Precise Isomerization Polymerization of Alkenylcyclohexanes: Stereoregular Polymers Containing Six-Membered Rings along the Polymer Chain,Journal of the American Chemical Society

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Precise Isomerization Polymerization of Alkenylcyclohexanes: Stereoregular Polymers Containing Six-Membered Rings along the Polymer Chain
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2011-07-27 , DOI: 10.1021/ja2043968
Daisuke Takeuchi ₁

Affiliation

Pd and Ni diimine complexes catalyze the isomerization polymerization of alkenylcyclohexanes to afford polymers composed of alternating trans-cyclohexane-1,4-diyl rings and oligomethylene spacers with high selectivity. The melting points of the polymers vary from 130 to 226 °C depending on length of the oligomethylene spacer.

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