Development of a new Lindqvist-like Fe6 cluster secondary building unit for MOFs†,Chemical Communications

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Development of a new Lindqvist-like Fe6 cluster secondary building unit for MOFs†
Chemical Communications ( IF 4.3 ) Pub Date : 2019-08-09 00:00:00 , DOI: 10.1039/c9cc04999a
Li-Dan Lin _{1,

2,

3,

4,

5} , Zhong Li _{1,

2,

3,

4,

5} , Dan Zhao _{5,

6,

7} , Jin-Hua Liu _{1,

2,

3,

4,

5} , Xin-Xiong Li _{1,

2,

3,

4,

5} , Shou-Tian Zheng _{1,

2,

3,

4,

5}

Affiliation

This work demonstrates a new Lindqvist-like [Fe^III₆(μ₆-O)L₄Cl₆]²⁻ (Fe₆, L = 2-(hydroxymethyl)-2-(pyridin-4-yl)-1,3-propanediol) cluster for the construction of a novel class of Fe-cluster organic frameworks. The novel Fe₆ cluster can be used to build not only a homometallic MOF, but also a heterometallic MOF by introducing copper halide clusters to the reaction system. In particular, the heterometallic MOF achieved a skillful combination of Fe₆ SBU and cuprous–halide clusters for the first time. Our synthesis strategy opens up an effective avenue to novel Fe-cluster-based MOF materials.

中文翻译：

为财政部开发了一种类似于Lindqvist的类似Fe ₆簇的二级建筑单元†

这项工作表明一个新林克韦斯特状的[Fe ^III₆（μ ₆ -O）L- ₄氯₆ ] ^{2- （}铁₆，L = 2-（羟甲基）-2-（吡啶-4-基）-1,3- -丙二醇）簇用于构建一类新型的Fe-簇有机骨架。通过将卤化铜簇引入反应体系中，新型的Fe ₆簇不仅可用于构建均金属MOF，而且还可用于构建异金属MOF。特别是，杂金属MOF首次实现了Fe ₆ SBU和卤化亚铜簇的巧妙结合。我们的合成策略为新型的基于铁簇的MOF材料开辟了一条有效途径。

更新日期：2019-08-09

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