个人简介

Associate Professor Senior Investigator Indiana University

研究领域

Inorganic Chemistry/Physical Chemistry

The Baik group is broadly interested in transition metal chemistry with a heavy emphasis on catalysis. Based on large-scale computer simulations, mechanisms of how transition metal systems can activate small molecules are investigated in detail. Of particular interest are water oxidation, carbon dioxide reduction and C-C/C-H bond activation in small organic molecules.

近期论文

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"Rationally Designing Bimetallic Complexes for Light-Driven Redox Catalysis: Controlling Which Metal Absorbs Light and Which is Reduced" Yang-Jin Cho, Douglas W. Crandell, Kyung-Ryang Wee, So-Yeong Jeong, Won-Sik Han, Chang Min Choi, Nam Joon Kim, Ho-Jin Son, Chongjin Pac, Sang Ook Kang, and Mu-Hyun Baik J. Am. Chem. Soc. 2015, submitted "The Origin of the Ligand-Controlled Regioselectivity in Rh-Catalized [2+2+2] Carbocyclizations: Steric vs. Stereoelectronic Effects" Douglas W. Crandell, Shivnath Mazumder, P. Andrew Evans, and Mu-Hyun Baik Angew. Chem. Int. Ed. 2015, submitted "Carbon Dioxide Reduction using a Bis(imino)pyridine Manganese Electrocatalyst" Tufan K. Mukhopadhyay, Nicholas L. MacLean, Lu Gan, Daniel C. Ashley, Thomas L. Groy, Mu-Hyun Baik, Anne K. Jones, Ryan J. Trovitch Inorg. Chem. 2015, submitted "Addition of Si-H and B-H Bonds and Redox Reactivity Involving Low-Coordinate Nitrido Vanadium Complexes" Rick Thompson, Ba L. Tran, Soumya Ghosh, Chung-Hsing Chen, Maren Pink, Xinfeng Gao, Mu-Hyun Baik and Daniel J. Mindiola Inorg. Chem. 2015, accepted "Computational and Spectroscopic Characterization of Key Intermediates of the Selective Catalytic Reduction Cycle of NO on Zeolite-Supported Cu Catalyst" Douglas W. Crandell, Haiyang Zhu, Xiaofan Yang, John Hochmuth, and Mu-Hyun Baik Inorg. Chim. Acta 2015, DOI: 10.1016/j.ica.2015.02.021, "How A Redox-Innocent Metal Promotes the Formal Reductive Elimination of Biphenyl Using Redox-Active Ligands" Daniel Ashley and Mu-Hyun Baik Chem. Eur. J. 2015, 21, 4308-4314 "How a [Co(IV)=O](2+) Fragment Oxidizes Water: Involvement of a Biradicaloid [Co(II)-((dot)O(dot))]2+ Species in Forming the O-O Bond." Douglas W. Crandell, Soumya Ghosh, Curtis Berlinguette and Mu-Hyun Baik ChemSusChem 2015, DOI: 10.1002/cssc.201403024, "The Mechanism of Redox Non-Innocent Ligand Assisted Nitrene-Transfer in a Zr(IV) Complex: Direct Ligand-to-Ligand Charge Transfer Preferred" Soumya Ghosh and Mu-Hyun Baik Chem. Eur. J. 2015, 21, 1780-1789 "Intramolecular ring-opening from a CO2-derived nucleophile as the origin of selectivity for 5-substituted oxazolidinone from the (salen)Cr-catalyzed [Aziridine + CO2] coupling" Debashis Adhikari, Aaron W. Miller, Mu-Hyun Baik and SonBinh T. Nguyen Chem. Sci. 2015, 6, 1293-1300 "Switching the Enantioselectivity in Catalytic [4 + 1] Cycloadditions By Changing the Metal Center: Principles of Inverting the Stereochemical Preference of an Asymmetric Catalysis Revealed by DFT Calculations" Shivnath Mazumder, Douglas W. Crandell, Richard L. Lord, and Mu-Hyun Baik J. Am. Chem. Soc. 2014, 136, 9414-9423 "Understanding Intrinsically Irreversible, Non-Nernstian, Two-Electron Redox Processes: A Combined Experimental and Computational Study of the Electrochemical Activation of Platinum(IV) Antitumor Prodrugs" Meghan C. McCormick, Karlijn Keijzer, Abhigna Polavarapu, Franklin A. Schultz, Mu-Hyun Baik J. Am. Chem. Soc. 2014, 136, 8992-9000 "[(Salcen)CrIII + Lewis Base]-Catalyzed Synthesis of N-aryl-substituted Oxazolidinones from Epoxides and Aryl Isocyanates" Robert L Paddock, Debashis Adhikari, Richard L. Lord, Mu-Hyun Baik and SonBinh T. Nguyen Chem. Comm. 2014, 50, 15187-15190 "A Multifunctional Ylide in the Synthesis of a Terminal Methylidene Complex of Niobium" Keith Searles, Karlijn Keijzer, Chun-Hsing Chen, Mu-Hyun Baik, and Daniel J. Mindiola Chem. Comm. 2014, 50, 6267-6269 "Computational Study of the Mechanism of Salen-Cr Mediated Formation of Cyclic Carbonates by Cycloaddition of CO2 to Epoxide" Debashis Adhikari, SonBinh T. Nguyen and Mu-Hyun Baik Chem. Comm. 2014, 50, 2676-2678 "Epitope Fluctuations in the Human Papillomavirus Are Under Dynamic Allosteric Control - A Computational Evaluation of a New Vaccine Design Strategy" Abhishek Singharoy, Abhigna Polavarapu, Harshad Joshi, Mu-Hyun Baik and Peter Ortoleva J. Am. Chem. Soc. 2013, 135, 18458-18468 "Studies of Iron-Mediated Pauson-Khand Reactions of 1,1-Disubstituted-Allenylsilanes: Mechanistic Implications for a Reactive Three-Membered Iron Metallacycle" David R. Williams, Akshay Shah, Shivnath Mazumder and Mu-Hyun Baik Chem. Sci. 2013, 4, 238-247 "Understanding intermolecular C-F bond activation by a transient titanium neopentylidyne: experimental and theoretical studies on the competition between 1,2-CF bond addition and [2+2]-cycloaddition/b-fluoride elimination" Hongjun Fan, Alison R. Fout, Brad C. Bailey, Maren Pinck, Mu-Hyun Baik and Daniel J. Mindiola Dalton Trans. 2013, 42, 4163-4174 "Understanding the Competion Between Dehydroalkoxylation and Dehydrogenation of Ethers with Ti-C Multiple Bonds" Marco G. Crestani, Andras Olasz, Balazs Pinter, Brad C. Bailey, Skye Fortier, Xinfeng Gao, Chun-Hsing Chen, Mu-Hyun Baik and Daniel J. Mindiola Chem. Sci. 2013, 4, 2543-2550 "Synthesis and Structural Characterization of Hexacoordinate Silicon, Germanium and Titanium Complexes of the E. coli Siderophore Enterobactin" Todor Baramov, Karlijn Keijzer, Elisabeth Irran, Eva Moesker, Mu-Hyun Baik and Roderich D. Suessmuth Chem. Eur. J. 2013, 19, 10536-10542 "A Four-Coordinate Thionitrosyl Complex of Vanadium" Ba L. Tran, Rick Thompson, Soumya Ghosh, Maren Pink, Mu-Hyun Baik and Daniel J. Mindiola Chem. Comm. 2013, 49, 2768-2770 "Model Studies of Molybdenum Electron Transfer Reactions" Franklin A. Schultz, Richard L. Lord and Mu-Hyun Baik Molybdenum: Its Biological and Coordination Chemistry - Ed. Alvin Holder, Nova Science Publishers 2013, 141-160