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Is It Possible to Make Magnesia-Based Cement Environmentally Friendly?
ACS Sustainable Chemistry & Engineering ( IF 7.1 ) Pub Date : 2024-11-06 , DOI: 10.1021/acssuschemeng.4c05985
Yongshan Tan, Shichang Liu, Mithila Achintha, Renjie Mi

Magnesia-based cement is recognized for its outstanding mechanical properties, but its environmental impact has not been thoroughly evaluated. This paper employs a comprehensive life cycle assessment methodology to systematically analyze the environmental effects of four kinds of MgO and 10 kinds of magnesia-based cements based on the data in the literature. The impacts include CO2 emissions, fossil fuel depletion potential, and overall environmental impact indicators. The results indicate that using Salt Lake magnesium residue to prepare MgO, e.g., LB-MgO and DB-MgO, can reduce over 60% of CO2 emissions, compared with traditional MgO (e.g., L-MgO and D-MgO) prepared with magnesite. Utilizing supplementary cementitious materials (e.g., fly ash and ground granulated blast-furnace slag) as substitutes for clinker in basic sulfate magnesium cement (BMSC) and magnesium phosphate potassium cement (MKPC) can also reduce approximately 16 and 45% of carbon emissions, respectively. In addition, carbonation-reactive magnesium cement (CRMC), which involves carbonation curing and replacing traditional MgO with Salt Lake magnesium residue, is the most environmentally friendly magnesia-based cement with an overall environmental impact indicator of 0.00078.

中文翻译:


镁基水泥可以做到环保吗?



镁基水泥以其出色的机械性能而著称,但其对环境的影响尚未得到彻底评估。本文采用全面的生命周期评价方法,根据文献中的数据,系统分析了 4 种 MgO 和 10 种镁基水泥的环境影响。影响包括 CO2 排放、化石燃料消耗潜力和整体环境影响指标。结果表明,与用菱镁矿制备的传统 MgO(例如 L-MgO 和 D-MgO)相比,使用盐湖镁渣制备 MgO(例如 LB-MgO 和 DB-MgO)可以减少 60% 以上的 CO2 排放。在碱性硫酸盐镁水泥 (BMSC) 和磷酸镁钾水泥 (MKPC) 中使用补充胶凝材料(例如粉煤灰和磨碎的粒化高炉炉渣)作为熟料的替代品,也可以分别减少约 16% 和 45% 的碳排放。此外,碳化反应镁水泥 (CRMC) 涉及碳化固化和用盐湖镁渣替代传统 MgO,是最环保的镁基水泥,整体环境影响指标为 0.00078。
更新日期:2024-11-06
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