Green Algae by Using an Aggregation-Induced Emission Luminogen Liu, X.; Yan, N.;* Wong, T. Y.; Lam, H.; Lam, J. W. Y.; Kwok, R. T. K.;* Sun, J.; Tang, B. Z.* ACS Nano 2022, 16, 14973-14981. Enantioselective synthesis of triarylmethanes via organocatalytic transfer hydrogenation of para-quinone methides Han, Z.; Zang, Y.; Liu, C.; Guo, W.; Huang, H.;* Sun, J.* Chem. Commun. 2022, 58, 7128-7131. Reductive Opening of Oxetanes Catalyzed by Frustrated Lewis Pairs: Unexpected Aryl Migration via Neighboring Group Participation Tang, L.; Zang, Y.; Guo, W.; Han, Z.; Huang, H.;* Sun, J.* Org. Lett. 2022, 24, 3259-3264. Photoactive Metal Carbonyl Complexes Bearing N-Heterocyclic Carbene Ligands: Synthesis, Characterization, and Viability as Photoredox Catalysts Tang, M.; Cameron, L.; Poland, E. M.; Yu, L.-J.; Moggach, S. A.; Fuller, R. O.; Huang, H.; Sun, J.; Thickett, S. C.; Massi, M.; Coote, M. L.;* Ho, C. C.;* Bissember, A. C.* Inorg. Chem. 2022, 61, 1888-1898. Organocatalytic discrimination of non-directing aryl and heteroaryl groups: enantioselective synthesis of bioactive indole-containing triarylmethanes Yan, Q.;1 Duan, M.;1 Chen, C.; Deng, Z.; Wu, M.; Yu, P.; He, M.-L.;* Zhu, G.;* Houk, K. N.;* Sun, J.* Chem. Sci. 2022, 13, 5767-5773. (1: equal contribution) Oxygen Quenching-Resistant Nanoaggregates with Aggregation-Induced Delayed Fluorescence for Time-Resolved Mapping of Intracellular Microviscosity Song, F.; Ou, X.; Chou, T. Y.; Liu, J.; Gao, H.;* Zhang, R.; Huang, X.; Zhao, Z.; Sun, J.; Chen, S.;* Lam, J. W. Y.; Tang, B. Z.* ACS Nano 2022, 16, 6176-6184. Asymmetric Synthesis of Pyrrolidines via Oxetane Desymmetrization Zhang, R.;1 Sun, M.;1 Yan, Q.;1 Lin, X.; Li, X.; Fang, X.; Sung, H. H. Y.; Williams, I. D.; Sun, J.* Org. Lett. 2022, 24, 2359-2364.(1: equal contribution) Aggregation-Induced Emission Luminogens for Cell Death Research Zuo, Y.; Shen, H.; Sun, F.; Li, P.; Sun, J.; Kwok, R. T. K.; Lam, J. W. Y.;* Tang, B. Z.* ACS Bio. Med. Chem. Au 2022, 2, 236-257. Chiral phosphoric acid-catalyzed regio- and enantioselective reactions of functionalized propargylic alcohols Qian, C.; Liu, M.; Sun, J.;* Li, P.* Org. Chem. Front. 2022, 9, 1234-1240. Catalytic Enantioselective Synthesis of 2,3-Dihydrobenzo[b]oxepines via Asymmetric Oxetane Opening by Internal Carbon Nucleophiles Zhang, T.; Zhuang, H.; Tang, L.; Han, Z.; Guo, W.; Huang, H.;* Sun, J.* Org. Lett. 2022, 24, 207-212. Asymmetric dearomatization enabled by chiral Bronsted acid activation of ynamides Li, X.; Sun, J.* Sci. Chin. Chem. 2022, 65, 3-4. Visible-Light Photoredox-Catalyzed Dicarbofunctionalization of Styrenes with Oxime Esters and CO2: Multicomponent Reactions toward Cyanocarboxylic Acids and γ-Keto Acids Bai, J.; Li, M.; Zhou, C.; Sha, Y.; Cheng, J.; Sun, J.; Sun, S.* Org. Lett. 2021, 23, 9654-9658. SPHENOL, A New Chiral Framework for Asymmetric Synthesis Zhang, R.;1 Ge, S.;1 Sun, J.* J. Am. Chem. Soc. 2021, 143, 12445-12449. (1: equal contribution) Mild Intermolecular Synthesis of a Cyclopropane-Containing Tricyclic Skeleton: Unusual Reactivity of Isobenzopyryliums Liu, S.; Qian, H.; Zhang, T.; Xie, H.; Han, Z.; Guo, W.; Huang, H.;* Sun, J.*Angew. Chem., Int. Ed. 2021, 60, 21272-21276. Organocatalytic Asymmetric Formal Oxidative Coupling for the Construction of All-Aryl Quaternary Stereocenters Li, Z.; Li, Y.; Li, X.; Wu, M.; He, M.-L.;* Sun, J.* Chem. Sci. 2021, 12, 11793-11798.