Short Total Synthesis of Ajoene,Angewandte Chemie International Edition

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Short Total Synthesis of Ajoene
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2018-08-19 , DOI: 10.1002/anie.201808605
Filipa Silva ₁ , Shaista S Khokhar ₂ , Danielle M Williams ₂ , Robert Saunders ₂ , Gareth J S Evans ₂ , Michael Graz ₂ , Thomas Wirth ₁

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We describe a short total synthesis of ajoene, a major biologically active constituent of garlic. The instability of allicin as the only other known alternative starting material has led to the development of a reliable procedure for the synthesis of ajoene from simple building blocks that is also suitable for upscale operations.

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