Electrochimica Acta ( IF 5.5 ) Pub Date : 2019-06-02 , DOI: 10.1016/j.electacta.2019.05.151 Priyakant Pushkar , Arvind Kumar Mungray
Self-sustainability of Benthic microbial fuel cell makes it a future possibility to solve the problem of the power source for low power devices. New 3D electrode; Resorcinol-Urea-Formaldehyde Carbon xerogel was synthesized on steel wool by using the one-pot method and tested in lab scale BMFC. Xerogel was prepared by heating polymerized aerogel at 900 °C in presence of Nitrogen. Magnetite was also added in aerogel to produce magnetite doped xerogel electrode. These composites were characterized by Scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), Chronocoulomerty (CC), Cyclic voltammetry (CV), and Electrochemical impedance spectrometry (EIS). Resorcinol xerogel provides good biocompatibility, hydrophilicity, porosity, and efficient surface for the electrode. 3D composite electrode enhanced the performance of BMFC. 3D Magnetite doped xerogel shows utmost performance with maximum power density of 895 mW m−3 in comparison of 14 mW m−3 produced by carbon felt. 3D Resorcinol xerogel proves its significance by enhancing power generation in the lab-scale BMFC reactor.
中文翻译:
三维间苯二酚-尿素-甲醛碳干凝胶电极的合成及其在底栖微生物燃料电池中的应用
底栖微生物燃料电池的自我可持续性使其成为解决低功率设备电源问题的未来可能性。新的3D电极;用一锅法在钢丝绒上合成间苯二酚-尿素-甲醛碳干凝胶,并在实验室规模的BMFC中进行了测试。通过在氮气存在下于900°C加热聚合气凝胶来制备干凝胶。磁铁矿也被添加到气凝胶中以产生掺杂磁铁矿的干凝胶电极。这些复合材料的特征在于扫描电子显微镜(SEM),傅立叶变换红外光谱(FTIR),X射线衍射(XRD),色散(CC),循环伏安法(CV)和电化学阻抗谱(EIS)。间苯二酚干凝胶为电极提供了良好的生物相容性,亲水性,孔隙率和有效的表面。3D复合电极增强了BMFC的性能。掺杂3D磁铁矿的干凝胶显示出最高的性能,最大功率密度为895 mW m-3与碳毡产生的14 mW m -3相比。3D间苯二酚干凝胶通过增强实验室规模BMFC反应器的发电量证明了其重要意义。