Suginome, Michinori - Kyoto University - Department of Synthetic Chemistry and Biological Chemistry

个人简介

Experience 1987-1988 Undergraduate Student with Professors Yoshihiko Ito and Zen-ichi Yoshida Department of Synthetic Chemistry, Kyoto University 1988-1993 Graduate Student with Professor Yoshihiko Ito Department of Synthetic Chemistry, Kyoto University 1993-2002 Assistant Professor Department of Synthetic Chemistry and Biological Chemistry, Kyoto University 1998-1999 Visiting Researcher with Professor Gregory C. Fu Sabbatical leave to Massachusetts Institute of Technology 2001-2004 PRESTO Researcher (JST)Research Area for "Synthesis and Control" 2002-2004 Associate Professor Department of Synthetic Chemistry and Biological Chemistry, Kyoto University 2004-present Professor Department of Synthetic Chemistry and Biological Chemistry, Kyoto University 2009-2014 CREST Researcher (JST)Research Area for "Creation of Next-Generation Nanosystems through Process Integration" 2014- CREST Researcher (JST)Research Area for "Establishment of Molecular Technology towards the Creation of New Functions" Education Kyoto University: B.S. in 1988; Ph.D. in 1993 Awards 1999 The Chemical Society of Japan Award for Young Chemist 2001 The Society of Silicon Chemistry Japan Award for Young Chemist 2005 Nagoya Silver Medal 2005 Mukaiyama Award, Society of Synthetic Organic Chemistry, Japan 2010 JSPS Prize, Japan Society for the Promotion of Science (JSPS) 2013 The Chemical Society of Japan Award for Creative Work 2015 The Humboldt Research Award

研究领域

In the Suginome group, a variety of research projects are pursued on the basis of synthetic organic chemistry, organometallic chemistry, main group metal chemistry, transition metal chemistry, polymer chemistry, asymmetric synthesis, etc. We always try to pursue innovative molecular and reaction design for establishing new synthetic methods, new molecular functions, new concept, new phenomena, new principles, etc. We are interested in development of new catalytic reactions for molecular synthesis, utilizing transition metal catalysts and organosemimetallic reagents. Boron and silicon are particularly interesting, serving as key elements in our chemistry. We are also interested in the synthesis and new molecular functions of single-handed helical polymers, particularly poly(quinoxaline-2,3-diyl)s.

近期论文

查看导师新发文章（温馨提示：请注意重名现象，建议点开原文通过作者单位确认）

Asymmetric Catalysis in Chiral Solvents: Chirality Transfer with Amplification of Homochirality through a Helical Macromolecular Scaffold Yuuya Nagata, Ryohei Takeda, and Michinori Suginome ACS Cent. Sci., 2019, 57, 1235-1240, 10.1021/acscentsci.9b00330 Pyridine-Based Organocatalysts for Regioselective syn-1,2-Silaboration of Terminal Alkynes and Allenes Yohei Morimasa, Kosuke Kabasawa, Toshimichi Ohmura, and Michinori Suginome Asian J. Org. Chem., 2019, 8, 1092-1096, 10.1002/ajoc.201900176 Lyotropic Liquid Crystallinity of Linear and Star Poly(quinoxaline-2,3-diyl)s: Isotropic-Liquid Crystal Phase Equilibria in Tetrahydrofuran Hirokazu Hasegawa, Ken Terao, Takahiro Sato, Yuuya Nagata, and Michinori Suginome Macromolecules, 2019, 52, 3158-3164, 10.1021/acs.macromol.9b00460 Telechelic Helical Poly(quinoxaline-2,3-diyl)s Containing a Structurally Defined, Circularly Polarized Luminescent Terquinoxaline Core: Synthesis by Core-Initiated Bidirectional Living Polymerization Shogo Kuriyama, Yuuya Nagata, and Michinori Suginome ACS Macro Lett., 2019, 8, 479-485, 10.1021/acsmacrolett.9b00165 Catalytic Generation of Rhodium Silylenoid for Alkene-Alkyne-Silylene [2+2+1] Cycloaddition Toshimichi Ohmura, Ikuo Sasaki, and Michinori Suginome Org. Lett., 2019, 21, 1649-1653, 10.1021/acs.orglett.9b00326 Helical Poly(quinoxaline‐2,3‐diyl)s Bearing 1,2,3‐Triazole Pendants: Synthesis by CuAAC and Use as Reusable Abnormal NHC Ligands in Gold Catalysis Pinglu Zhang, Takeshi Yamamoto, and Michinori Suginome ChemCatChem, 2019, 11, 424-429, 10.1002/cctc.201801361 A bidirectional screw‐sense induction of poly(quinoxaline‐2,3‐diyl)s that depends on the degree of polymerization Yuuya Nagata, Tsuyoshi Nishikawa, Ken Terao, Hirokazu Hasegawa, and Michinori Suginome J. Polym. Sci. Part A: Polym. Chem., 2019, 57, 260-263, 10.1002/pola.29224 A Planar-Chiral Pillar[5]arene-Based Monophosphine Ligand with Induced Chirality at the Biaryl Axis Yuuya Nagata, Yasuo Shimada, Tsuyoshi Nishikawa, Ryohei Takeda, Makoto Uno, Tomoki Ogoshi, and Michinori Suginome Synlett, 2018, 29, 2167-2170, 10.1055/s-0037-1610635 Enantiospecific Suzuki-Miyaura Coupling of Nonbenzylic α-(Acylamino)alkylboronic Acid Derivatives Toshimichi Ohmura, Kyoko Miwa, Tomotsugu Awano, and Michinori Suginome Chem. Asian J., 2018, 13, 2414–2417, 10.1002/asia.201800536 Abnormal Sergeants-and-Soldiers Effect of Poly(quinoxaline-2,3-diyl)s Enabling Discrimination of One-Carbon Homologous n-Alkanes through a Highly Sensitive Solvent-dependent Helix Inversion Yuuya Nagata, Tsuyoshi Nishikawa, and Michinori Suginome Chem. Comm., 2018, 54, 6867-6870, 10.1039/C8CC02836B Chirality-Amplifying, Dynamic Induction of Single-Handed Helix by Chiral Guests to Macromolecular Chiral Catalysts Bearing Boronyl Pendants as Receptor Sites Takeshi Yamamoto, Ryo Murakami, Satoko Komatsu, and Michinori Suginome J. Am. Chem. Soc., 2018, 140, 3867-3870, 10.1021/jacs.8b00529 Elucidating the Solvent Effect on the Switch of the Helicity of Poly(quinoxaline-2,3-diyl)s: A Conformational Analysis by Small-Angle Neutron Scattering Yuuya Nagata, Tsuyoshi Nishikawa, Michinori Suginome, Sota Sato, Masaaki Sugiyama, Lionel Porcar, Anne Martel, Rintaro Inoue, and Nobuhiro Sato J. Am. Chem. Soc., 2018, 140, 2722-2726, 10.1021/jacs.7b11626 Palladium-Catalyzed β-Elimination of Aminoboranes from (Aminomethylsilyl)boranes Leading to the Formation of Silene Dimers Toshimichi Ohmura, Hiroki Nishiura, and Michinori Suginome Organometallics, 2017, 36, 4298–4304, 10.1021/acs.organomet.7b00695 4,4'-Bipyridine-Catalyzed Stereoselective trans-Diboration of Acetylenedicarboxylates to 2,3-Diborylfumarates Toshimichi Ohmura, Yohei Morimasa, and Michinori Suginome Chem. Lett., 2017, 46, 1793–1796, 10.1246/cl.170848 (Open Access) Asymmetric Cycloisomerization of o-Alkenyl-N-methylanilines to Indolines through Iridium-Catalyzed C(sp3)–H Addition to Carbon–Carbon Double Bonds Takeru Torigoe, Toshimichi Ohmura, and Michinori Suginome Angew. Chem. Int. Ed., 2017, 56, 14272–14276, 10.1002/anie.201708578 Synthesis and Solution Properties of a Rigid Helical Star Polymer: Three-Arm Star Poly(quinoxaline-2,3-diyl)Hirokazu Hasegawa, Yuuya Nagata, Ken Terao, and Michinori Suginome Macromolecules, 2017, 50, 7491–7497, 10.1021/acs.macromol.7b01797 Chirality-Switchable 2,2'-Bipyridine Ligands Attached to Helical Poly(quinoxaline-2,3-diyl)s for Copper-Catalyzed Asymmetric Cyclopropanation of Alkenes Yukako Yoshinaga, Takeshi Yamamoto, and Michinori Suginome ACS Macro Lett., 2017, 6, 705–710, 10.1021/acsmacrolett.7b00352 Rhodium-Catalyzed C(sp2)–H Addition of Arylboronic Acids to Alkynes Using a Boron-Based, Convertible ortho-Directing Group Takeshi Yamamoto, Aoi Ishibashi, and Michinori Suginome Chem. Lett., 2017, 46, 1169-1172, 10.1246/cl.170404 New Chiral Functions Based on the Dynamic Induction of Macromolecular Helical Chirality by Chiral Side Chains Michinori Suginome, Yuuya Nagata, and Takeshi Yamamoto J. Synth. Org. Chem. Jpn., 2017, 5, 476-490, 10.5059/yukigoseikyokaishi.75.476 (Japanese) Synthesis and Catalytic Applications of a Triptycene-Based Monophosphine Ligand for Palladium-Mediated Organic Transformations Franco King-Chi Leung, Fumitaka Ishiwari, Yoshiaki Shoji, Tsuyoshi Nishikawa, Ryohei Takeda, Yuuya Nagata, Michinori Suginome, Yasuhiro Uozumi, Yoichi M. A. Yamada, and Takanori Fukushima ACS Omega, 2017, 2, 1930-1937, 10.1021/acsomega.7b00200