Development of the Applications of Palladium on Charcoal in Organic Synthesis,Advanced Synthesis & Catalysis

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Development of the Applications of Palladium on Charcoal in Organic Synthesis
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2018-07-16 , DOI: 10.1002/adsc.201800343
Xiang Liu ₁ , Didier Astruc ₂

Affiliation

Palladium on charcoal (Pd/C) has lots of salient merits: (i) it is a cheap and commercial source of palladium, (ii) it shows efficient catalytic activity even without ligands, (iii) as a heterogeneous catalyst it is easily recycled many times by simple filtration, and (iv) it is applicable to a great number of reactions and substrates, although it is eventually less efficient than homogeneous Pd catalysts containing some sophisticated ligands. This review recalls the main background and summarizes the progress made essentially during the last twelve years in Pd/C‐catalyzed organic synthesis since the reviews by Felpin's group and Seki in 2006.

中文翻译：

钯炭在有机合成中的应用研究进展

木炭上的钯（Pd / C）有很多突出的优点：（i）它是便宜的商业钯来源，（ii）即使没有配体也显示出有效的催化活性，（iii）作为非均相催化剂，易于回收通过多次简单过滤可以过滤许多次，并且（iv）适用于大量反应和底物，尽管最终效率不如含有某些复杂配体的均相Pd催化剂。这篇综述回顾了主要背景，总结了自Felpin小组和Seki于2006年进行综述以来，过去十二年来Pd / C催化的有机合成所取得的进展。

更新日期：2018-07-16

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