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Sequential X-ray-Induced Single-Crystal to Single-Crystal Transformation followed by Topotactic Reduction in a Potassium Crown Ether Complex of Tetrachloroaurate(III)
Inorganic Chemistry ( IF 4.3 ) Pub Date : 2018-10-05 00:00:00 , DOI: 10.1021/acs.inorgchem.8b02130 Navpreet K. Sethi 1 , Adrian C. Whitwood 1 , Duncan W. Bruce 1
Inorganic Chemistry ( IF 4.3 ) Pub Date : 2018-10-05 00:00:00 , DOI: 10.1021/acs.inorgchem.8b02130 Navpreet K. Sethi 1 , Adrian C. Whitwood 1 , Duncan W. Bruce 1
Affiliation
During data collection, the unreported potassium crown ether salt [K(18-crown-6][AuCl4] undergoes a sequential X-ray-induced and irreversible single-crystal to single-crystal transformation from P1̅ to C2/c followed by a topotactic reduction to crystalline [K(18-crown-6][AuCl2] within the same C2/c space group.
中文翻译:
X射线诱导的四氯金酸酯钾(III)钾冠醚络合物中的单晶到单晶的连续X射线诱导转变,然后全势还原
在数据采集期间,未报告钾冠醚盐[K(18-冠-6] [AUCL 4 ]经历连续的X射线引起的和不可逆的单晶到单晶变换从P 1到c ^ 2 / ç随后通过在相同的C 2 / c空间基团中完全还原为晶体[K(18-crown-6] [AuCl 2 ])。
更新日期:2018-10-05
中文翻译:
X射线诱导的四氯金酸酯钾(III)钾冠醚络合物中的单晶到单晶的连续X射线诱导转变,然后全势还原
在数据采集期间,未报告钾冠醚盐[K(18-冠-6] [AUCL 4 ]经历连续的X射线引起的和不可逆的单晶到单晶变换从P 1到c ^ 2 / ç随后通过在相同的C 2 / c空间基团中完全还原为晶体[K(18-crown-6] [AuCl 2 ])。