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Preparation of Hierarchical Spinel NiCo2O4 Nanowires for High-Performance Supercapacitors
Industrial & Engineering Chemistry Research ( IF 3.8 ) Pub Date : 2018-02-07 00:00:00 , DOI: 10.1021/acs.iecr.7b04412
Chen Hao 1 , Saisai Zhou 1 , Junjie Wang 1 , Xiaohong Wang 1 , Haiwen Gao 1 , Cunwang Ge 2
Affiliation  

Hierarchical spinel NiCo2O4 nanowires were synthesized by a facile hydrothermal method followed by an annealing treatment. The prepared NiCo2O4 nanowires presented a hierarchical mesoporous structure. Moreover, the effects of precipitant and solvent on morphologies of NiCo2O4 were researched. The results reveal that the hierarchical mesoporous structured NiCo2O4 exhibited corking supercapacitor performance with a high specific capacitance of 2876 F·g–1 at a current density of 1 A g–1, even increased to 10.0 A g–1, the specific capacitance could still remain 1290 F g–1, what’s more, the capacitance retention reached 84.7% after 500 cycles, which indicates an excellent electrochemical performance. The results demonstrate hierarchical mesoporous NiCo2O4 potential to be a promising supercapacitor electrode materials and inspire furthered research on binary metal oxides as charge storage materials and offer a new route for the large-scale production of high-performance supercapacitor electrode materials.

中文翻译:

用于高性能超级电容器的尖晶石型NiCo 2 O 4纳米线的制备

通过简便的水热方法,然后进行退火处理,合成了尖晶石型NiCo 2 O 4纳米线。制备的NiCo 2 O 4纳米线呈现出分层的中孔结构。此外,研究了沉淀剂和溶剂对NiCo 2 O 4形貌的影响。结果表明,在1 A g –1的电流密度下,分层的介孔结构NiCo 2 O 4表现出具有超级电容的性能,具有2876 F·g –1的比塞超级电容器性能,甚至增加到10.0 A g –1。,比电容仍可保持1290 F g –1,而且,经过500次循环后,电容保持率达到84.7%,这表明它具有出色的电化学性能。结果表明,分层的介孔NiCo 2 O 4潜力是一种有前途的超级电容器电极材料,并激发了对以二元金属氧化物作为电荷存储材料的进一步研究,并为大规模生产高性能超级电容器电极材料提供了一条新途径。
更新日期:2018-02-08
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