Formation and Structural Diversity of Organo-Functionalized Tin–Silver Selenide Clusters,Chemistry - A European Journal

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Formation and Structural Diversity of Organo-Functionalized Tin–Silver Selenide Clusters
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2017-10-16 04:05:55 , DOI: 10.1002/chem.201703614
Niklas Rinn _{1,

2} , Lukas Guggolz _{1,

2} , Katharina Gries _{2,

3} , Kerstin Volz _{2,

3} , Jürgen Senker ₄ , Stefanie Dehnen _{1,

2}

Affiliation

Two organotin silver selenide clusters with isomeric ternary cluster cores are obtained depending on whether the organic groups are keto-functionalized or further transferred into hydrazine units. This work reports on the formation of these two clusters and a third, mixed valence species from the same intermediate under different reaction conditions. The intermediate and the products were studied by a variety of experimental and quantum chemical methods.

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