We report sulfonated hypercrosslinked polymers (SHCPs) as heterogeneous catalysts for the selective esterification of hexanoic acid with benzyl alcohol. The SHCPs demonstrate tuneable catalytic activity and selectivity, outperforming conventional acid catalysts. We also explore detrimental structural changes over multiple cycles, providing insights for optimising long-term catalyst performance.

中文翻译：

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用于选择性酯化反应的可调磺化超交联聚合物：深入了解性能和稳定性


我们报道了磺化超交联聚合物 （SHCP） 作为己酸与苯甲醇选择性酯化反应的非均相催化剂。SHCP 表现出可调节的催化活性和选择性，优于传统的酸催化剂。我们还探讨了多个周期中的有害结构变化，为优化长期催化剂性能提供见解。