Electrochemical dehydrogenative cyclization of 1,3-dicarbonyl compounds†,Chemical Communications

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Electrochemical dehydrogenative cyclization of 1,3-dicarbonyl compounds†
Chemical Communications ( IF 4.3 ) Pub Date : 2018-04-19 00:00:00 , DOI: 10.1039/c8cc02472c
Zheng-Jian Wu _{1,

2,

3} , Shi-Rui Li _{1,

2,

3} , Hao Long _{1,

2,

3} , Hai-Chao Xu _{1,

2,

3}

Affiliation

The intramolecular C(sp³)–H/C(sp²)–H cross-coupling of 1,3-dicarbonyl compounds has been achieved through Cp₂Fe-catalyzed electrochemical oxidation. The key to the success of these dehydrogenative cyclization reactions is the selective activation of the acidic α-C–H bond of the 1,3-dicarbonyl moiety to generate a carbon-centered radical.

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